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By M. R. Coffin

Since the plant startup in 1972, the leaching and jarosite precipitation circuits at the zinc plant of the Kidd Metallurgical Division have been reconfigured several times to improve overall performance, and/or to respond to market conditions. For the most part, the circuit changes have been driven by two market factors: the price of zinc and the price of silver. Until recently, circuit modifications undertaken to improve zinc extraction and recovery came at the expense of silver recovery, and vice versa. In 2004, the plant was modified once again to produce a precious metals-bearing residue, but additional leaching circuits were added to ensure that zinc extraction and recovery did not suffer as a consequence. The development of the zinc plant of the Kidd Metallurgical Division is updated in this paper, with a focus on the recent circuit modifications and associated control strategies that were implemented to maximize zinc and precious metals recoveries, and control the quality of the jarosite residue.

Jan 1, 2006

By R. B. Roberts, A. L. Mular

A simple way to determine the IEP of oxide minerals is described. The method is shown to apply for fine powders of Fe203 and ZnO. The IEP lies at pH 6.95 for Fe203 and at pH 9.08 for ZnO.

Jan 1, 1966

By Dan Marshall, David H. Watkinson

Abstract - Cobalt, Ontario, is renowned for the 12.6 billion grams (445 million ounces) of silver produced from the area since discovery in 1903 by workers of the Timiskaming and Northern Ontario Railway. Native silver generally occurs with cobalt arsenides and sulfosalts in near-vertical carbonate veins cutting the Huronian sedimentary rocks of the Gowganda Formation, the Archean metavolcanics and/or the Nipissing diabase. All major deposits have been found within a few hundred meters of the unconformity between the Archean and Huronian rocks in general proximity to the Nipissing diabase and volcanogenic sulfide mounds within the Archean meta-volcanics. Silver has been mobilized from one or more of the local country rocks by hyper-saline brines and deposited in or near zones of mixing where the saline brines encounter paleometeoric water transported to depth along the unconformity or local structures. Previous work has shown that chloride complexes are the dominant ligands responsible for silver transport. These hypersaline brines, represented as halite-bearing fluid inclusions at room temperature, have been trapped as primary fluid inclusions within vein minerals. Pressure-temperature conditions of vein formation have been derived from mineral equilibria, maximum lithostat and fluid-inclusion studies. These data are consistent with vein formation occurring over the temperature range 300°C to 350°C, with pressures constrained between 60 Mpa and 136 Mpa (600 bars and 1360 bars).

Jan 1, 2000

By I. Jackman

"Gold is present in different forms and associations in different ores. Flotation is used to recover gold and minerals associated with gold, but the applicability and type of flotation vary. The purpose of flotation in a gold recovery plant is largely dependent on the mineralogical association of the gold, and environmental and economic considerations. In this paper, the role of flotation in the recovery of gold is reviewed. The paper will describe examples of gold recovery by flotation including flotation of native gold, gold associated with sulphides including specifically copper sulphides, gold associated with tellurides, gold ores containing carbonaceous material and gold contained in tailings.INTRODUCTIONFlotation is widely used in the recovery of gold. However, the objectives and the mode of application are quite variable dependent on the type of ore, the gold association(s), other metal values, marketing considerations and environmental requirements. In this paper, a range of different applications of flotation incorporated in the recovery of gold are discussed. The reasons for each particular application are outlined and metallurgical results are presented.The mineralogy of the ore and the gold associations are fundamental influences on gold recovery. The use of flotation to concentrate gold is dictated by the mineralogy of the ore and gold. The fundamental factors are mineral/gold size, liberation size, association of the gold and type of gangue minerals or other valuable minerals. Gold can exhibit a range of sizes in a host from relatively large size (+50 µ) to refractory size (1 µ and sub-micron size). Similarly, the gold can occur in a number of phases in the same host. For example, the gold was present as petzite (AgAu telluride), calaverite (AuTe2) and native gold in a gold telluride ore and each of these minerals was associated with the pyrite host.Understanding the gold mineralogy and association is important in establishing the correct process route. The gold mineralogy is established by good mineralogy, use of diagnostic tools such as diagnostic leaching and assay by size fraction analyses and basic metallurgical testwork."

Jan 1, 1995

By J. Lee, R. G. Rosehart

"The basic problem of arsenic contamination from mine water is discussed. Effective methods of removal involving chemical precipitation, activated carbon adsorption, ion exchange and reverse osmosis are discussed. As well as an economic analysis, detail is also paid to other ions in solution which are removed simultaneously.INTRODUCTIONThe object of this paper is to review arsenic and its removal from gold extraction plant effluents. The first method considered is chemical precipitation. A second method is sorption processes, such as ion exchange resins and activated carbon adsorption. A third method is the possible application of reverse osmosis for the treatment of mine waste waters containing arsenic.Arsenic pollution in the gold mining communities of Canada and Ghana have been extensively studies (l, 2). Lynch(3) Shabunin, Gutman and Kogan( 4), Hollo, Troth, Vennes and Illinigi (5) and Hau(6) have reported their removal methods of arsenic by chemical precipitation, ion exchange and biological methods. Their conclusions were that the precipitation with Fe2+ and Fe3+ ions was most effective.Scope of the ProblemInitial aspects of this research program involved a detailed analysis of the operation of a gold extraction plant located in Canada. The name and location of the mine is proprietary information. Figure 1 gives a basic process schematic with the main tailing streams identified.Table 1 gives information as to the various mine streams and their physical and chemical composition. In this study, primary attention is paid to the removal of dissolved arsenic from waste waters. Solids from this type of operation can always be back-filled. As could be anticipated, the dissolved As content of the primary flotation tailing stream is very low. The dissolved As level in the secondary processing stream and the roasting quench water is quite high. The reason being that at this stage of the process, the arsenic has been freed from the arsenopyrite forms."

Jan 1, 1972

By G. A. Kosick, G. S. Dobby, O. Matwijenko

"A 100 kg/hr portable flotation pilot plant has been operated at Kidd Creek Mines with the objectives of:(a) determining performance expected by column flotation circuits on primary zinc and copper cleaning, and (b) evaluating column flotation circuit configurations.The self-supporting pilot plant, owned by Minnovex Technologies Inc. and operated by Minnovex and the University of Toronto, consisted of three 16 cm diameter by 6.5 m high columns and a bank of four Denver No. 7 cells. It was configurable to any arrangement using these four (or fewer) units. The columns were controlled through the use of multiple pressure transducer measurements. This paper presents the approach to testing and the results of more than 70 circuit tests. INTRODUCTIONThe integration and retrofitting of flotation columns within existing mechanical cell flotation circuits is becoming a common occurrence. The correct approach to this integration, however, is often difficult to define, due to a scarcity of previous experience and the difficulty in predicting column circuit performance. In most cases, the effect of column implementation has been experimentally assessed using a single pilot column, with the consequence that selection of an appropriate circuit to implement is difficult. Important considerations are the impact that column water addition will have on the existing operations, and the differences between mechanical cell and column performance in integrated cleaning circuits.To address the problem of circuit selection a portable flotation pilot plant, consisting of both columns and mechanical cells, was designed and constructed by Minnovex Technologies. The pilot plant was structured for complete flexibility of circuit configuration, with the intent to provide a means by which both research and plant personnel could determine the best possible column circuit configuration for a given application."

Jan 1, 1990

By P. -M. Tardif, S. Outalha, R. Le

"This paper proposes a new direction to implement an underground mine communication system. It presents actual underground communication systems and discusses their technological limits. A new system based on a wireless local area network (WLAN), together with its main systems characteristics, is then proposed. This paper also presents an experimental protocol for radio frequency propagation measurements. Finally, the paper describes the projected implementation of a WLAN in an experimental mine. IntroductionDuring the last decade, a number of Canadian mining companies have invested in modern communications systems in order to automate processes and reduce operational costs. Safety of miners is also a concern, regulated by health and safety regimes.Underground communication systems rely mainly on analog technology (especially the leaky feeder). Digital upgrades have been made to modernize this technology using a coaxial or fibre optic cable to transmit voice, documents, commands, controls, and video. Therefore, all wired equipment can benefit from an increase in efficiency from the digital technology.However, when it comes to mobile equipment, the only medium was, and is, still radio waves. With the advent of the wireless local area network (WLAN) standard, one can use a technology similar to that of the cellular phone to connect transparently different equipment. WLAN enables the transmission at rates higher than 2 M bits of voice, documents, commands, controls, identification, and of course, digital video. This technology was developed with inbuilding use in mind. Now, one can try to adapt it to underground mines."

Jan 1, 2000

By A. E. Cameron

The curve of coal production in Nova Scotia over the past forty years shows a definite maximum reached in 1913. Continued production to this maximum will require a greater tonnage per man-day, and this means there cannot be any increase in total man power used in the operations. There are still large reserves of coal but much of it will require washing or beneficiating to make a usable product. By-product recovery based on the present product ion is relatively satisfactory. Further development of secondary industries requires adequate markets for the bulk materials produced by the processing. It also requires access to other raw materials as well as markets for the principal product of the operations. Scientific investigation and research are needed to prove the quantity and value of lower grade or poorer quality coals, and methods for their recovery and utilization. Economics of further processing of present and future production must be investigated beforehand, if a successful development is to be assured. Such development cannot be expected largely to replace present markets. Production of coal for genera l use must continue to form the major function of the coal industry of the Province. Costs per ton must decrease, or subsidies or other assistance must increase, if the industry is to survive. Costs of investigation and research and costs of capital outlay for further development muse be met.

Jan 1, 1944

By Claude Bazin

"Laboratory semi-batch flotation tests were conducted using two different sulphide ore samples. The size reduction was adjusted to cover a wide range of flotation feed size distributions. Results show that similar recoveries can be achieved independently of the fineness of grind. This result suggests that possible energy savings could be achieved by a redistribution of the power between the grinding and regrinding mills. The behaviour of the selectivity curves shows that some gangue minerals are more sensitive to particle size than other ones, implying the existence of preferential associations between minerals in the ore.INTRODUCTIONInteractions between grinding and flotation have been studied for many years, and still a robust model to link the two processes lacks to be developed (Girard et al., 2005; Bazin et al., 2001). The ore size reduction liberates mineral grains, while flotation separates them into valuable minerals and gangue. The more size reduction that is applied to the ore the more important is the mineral liberation but also the production of fine particles that can pose problems during flotation (Trahar and Warren, 1976). The definition of the grinding requirement for flotation is a complex problem (Rickelton and Dell, 1977; Sosa Blanca et al., 2000; Morrison, 1993; Wei and Gay, 1999).This paper analyzes the effect of the fineness of grind using semi-batch flotation test results. The first two sections describe the test procedure and the results. The third section analyzes the results in terms of liberation and selectivity, and proposes a possible redistribution of power between grinding and regrinding mills."

Jan 1, 2006

By J. Visman

"The Compound Water Cyclone is a concentrator for the wet processing, in bulk, of finely divided materials such as slack coal, fine ores and mineral sands. It was originally developed by the Fuels and Mining Practice Division of the Mines Branch, Department of Mmes and Technical Surveys, Ottawa, for the cleaning of friable slack coals and slurries.Since its introduction in the coal industry in 1962, its application to other materials has also been studied, with special emphasis on simplicity of operation and low over-all cost per ton of finished product .In this paper, a description is given of commercial two-stage units presently available for the processing of granular materials, including wastes a1:1d other low-grade products. A pneumatic control system is used for operating the cyclone under back pressure .and for automatic cut-point adjustment. An account is given of results obtained on coal mineral sands and ores in the Wes tern Regional Laboratory of the Department of Mines and Technical Surveys. Results of several industrial applications are discussed."

Jan 1, 1966

By Willem P. C. Duyvesteyn

"Scandium International Mining Corp (SCY) has been involved in the commercial development of its Nyngan Scandium Project for about ten years. Various studies at a variety of global R&D organizations have been carried out in an attempt to define the deportment of scandium in both the limonite as well as the saprolite phases of Nyngan ore to assist with process development. Technologies such as sulfuric acid baking, high pressure acid leaching, sulfuric and hydrochloric acid atmospheric leaching and heap leaching have been extensively investigated both at the bench and pilot scale level to arrive at the most economic process flow sheet that will be discussed in some detail in this paper. Solvent extraction, ion exchange and other refining technologies have been tested and an optimum configuration has been established for the Nyngan project which is expected to be the first primary scandium mine and metallurgical plant in the world.Because of a lack of product availability the current scandium market is limited to less than 20 tons per year. Technologies have been identified to produce product with different specifications for aluminum alloys and solid oxide fuel cell applications. Preliminary economics have identified that Nyngan will be a robust and low capital cost project that can readily be expanded as the size of the scandium market increases."

Jan 1, 2016

By W. E. Davies

"This paper is the sequel to that on Developments in Sintering Efficiency delivered by Davies and Mitchell at the International Ore Dressing Congress, Stockholm, 1957. Attention is drawn to the fundamental concept of sintering as a heat transfer process, in which the ignition heat is continually transferred onward through the bed as a heat wave. By its passage, this heat initiates endothermic 'changes, such as carbonate decomposition, whose energy requirements are supplied by the combustion of the fuel contained in the bed.Ideally, the heat wave should be generated by the ignition hood followed by the pre-heating of the incoming air. The fuel content of the bed should be no more than the theoretical quantity needed to balance the endothermic changes. In practice, the heat wave is seriously short of energy and this is offset by excess fuel in the bed. As a result, sinter quality suffers, more return .fines are produced, and fuel is wasted, a loss of efficiency which could be avoided if the fundamentals of correct ignition were more widely appreciated.Sintering speed, otherwise heat wave velocity, is a function of the rate at which the incoming air acquires .heat from the cooling sinter and imparts it to the unburned feed below the combustion zone. It is thus a function of rate of air flow and so depends on bed permeability>. Ways of• improving and maintaining permeability at the maximum consistent with thorough sintering are discussed, particular reference being made to taconite concentrates. The possibilities of recrystallizing refractory ores into forms more amenable to physical concentration techniques by sintering are visualised, very little expenditure on heat energy being required when the process is operated near the ideal conditions."

Jan 1, 1960

By Owen Matthews

THE property of Cochenour Willans Gold Mines, Limited, is in Dome township, Red Lake area, northwestern Ontario, a hundred miles north of Kenora and close to the Manitoba border. 'Planes of Canadian Pacific Air Lines, Limited, serve the district daily, except Sundays, from Kenora, Ontario, and Lac du Bonnet, Manitoba, passengers being trans-ported from Winnipeg to Lac du Bonnet by car. Freight is handled by the Patricia Transportation Company. It is brought in from Hudson, Ontario, on the Canadian National railway, in summer by water and in winter by tractor trains over the frozen lakes. The first staking on the property was done during the 'rush' of 1926 and 1927 by William M. Cochenour, and on April 30th, 1928, a syndicate was formed, taking in claims of W. M. Cochenour and Dan Willans and H. G. Young. Surface trenching was carried on almost continuously until 1934. In October, 1932, Ventures Limited took an option on the property, and in December of that year they carried out an extensive diamond drilling programme, but considering the results did not justify further work, they relinquished the option. In July, 1934, further surface work was carried out under the supervision of W. P. Mackle and, on the strength of his report, Noah Timmins Incorporated took an option on the property and agreed to make an initial expenditure of $100,000 on development work. This was carried out under the direction of Hollinger Consolidated Gold Mines and included the sinking of a shaft to a depth of 165 feet, establishment of a level at the 150-foot horizon, and some 1,900 lineal feet of drifting and cross-cutting. The results obtained from this work were not considered of sufficient promise and the option was terminated in August, 1935. Mr. Cochenour then approached Alex Mackenzie and associates, and the present Company, Cochenour Willans Gold Mines, Limited, was organized on April 9th, 1936, and sufficient money was raised to continue operations. Under the direction of W. P. Mackle, the shaft was deepened and a second level was established at the 275-foot horizon; but, due to several adverse reports by outside engineers, it was found impossible to raise sufficient money to carry on the work and operations were suspended in December, 1937. In January, 1939, an agreement was entered into with Gold Eagle Gold Mines for the milling in their plant of some Cochenour ore. A total of 4,959 tons was treated, and the results were so encouraging that further finances were raised by C. A. Gentles & Company, of Toronto. Following further development in the mine, it was decided to erect a mill. Construction was started on September 1st and the mill was turned over on November 29th. The first gold brick was poured on December 23rd.

Jan 1, 1942

By R. O. Burt

"Gravity Concentration, the oldest form of Mineral Processing, remains of major importance to the Industry. Current applications of Gravity Concentration are briefly examined.The Paper details one approach to the development of a Gravity Concentration Plant, from laboratory and mineralogical techniques, through Pilot Plant testing, where applicable, to the actual design of the plant.INTRODUCTIONGravity Concentration, once the major method of concentrating minerals has, for much of the twentieth century been regarded, like the dodo bird, as obsolete. However, in more recent years it is enjoying something of a renaissance, and is once again being treated as a useful, economic alternative in the Mineral Processing Engineers' arsenal.An indication of the broad application of gravity concentration is the variety of minerals presently recovered. A list is given in Table 1; this list is not exhaustive."

Jan 1, 1984

By M. Massinaei, M. R. Yarahmadi, S. Zeidabadi, M. Oliazadeh

"Although the majority of new flotation column installations continue to be for cleaning or recleaning, an increasing number of flotation projects are specifying columns for roughing or scavenging duties. NICICO has recently installed flotation columns operating in rougher, cleaner and re-cleaner circuits at three new copper concentrators; Miduk, Sungun and Sarcheshmeh. Miduk is probably one of the unique operations that use flotation columns in a rougher circuit. The Miduk rougher circuit comprises five CISA parallel columns. The rougher concentrate constitutes 88% of final concentrate and reports to concentrate thickener. The rougher tailings are scavenged with ten 50 m3 mechanical cells. The scavenger concentrate is then reground and cleaned in three 3.2 m columns in parallel. The cleaner tailings are scavenged in six 50 m37mechanical cells. The cleaner tailings along with the rougher scavenger constitute final tailings.In Sarcheshmeh, the cleaner concentrate is re-cleaned in a column. The column tailings are sent back to the cleaning circuit and the concentrate is reported to the concentrate thickener.This paper reviews performance details of the flotation columns utilized in rougher circuits at Miduk and compares their metallurgical performances in an industrial scale with columns at cleaning circuits for copper flotation. Practical limitations for applying the flotation columns in rougher circuits will be discussed in details.INTRODUCTIONThe use of flotation columns has grown rapidly since the first successful commercial application at Mines Gaspe, where columns were used in a cleaning circuit to float molybdenite. Early applications of columns were restricted to replacing or adding final cleaning stages in existing circuits. Columns can achieve superior cleaning as compared to conventional cells due to their ability to support a large froth depth and the use of water for washing froth. Wash water travels down through the froth and crosses the pulp/froth interface, replaces the entrained particles reporting to the froth from pulp and improve the concentrate grade."

Jan 1, 2011

By Tony Moore, Peter Riccio

"MMG (Minerals and Metals Group) operates the LXML Sepon’s mineral processing facility located 40 kilometers north of the town of Sepon, in the Savannakhet Province, Lao PDR. The Sepon copper plant produces 70,000 tons/year of LME grade A copper cathode using leachautoclave- SX/EW-flotation technology (Baxter et al., 2003). Pyrite recovery in the flotation circuit is critical to the operation, as it is used to generate acid and soluble ferric ion for the leach circuit. Low pyrite recovery has been an on-going challenge in the flotation circuit. Final tailings characterization work done by Ian Wark Research Institute (Bassell et al., 2006) showed that the pyrite losses to the tailings are made up of a combination of coarse liberated particles and finer particles that have been coated by clay fines.In December of 2005, a joint Cytec-MMG technical program was initiated to address the pyrite recovery issue. A series of diagnostic tests were performed in the Cytec Stamford Research Facility using synthetic plant water showing that the collector was precipitating as a metal salt and was unavailable for mineral attachment. The tests also identified several collector chemistries that would likely be robust in the low pH (< 1), high dissolved metal ion environment and will not complex with metal ions in solution. With the support of the Sepon on-site engineers, an extensive, successful laboratory program was completed, which was subsequently followed by on-plant testing that showed a step wise improvement in pyrite recovery.INTRODUCTIONLow pyrite recovery has been an ongoing problem in the flotation circuit at Sepon. Sulfur recovery (indirect measure of pyrite) was improved from 40% to 65%-75% in mid-2005 when on site laboratory work confirmed that AERO® 8045 Promoter was a more effective collector then AERO® 407 Promoter. However, sulfur recoveries above 65% could never be achieved. Sepon requested the Ian Wark Research Institute to complete a surface analysis study using Scanning Electron Microscopy, X-ray Photoelectron Spectroscopy, and Time-of-Flight Secondary Ion Mass Spectroscopy to determine if clay coated pyrite played a role. It was concluded that the pyrite losses to the tailings are made up of a combination of coarse (+ 100µm) liberated particles and finer (-74µm) particles that have been coated by clay fines. The majority of the losses appear to be due to the former. In December of 2005, a series of diagnostic tests were performed in Stamford using synthetic plant water in order to identify what chemistries would likely be robust in the slimy low pH and high dissolved metal ion solution environment. Results showed that several chemistries would not complex with ferric, ferrous or copper in solution and therefore should perform well in the Sepon flotation. The incumbent collector, AERO® 8045 Promoter was complexing with metal ions in solution. This resulted in the collector not being available for adsorption onto pyrite."

Jan 1, 2011

By T. Belem

The main objective of this study is to better understand the effect of underground CPB placement conditions on its microstructural, hydro-mechanical and geochemical properties. To reach this objective, three PVC columns, each 3 m high, were built, and were filled with CPB material. The columns allow simulating undrained (UD), half-drained (HD) and fully-drained (FD) conditions along with the measurement of resulting self-weight consolidation settlement of the CPB. Bleed and drainage waters were also collected from each column for geochemical analyses (pH, Eh, EC, SO42- content). After 90-days of curing time, a total of sixty CPB samples were cored from the backfill columns and subjected to uniaxial compression tests followed by physical characterization (Gs, void ratio, water content, degree of saturation, specific surface area). The results showed that the total drainage water and the maximum observed settlement occur mainly within the first 72 hours after the columns are filled. The corresponding volumetric strains suggest that in situ backfilled stopes simulated behave in a similar way to the fully-drained (FD) or the half-drained (HD) conditions. The MIP test results show that the pore structure varies between the top and the bottom of each column.

May 1, 2007

By R. E. Jones

"Crusher sizing and application in mining operations is the selection of a crusher or a series of crushers to reduce run of mine ore to a size suitable for either autogenous or conventional grinding. It is important that the crusher or crushers be sized to operate within the range to which they have been designed. By the range to which they have been designed, we mean that the reduction ration must be held between specified limits. Reduction ration is the relationship between feed size to product size.In todays plants reduction is usually accomplished in three stages by primary, secondary and tertiary crushers.Primary crushers are either jaw or gyratory and are designed to handle run of mine feed at an open side setting of 5-1/2” to 7”. Reduction ration should not exceed 7 to 1.Jaw CrushersThe model size of a jaw crusher signifies the feed opening. A model 60 x48 jaw has a feed opening 60” wide by 48” long. The 48” is the dimension between the top of the swing jaw and the top of the stationary jaw. The 60” is the width between the two side frames. The crusher open side setting is the discharge opening at the bottom of the crushing chamber with the jaws in an open position. When corrugated jaw plates are used, the open side setting is measured from tip of one jaw plate to the valley of the opposite jaw plate. If a jaw crusher has a 6” open side setting with a 1” jaw motion, you could also say it has a 5” closed side setting."

Jan 1, 1974

By H. E. Grier, H. H. Aronson, H. F. Coffer

"Nuclear explosions are currently being planned for use in oil and gas production, the recovery of oil from oil shale, gas storage and copper leaching. The current status of each of these projects is discussed, with emphasis on the economics of each application. The first commercial application of nuclear explosives will be in gas stimulation. Project Gasbuggy will be rapidly followed by two additional shots, also related to gas production. These three events, each in a different formation, will be described in this paper with a discussion on their significance to the world's oil and gas industry. The use of nuclear explosives in oil and gas stimulation should be a standard accepted practice within a few years. Calculations based on explosions in media such as tuff, alluvium, granite and dolomite predict large increases in productivity when nuclear devices are used in tight, thick formations. The broken-up rock resulting from the explosion becomes the new well bore, with a production rate of six to twelve times that of a normally completed well.Also included in the paper is a discussion of the real or possible problems associated with nuclear explosive engineering. The only major foreseeable problem is the seismic shock wave. This limits the size of explosive which can be used near important surface structures. A discussion is included on the radiation problem, which we believe to be largely psychological in the case of contained explosions."

Jan 1, 1968

By Andre L. De Vegt, Cees J. N. Buisman

"For the past eight years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Metal and sulfate can be removed from mine waters using two biological steps:1. Sulfate reducing bacteria convert sulfate to hydrogen sulfide (H2S). The H2S reacts with the dissolved metals to form insoluble metal sulfide precipitates.2. Sulfide oxidizing bacteria convert excess H2S to elemental sulfur.Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove metals and sulfate as described above. The system has been operating since May 1992 treating a flow of 5000 m3/d. A test program, utilizing a large scale pilot plant, will commence in November 1995 at a copper mine in the U.S.A. to remediate groundwater contaminated with sulfate and heavy metals. Biological reactor performance and selective metal recovery will be studied. Sulfur dioxide (S02) can be removed from fluegas using a combination of scrubber technology and the two biological steps. The end product is elemental sulfur. A commercial size biological desulfurization plant has been in operation since July 1994 treating 50,000 Nm3/h of fluegas. Sulfide can be removed from mining waters or anaerobic wetlands using a THIOPAQ® Sulfide Oxidizing reactor.lntroductionSulfur can be present in various water and gaseous streams in a mining operation. In many cases the sulfur compounds have to be removed because of toxicity, corrosive properties and contribution to acid rain. Mine waters can contain dissolved heavy metals. An efficient way to remove dissolved metals removal is the precipitation as metal sulfides. Paques has developed and installed treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. These treatment systems biologically convert sulfate to hydrogen sulfide (H2S) which can be used in heavy metal precipitation. Excess H2S is biologically converted to elemental sulfur. This paper provides an overview of these newly developed biotechnological treatment systems."

Jan 1, 1997