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By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By Mark Freberg

"IntroductionThis chapter is intended to provide information on the operation and maintenance of several pieces of equipment used in heavy media separation. Most heavy media separation circuits, particularly those involving bath separators can be considered as high maintenance areas. Because of this the efficient operation and maintenance of these circuits is very important if the cost per ton of material treated is to be kept to an acceptable level.Heavy media separation (HMS), is a process used to separate particles of different specific gravities. Under laboratory conditions the ideal way to separate two types of particles which have different specific gravities is to suspend them in a heavy liquid which has a specific gravity between those of the two types of particles. Those particles with the lower specific gravities will float on top of the liquid while the higher specific gravity material will sink to the bottom. Given enough time and a sufficient volume of heavy liquid this process will be essentially insensitive to the sizes of the particles involved.Heavy media separation circuits make use of the same principles described above. The material to be treated is introduced into a mixture of finely ground solids, called media, and water which takes the place of the heavy liquid; the mixture of solids and water is known as medium. The separating force can be either gravity or centrifugal force. The type of solids used as media varies but it is usually a high specific gravity material such as magnetite, galena or ferrosilicon.Heavy media separation is used extensively in the cleaning of coal and to a lesser extent as a preconcentration step in base metal and iron ore operations."

Jan 1, 1989

By M. J. Nicol, T. Moyo

Ammoniacal solutions are an effective lixiviant for the oxidative dissolution of some mineral sulphides. A detailed study of the anodic dissolution of chalcopyrite in ammonium sulphate-ammonium hydroxide solutions has been carried out using cyclic voltammetry, chrono-amperometry and rest potential measurements. The role of the copper(II)/copper(I) redox couple in the oxidation process has been evaluated. Rest potentials have been found not to be affected by oxygen but to increase with an increase in initial copper(II) concentration. Pseudo-steady-state anodic current densities measured in the absence of copper(II) ions at the rest potentials obtained in the presence of copper(II) ions increase with increasing concentration of copper(II) ions, confirming the positive effect of copper(II) ions on the rate of dissolution of the mineral. Cyclic voltametric and chrono-amperometric data show that in the absence of initial copper(II) ions, the rate of dissolution in the presence of dissolved oxygen is significantly lower. These results confirm that the effective oxidant for the mineral under the conditions of the study is copper(II) and not dissolved oxygen. Coulometric measurements have been used to establish the stoichiometry of the anodic reaction at different potentials.

Jan 1, 2014

By Bert S. Hall

"The purpose of this paper is to review the evidence at hand concerning the earliest centuries of cast iron in Europe, from roughly 1400 A.D. until the second half of the sixteenth century. For the most part it is concerned with the relationship between two technologies which emerged first in China and then later appear in Western lands, gunpowder weapons and iron founding. We should not assume, as I hope to show later in this discussion, that weapons constituted the only product for which the iron founder had any market, but it is clearly true that attempts to produce weapons constituted the most severe technical challenge for the early founder. Firearms appear for the first time in Europe in the 1320s and develop into significant weapons on the field of battle by the end of the century. Theirs is a complex history, subject neither to easy summary treatment nor to simplified models of development. I hope to be able, through the analysis of the evidence concerning cast iron, to show that one important strand in the fabric of gunpowder's history concerns the materials from which cannon could be made. This question is subject to a number of shades of meaning, because ""cannon"" can be made for many purposes under a profusion of different names, and under sharply varying conditions of use. As a result, the question of materials is frequently really a question of competing materials, and involves a complex set of factors, of which production costs and the ultimate safety of the user seem the most important. Judged in this manner cast iron was an important but unsatisfactory metal for weapons purposes until 1543, at which time English founders learned to make iron muzzle-loading cannon which could rival bronze ordnance in most important performance criteria, but which cost much less to produce. With that event, the history of cast iron and the history of weapons entered into the close relationship that persisted until the advent of rifled artillery made of steel in the middle of the nineteenth century."

Jan 1, 1999

By Fathi Habashi

"On August 3, 1888, German Patent No. 43977 entitled ""A Process for the Production of Aluminum Hydroxide"" was issued*. The discovery which led to the patent was made by the Austrian chemist Karl Josef Bayer (1847-1904) (Fig. 1) who was at that time in Russia, and the process became known as the Bayer Process in his honour(1)(2)- The process imediately achieved industrial success, displacing the pyrometallurgical process that had been used until that time to produce alumina. The Bayer Process involved the pressure leaching of bauxite with NaOH solution to obtain sodium aluminate solution from which aluminum hydroxide was precipitated by seeding. Today bauxite is not only the principal source of aluminum but also of gallium, both metals being effectively recovered by the Bayer Process. The purpose of this paper is to outline the historical background of this discovery and its importance to hydrometallurgy."

Jan 1, 1999

By K. Niboucha, M. Zergoug, S. Brick-Chaouch, H. Houali

"Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items:•,Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists;•,Range of protection (potential of protection along the pipeline);•,Influence of the isolation resistance of the coating on the range of protection;•,Effect of the aging of the coating and its influence on the current of protection."

Jan 1, 2005

By H. Houali

Corrosion is an electrochemical process that causes degradation and deterioration of various steel works (pipelines, drains, cisterns) whether they are buried, immersed, or not. Worldwide, we estimate that corrosion destroys a quarter of the annual production of steel at a rate of 5 tons per second. Several techniques are used to protect against corrosion. Among these processes, Cathodic protection, which is regarded as the best technique to assure the protection of steel, works against this phenomenon. This is achieved either by a system of reactive anodes, or by the technique of impressed current protection or other techniques. Before any installation of cathodic protection, a preliminary study and pre-evaluation of certain parameters must be made. In the present work, we will present an example of dimensioning of an installation of cathodic protection by imposed current of a pipeline using solar energy, where we discuss the following items: ? Evolutions of the potential as well as current along the pipeline and their respective expressions deduced from the laws known as telegraphists; ? Range of protection (potential of protection along the pipeline); ? Influence of the isolation resistance of the coating on the range of protection; Effect of the aging of the coating and its influence on the current of protection

Jan 1, 2005

By A. S. Romaniuk

More than a decade ago, CANMET management recognized the need to make better use of existing technological information in mining and extractive metallurgy-two fields basic to the economic well-being of Canada. There were at that time no indexes or files dedicated to disseminating technical information for the many minerals mined and processed in Canada, including coal. CANMET, with the nation's largest research and library resources in the minerals field, was in a unique position to fill this need. Initial efforts were concentrated on building a mining file, beginning with identification of world sources of published information, development of a special thesaurus of terms for language control and adoption of a manual indexing/retrieval system. By early 1973, this file held 8,300 references, with source, abstract and keywords given for each reference. In mid-1973, operations were computerized. Software for indexing and retrieval by batch mode was written by CANMET staff to utilize the hardware facilities of EMR's Computer Science Centre. The resulting MINTEC file-one of the few files of technological information produced in Canada-is the basis for the national literature search service in mining offered by CANMET. Attention is now focussed on building a sister-file in extractive metallurgy using the system already developed. Published information sources have been identified and a thesaurus of terms is being compiled and tested. The software developed for CANMET's file-building operations has several features, including the selective dissemination of information and production from magnetic tape of photo ready copy for publication, as in a bi-monthly abstracts journal.

Jan 1, 1979

By P. Lin, S. G. She

"In June 1985, Chinese Society for Rock Mechanics and Engineering (CSRME) was established. During the past 30 years, various major achievements are made in the discipline of rock mechanics and rock engineering field, especially in the last ten years. This paper will discuss the main rock engineering progress in association with China National Science and Technology Awards, “973 Program”, and “Tan Tjongkie Lecture”. The current status of rock engineering in China and some hot problems are summarized. Furthermore, some suggestions are given for addressing those problems. INTRODUCTIONThe modern concept of rock mechanics and engineering was initiated and developed after the Second World War. In this regard, the International Society for Rock Mechanics (ISRM) was established in 1962, subsequently further promotes its development. In June 1985, the Chinese Society for Rock Mechanics and Engineering was established. Various chief scientists, including professors Tan Tjangkie, Pan Jiazheng, Sun Jun, Wang Sijing, Qian Qihu, have made their huge efforts to the development of Rock Mechanics and Engineering in terms of the large-scale rock engineering projects in China.The achievements in the last 30 years significantly promote the development of China in different fields, such as energy, transportation, national defense and other national economy and major infrastructure facilities (Wang et al. 2004; Qian 2010, 2011). In other words, these projects also promoted the science and technology progress in rock mechanics and engineering across the world. Reviewing and analyses of the experiences on those key rock projects are beneficial to its technological development. She and Dong (2013), in view of literature statistical analysis, discussed the status and research progress in rock mechanics field associated with the last 30-year China's developments, including the rock strength and deformation theory, rock fracture and damage mechanics, the constitutive relation of rock dynamics, rock field coupling, rock reinforcement and stability analysis, etc. The challenging issues in rock mechanics were also proposed, which are the main concerns in rock engineering practices, engineering exploration, design, construction and operation."

Jan 1, 2015

By Gordon Nelson

The Homestake gold mine is one of the largest and oldest continuously operating gold mines in orth Ame rica. To date this mine has produced in excess of 128.000.000 tons of ore containing almost 34 million ounces of gold . Gold mine ralization is restricted to the Homestake Formation. This unit is a metamorphosed iron-formation which is enclosed by pellitic metasedime nts below (Poorman Formation) and a pellitic to qua rt zitic unit (Elli son Formation) above. The e ntire Precambrian sequence. in the Lead area. has been subjected to a multi-stage defo rmation episode which ha c reated an extremely complex structural setting for the Homestake orebodies. Metamorphic grade inc reases from greenschi st ro amphibolite in a northeast d irecti on acros the mine area. Present thickness of the Home take fo rmation va ric from O to »400 fee t. The amount of thicke ning and th inning which is attributable to tectonic deformation or original sedimenta ry di fferences is not known. Orebodies constitute onl y a small pe rcentage of the Homestake Formation and do not occur along a pa rticul ar stratigraphic pos ition within the unit. Gold i assoc iated with inc reased py rrhotite and a rsenopyrite concentrations within the iron formation. Inc reased \ cin qua rt z development and chl oritic alteration usuall y accompany this minerali zation. Local remobilizati on of mine ralization due to metamorphi sm has occurred. Homestake mine ralization has been shown to be of sy ngeneti c origin . Because no feeder zones have yet been recognized a di stal source for the mine ralization is inferred .

Jan 1, 1986

By D. M. Ramsey

HIGH-INTENSITY magnetic separation as now practised in the commercial treatment of a large variety of industrial minerals is a com-paratively recent development, having had its practical beginning about ten years ago when it became necessary to devise more effective methods for the purification of the electric furnace abrasives and refractories-silicon carbide and fused aluminium oxide. The fundamentals of magnetic separation are, of course, very well under-stood; bur while very, very old in principle, the process has, in recent years, been developed to a point of far greater usefulness than heretofore. In fact, until the development of the high-intensity process,. magnetic separation was limited largely to the removal of tramp iron? with magnetic pulleys and the removal of the very highly magnetic portions of industrial minerals by means of horizontal conveyor-belt-type separators. All magnetic separation processes depend for their success on the fact that various materials are kinetically influenced to a greater or lesser degree by the force that we speak of as 'magnetism'. We have now come to regard 'magnetic separation' and 'high-intensity magnetic separation' as two different and distinct methods. However, both depend upon the reaction of a particle when placed in a magnetic field. The common types of magnetic separators quite generally operate on the principle that a magnetic particle can be lifted by a powerful magnetic force from a stream of material moving on a belt or other type of conveyor. The application of the force removing magnetic material by this scheme is directly opposed to the force of gravity and is, therefore, limited to sub-stances of a relatively high order of magnetic susceptibility, such as metallic iron and magnetite. Until a few years ago, one very important principle was almost entirely overlooked. Practically every substance is susceptible to some extent, at least, to magnetic attraction, and by the application of a magnetic force great enough, and properly applied, separations of materials heretofore considered 'non-magnetic' can be accomplished.

Jan 1, 1937

By J. B. De Hart

In the September issue of the Bulletin, 1923, there is a paper by J. A. H. Church on "The Spontaneous Combustion of Coal in Mines", which is more or less a general discussion of the subject. Mr. Church gives a list of mine fires which have occurred in Alberta. Of the total of thirteen fires, six are attributed to spontaneous combustion. Of these six fires, it will be noted that five are in thick pitching seams. These fires occurred in the following mines during the years shown, at Frank in 1909; at Lovett in 1916; at Cadomin in 1920; at Yellowhead in 1922, and at Cadomin in 1923. Every one of these fires has occurred, as Mr. Church points out, in a seam of over 12 feet in thickness, and furthermore not one of these fires has been extinguished, although in every case large sums of money were expended and considerable risks . taken in fire fighting. Now it is quite evident from these facts that mines working seams of this nature are faced with a very grave danger and it behooves us to study the matter and endeavor to arrive at some practical method of preventing the loss of our coal mines from this cause.

Jan 1, 1924

By I. E. Puddington, F. W. Meadus

The beneficiation of barite in mill tailings using an agglomeration technique has been demonstrated. Barite was selectively absorbed from a conditioned aqueous slurry into a collector oil by mechanically mixing slurry and oil. The resulting oil-bonded barite-containing agglomerate was washed, to remove gangue material, and further mechanically contacted with dilute H2SO4 This treatment resulted in the transfer of barite into the aqueous phase. Grades as high as '97% BaSO4, with recoveries of 80%, have been obtained using this technique.

Jan 1, 1973

By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By C. D. M. Chisholm

Introduction The Sullivan orebody is a sulphide replacement deposit in beds of argillaceous quartzites. The general strike of the vein is north and south, with rather an abrupt change to northwest in the north limits, and a pronounced steepening of the dip in the same area. An east-west section across the orebody in the vicinity where the change in strike occurs will show the dip-to the east-to be about 10° to 20° above the 4500 level, 20° to 30° between the 4500 and 3900 levels, and 35° to 45° between the 3900 and 3500 levels. It is this last section, averaging 75 feet in thickness, that is being mined by the blast hole method discussed in this paper. Typically, the mineralization throughout this section follows the same general pattern between footwall and hanging-wall, there being solid sulphides for a width of 30 to 50 feet, above which lie quartzite beds of varying widths separated by ore bands which also vary in width and in grade. This banded part of the vein usually extends for 30 to 40 feet above the solid sulphides, with commercial ore terminating on reaching a siltstone bed. Development is generally carried to the highest ore band which, when averaged with the underlying quartzite band, will assay about the marginal limit in lead and zinc. When wide stopes are opened, sloughing to the siltstone usually occurs and, although the values are too low to carry the cost of developing and mining, the caved muck can be handled profitably with only haulage and treatment to be considered.

Jan 1, 1946

By I. I. Inculet, M. A. Bergougnou, J. D. Brown, R. M. Quigley, D. K. Faurschou

"Coal from Hat Creek, B. C., has been successfully beneficiated to remove ash while retaining calorific value by a dry electrostatic separation process using a fluidized bed for triboelectrification. Two samples of Hat Creek coal used in the beneficiation experiments have been characterized particularly with respect to their mineral and clay content. The calorific value recovery exceeds the simple dry coal recovery because of the heat lost in altering the clay minerals of the ash fraction during burning. Recoveries and ash contents of the beneficiated coal are comparable to recoveries by water washing, but the dry process avoids the potential water pollution problems.IntroductionProposals have been made which suggest an interim Canadian coal production target for the end of the century which will require a four- to fivefold increase over the 1977 production. This implies a nominal annual growth rate of about 6070 to achieve a production rate of 115 to 140 million tonnes/year. Whether or not this target is realistic, it is becoming increasingly evident that coal must be utilized more fully on a world-wide basis. The crisis in Iran has provided the latest stimulus to renewed interest in Canadian coals for domestic use and export.The emerging new era of coal utilization for fuel and chemical feedstock will not, however, generally tolerate the level of coal technology which prevailed prior to the availability of abundant cheap oil and natural gas. Economic, environmental and resource management considerations will necessitate, for example, the use of improved methods of beneficiating coal. Continued development and application of conventional processes, principally aqueous, involving heavy media and cyclones will solve many of the problems. However, less conventional processes may be preferable or necessary in certain applications."

Jan 1, 1980

By Euler De Souza

"The uninterrupted operation of a ventilation system is critical to ensure the mine meets its scheduled production and, as important, is vital to the health and safety of all personnel working underground. Those operating the mine ventilation system must have fundamental engineering training in the art of fluid dynamics and have a good comprehension and control of the mine ventilation network. Ventilation management by untrained and inexperienced personnel may result in serious consequences when the system becomes ineffective. This paper shares observations and experiences pertinent to the occurrence of upset conditions as a result of the improper design and operation of mine ventilation systems. A series of real life case studies are presented to describe disruptions to mine ventilation systems and the gradual deterioration of system operational efficiencies leading to eventual failure. Special focus is given to mistakes made and on the resulting serious consequences. The case studies also demonstrate how each upset condition was resolved, permitting the mines to safely resume production activities.INTRODUCTIONThe ventilation of operating mines is a continuously changing and evolving system; upset conditions will occasionally occur, but should be promptly resolved in order for the system to function properly, according to design, and in compliance.Those designing, managing or operating the mine ventilation system must have pertinent training and have a good understanding of fundamental ventilation concepts to be able to devise and implement engineering solutions to day-to-day challenges. Realistically, the operator must also have extensive practical experience and be able to effectively apply operating procedures, design criteria and ‘best practices’. They must be able to, on a daily basis, evaluate the mine ventilation system, determine and locate any problems, understand the causes of each problem, find a solution, and promptly and efficiently correct those problems.Ten case studies are presented to demonstrate how fundamental design or operational mistakes can lead to adverse conditions or to catastrophic consequences, how detailed on-site engineering assessments can be employed and how simple, low cost, engineering solutions can be implemented to successfully resolve the issues and return the ventilation system to compliance, permitting the mines to safely resume production activities."

Jan 1, 2019

The teaching of geophysics in Canada at the present time presents a variety of approaches to the subject, and the different paths adopted imply, in turn, an uncertainty in the minds of some educators as to the role this science is to play in the future progress of geology, and a hesitancy to commit themselves to foster its development. The pedagogical attitudes vary from a whole-hearted acknowledgment that the science of geophysics is fundamental to the understanding of terrestrial phenomena (including, of course, geological processes) to a hesitant immersion of the toe to test the water's temperature (which is, of course, essentially a geophysical experiment) before deciding whether or not the time is ripe for total immersion. The present discussion has been organized in the hope that it will help to clarify the roads to geophysics and assist educators in making a more understanding choice of the best paths for them to follow, according to their particular requirements and objectives. Before proceeding further, however, it is necessary to define the term geophysics and circumscribe the field it covers. In the first place, it should be emphasized that geophysics is NOT confined to the art of geophysical prospecting. The popularization of geophysics has unfortunately engendered a general misconception of the word, and consequently a tendency to ignore the wider meaning of the term. Etymologically, geophysics means the physics of the earth. It is so understood by the International Union of Geodesy and Geophysics and the various geophysical societies which adhere thereto. To them, geophysical prospecting is but a very small field indeed, which they consider had best be left to engineering and prospecting organizations.

Jan 1, 1951

By Georgy A. Cherkashov, Andrey V. Efimov, Yury S. Borodaev, Nadezhda N. Mozgova, Sergey G. Krasnov, Tamara V. Stepanova, Alexander M. Ashadze

"Abstract - A horizontal mineralogical-geochemical ore zonation with a southeast to northwest trending succession of Cu and Fe (Zn) main zones has been discovered in the Logatchev hydrothermal field (14°45??N Mid-Atlantic Ridge). The major minerals are pyrite, chalcopyrite, bornite, isocubanite, digenite and chalcocite. Zn-sulfide, marcasite and covellite are less abundant. Rare minerals are native copper, zincian copper and cobalt pentlandite (first found in oceanic massive sulfides), Cu and Cu-Co-bearing Fe-disulfides. Two groups of the main sulfide assemblages with different copper contents are recognized: Group I comprises assemblages with primary sulfides (isocubanite, chalcopyrite, pyrite and Zn-sulfide; Cu up to 35 wt% in Cu-bearing minerals); Group II contains assemblages with secondary Cu-rich sulfides (bornite, digenite, chalcocite; Cu ~60 wt%) as well as rare minerals (cobalt pentlandite, native copper and zincian copper). The assemblages of Group I formed at a temperature of about 300°C; the sulfur fugacity (log fs2 atm) at 300°C is probably 9.9. Relations between minerals of this group are contradictory, attributed to non-equilibrium environments, and no unified sequence of crystallization of minerals has been determined. Minerals of Group II replace, rim or cross the assemblages of Group I. Group II minerals crystallized in a distinct sequence (cobalt pentlandite-bornite-digenite- chalcocite-native copper), with increasing copper content from the start to the end of the depositional sequence. This may correspond to pH from 7 to 8 near Eh = -0.2 at 250°C. Minerals of this group were generally formed under hypergene alteration processes. Compositions of ore minerals were studied by means of electron microprobe analysis (EMPA) (150 analyses). Narrow composition fields were revealed in all main sulfides, which comprised known experimental data. ZnS contains 6.0 to 28.0 mol.% FeS, which is close to data known for other hydrothermal massive sulfides from the Mid-Atlantic Ridge (MAR). A common admixture in ZnS is Cu (0.16 to 1.32 wt%). Rare grains of unusual anisotropic Fe-disulfides, (Fe0.95Cu0.05)S2 and Cu(Fe,Co)9S20, were found among the ore minerals."

Jan 1, 1999