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By R. Batterham

"The history of mineral processing is indeed long and has always been tied to mining methods of the day. While many new processes and devices have been developed, the most significant trend in recent times has been the ever increasing scale of operations. There is serious doubt this ongoing trend is enough to match the global trend of falling grades and rising energy demands needed for mineral processing. As well we see that globally, the social licence to operate for mining (and hence mineral processing) is far from secure. Indeed, some argue that mining as we know it is dying and in the future, mining will be much more environmentally secure, even to the extent of insisting upon “in place” recovery and only bringing to the surface the valued product. In this paper we comment on the ramifications of broader uptake of more sustainable mining for mineral processing methods and address the specific question of whether recent progress in in place recovery will lead to a timely breakthrough. The answer proposed is that this is possible in the next 10 - 20 years but in the meantime, the focus is just as likely to be on removal of waste much earlier in circuits. Either way, mineral processing as we know it will change significantly. INTRODUCTION Mineral processing has a long history well covered in a recent publication (Habashi, 2006) who points out “the ancient Egyptians knew already that it would be easier to melt an earth rich in gold particles than another which is poor. As a result, all efforts were made to enrich the gold by washing away the light gangue minerals. Similarly, another ancient method for enriching gold particles from a river stream was by means of fleece, hence the Greek myth of the “golden fleece”. Since the middle ages, striving for improved economics has driven a string of innovative developments in milling and separation. The reader is again referred to the informative and illustrative text by Habashi."

Jan 1, 2018

By Z. H. Wang

The internal parameters of ball mill are very important in the grinding process and have significant impact on the grinding results. Accurate measurement of the internal parameters of ball mill is crucial and indispensable for optimization and control of grinding process. In this paper, a novel tri-sensor measurement method was used to measure the external signals (i.e., bearing pressure, sound intensity and power consumption) of ball mill. Mathematical models, which link the external signals of ball mill with its internal parameters, were established to predict the internal parameters of ball mill. Experimental results showed that the mathematical models could directly predict the internal parameters of ball mill once the external signals were obtained. The tri-sensor measurement method and the mathematical models proposed in this paper provided a new way and solid basis for optimization and control of ball milling.

Jan 1, 2014

By X. Q. Cao

As the second largest phosphate resource in the world, Chinese phosphate ores generally grades with low of P2O5. The presentation of beneficiation test on the low grade of phosphate rock in this paper may be used for a reference for development and utilization of the similar reserves. The ore is a marine sedimentary phosphate rock containing low grade of P2O5 and high content of MgO and R2O3; The banded structure shows its suitability for heavy medium separation. The laboratory heavy liquid testing results indicate that as specific gravity of the heavy liquid is 2.85 g/cm3, a rougher concentrate assaying 28.71% P2O5 could be obtained while the rougher tailings contain only 4.47% P2O5. When the combined process with heavy liquid separation followed by direct & re-verse flotation is employed to treat the feed containing 21.15% P2O5, 3.79% MgO, 1.86% Fe2O3, 3.66% Al2O3, 23.75% A.I, and specific gravity of heavy liquid is 2.84 g/cm3, the optimum mesh of grind is 67.5% minus 200 mesh, a phosphate concentrate contained 32.51% P2O5, 0.48% MgO, 0.81% Fe2O3, 1.69% Al2O3 can be produced at a yield of 55.24%. The concentrate P2O5 recovery is 85% with which quality comply with the Class A specifications for production of phosphate fertilizer.

Jan 1, 2014

By P. Vijay Kumar

Phosphate minerals are conventionally concentrated by flotation process using soap or soap- light diesel oil emulsion as collector. Some plants use detergents such as sodium petroleum sulfonate or alfa olefin sulfonate to enhance efficiency of soap flotation. It is reported that urea a known hydrotrope enhances flotation efficiency of soap as efficiently as alfa olefin sulfonate or linear alkyl benzene sulfonate at bench scale tests. In the present study tri sodium citrate also a known hydrotrope is tested as promoter in the flotation of phosphate mineral from Eshidiya ore.

Sep 1, 2012

By Jyotirmoy Sarma

The surface-active agent, like sodium humate, in the present systems produces a very stable suspension. Saline water up to 15% is used as a flocculating agent for recovery of water from the dispersed phase containing 1% solid. The recovered water in the presence of humate at different concentrations (0.05-0.2%) and at pH 8 also produces a stable dispersed phase of iron ore fines and tailings. The beneficiation techniques adopted in the present systems can increase ~ 2-3% iron value in the concentrate of iron ore fine, however, for tailings the increase in iron value is not observed. Keywords: beneficiation, flocculation, iron ore fines, tailings, saline water, surface-active agent

Sep 1, 2012

By C. Y. Sun

China is a country with abundant resources of tungsten, taking one of the world?s top-positions regarding both the total reserve and the amount of industrial production. China?s tungsten resources occur mostly in multi-metallic deposits rather than in single-metallic deposits. China?s multi-metallic tungsten ores have the characteristics of coexistence with other valuable components such as molybdenum, bismuth, copper, sulfur and fluorite. These ores are usually low in grade and difficult to process. The technological challenge in mineral processing lies in separation of multi-metallic components in these complex ores and a comprehensive utilization of natural resource. Several cases of industrial practice of processing China?s typical multi-metallic tungsten ores are presented.

Jan 1, 2014

By Guanghua Ai, Xiong Huang, Huashan Yan, Ting Li, Tingsheng Qiu

"Cyanide tailings of gold and silver concentrates contain considerable quantities of copper-lead-zinc sulfide minerals that can be recovered. However, the strong inhibition effect of cyanide often makes it difficult to recover these sulfide minerals effectively. In this research, a sample of cyanide tailings was investigated based on the principles of process mineralogy; activating flotation tests were carried out for the target minerals in the tailings, and the activation mechanism of the activator and its influence on the target minerals were investigated by Fourier transform infrared spectroscopy (FTIR). Mixed flotation of copper and zinc was carried out using QJ-01, a combined agent containing sulfite, as the activator of copper and zinc minerals, and ammonium dibutyl dithiophosphate (ADD) and butyl xanthate (BX) as the combined collector. Copper concentrate was obtained from the mixed concentrate by using a combined inhibitor of sodium sulfide and zinc sulfate to inhibit the zinc mineral. Zinc concentrate was extracted from the copper tailings by using copper sulfate as the activator and BX as the collector. The flotation test yielded copper concentrate with a grade of 22.56% and recovery of 76.96%, and zinc concentrate with a grade of 42.56% and recovery of 82.29%, which shows that comprehensive recovery of the sulfide minerals – copper and zinc –from the cyanide tailings was realized. The FTIR analysis showed that CN- was chemisorbed on the surface of chalcopyrite and sphalerite following cyanide treatment, while the combined activator QJ-01 containing sulfite reduced CN- into SCN- and weakened the complexing ability of CN- with metal ions on the mineral surface, thus achieving a good activation effect on chalcopyrite and sphalerite. The results of this study can provide practical guidance in increasing the resource utilization ratio of cyanide tailings in gold mines, and thus contribute to alleviating environmental problems caused by stockpiling cyanide tailings. INTRODUCTION Cyanidation, the most widely used technology for extraction of gold, has several advantages such as high recovery, process maturity, low cost, etc. According to available data, the annual discharge of cyanide tailings from China's gold mines exceeds 20 million tons (Li et al., 2011). Lower grades of exploitable gold ore entail increased discharge of cyanide tailings. Huge quantities of cyanide tailings are regarded as waste and stored, resulting in significant wastage of land resources. Moreover, residual beneficiation reagents, cyanide ions, and heavy metal ions in cyanide tailings cause severe pollution of water and land (Laitos et al., 2013; Donato et al., 2007; Mudder and Botz, 2004). In addition, cyanide tailings often contain valuable elements such as gold, silver, copper, lead, zinc, sulfur, and iron, which, if not recycled, would result in considerable wastage of resources. Hence, it is imperative to study the reduction and safety of cyanide tailings, and the mineral resources present in them."

Jan 1, 2018

By Cheng Xiang, Nan Ye, Xinyuan Ke, Yang. Jiakuan, Huabin Wang

Bayer red mud is a highly alkaline residue produced by the alumina industry through the Bayer process. Its disposal is a worldwide problem. The high alkali content and poor pozzolanic activity is aconstraint for its utilization on construction materials. In this study, the red mud was activated through an alkali-thermal method to improve its activity so that it can be utilized in geopolymerization. The red mud was mixed with different amounts of sodium hydroxide, and calcined under 800 °C to produce geopolymer precursors, and then mixed with water directly to prepare one-part geopolymer. X-ray diffraction was conducted to study the phase transformation of red mud and the mechanism of its geopolymerization. Nitrogen Isothermal Adsorption tests were conducted to analyze the pore structure of the geopolymer binders. The results show that calcinations with alkali would promote the Al in red mud transforming into glassy SiO2 to form the N-A-S phase which is soluble in water. When the red mud was calcined at 800 °C with a Na2O addition more than 10%, the dissolving of Si and Al from red mud was greatly improved. The thermal-alkali activated red mud with 10% Na2O obtaining a compressive strength of 9.77 MPa after it reacted with water and cured for 7 days at 20 °C and 95% RH. But the strength decreased as the curing time extended to 28 days. The reason is suggested to be that the polymerization of Al-O and Si-O is unstable due to the low Si/Al ratio of red mud. The alkali in the structure dissolves again into the pore water and corrupts the pore structure. Therefore, the thermal-alkali red mud should be combined with other reactive aluminosilicate materials such as granulated blast furnace slag to absorb the alkali released by the thermal-alkali red mud at the latter curing days.

Jan 1, 2014

By A. Zangooi

Frothers play major roles in flotation through interaction at the air/water interface. A method of determining frother adsorption density (coverage), i.e., the number of molecules per unit of interfacial area of bubble surface, is introduced. The technique is based on mass balancing the frother around a continuously operated bubble column. The mass balance requires collection of bubbles before they burst. The column design and operating procedure is reviewed, and some preliminary results discussed. Keywords: flotation, colorimetric frother analysis technique, frother mass balance, coverage

Sep 1, 2012

By E. Burdukova

This paper explores the relationship between the rheological behaviour and mineralogical nature of three different natural ore types. Rheological measurements performed here on Platreef, Kimber-lite and Norseman-Wiluna ores are correlated with the variation of phylosilicate mineral content in these ores and the corresponding physical properties of selected phylosilicate mineral groups. Preliminary results show that the clay mineral group (talc) has the least effect on both Bingham yield stress and viscosity of the three ore slurries tested, whereas the serpentine mineral group has a dramatic increasing effect on the Bingham yield stress especially at very low solid volume fractions. The Bingham viscosity of the mineral slurry appears to be the most influenced by the presence of the swelling clay mineral group (smectite). Significant increases in either Bingham yield stress or viscosity due to elevated contents of these problematic phylosilicate mineral groups are likely to cause negative effects on the processing and manageability of mineral slurries but it is unclear which is likely to have a more detrimental effect.

Jan 1, 2014

By B. K. Gorain

Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine. Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects. The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems Keywords: mineral processing, flotation, flotation problem solving, flotation optimization, plant design, innovation

Sep 1, 2012

By B. Friedrich, A. Weyhe, H. Heegn

"Nickel-metal hydride batteries (Ni-MH) are storers of electrochemical energy, which have a higher specific storage capacity than lead or nickel-cadmium batteries. The demand for Nickel-metal hydride batteries is increasing rapidly since their market launch in the early 1990’s. Today there is no suitable and sustainable recycling process to recover nickel, cobalt and rare-earth metals. The discarded batteries are used today in the steel industry as alloy material because they contain nickel. Cobalt and rare-earth metals (RE) are lost; they are non-recycleable.In a German governmental funded research project, IME Aachen, ACCUREC Mühlheim and UVR-FIA Freiberg are cooperating in processing as well as in creating a feasibility study. The target of this project is the development of a new recycling process for metal recovery from Ni-MH-batteries. The proposed process described in this paper consists of a combination of mechanical, pyrometallurgical and hydrometallurgical processing steps. This process is capable of treating all types of Ni-MH-batteries. After comminution steel and organics are separated. The separated Ni-MH is smelted in an electric arc furnace. The products are a nickel-cobalt alloy and a slag phase enriched with rare-earth oxides for further treatment to ‘mischmetal’. Both the Nickel-Cobalt alloy and the ‘mischmetal’ will be directly used in battery production."

Jan 1, 2003

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By Zhen Hu, Chenghang Wang, Jianjian Zou, Xiujuan Li, Hanwen Li, Tai Wang, Baoxu Song

A rare earth deposit in Sichuan, China is rich in wulfenite in addition to bastnaesite and barite, and the deposit has already adopted high intensity magnetic separation technique to pre-enrich the rare earth minerals, during which the wulfenite and barite have been left in the non-magnetic product. Because the chemical composition of wulfenite is only 24.17% Mo and 42.15% Pb, it is very hard to obtain qualified lead or molybdenum concentrates by physical separation process. To pre-concentrate the wulfenite, flotation has been first introduced, and by using 100g/t GY-7 as dispersant, 1500g/t CP-1 as depressant and 160g/t GY-4 as collector, a floatation concentrate assaying 15.52% Mo with a recovery of 86.12% was obtained. Then a leaching process was conducted by using 1.2mol/L Na2S as leaching agent, and molybdenum can be translated into sodium molybdate in the solution with a leaching recovery of 99%. To recover rare earth oxides (REO) and lead from the leaching residue, a magnetic separation process has been conducted. Above all, by the whole process, the molybdenum recovery reaches 86.16% in the sodium molybdate solution, and a lead concentrate assaying 54.59% Pb with recovery of 27.99% could be obtained.

Jan 1, 2014

By S. K. Chaurasiya

o meet the ever increasing demand of iron oxide feed stock for rapidly growing domestic steel industries and to effectively manage the depleting reserve of high grade lumpy iron ore, Pelletization of iron ore fines/slimes are expected to play a dominant role in the near future. Use of pellets will also enable the blast furnace operator to achieve higher levels of productivity with lowering of operating cost. The effective utilization of Iron Ore Slimes is important not only from the point of view of optimum utilization of Iron values in the mined ore but also for preventing environmental pollution. A significant amount of slime is being accumulated at the tailing dam of one of the iron ore mines and with the present scale of operation the tailing dam will be filled in another 10 years. Hence to increase the life of tailing dam and for better utilization of the iron values a study has been carried out for the suitability of pellet manufacturing with slimes and fines at our laboratory. The pelletization studies are aimed for optimization of various parameters for production of Blast furnace/ DR grade pellets from beneficiated slimes and Fines. This paper attempts to describe the production of blast furnace grade pellets from beneficiated slime and fines and its characterizations.

Sep 1, 2012

By Dilip Kumar Mohanty

In today?s world, Sustainability is the key issue before the mankind. With the ever-increasing population & unimaginable boost in industrial growth to cope up with a steady increase in demand and fast change in life style of a human being, the natural resources are exploited to such an extent that the very existence of living beings in this earth planet is threatened. In such devastating situation, the concept of Sustainability emerges out as a great savior. This concept focuses on minimum/ judicious use of natural resources, thereby preserving the resources for future generation while meeting the bare minimum requirement of the present generation. For an emerging economy like India, Mining and Mineral based industries form the back bone of our economic development. Thus, sustainability of mining and mineral processing industry has a far reaching impact on sustainable economic development of our nation. While at a macro-economic level, we have to strike a balance between economic development vis-à-vis socio-economic & environmental impacts, Industries have to ensure judicious and frugal use of natural resources by making use of energy efficient plants & machineries and adopting befitting technology for reduction & recycling of waste. In the context of the above, it would be interesting to look into the sustainability measures taken up by National Aluminium company (Nalco) at its Crushing & conveying plant at Panchpatmali Bauxite Mine, which is incidentally Asia?s largest Bauxite Mine. In the backdrop of the above stated facts, in this paper the authors make an attempt to bring out the sustainability issues in areas of energy conservation, environmental impact/pollution vis-a-vis mitigation measures adopted in crusher & conveyor plant of Panchpatmali Bauxite Mine & CSR / peripheral developmental activities undertaken by Nalco to mitigate the socio- economic impacts. Keywords: sustainability, energy efficiency, recycle, csr, peripheral development

Sep 1, 2012

By Xiaoxu Sun, Jianchao Yao, Jiancheng He, Shijie Lu, Hongxi Zhou

"With the trend of increasingly more mineral resources turning low-grade and refractory, more and more new ore bodies being developed worldwide are more finely grained, which drives the rapidly development and application of techniques related to tower mills (vertical spiral stirred mills). However, the lacking in fundamentals of fine grinding, as well as standard procedures for equipment selection and scale up, seriously restraint high efficient application of tower mills. Taking grinding media motion characteristic and grinding intensity as a breakthrough point, this paper studies mechanisms behind how critical parameters affect grinding efficiency of tower mill, including ratio of screw pitch and diameter, agitator rotation speed, grinding media size. Several sets of orthogonal test are conducted on the quartz ore using the grinding system of KLM-3 tower mill. All the tests are under the same character of feeding mineral and undergo the consistent sampling for at least 60min grinding time. The input power is measured by a torque measurement system and the grinding products are analyzed by the laser particle size analyzer. The test results show the influence of parameters on grinding efficiency. Among the three important parameters, the effect of grinding media diameter is the biggest, followed by the agitator tip speed, and finally the ratio of screw pitch and diameter. For the different particle size of grinding products, the best combination of grinding parameters is different, with the mineral size becoming finer, the ratio of screw pitch and diameter become smaller, the diameter of grinding media become smaller, while the agitator tip speed does not change too much. The conclusions of the study help us to improve the grinding efficiency of the tower mill, to assist in the selection and optimization of working parameters, establish new scale up method on the basis of grinding model and eventually provide theoretical basis of rational selections of structural and media physical parameters within tower mill."

Jan 1, 2018

By Kang N. Zhong, Hui H. Luo, Yi H. Wei, Yu L. Wang

"More than 85% of phosphorous reserves in China occur as middle-low grade phosphate of sedimentary origin. The main gangues are dolomite, quartz, silicates, and clays. The characteristics of minerals are finely disseminated. Flotation results have shown that the floatability of apatite of this kind of ore is much worse than that of igneous and metasedimentary origin because of its high specific surface area. Although some effective depressants, such as naphthalene sulfonate and phenanthrene sulfonate, are used to decrease the MgO content in the P2O5 concentrate, its presence is still high (about 2%) in the Chinese concentrates. Meanwhile, the wastewater may cause some environmental problems. Batch flotation results and measurements of specific surface area and CO3 2- have revealed that there is a relationship between the floatability of apatite and the surface area.A two-stage flotation flowsheet, which includes a combination of direct and reverse flotation, was developed for beneficiating sedimentary phosphate ores. The direct flotation was conducted in an alkaline medium and most of the apatite and carbonate minerals floated leaving quartz and siliceous gangue in the sink. In the reverse flotation circuit, the floated product was further beneficiated in an acidic medium to eliminate the carbonate as a float product. Apart from the high quality of concentrate, the two-stage flotation also facilitated the treatment and the recycling of wastewater. A wastewater recycling procedure was developed and tested in a continuous flotation process. The key factor was the careful selection of effective and non-toxic reagents."

Jan 1, 2003

By S. Jagdish

India ranks fourth in the world of iron ore production and exported 55% of the total iron ore production of 180.9 million tons in 2006-07. As per United Nations Framework Classification (UNFC), the total iron ore reserves in India is 25249 mt. This consists of about 14630 mt of Hematite ore and 10619 mt of Magnetite ore. While the deposits of magnetite iron ore are limited to the states of Karnataka, Andhra Pradesh and Tamil Nadu, hematite ore is available in abundance in Jharkhand, Orissa, Chhattisgarh, Karnataka and Goa. National Steel Policy, declared by government of India in 2005 envisages 110 million tons of steel production by 2020. This is likely to be revised upwards. Massive exploration work in iron ore is needed to convert the available resources of iron ore into reserve category. Steel Authority of India Limited (SAIL) produced more than 24.5 million tons of iron ore during 2006-07 and plans to produce 42.0 million tons per year by the year 2010-11 to meet the requirement for a hot metal production of 26.2 million tons. While processing iron ore, the challenge faced would be the reduction of the gangue materials ? alumina and silica. It is proposed to bring down alumina and silica in the iron ore to less than 2% each from the current level of 2.5%~3.5% each. Appropriate beneficiation schemes are being developed depending upon the mineralogical characteristics of iron ores at different mines in the country. The state-of-art beneficiation technologies like Hydro-cyclone, jigging, magnetic separation etc. will be incorporated. SAIL?s corporate plan envisages blast furnace burden of 15% iron ore lumps, 15% pellets and 70% sinter by 2010. This strategy opens up the opportunity of utilization of micro fines generated in the mining and beneficiation processes for pellet making. This also directs towards all together new technological approach to the beneficiation process. SAIL is planning to set-up three pelletisation plants of 2~3 mtpa capacity. Environmental issues like reduction in slime loss and utilization of dumped low-grade iron ore are very important. R&D Centre for Iron and Steel, SAIL has carried out extensive laboratory investigations in the above area. This will help in reducing the loss of valuable iron through slimes and also increase the iron ore resource base. Laboratory investigations indicate that low grade dumped ore fines with Fe: 55.5% can be upgraded to a product with Fe: 66.2% with about 48% recovery.

Jan 1, 2014

By X. S. Yuan

With a demand for increasing energy efficiency and a need for improving bitumen recovery, a highly integrated solution for sustainable lease development of Aurora North of Syncrude has been proposed and implementation plans are underway. Flocculation and thickening technology as an important component of the integrated solution provides Syncrude an opportunity of rapid heat recovery from tailings and more flexible tailings closure and reclamation options. Flocculation of fine-particle suspensions by polymers is a non-equilibrium process whose performance is strongly influenced by physical and chemical variables. While polymeric flocculants are frequently used to establish the chemical conditions favorable for flocculation, the actual performance of a flocculation process generally depends more on the physical variables, such as the hydrodynamic conditions in mixing the flocculants and slurry. In order to study the effect of hydrodynamic conditions on flocculation of Syncrude fine tailings, a standardized laboratory test procedure called power flocculation has been developed in comparison with the conventional manual mixing methods. It is shown that the agitation speed and time in conditioning the flocculant solution and the slurry have a profound effect on the flocculation performances measured by initial settling rates, supernatant clarity and sediment density. It was found that the optimum bench test conditions for power flocculation of Aurora fine tailings with a sand-to-fine ratio (SFR) of about 1:1 are conditioning of the flocculant solution and the tailings slurry at 250 rev/min to 300 rev/min in 20 s to 40 s. The test results are inter-preted with a flocculant adsorption/redistribution kinetic model that helps understanding of the effect of hydrodynamic conditions on flocculant adsorption, floc formation and floc growth.

Jan 1, 2014