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By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By Lawrence W. Scott

This report presents several systems for continuously monitoring the quality of air in underground mines that are being developed by the Bureau of Mines. Underground stations measure methane, carbon monoxide and nitrogen dioxide concentrations, air velocity, and air temperature. This information is transmitted over a single telephone pair to central stations located on the surface. The central stations display alarms and the data is selectably displayed on digital panel meters.

Jan 1, 1977

By William J. Campbell

One of the principal objectives of the Bureau of Mines program for developing super refractory materials is to obtain fundamental data on the physical properties of refractory oxides. This particular investigation obtained accurate thermal expansion coefficients for alpha alumina and evaluated, critically, those coefficients with other published values. High-temperature X-ray diffractometer measurements, by the Bureau, showed that alpha alumina expands anisotropically with expansion parallel to the c axis approximately 10 percent greater than parallel to the a axis. Thermal expansion characteristics of four different alumina samples were determined up to 1,200° C.; the results are presented in both tabular and graphical form. The combined random and systematic errors in the measurements are considered less than 3 percent above 500° C, and approximately 2 percent at 1,000° C. No differences in expansion were observed between the samples or between the heating or cooling cycles.

Jan 1, 1961

By L. A. Schutz

Personnel of the Bureau of Mines have conducted investigations in the principal asbestos mines and mills in the United States, to determine the concentration of airborne asbestos fibers in the workplace, and to establish the exposure of workers to such fibers. 'The surveys were conducted using the sampling and evaluation method recommended by the National Institute for Occupational Safety and Health. The method consists of collecting the air-borne sample on filters and, after appropriate sample preparation, counting the fibers utilizing phase contrast microscopy. The results of the investigation show that fiber concentrations are low in the asbestos mines but high in the asbestos mills, ranging well above 5 fibers/ml of air based on a count of fibers greater than 5 urn in length.

Jan 1, 1973

By T. A. Henrie, J. D. Marchant, E. S. Shedd

Cerium metal was electrowon in a fluoride bath from cerous oxide and tapped from the cell during prolonged operation . Electrolyte constituents were CeF , BaF₂ , and LiF. Twenty- seven pounds of metal of 99.8 percent purity were produced at a rate of 3 pounds per hour and tapped from the cell . Principal impurities were molybdenum , aluminum , oxygen , and carbon . The operating parameters , such as electrode geometry , bath compositions , and oxide feed rate , were investigated . Anode reactions were found to be important factors in cell operation . Stable cerous oxide reacted more uniformly at the anode surface than ceric oxide . Electrowinning was conducted in crucible hearths consisting of both frozen electrolyte and molybdenum metal . Both materials proved satisfactory and did not react with the molten cerium . Stable cerous oxide was prepared by carbothermic reduction and used as a feed material . Cell design proved to be an important factor in continuous cell operation . Complementary to the investigations of electrowinning of cerium , the metal was purified by electrorefining in a chloride electrolyte .

Jan 1, 1964

By James R. McVey

A new method for measuring deformations of rock surfaces in underground excavations has been suggested by Dr. James Powell of Brookhaven National Laboratories (BNL) and subsequently developed and successfully demonstrated in a mining environment by the Federal Bureau of Mines, Spokane Mining Research Center (SMRC) and Brookhaven National Laboratories. The system uses 35-mm photography of targets strategically located on surfaces of interest, such as across the roof and on the sides of a mine drift or tunnel. The optimum tar-get, as determined in this investigation, consists of a white ?X? made with 1/8-inch-wide reflective tape on a black 6-inch square. Photographs, taken in pairs from two separated camera positions and at regular time intervals, were analyzed at the Bureau by hand and at Brookhaven National Laboratories using techniques and equipment similar to those used in cloud chamber film analysis. Test results show that deformation-measurement accuracies of better than ±0.020 inch in a drift that is 20 feet wide can be expected. This degree of accuracy, plus providing displacement data in the X, Y, and Z directions (rather than the one direction formerly possible), makes this a noteworthy and useful tool for industry as well as for mining research.

Jan 1, 1974

By N. H. Coates

The Bureau of Mines determined average film coefficients of heat transfer for helium flowing through smooth, water-cooled tubes at Reynolds numbers of 5,000 to 25,000, helium inlet temperatures of 1,600° to 2,600° F, average temperature difference across the helium film of 800° to 1,300° F, and heat flux to 215,000 Btu/(hr)(sq ft). Since helium was the only gas used, the ranges of values for physical properties of the fluid are limited--thermal conductivity from 0.15 to 0.20 Btu/(hr)(sq ft)(O F/ft), viscosity from 0.082 to 0.104 lb/(ft)(hr), and Prandtl number from 0.63 to 0.68. Four equations, three of them dimensionless, correlate these coefficients with other properties of the helium--bulk temperature, film temperature, dimensionless parameters based on temperature, and the ratio of wall temperature to bulk temperature.

Jan 1, 1966

By Wilbert J. Huff

The Explosives Division of the United States Bureau of Mines makes certain laboratory and field investigations that deal with explosions, explosives, ignition, and combustion, together with many related problems, such as the cause and prevention of fires, and certain fundamental scientific questions bearing upon the determination of the chemical and physical mechanisms underlying some of the important phenomena encountered. Its work on explosives has been particularly directed toward determination of the chemical and physical characteristics of explosives designed for use in coal mines and in a more limited way to those used in metal mines, tunnels, quarries, and other engineering operations. This testing is handled by two units of the Explosives Division, as follows:

Jan 1, 1937

The object of this program was to design and build a self-contained system for remote monitoring of the atmosphere in mines. The system developed uses the mine pager phone line as the primary communication channel and also has the capability of using 208 Hz in the ELF band for wireless transmission through the earth. The depth for through-the-earth transmission is expected to be about 80 to 90 meters in high conductivity soil and is limited by the noise level in the ELF band-pass filters. The underground components of the TEM System are energized by mine power through a battery charger - storage battery power supply. In the event of mine power failure the battery capacity is more than sufficient for one week's operation with interrogations every four hours.

Jan 1, 1980

By Sidney Katell

Continuing the series of cost bibliographies which was initiated with the publication of Information Circular 7516 in October 1949, the present report covers the period from January 1959 through December 1959. The abstracted articles, concerned with all facets of cost engineering in the field of petroleum and chemical plants and related facilities, were obtained from the following sources: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Report of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Chemical Week. 6. Coal Age. 7. Coal Utilization. 8. Cost Engineering. 9. Industrial and Engineering Chemistry. 10. Nucleonics. 11. Oil and Gas Journal. 12. Petroleum Engineering. 13. Petroleum Refiner. 14. World Oil. On Oct. 16, 1959 a cooperative agreement between the Bureau of Mines and the American Association of Cost Engineers became effective. This agreement provides for the publication of the annual bibliography under the sponsorship of both groups with the work load involved in the preparation divided equally between the two. As a result, the present report partially reflects the efforts of the members of the Association.

Jan 1, 1960

By J. A. Eisele

The Bureau of Mines is investigating the recovery of alumina from domestic nonbauxitic resources, including anorthosite. The United States has large reserves of anorthosite, but its aluminum content is less than 50 pct soluble in acid, unless a source of fluoride is added to the acid. A flowsheet that includes leaching with HCl and fluoride followed by crystallization of AlC13.6H20 from the pregnant liquor by HCl gas injection was designed. Approximately 90 pct of the aluminum values were recovered from the anorthosite when a ratio of 0.14 mole of fluorine per mole of aluminum was used. Sodium chloride is cocrystallized with the A1C13.6H20 but is removed by water washing of the Al203 product. A material balance is given based on results of laboratory studies of the unit operations.

Jan 1, 1983

By Albert L. Toenges, Louis A. Turnbull, Henry E. Dekay, James N. Scudder

A preliminary survey of coke and steel plants conducted by the Bureau of Mines in cooperation with the Office of Solid Fuels Coordinator and under the auspices of the Coke Production Committee indicated that a very appreciable increase in pig-iron production would be obtained if pres- ent blast furnaces were supplied with a more uniform coke. Control of the sulfur and ash content of coal used for making coke is an important factor in producing uniform coke and thus increasing blast- furnace efficiency. In some mines producing metallurgical coal, the analysis of the coal bed shows a wide range of sulfur and ash content. To obtain production of coal with minimum deviation in sulfur content sampling, grading, selective mining, blending, and surface preparation are practiced at some mines with satisfactory results. The mines selected for this study have developed these methods and are successfully producing coal of uniform sulfur and ash content. The systems employed at different mines vary according to the physical character- istics of the coal bed, the manner of occurrence of impuritites in the coal, the development plan and mining system, surface preparation and the acceptable impurity content of the prepared coal. The ash content of the coal can be controlled by face preparation and in the cleaning plant. The introduction of some method or practice at other mines might make possible the use of coal for inetallurgical purposes that otherwise could not be used for making coke because of the wide variation of sulfur and ash content.

Dec 1, 1943

By Seth T. Reese

THE INJURY DATA and experience at coal mines in the United States for 1951 are presented in this bulletin under the following general heads: (A) General injury experience: Tables 1 to 18: Contain current data on number of fatalities and nonfatal injuries, frequency and severity rates, average severity, major and detailed injury agencies, and distribution of injuries by part of body and days of disability. (B) Selected injury data: Tables 19 to 43: Contain current data on various selected factors of operating and physical conditions that contributed to the occurrence of injuries at bituminous-coal, lignite, and anthracite mines. These factors include extent of hand and machine loading, size of mine by employment and production groups, thickness of bed or vein, duration and number of work shifts, rating of mine as gassy or nongassy, types of cap lamps, explosives, and combination of factors that influence mine safety. (C) Injury experience by States: Tables 44 to 50: Contain current data on number of fatalities and nonfatal injuries, frequency and severity rates, average severity, major causes and principal agencies, injury records of all coal-producing States, and the relative standing by States according to injury-frequency rates. (D) Major disasters: Table 51: Lists the coal-mine disasters that occurred during 1951, giving location, source, and cause. A major disaster in coal mining is defined as a single accident in which or as a result of which five or more men lost their lives. (E) Historical coal-mine injury experience: Tables 52 to 86: Contain data on injuries, injury-frequency rates, employment, and production at bituminous-coal, lignite, and anthracite mines from the earliest records through 1951.

Jan 1, 1955

By Russell E. Griffin

Dielectric constants and dissipation factors were measured for six rocks over the 20-to 100-megahertz frequency range by means of the susceptance-variation method. Results for both dry and moist specimens are presented and compared with data reported by others. Loss factors calculated from the data presented are important to the Bureau's study of rock fragmentation by means of dielectric heating.

Jan 1, 1967

By E. P. Youngman

The mining law now in force in Finland is the Imperial Russian Ukase of 1883, promulgated November 12, 1883, by Czar Alexander III, with the sanc- tion and permission of the Finnish Estates. This law repealed prior legisla- tion, as follows: Crdinance of liay 25, 1857, concerning the appropriation of ores and minerals; as wall as the right to remove and utilize them; proclama- tion of January 20, 1868, amending, the ordinance of May 25, 1857; proclama- tion of October 3, 1621, concerning the appropriation of precious metals; and the proclamation of October 30, 1878, concerning prospecting for gold, etc., in Finnish Lapland. A proposal for a new mining lar is still being considered by the Finnish Diet. This new law, if and when promulgated, will differ only slightly from the law of 1683 but will be drafted in more modern language."

Jun 1, 1932

By D. Bienstock

A rig was constructed to burn 100 to 125 lb of coal per hour at 4,000° F in a cyclone burner with oxygen-enriched air preheated to 1,500° F to ascertain the problems in the coal-fired MHD generation of power. Potassium carbonate was added to the coal at several concentrations up to 1.23 g-moles/kg of coal (17 lb K2C03/100 lb coal). Boiler-tube materials maintained at wall temperatures of 800° to 1,500° F were exposed to the combustion effluent of 1,800° to 2,500° F. Practically complete removal of sulfur dioxide from the stack gas was achieved with the seed addition. Nitric oxide formation followed theoretical expectations at combustion temperatures with some decomposition of the NO occurring as the gas cooled flowing through the system. Nitrates in the fly ash were less than 1.7 percent of the total fixed nitrogen. With aqueous extraction of the fly ash a maximum recovery of 75 percent of the potassium was obtained. Haynes 25 was unattacked at a wall temperature of 1,500° F in combustion gas at 2,500° F; the stainless steels 310, 316, and 446 were resist-ant at a metal temperature of 1,100° F in gas at 2,100° F.

Jan 1, 1970

By R. P. Vinson

The Bureau of Mines evaluated two real-time light-scattering dust monitors by measuring their response to Pittsburgh Seam coal dust and Arizona road dust (ARD). Both monitors, the model PDS-l, a personal dust sensor, and the model PCD-l, a digital dust indicator, are made in Japan by Sibata Scientific Ltd. Tests were conducted inside a laboratory aerosol chamber designed to maintain a uniform spatial distribution of the test dust. PDS-l and PCD-l measurements of concentrations for each test dust were averaged over 4-h test periods and compared with simultaneous gravimetric measurements. Both dust monitors responded linearly with mass concentration with both coal dust and ARD. However, the linear response of the PDS-l differed from that of the PCD-l for both dusts.

Jan 1, 1987

By Roy C. Bartholomae

An accurate characterization of the vibration environment and a vibration qualification test derived from it will be a very useful tool for manufacturers of instrumentation for use on underground coal mining equipment. Recognizing this, the Bureau of Mines sponsored a study wherein vibration levels were measured on mining equipment to form a basis for developing the required vibration test. The data base was composed of 160 samples taken at different positions on a variety of underground machinery. The data were analyzed and presented in a format typical of military vibration qualification tests. The form was shown to be virtually identical to the swept sine test envelope specified in MIL-STD-810B for tracked vehicles.

Jan 1, 1982

By K. K. Kelley

Despite the wide interest in titanium and its compounds, no heat and free-energy-of-formation values for titanates (that is, compounds formed from titania and other metal oxides) have been available heretofore except for ilmenite (FeTi03). Such data are needed for understanding and developing processes for producing titania and titanium tetrachloride from ores (and possibly slags) and in connection with ceramic usage of titania. This paper reports experimental measurements of the heats of formation at ordinary temperature of 11 titanates-ilmenite, perovskite, barium metatinate, strontium metatitanate, barium-strontium metatitanate, barium orthotitanate, strontium orthotitanate, barium-strontium othotitanate, geikielite, magnesium-titanium spinel, and magnesium dititanate. The experimental method was solution calorimetry. The solution calorimeter was operated at 73.7°C. and used a strong hydrofluoric-hydrochloric acid mixture as the calorimetric fluid and reaction medium.

Jan 1, 1954

By D. W. Frommer, L. Bonicatto, M. M. Fine

A mineral - dressing investigation was conducted to demonstrate the ability of an anionic silica - flotation process to produce high- grade concentrates from submarginal iron ores of the western Mesabi and Menominee ranges . Commercially available equipment and reagents were used . Samples from the Menominee range were exclusively from the Groveland , Mich . , mine and contained hematite as the chief iron - bearing mineral . Bench- scale investigations established that the anionic silica flotation method can function effectively on a variety of undeslimed ores . Continuous tests completed on one Mesabi semitaconite ore and on Groveland mill feed , have verified the validity of the bench research . The Mesabi samples yielded a concentrate containing 60.3 percent Fe and 6.0 percent Sio with an accompanying iron unit recovery at 90.5 percent . Iron recoveries from the mill feed ranged from 79.0 to 87.4 percent .

Jan 1, 1964