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By George Langford

Introduction The manufacture of ductile beryllium is one of the most interesting problems confronting the metallurgist today, and one which becomes more acutely in need of resolution as the uses for beryllium increase. Beryllium belongs to the hexagonal group of metals along with zinc, magnesium, and cadmium. The melting point of the metal is about l,280°C. ± 5°C. Due to its brittleness, the metal's chief use is as an alloying agent in copper and iron. The very low absorption coefficient of beryllium for x-rays makes the metal ideal for x-ray windows, and, similarly, because of its low capture cross-section for neutrons, the metal holds a preferred position in the field of nuclear physics. Modern x-ray diffraction methods were responsible for explaining the mechanism whereby zinc metal, although brittle when cast, could be made ductile at room temperature. The diffraction patterns of zinc and magnesium indicated the importance of the parts played by recrystallization and preferred orientation in this mechanism. It was with this in mind that an Investigation into the recrystallization and preferred orientation of beryllium was undertaken. The investigation, after a series of experiments were conducted involving cold-working and annealing, yielded the recrystallization temperature curve for beryllium. Both the texture of preferred orientation and the effect of recrystallization on this texture when subjected to compressive stresses were also determined. W. A. Alexander, J. K. Swinton and L. M. Pidgeon, in their investigation on The Recrystallization Temperature of Beryllium (C.I.M., Trans., Vol. L, 1947, pp. 657-664), utilized the Brinell ball as a means of cold straining the metal. Sufficient strain was developed to estimate the recrystallization curve for the metal. However, in order to determine the lowest recrystallization curve, as well as to develop a preferred orientation structure, larger deformation than that possible with a Brinell ball was required. The plastic deformation of beryllium can be carried out at an elevated temperature above 700°C. Above 850°C., the metal is quite ductile and can be readily compressed or extruded.

Jan 1, 1948

By R M. Ennis, J. C. Botham

This paper is one of a series pre-pared to study the role of fuels and reductants in metallurgical processes, especially from the viewpoint of Canadian requirements. The object of these studies is to provide a reason-ably authoritative interpretation on the interrelation of fuels in light of the considerable changes that have taken place in the Canadian energy field during the past few years. Previous papers in this group have dealt with the problem generally, and specifically in terms of the development of the iron and steel industry of Western Canada. These latter papers, presented at the Symposium on Iron and Steel in Western Canada held in Edmonton, Alberta, on September 8-9, 1959, surveyed the ferrous processes of interest for use in Wes tern Canada, especially with regard to solid fuel requirements. At that time it was evident that there was a need for a similar study of the fuels aspect of the non-ferrous metals industry.

Jan 1, 1961

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By D. L. Griffith

THE realization by metallurgists of the important effect that traces of impurity may have upon the properties of a metal, and their steady demand for purer and still purer metals, have made the special cools for &apos;trace&apos; analysis of increasing value. In the United States at least, spectrographic analysis is becoming the standard method for determining the impurities in zinc die-casting alloys. The Hudson Bay Mining and Smelting Company, as a producer of virtually pure zinc, uses the spectrograph to control the purity of its products, and-as the electrolytic method is employed here-to control both the impurities in the electrolyte and those &apos;trace&apos; elements, which, while they do not contaminate the zinc, have a great effect on the plating efficiency. The general plan of the laboratory is shown in Figure l; the housing for air purification, which is on the roof, is indicated by broken lines. One of the chief factors affecting the layout was the easy way in which a spectrographic assay can be spoiled by contamination. To minimize the quantity of dust tracked in, the laboratory was made separate from the general research laboratories, and an office was placed between the two. This arrangement has its drawback because of the traffic through the office, but it has effectively cut down dust. For similar reasons, the available space was subdivided into a number of small rooms, and the air currents in the laboratory were so arranged that dust would be carried where it would do least harm. Air is drawn in at the roof over a 50-kilowatt bank of Calrod heaters, through Annis air filters, by a No. 4 Sirocco fan. Most of it is forced into the spectrograph room, but some goes to the office and darkroom. The air flow is from the spectrograph room, through the plate-measuring room, into the chemical laboratory, where it is exhausted by a No. 1% Sirocco fan on the fume hood. Air can also re-circulate from the plate-measuring room back to the heater. The arrangement is such that the air in the laboratory is maintained at higher pressure than the outside air; consequently, no dirt enters through cracks about the windows and doors. A thermo-regulator holds the temperature constant within one or two degrees; only on the hottest days in summer does the temperature rise enough to affect the focus of the instrument.

Jan 1, 1940

By M. W. Wadsley

"Physical and chemical property models are widely used in process engineering. There exist, in the published literature, completely empirical models of &apos;&apos;thermodynamic properties"", that is, property models that are not consistent with the laws of thermodynamics. There also exist property models that purport to be thermodynamically consistent but are flawed in their implementation. There are also published property models that are consistent with the laws of thermodynamics but that do not reproduce property values with an acceptable accuracy. A practicing engineer might be asked to assess very different property models for which there are a variety of claims. This paper discusses features of thermodynamic and empirical property models that may assist in their practical evaluation and implementation."

Jan 1, 2005

By Tim Grain Joseph

This paper considers the duty cycle of an electric cable shovel and correlations with measured passive seismic responses of the underfoot oil sand material in-pit. It has been observed that the cyclic activity during operation of any shovel in the oil sands environment causes the material to deteriorate and provide a less than ideal footing for this large item of equipment, whose dead weight approaches 1500 tons with a footprint of merely 75 square yards. Consequences are manifest in the form of carbody and side frame cracks, and associated downtime, maintenance activity, cost, and subsequent loss of availability. The objective of these considerations, as part of the Oil sands Equipment Interaction Program (OsEIP); currently a joint venture between Syncrude Canada Ltd., JPi Ltd., Caterpillar Inc., P&H MinePro and the University of Alberta; is to identify and provide feedback to the manufacturer and end user adverse shovel - ground conditions. This would enable the manufacturer to incorporate greater knowledge into the design process and the end user to direct operations in an enhanced proactive maintenance stance.

May 1, 2002

By E. Lovera

ABSTRACT: The current study analyzes the feasibility of an odd operation: to obtain, using a properly tailored drilling and blasting scheme, blocks suitable for the production of dimension stone from tunnel driving. Clearly, a compromise must be found between the rate of progression and the achievement of workable blocks. As a case study, a civil work under consideration in northern Italy was examined. The work was planned to cross a conglomerate that has traditionally been locally exploited for the production of highly prized paving and lining stones with excellent strength and aesthetic features. Natural exposures and mined-out quarries were available for tests. The relevant rock data are given, blast designs are shown (within the limitations of contour accuracy), and the test program is described.

Jan 1, 2011

By C. Moctezuma

Since the start up of the IMMSA electrolytic zinc refinery in 1982, the dissolved iron coming from the acid attack of the ferrites has been precipitated by the jarosite process. At the beginning of operations, sodium jarosite was produced; however, the plant was converted to ammonium jarosite in 1990. The final storage of the residue is on the company&apos;s property adjacent to the plant, over the natural surface of the land. Before the construction of the refinery, several studies were done in order to evaluate the characteristics of the ground, such as, permeability, underground water localization, etc. The results showed that the site was adequate for the storage of this kind of material. For several years, the jarosite residue was filtered on rotary drum filters and was sent as a pulp to the storage area for settling. The water from the storage pond was recycled to the re-pulp tank for the jarosite residue. These filters were replaced in 1999 by an automated filter press. Since then, the jarosite residue has had a lower water content, and the zinc recovery improved. At present, a second filter press for the jarosite circuit is in the acquisition process to diminish the soluble zinc content in the residue from the present value of 2% to < 1% Zn.

Jan 1, 2006

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By Alain Simard, Sylvain Lacroix, Louis-Martin Dubé, Pierre Pilote

"The Harricana-Turgeon belt (HTB) is a poorly known volcano sedimentary belt in the NW part of the Abitibi Sub-province; it includes the Matagami, Joutel, Brouillan and Casa-Berardi mining districts. The HTB is dominated by volcanic rocks, which covers 65% of its surface area, followed by sedimentary (18%) and plutonic (17%) rocks. It is also transected by numerous deformation zones located either at the contacts of volcano-sedimentary units and granitoid bodies or cross-cutting them. A preliminary geological synthesis shows that mineral deposits are associated with certain regional geologic elements.The volcano-sedimentary units are grouped here into twelve band-shaped lithotectonic domains, most of which extend for more than 150 km E-Win the HTB. Each domain is defined by lithologies and facies associations, and gradiometric and electromagnetic signatures.Eight domains are composed of basaltic or basaltic to komatiitic associations, interlayered with thin pelagic sediments, representing sub-marine lava plains. Two domains are composed of basaltic to rhyolitic associations that are interpreted as volcanic arcs formed by one or several central volcanic complexes.The sedimentary rocks are grouped into two lithotectonic domains. Each is composed of rhythmic sequences of turbiditic sandstone- siltstone-shale, Algoma-type banded iron formations and conglomerates bearing plutonic and volcanic pebbles. These three facies come partly from mass flow at the bottom of a slope in a moderately deep marine environment. In each domain, a conglomerate sandstone- siltstone sequence, containing poly genetic pebbles of local provenance, is similar to Timiskaming-type alluvial deposits.The nineteen granitoids, found within the HTB and at its border, belong to numerous petrographic suites, and have been grouped into four structural families: pre-tectonic, pre- to early-tectonic, syn- to late-tectonic, and late- to post- tectonic. The pre- to early-tectonic plutons are presumed to be sub-volcanic and are generaly associated with the volcanism of central complexes.The HTB mineral resources consist essentially of polymetallic (Cu-Zn-Ag-Au) and gold (Au-Ag) deposits. The polymetallic deposits are located exclusively in the two lithotectonic domains composed of basaltic to rhyolitic associations (Matagami-Brouillan and Joutel Raymond). All gold deposits are associated with deformation zones superimposed on lithotectonic domain contacts and highlighted by graphitic units. Most of the deposits are hosted in the Casa-Berardi and Douay deformationzones, located at the contact of the Cartwright basaltic to komatiitic domain and the Taibi sedimentary domain"

Jan 1, 1990

By K. A. Natarajan, M. N. Chandraprabha

Selective separation of minerals from complex sulphide ores is a challenging task and it is often difficult to get commercially acceptable individual concentrates by conventional selective flotation using inorganic collector reagents. Microbially-induced mineral beneficiation has proved to be more effective, economically viable and an environmentally benign process for the effective separation of various minerals. Applications of microbially-induced mineral beneficiation are demonstrated in this paper with respect to beneficiation of complex multimetal sulfides. The role of adapted microorganisms and bioreagents in the beneficiation of complex sulphide minerals are also illustrated.

Jan 1, 2009

By Fred A. Webber

STEEL ROPE WIRE is one of the more specialized commodities among the many grades of highcarbon steel wires. In its production there are many metallurgical aspects of interest from the steelmaking on through the final stages of wire drawing. We produce rope wire in an integrated mill com prising all the operations from the blast furnaces to finished wire drawing in the wire mills. Steelmaking is carried out with close control on hot metal, selection of scrap, and fluxing materials. The basic open hearths are of 170 tons capacity. Steel is teemed into 19 1/2 in by 19 1/2 in big-end-down molds and is hot-topped with the use of clay refractory hot-tops. The weight of this ingot is 6,900 pounds. All high -carbon steel ingots are charged hot into the soaking pits and are then rolled through the blooming mill in 16 p asses to a bloom ax~ in. by 41/2 in. and approximately 65 feet long. Necessary bottom and top crops are taken on the bloom as it passes from the blooming? mill to the billet mill. The still hot bloom is continuously rolled through the billet mill in . 5 passes to a 2 3/8 in. square. Billets are cut to 32 feet in length by a flying shear and then allowed to cool on the hot bed.

Jan 1, 1957

By A. B. Baldwin

"Uranium and thorium mineralization occurs at several localities in eastern Quebec along the north shore of the Gulf of St. Lawrence. The main occurrences are near Sept-Iles, Baie Johan Beetz, Romaine and St-Augustin river. Mineralization occurs mainly as disseminated uraninite, uranothorite, uranothorianite, monazite and minor zircon and allanite. Yellow to orange oxidation products are observed along fracture planes of the uranium-bearing deposits to a depth of a few feet. Magnetite, biotite and smoky quartz have a distinct tendency to accompany the radioactive minerals. The host rocks include white to pink pegmatite, pink granite and also, in the case of the Romaine and St-Augustin River occurrences, cream to grey plagioclase-rich, well foliated paragneiss and migmatite. Radioactivity near secondary structures, such as fractures and joint planes, indicates some reconstitution of radioactive minerals.The North Shore of Quebec is the northeast extension of the Grenville sub-province. It is also a uranium-thorium metallogenic province."

Jan 1, 1970

By Ben Sheneider

AT THE Flin Flon plant of the Hudson Bay Mining and Smelting Co., Limited there are two types of multiple hearth furnaces used in the roasting of sulphides. This pa-per will deal primarily with the wedge-type furnace in the roasting of zinc concentrates. The other furnace, the Nichols-Herroshoff type, is used in the copper smelter and is described in the papers given by (1) J. H. Ambrose in 1935 and (2) R. E. Mast and G. H. Kent in 1954. The design and operation of these roasting furnaces at the present time is essentially the same as given in the write-up in 1954. No at-tempt will be made here to describe these furnaces, except to mention that there are five Nichols-Herreshoff multiple-hearth furnaces, four of which are used to roast a dried mixture of copper concentrate, zinc plant residue, and flux, before this material is fed to the reverberatory furnace.

Jan 1, 1961

By B. G. Cousins, B. O’Rourke, C. Spence

"Some non-flotation chemicals are added to flotation circuits directly and indirectly to control issues such as scaling and dust in other areas of the operations. Since dosage levels are generally not high, a standard laboratory float test may not be able to determine the effect of a specific chemical on the productivity of the flotation circuit. This paper presents a laboratory testing protocol that uses kinetic float studies to test the effect of normal to extreme doses of antiscalant and dust chemistries (5–100 g/t). Results indicate that this protocol helps to predict potential interference by a particular chemistry on the flotation circuit.RÉSUMÉ Certains produits chimiques ne servant pas à la flottation sont ajoutés directement et indirectement aux circuits de flottation afin de contrôler des problèmes tels que l’entartage et la poussière dans d’autres secteurs des opérations. Étant donné que les niveaux de dosage sont généralement faibles, un essai standard de flottation en laboratoire pourrait ne pas être en mesure de déterminer l’effet d’un produit chimique spécifique sur la productivité du circuit de flottation. Le présent article définit une procédure d’essai en laboratoire qui utilise des études cinétiques de flottation pour vérifier l’effet de doses normales à extrêmes de produits chimiques antitartre et anti-poussière (5 à 100 g/t). Les résultats indiquent que ce protocole aide à prédire l’interférence potentielle d’un produit chimique particulier sur le circuit de flottation."

Jan 1, 2016

By M. Matsuda

The Hitachi refinery of Nikko Smelting & Refining Co. Ltd. began its electrolytic copper refining operations in 1911. In December 2002, the refinery changed its operation scheme by introducing the ISA permanent cathode technology for the first time in Japan. The change resulted in higher productivity, better cathode quality, and lower operational costs. The operation has been continuously improved to reach a 20% higher production capacity than the original one. For the electrolyte purification process, the Hitachi refinery has developed a new process for removing impurities. The process involves As, Sb and Bi adsorption from the electrolyte by means of chelating and ion exchange resin. The new resin process will achieve higher efficiency in removing impurity.

Jan 1, 2007

By M. B. Greyver

The results of laboratory tests on iron precipitation from non-decopperized nickel anolyte are discussed. The parameters (pH, oxygen consumption and stirring speed) for iron precipitation from the anolyte, using the oxygen in the air, were determined. In the experiments conducted under optimized conditions, the residual concentration of iron in the anolyte after precipitation was 0.7-2.7 mg/L, and the copper and nickel losses to the solid phase were 0.05-0.07% and 0.05-0.16%, respectively. The filtration ability of the iron slurry obtained was 2 to 5 times higher as compared to that after chlorine oxidation and oxyhydrolysis. The leaching of the non-ferrous metals from the iron cake made using the separate nickel anolyte purification process was possible by dissolution in sulphuric acid. It was established that after cobalt precipitation from the copper- and iron-depleted anolyte, the precipitates obtained had lower ratios of Fe:Co and Ni:Co.

Jan 1, 2006

By J. D. Robertson

An in situ water sampling device has been developed to measure biologically-available or “labile” metals in natural waters and effluents. The active mechanism involves the use of a polyacrylamide gel layer to quantitatively control metal transfer to a trace-metal-adsorbing, gel-imbedded resin. Because the resin only adsorbs free metal ions (the gel sampler methodology is a kinetic speciation technique), and because metal bioavailability is related to the free-ion activity, the device provides a direct measure of the biological-availability of metals in the environment sampled. The prototype consists of a layer of ion-permeable polyacrylamide gel which separates the solution to be sampled from an ion exchange resin. Because approximately 90% of the polyacrylamide gel is water, mass transport through the gel is diffusion-controlled, and is therefore well defined. Metal ions are rapidly bound by the resin, creating a steep concentration gradient in the gel. The amount of labile trace metal that accumulates on the resin can be related directly to the concentration of the metal in solution, the exposure time and the molecular diffusion coefficient of the labile species. In addition, the passive nature of this device affords it the potential to address many of the limitations presented by conventional sampling methods, such as sample contamination introduced during collection or filtration and changes in trace metal speciation prior to analysis. Laboratory studies and limited field trials indicate that the sampler behaves as anticipated and illustrate that biologically- available metal concentrations in many environments are a small fraction of the total concentrations and often significantly less than the dissolved concentration. The implications of this on regulatory criteria are discussed. Additional field trials and correlation with bioassays are currently underway.

Jan 1, 2000

By W. J. Wolfe

"Quartz Hill is a large, low- to moderate-grade quartz vein stockwork porphyry molybdenum deposit, discovered in 1974 during a regional stream sediment geochemical reconnaissance survey of southeast Alaska conducted by United States Borax and Chemical Corporation. Mineralization is localized in the upper parts of an Upper Oligocene (30 Ma) composite quartz monzonite stock which is emplaced discordantly into older Cretaceous to Early Tertiary terrain of the Coast Range igneous metamorphic complex of the northwest North American Cordillera. Subsequent fault-controlled, complex multi-stage intrusion, concentrated in the core of the Quartz Hill stock, produced successive pulses of hydrothermal alteration and molybdenum mineralization at about 27 Ma. Overall, the deposit is tabular and flat-lying and well suited to open pit mining. The 0.05% MoS2 grade limit covers an area of approximately 1500 m by 2750 m and extends to a maximum depth of 520 m below surface. Details of grade distribution show two separate lobes of higher grade material within the larger low-grade deposit.A ten year program of exploration drilling, underground development, sampling and metallurgical testwork led to a 1983 feasibility study based on a resource of 1600 million tonnes grading 0.127% MoS2 at a 0.08% MoS2 cutoff The large size of the deposit and its homogeneous grade distribution, typically showing gradual outward decrease of grade, makes in pit grade selection practical at several cutoff levels. Cominco Ltd. now reports a Probable Resource of 210 million tonnes averaging 0.22% MoS2 with a further Possible Resource of 1100 million tonnes averaging 0.12% MoS:z. At low molybdenum metal prices which have persisted for 10 years since the molybdenum price spike of the late 1970s and early 1980s, the Quartz Hill deposit is sub-economic."

Jan 1, 1995

By J. S. Redpath

Eighty feet of overburden, thirty feet consisting of fine, water-bearing sands, was encountered during the construction of a shaft collar for Chimo Gold Mines Limited at its Louvicourt, Quebec, property. This paper describes the excavation and construction methods used on the project. Open-cut methods, a sheet pile cofferdam, chemical grouting and special blasting methods were used during excavation. Concrete placement was hampered in the lower portion by a heavy water flow, and aided in the upper portion by an unusual method of form bracing. Plant and • pum11ing facilities are also described.

Jan 1, 1966