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By A. L. Service

In 1965 the Western phosphate industry ranked third after Florida and Tennessee in total mine and marketable production of phosphate rock and phosphate rock products. It has become an important regional industry and, since the close of World War II, it has become important in the national phosphate economy. This report includes an evaluation of the trends and outlook for the Western phosphate industry through 1975 as part of the Bureau's program to determine the rate at which the Nation's mineral resources are being utilized. The first part of this report is concerned with the relationship between the Western phosphate industry and that of the United States and the world. It describes the principal phosphate deposits and discusses production, export, and import of phosphate rock and marketable products. The second part of the report is concerned with the Western phosphate industry and discusses trends and outlook through 1975. Projections for the utilization of phosphate rock, phosphate fertilizers, and elemental phosphorus have been developed and extended through 1975 in an effort to provide data and information pertaining to the rate of depletion of the Nation's phosphate resources.

Jan 1, 1967

By Ralph B. Stevens

The objective of this 20-month program was to define the relationships between mine ventilation, temperature, humidity, ore properties, material's used in mine operations, etc., and the spontaneous combustion problem in underground metal mines. Tradeoff studies of availability, reliability, cost, and maintenance of spontaneous combustion protection sensors and telemetry were conducted, after which a prototype system was selected from four design alternatives. This selected system was then laboratory tested and demonstrated in an underground copper mine.

Jan 1, 1979

By Jr. Flynn

This U.S. Bureau of Mines publication is a compilation of fundamental cyanide chemistry data obtained through review of the scientific literature. It includes information on thermodynamics and chemical equilibria, ultraviolet-visible and infrared spectra, and the chemistry and photochemistry of cyanide, chemical species derived from cyanide, and metal cyanide species. It also includes guidance on the use of the data for solving practical problems in precious metals applications. This publication is intended mainly for use as a reference by personnel in the precious metals industry and regulatory agencies, and other cyanide users, to provide comprehensive information on cyanide chemistry. The document should assist in the formulation of effective policies for cyanide control in the construction, operation, and closure phases of precious metals mining and metallurgical operations. In addition, the data in this publication will be useful in other contexts, such as dealing with industrial cyanide usage, cyanide-containing wastes and associated environmental problems.

Jan 1, 1995

By E. A. Ziemba

The modified in-situ process is one of the methods being considered for extracting oil from oil shale. One of the questions to be answered for this approach is the environmental consequence of underground retort abandonment. This report outlines a study which addresses the question in terms of a grouting solution. It covers the development of a spent shale ash based grout which will fulfill the environmental requirements in terms of strength, stability, and impermeability. In addition, it will allow the reinjection of up to 50 percent of material mined and surface retorted as part of this process.

Jan 1, 1982

By Pamplinm J. W.

"INTRODUCTION For the past six years the United States Bureau of Mines in cooperation with the University of Alabama, Tuscaloosa, Ala., the Missouri School of Mines and Metallurgy, Rolla, Mo., and certain operating companies of the Florida land-pebble phosphate district have conducted an investigation to determine the amenability of phosphatic sands to concentration. 4 This paper discusses briefly an investigation of the concentration of fine phosphatic sanads of the land-pebble district of Florida. The process used - namely, the tabling of material previously given a selective oiling treatment - is new in its application to the phosphate industry, although old in principle.The feed to the standard phospidate washery is a hydraulically wined mixture of phosphate pebbles, quartz sand, and clay in which the quartz sand grains are segregated in the fine sizes. Me standard method of concentrating (washing) consists of wet-screening. at about 20 mesh to recover the plus 20-mesh material. 5 Lately some of the washeries have introduced hydraulic classifiers for sizing of the screen undersize to recover the coarser spigot products, but even this additional treatment allows much of the fine phosphate to be wasted."

Dec 1, 1932

By Donlad B. Lindsay

This report describes a field-test program to determine the effectiveness of a polymeric wall sealant to reduce the excape of naturally occurring radio-active gas radon from the walls of an underground uranium mine into the ventilation air. A 75-foot-long, dead-end drift with a surface area of about 6,000 ft2 was used as the test site in which the average natural radon flux from the normally dry rock was 16 fCi/cm2-s. The effect on radon emanation of wetting the walls with water to a depth of 3 inches was tested, after which the rock was completely covered with a coating of dry-mix concrete to provide a base for the sealant, an acrylic latex. Sealant was applied in two coats to about 0.25 mm thick. An overall reduction of average radon flux of about 75 pct was achieved. Radon production and other environmental values were measured continuously and automatically by a Bureau of Mines data acquisition system. A commercial microcomputer was programed to convert raw data to engineering units and to perform other useful operations while recording all data on magnetic diskettes. Direct measurements of radon flux from the rock surface were made by a charcoal adsorption technique.

Jan 1, 1981

By O. P. Hood, G. St. J. Perott, S. P. Kinney

"FOREWORD (By O. P. Hood, Chief mechanical engineer).During the war certain suggestions concerning power production were made by Mr. Walter E. Trent to the War Inventions Board, and at the request of the War Department facilities for experimental work were provided on the grounds of the. Bureau of Standards.The experiments were along the line of controlling the conditions of combustion in a closed space. In order to reduce slag troubles, experiments were carried out for removing ash from powdered coal. After the war, work along this line was continued, resulting in the Trent Process, which agitates or beats together powdered coal, water and oil.A new technology had previously been given to ore preparation by the use of small quantities of oil in water with froth flotation, and although the methods, results and mixtures of the Trent Process were quite different, yet the same physical phenomena of differential wetting used, and the possibility of there being interesting results in fuel technologic was evident. A cooperative agreement was entered into, whereby the Bureau of Mines was to investigate the underlying physical and chemical facts and make them public, and the Trent Corporation was to pay the cost of the investigation.The several reports as made have been available to any one interested, and are now to be published. While the Bureau of Mines felt justified in investigating the physical phenomena so far as might be done in a laboratory, and so far as public interest might reach, no attempt was made to discover the commercial possibilities which development might bring. The question of commercial possibilities must be left for commercial enterprise to answer."

Jul 1, 1921

By M. M. Tilman

Etchants containing hexavalent chromium and sulfuric acid are used in a variety of surface-finishing operations. When the resultant spent solutions are discarded, substantial quantities of chromium are lost and pollution prob¬lems are created. To minimize the undesirable environmental effects while improving metal and minerals recycling technology, the Bureau of Mines is con¬ducting research on a method for the economic inplant recycling of these waste etchants. Trivalent chromium, produced when the etchant reacts with a substrate, is oxidized in the anode chamber of a diaphragm cell; other metals, dissolved during the etching operation, are transferred to the catholyte. When waste brass etchants are treated in this manner, all of the trivalent chromium is oxidized and more than 40 percent of the copper and zinc is removed. Similar copper removal and chromium oxidation are achieved with waste printed circuit board etchants and rinse waters from plastic etching operations. The electrical energy needed to regenerate 1 kg sodium dichromate is less than 9 kwhr. Regenerated brass etchants evaluated by two companies equaled or exceeded the performance of fresh etchants.

Jan 1, 1979

By T. W. Quayle

This paper describing mining practices at the United Verde copper mine, Jerome, Ariz., is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts f the United States. At present mining operations are being conducted both underground and by electric shovels in an open pit. The open-pit work has been described by E. M. J. Alenius in a previous publication of the Bureau of Minos;3 the present paper will be confined to a description of the underground mine. The underground methods comprise horizontal cut-and-fill, shrinkage with delayed filling, horizontal square-set, inclined square-set, and top slice. The normal daily production of the underground mine is 3,000 tons of copper ore per day, requiring the employment of 900 men underground.

Jan 1, 1931

By C. W. Davie

"This paper is the second of a series of progress reports4 on a study of the hydrometallurgy of manganese which is being conducted in an endeavor to make possible utilization of the large deposits of low-grade domestic manganese ores that occur in several States.There are at least four processes in which a knowledge of the action of SO2 gas on manganese oxides at elevated temperatures may prove of value.One of these involves dissolution of manganese from ores. The Bureau of Mines has investigated the hydrometallurgy of manganese by a process in which SO2 gas, a waste product at many smelters, is passed into water to form a solvent for manganese. Although several manganese minerals were readily dissolved, rhodochrosite (MnCO3) was attacked but superficially.5 Recent experiments have shown that a roast at 650 to 9000 C. converts the manganese of rhodochrosite to a form that is quickly dissolved by a weak SO2 solution.6 Introduction of smelter gases containing much as 5 per cent SO2 during such a roast would not add much to the cost of the operation, and might result in the formation of considerable water-soluble manganese sulpate.Another case involves a subsequent step in the hydrometallurgical process, namely, the formation of oxides of manganese with simultaneous evolution of SO2 by the heating of the MnSO4 produced by evaporating its solution.A third has to do with the roasting of zinc sulphide ores containing manganese as a preliminary to leaching. During purification of the solutions to be used for the electrolytic deposition of zinc the iron must be oxidized to make possible its removal. Manganese dioxide has been used for this purpose,7 and since manganese compounds are present in some zinc concentrates,8 it is of interest to learn what happens to the manganese in a zinc sulphide or on roasting, and what portion of the manganese in the roasted product might be available for oxidation."

Oct 1, 1930

By D. H. Yardley

A major purpose of this contract was to evaluate a variety of dust suppressants to determine their effectiveness in mitigating dust from taconite tailings. During the course of the investigation tailings from pilot-plant tests of Minnesota copper-nickel ores became available and chemical binders were also tested for dust mitigation effectiveness on this mineralogically different material. Field-test plots were established on taconite tailings and wind tunnel laboratory tests conducted. The laboratory tests consisted of comparing treated and untreated samples at wind velocities of 40 mph using a weight-loss method and direct dust emission measurements. It was shown that the emission of fine dust from taconite tailings, in the range of 4.5 microns to 0.85 microns, could be reduced by 99 percent using certain chemical suppressants. It was also demonstrated that a straight water spray on coarse tailings (3/4" to + 10 mesh) reduced dust emission by 95 percent. Although eight different chemicals were tested, most of the tests were made using Coherex, ammonium lignin sulfonate and sodium silicate. These same dust suppressants were used, singly and in combination on almost 75 field-test plots. The Coherex appears to provide the best results in terms of economics and durability. Wind tunnel tests on treated and untreated Cu-Ni tailings demonstrated that applications of dust suppressants reduced fugitive fine dust by better than 99 percent.

Jan 1, 1980

By G. E. McElroy

The purpose of tins paper is not to present new date on the pressure losses due to bends and chances of area in mine openings through which air flows, but rather to correlate existing data, determined mainly on small duct systems and expressed in a variety of ways, according to uniform methods that facilitate their use in pressure-loss computations. These are required in such, air-flow problems as determining the quantity that will flow through is mine openings under a certain pressure difference or, conversely, the pressure difference that will be required to maintain a certain rate of flow. Air flowing through h ducts, such as mine airways, encounters resistance to flow due to interference of the individual air streams with each other caused by the wall surfaces. The result is that part of the kinetic energy of the flowing stream is converted to heat; and constant renewal of the kinetic energy from the total energy of the flow is required to maintain it. This process manifests itself by a decrease of the total pressure (static pressure plus velocity pressure; of the air in the direction of flow; in order that flow pray occur, there must necessarily be a differences in total pressure between the two cads of the air-ay equivalent to the pressure losses occasioned by the flow, which automatically adjusts itself in magnitude to the pressure difference maintained.

Jan 1, 1932

By Tim F. Dyson

Feasibility of employing automated processing and detection techniques in the mine disaster communications problem is demonstrated. Efficient processing methods are developed. These methods have been demonstrated both in a laboratory and in a field environment. Evalua¬tion of existing computer capacity is given along with recommendations for expansion.

Jan 1, 1981

By Parry. V. F., John B. Goodman

"INTRODUCTION The Denver region coal field, covering an area of approximately 7,640 square miles, extends from the Wyoming State line to the middle of El Paso County, Colo. The coal in this region is subbituminous in rank. Much of it is used as domestic fuel. During the last decade the production of coal in this field has remained fairly constant at an average of 2,600,000 tons per year. This production has come from 50 to 60 mines, 88 to 90 percent of the production being from the section of the field north of Denver.According to the Standard Specifications for Classification of Coal by Bank of the American Society for Testing Materials 4/ the coals in this region are classified in the Subbituminous B and C group. On the as—mined basis, they contain about 22 percent moisture and average 9,600 B.t.u. per pound. They are noncoking and slack to a variable extent when exposed to the weather. This is characteristic of subbituminous coals."

Aug 1, 1939

By Everard Leland

This paper, describing the mining practices at the Pilares mine, Pilares de Nacozari, Sonora, Mexico, is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts. At present (1930) practically all the mineral production from the Nacozari district is from the Pilares mine of the Moctezuma Copper Co., a subsidiary of the Phelps Dodge Corporation. The ore is mined for its copper but contains associated silver in small quantities.

Jan 1, 1930

By T. F. Anstett

The Bureau of Mines estimated the potential availability of rare-earth oxides (EtEO), including yttrium, and thorium, which is also contained in the rare-earth bearing minerals monazite and bastnasite, from 38 'properties in market economy countries (MEC's). Only nine of the properties evaluated produce or would produce REO as the primary product; the others contain REO as a byproduct, chiefly from mineral sands operations recovering rutile, ilmenite, and zircon. Nearly 77% (2,578,000 mt) of the total 3,355,000 mt of recoverable RE0 evaluated is from producing properties. It is estimated that 21% (705,000 mt) of this total is from properties that could not realize a positive rate of return at the January 1984 market prices for the recovered commodities. At production capacities assumed for this evaluation, the amount of RE0 potentially available from producers ranges from an estimated 46,500 mt in 1986, to a peak of 50,900 mt in 1992, to 49,900 mt by the year 2000. Total MEG production in 1984 was estimated at 40,700 mt. Assuming demand does not increase sharply, producing properties can continue to fulfill overall REO demand through at least the end of this century.

Jan 1, 1986

By Thomas A. Phillips

The Bureau of Mines presents an economic evaluation of its leach- electrolysis process for recovering lead from galena concentrate. In this process, galena concentrate is leached at 200° F with a ferric chloride-brine solution to extract lead while leaving sulfur in the residue, which is discarded. The solution after leaching is concentrated and cooled to 100° F by vacuum evaporation to crystallize lead chloride from which metallic lead and chlorine are produced by fused-salt electrolysis. Chlorine is used to regenerate the spent leach solution before it is recycled. A cost estimate was prepared for a plant capable of producing 300 tons per day of lead, 330 days per year. The fixed capital cost on a third-quarter 1977 basis Fs $27,500,000, and the estimated operating cost without a charge for the concentrate is 4.9 cents per pound of lead product. Assuming a selling price for corroding-grade lead of 31 cents per pound and a charge for the concentrate of $332 per ton, the interest rate of return on investment after taxes is 16 percent. The leach-electrolysis process, therefore, appears to be economically attractive under the assumed market conditions.

Jan 1, 1978

By Thomas E. Marshall, Michael Dunn, L. J. Prosser, Anthony T. Iannacchione

During the past few years, the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) examined and characterized conditions at a majority of the underground stone mines in the United States. Observations at these mines revealed a limited degree of roof monitoring beyond visual inspection and sounding. When monitors are used, they typically require the miner to measure movement at the roof. If conditions are unstable, the mine rmay be in a hazardous situation while recording data. Based on this scenario, researchers surmised that a simple, inexpensive monitor with the capability of recording data at a distance from the mine roof would be a safer way to gain the information. Additionally, more widespread use of monitors could potentially lead to better understanding of roof movement in general. A monitor to meet this need was designed, tested, and subsequently improved as experience was gained in its’ use at a number of underground stone mines. The Roof Monitoring Safety System (RMSS) can provide an initial indication of movement in roof beams. By understanding and measuring roof movement in underground mines, the potential for injuries and fatalities to mine workers from falls of ground can be reduced. Also, officials at a mine with a history of data are better prepared to make a decision on remedial actions in the event of ground falls. This paper will outline the evolution of the RMSS and how it can be used in a comprehensive proactive ground control safety program. Also included is a case history describing how the RMSS was used in an evaluation of the effectiveness of a mechanical impact scaling machine at an operating limestone mine.

By W. E. Robinson

Oil-shale kerogen was processed into oil and oil products before the first oil well was completed by Drake in 1859. However, because of economic and other advantages, natural petroleum has been the principal source of liquid fuels and lubricants since 1859 and is a convenient root of many [organic] chemicals in common use today. In recent years the difference has narrowed between the cost of producing liquid fuels from well petroleum and other sources. This narrowing of cost difference has resulted both from the increased cost of finding new sources of petroleum in the United States and the experimental demonstration of lowered costs for synthetic liquid fuels by the Federal Bureau of Mines and by industry. Available petroleum resources of this country are being reduced and eventually may be inadequate to meet the demand. Alternate means of assuring an adequate supply of liquid fuels for this country include the development of processes for utilizing other carbonaceous materials such as oil shale and coal.

Jan 1, 1960

By D. Harrington

Part III-B, presented in this circular, completes the series reviewing the literature on effects of breathing dusts with special reference to silicosis; it includes data on the status and cost of compensation for silicosis in the United States and several foreign countries and a summary and general conclusions covering the whole series. Parts I, II, and III-A of the series have been issued as Information Circulars 6935, 6840, 6948 , and 6957; Part I defines and classifies dusts, indicates sources of exposure, and describes the physiological effects of breathing dusts; Part II-A discusses the principal dust factors producing pulmonary pathology and methods of determination of dust in air; Part II-B presents data on the engineering and medical control in the prevention of dust diseases and general recommendations for their control in industry; and Part III-A deals with the economic and legal aspects of dust diseases in industry.

Jan 1, 1936