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By J. Autio, H. Malmlund

The excavation damage zone (EDZ) caused by drill and blast excavation consists of intense damage adjacent to the remaining half barrel of the blast hole, new fracturing induced by the blast and reactivation of pre-existing fractures. The properties of intense microfracturing adjacent to the half barrels of remaining blast holes are based on study of rock samples from ZEDEX-tunnel and it’s extension at Äspö and the Research tunnel at Olkiluoto in Finland. The new and reactivated fracturing is based on results of mapping of slots cut in the rock in ZEDEX-project. The zone of increased porosity adjacent to half barrels, which penetrates to a depth of some centimeters was studied by using novel 14C-PMMA method. The penetration of the radial fractures, which is an order of magnitude deeper, was studied by mapping using color penetrant. Results of EDZ studies carried out at Äspö HRL in Sweden and in Research Tunnel at Olkiluoto show that the properties of EDZ can be affected significantly by engineering design. The result imply that the additional pore volume caused by distinct fracturing around the blast holes caused by state-of-the-art smooth blasting technique could be of the same order as that of the damaged zone adjacent to the surface of the half barrels. Durch Bohr- und Sprengarbeiten entstandene Eigenschaften der Auflockerungszone: Die durch Bohr- und Sprengarbeiten entstandene Auflockerungszone besteht aus einem großen, an das Resthalbrohr des Bohrloches angrenzenden Schaden, neuer Rissbildung und einer Reaktivierung der bereits existierenden Risse. Die Eigenschaften einer immensen, an die Halbrohre der Restbohrlöcher angrenzenden Mikrorissbildung beruhen auf einer Studie über die aus dem ZEDEX-Tunnel gewonnenen Gesteinsproben und deren Fortsetzung im Untertage-Labor Äspö (Hard Rock Laboratory, HRL) in Schweden und im Forschungstunnel bei Olkiluoto in Finnland. Die neue und reaktivierte Rissbildung basiert auf den Auswertungsergebnissen der Schlitze, die bei dem ZEDEX-Projekt ins Gestein geschnitten wurden. Die Zone der vermehrten, an die Halbrohre angrenzenden Porösität, die in ein paar Zentimeter Tiefe eindringt, wurde anhand der neuen 14C-PMMA-Methode untersucht. Das Eindringen der etwas tiefer gelegenen radialen Risse wurde anhand eines farbigen Eindringungsmittels untersucht. Die in Äspö und Olkiluoto durchgeführten EDZ-Studien zeigen, dass die EDZ-Eigenschaften wesentlich durch Engineering Design beeinflusst werden können. Das durch Bohrarbeiten verursachte Hohlraumvolumen der Rissbildung um den Tunnel herum ist ähnlich wie das Hohlraumvolumen der Bruchzone um die Bohrlöcher herum. Caractéristiques d’une zone endommagée par le creusement résultant d’un creusement par forage et dynamitage: La zone endommagée par le creusement résultant d’un creusement par forage et dynamitage présente un endommagement intense adjacent au demi-cylindre restant du trou de mine, une nouvelle fracturation et la réactivation des fractures préexistantes. Les caractéristiques de la microfracturation intense adjacente aux demi-cylindres des trous de mine restants reposent sur l’étude des échantillons de roche en provenance du tunnel ZEDEX et de son extension au laboratoire souterrain d’Äspö (« Hard Rock Laboratory » ou HRL) en Suède et du tunnel de recherche d’Olkiluoto en Finlande. La fracturation nouvelle et réactivée repose sur les résultats du placement des rainures sur la roche dans le projet ZEDEX. La zone de porosité accrue adjacente aux demi-cylindres et pénétrant à une profondeur de quelques centimètres à fait l’objet d’études recourant à la nouvelle méthode 14C-PMMA. La pénétration des fractures radiales, considérablement plus profondes, a été étudiée par placement en utilisant un agent pénétrant coloré. Les résultats des études EDZ effectuées à Äspö et à Olkiluoto montrent que les caractéristiques de l’EDZ sont susceptibles d’être affectées de manière significative par la conception technique. Le volume vide de fracturation résultant du dynamitage autour du tunnel est du même ordre que celui de la zone concassée autour des trous de mine.service.

Jan 1, 2003

By L. A. Cornish, I. A. Mwamba, R. A. Couperthwaite

"In previous work by the authors, it was established that additions of 0.2 at.% Ru to an Fe-40 at.% Al alloy improved the corrosion and oxidation resistance of the alloy. The alloy was produced by mechanical alloying and spark plasma sintering and the work showed that nonequilibrium processing was able to significantly refine the grain size of the material. The sintered material had a higher hardness than the as-cast material and the change in grain size did not significantly affect the oxidation and corrosion. In the present research, the mechanically alloyed powder was coated onto a mild steel substrate using cold-spray coating at a gas pressure of 10 bar and a temperature of 500°C. The coatings were found to be 5–10 um thick, although thicknesses of up to 30 um were observed. The coated materials were subjected to oxidation and corrosion tests to determine the effectiveness of the coating in increasing the oxidation and corrosion resistance of mild steel. This was done to determine the effectiveness of cold-spray coating as a technique to coat these mechanically alloyed powders. IntroductionPrevious work conducted by Mintek (Couperthwaite et al., 2013, 2015) investigated the effect of precious metal additions on the structure, oxidation and corrosion properties of an Fe-40 at.% Al (Fe- Al) alloy. Initial work determined that additions of more than 0.5 at.% precious metal did not improve the oxidation and corrosion properties of the materials and in some cases even decreased the resistance to corrosion. Further work identified Pt and Ru as beneficial additions to the FeAl alloy. Four alloys were then produced by mechanical alloying and sintering (FeAl–0.2 at.% Pd, FeAl–0.2 at.% Ru, FeAl–0.5 at.% Ag, FeAl–0.5 at.% Pt). These alloys were all successfully produced by melting and casting and mechanical alloying sintering and it was found that the nonequilibrium processing greatly decreased the grain size of the materials compared to the ascast materials. It was found that the additions of Ru and Pt were still the most beneficial to the oxidation and corrosion properties, with Ru being considered the most beneficial."

Jan 1, 2016

By C. Tokoro, T. Kato

The objective of this study is to improve the shrinking core model for particles with a particle size distribution and clarify the activation mechanism of rare earth elements dissolution by mechanochemical activation. To achieve this objective, the method, called the doubly integrated micromodel, was applied for a shrinking core model in this study. This method consists of integrating the batch leaching rate of a single particle over the distribution of both feed particle size and reactor residence time to arrive at the fraction unleached. The usefulness of the shrinking core model improved by doubly integrated micromodel was confirmed by comparing it with a shrinking core model. To apply the shrinking core model improved by doubly integrated micromodel to rare earth elements dissolution from weathered residual rare earth ores by mechanochemical activation, leaching experiments were performed for grinding samples by planetary ball milling. The reaction equation of mechanochemical reaction by planetary ball milling for weathered residual rare earth ores was investigated by x-ray absorption fine structure analysis. As a result of a kinetics study, the rate-determining process of leaching changed from reaction to diffusion reaction control by planetary ball milling. Based on these results, it was revealed that the main mechanism of activated rare earth elements dissolution from weathered residual rare earth ores was a mechanochemical reaction by planetary ball milling. Keywords: Mechanochemical reaction, particle size distribution, shrinking core model

Jan 1, 2020

By K. C. Corin, M. Tadie, N. Ndamase

Fresh water conservation efforts and strict environmental regulations have forced the mining industry to reduce freshwater consumption and effluent discharge. This is achieved by recycling process water back to mining processes. The performance of flotation circuits depends on the pulp chemistry. When process water is recycled to flotation cells, organic and inorganic species that have accumulated over time alter the pulp chemistry. The presence of accumulating ionic species such as SO4 2- and S2O3 2- has been found to hinder the adsorption of collector ions onto mineral surfaces. Sulphide minerals are semi-conductors; electrochemical reactions take place on their surfaces. The adsorption of collectors onto mineral surfaces takes place via electrochemical reactions. This study, therefore, aims to investigate how the presence of accumulating ionic species at varying ionic strengths affects the adsorption of sodium ethyl xanthate onto chalcopyrite from an electrochemical perspective. Synthetic plant water comprised of single salts with varying ionic strengths was used. Rest potential measurements were conducted to investigate collector-mineral interactions in the presence of these ionic species. Microflotation tests were performed to determine whether the presence of these ionic species affects mineral floatability. Higher chalcopyrite recoveries were achieved in the presence of SO4 2- than in the presence of S2O3 2-. Rest potential measurements were found to successfully predict microflotation performance in the presence of the ions of interest. Keywords: Flotation water quality, electrochemical adsorption; xanthate collectors

Jan 1, 2020

Book reviews Natural gas substitutes from coal and oil, by S.A. Qadar. Amsterdam, Elsevier Science Publishers, 1985. U.S.$83.25. Reviewer: U. Grimsehl High heat production (HHP) granites, hydrothermal circulation and ore genesis. London, The Institution of Mining and Metalurgy, 1985. 593 pp. £30. Reviewer: S.A. de Waal 2. Recent publications Uranium recovery from phosphates and phosphoric acid, by S. Huwyler. 3rd edition. Wirenlingen (Switzerland), Swiss Federal Institute of Reactor Research, EIR-Bericht (C) no. 1. Apr. 1985. 56 pp. Geological aspects of mining productivity. Canada's base metal resources, by B.W. MacKenzie. Kingston (Canada), Centre for Resource Studies, Queen's University, Technical Paper no. 6, Aug. 1985. 115 pp. $10.Taxation policies in the Canadian minerals industry, edited by M. Wojciechowski. Kingston (Canada), Centre for Resource Studies, Queen's University, 1985. Mineral policy update 1984: Policy and program changes afecting the Canadian mineral industry, by M.l. Wojciechowski and M.L. McAlister. Kingston (Canada), Centre for Resource Studies, Queen's University, 1985. $12. 3. Mintek reports Report MU7 The selective solvent extraction of pal/adium by the useof di-normal hexyl sulphide. Report M218 Modification of the design of screen boxes for carbonin-pulp and resin-in-pulp plants. Report M225 The commissioning, operation, and maintenance of an on-line corosion-monitoring station for the mining industry. Report M231The determination of selected lanthanoid elements by atomic-absorption spectroscopy using electrothermal atomization. Report M233 A computer programme for the prediction of hydrocyclone performance, parameters, and product size distributions. Report M234 The solvent extraction of base metals by mixtures of carboxylic acids and non-chelating oximes. 6 The efect of particle size and coloid stability on the wet high-intensity magnetic separation of uranium from cyanidation residues. Report M238 The beneficiation of fine coal. Report M240 The spectrophotometric determination of tin in silicates and tungsten-bearing materials. Report M242 Wear and performance of materials in pipelines for the hydraulic conveyance of fused ash. IPMI award for distinguished achievementThe International Precious Metals Institute has announced that Professor Henry C. Taube, Nobel Laureate, wil be the recipient of their 1986 Distinguished Achievement Award. Dr Taube is Professor of Chemistry at Stanford University, Palo Alto, California.

Jan 1, 1986

By Y. Jiao, V. S. Thompson, D. W. Reed, Y. Fujita, J. E. Aston

Rare earth elements (REE) are vital components in modern electronics and green technology products. Supply is tight and global demand is expected to increase, leading to high risk for the economic and national security of countries largely dependent upon foreign supplies. Recycling of REE from consumer and industrial waste materials is a possible way to help meet demand. We have shown previously that biohydrometallurgy can play an economically and environmentally sustainable role in REE recycling, particularly if agriculture or food wastes are used to produce organic acid bioleaching agents. A challenge for organic acid-based bioleaching is the incomplete conversion of the carbon substrate to an optimal organic acid biolixiviant with high REE extraction capability from a variety of REE-containing feedstocks (e.g., mining wastes, magnets from end of life products, spent batteries, etc.). To help meet this challenge a metabolic model was developed for Gluconobacter oxydans to identify options for improving sugar conversion to organic acids. Model predictions were consistent with laboratory data for the microbial consumption of glucose and production of gluconic acid, and suggested that providing growth conditions with relatively high C:N molar ratios could result in lower pH biolixiviant production and thus improve bioleaching. Keywords: Gluconobacter oxydans, bioleaching, metabolic modelling, rare earth elements summaries 2019: U.S. Geological Survey, 200 p., https://doi.org/10.3133/70202434.

Jan 1, 2020

By M. Krasowska, W. Skinner, R. K. Asamoah

Understanding chemical interactions at solid-liquid interfaces have played a pivotal role in improving mineral flotation performance, increasing the rate of mineral crystallisation and profitable leaching of valued minerals and metals. This paper highlights gold leaching with links to surface and interfacial chemical processes occurring, and opportunities to maximise extraction while reducing usage of more recent scarce resources. From the review, there is a significant link between surface and interfacial processes and gold leaching performance. Evidently, gold leaching kinetics could be increased by changing leaching conditions, including manipulating the surface and interfacial interactions. Control of surface and interfaces during gold extraction could enhance rapid, smarter gold extraction and mitigate formation of passivation layers. Keywords: Surface and interfaces, refractory ores and concentrates, gold leaching, reaction mechanism and kinetics

Jan 1, 2020

By M. L. Mahlatji

Mechanical alloying of an equiatomic mixture of crystalline Ti and Pt elemental powders in a high-energy ball mill formed an amorphous alloy by solid-state reactions. Mechanical alloying was carried out in an argon atmosphere at a rotation speed of 1200 r/min and a 20:1 ball-to-powder weight ratio, for time intervals of 4 to 40 hours. At an intermediate stage of mechanical alloying, scanning electron microscopy showed the formation of characteristic layered structures of inhomogeneous composition within the powder particles. X-ray diffraction analysis showed the gradual disappearance of crystalline Bragg peaks and the emergence of broad amorphous maxima as milling progressed. The amorphization process was completed after 8?12 hours. The amorphous state of the product indicated that temperatures during processing did not exceed the crystallization temperature of the alloy.

Jan 1, 2014

By S. A. Ghoreishi-Madiseh, F. P. Hassani, H. Rafezi, H. R. Manouchehri, A. Shadic, A. P. Sasmito

Weakening rocks by taking advantage of microwave-induced microcracks is a promising solution for comminution processes. This paper investigates the effects of microwave treatment of the rock/or samples in single and multi-mode cavities. Based on the experimental results of using a 2.45 GHz microwave generator, the performance of different cavity setups and their impact on the energy effectiveness of the microwave irradiation was examined. Physical interpretations were drawn from multiple experiments with a relatively wide range of power rates and exposure times. Both basalt and kimberlite samples were used in experiments, and their results were systematically compared. For single-mode cavity tests, a microwave applicator waveguide antenna was placed at different distances from the samples to evaluate the effects of sample positioning on microwave heating, both numerically and experimentally. Eventually, cavity performance was assessed by using calorimetric test results, and strength decay was documented based on the spallation of the samples. It was found that the singlemode cavity setup has unique properties that can significantly improve the electromagnetic heating and therefore, strength degradation process. Keywords: Microwave, fragmentation, energy effectiveness, calorimetry, mine-to-mill

Jan 1, 2020

By D. K. Weatherley, T. P. Oladele, L. B. Bbosa

Comminution is a critical stage of mineral processing which aims to reduce the size of ore particles through breakage, consequently increasing the likelihood of liberation of valuable minerals. Several factors, such as pre-existing cracks, mineralogical composition and particle size, are known to affect ore breakage behaviour. While investigating the contributing role of each factor is essential to improve understanding of breakage, isolating individual factors by experiment is typically impractical. Numerical techniques such as the Bonded Particle Model-Discrete Element Method (BPM-DEM) have been developed as a means of studying closely controlled breakage conditions. This study evaluates this technique in modelling the effect of pre-existing cracks breakage behaviour for synthetic ore specimens during impact breakage in a short impact load cell (SILC). Synthetic ore was modelled as a collection of discrete entities connected by brittle-elastic beams. Model parameters were calibrated against macroscopic material properties of a conventional homogenous synthetic ore. The extent of pre-existing cracks within specimens was prescribed by varying discontinuities between the connecting entities. An approach with the insertion of seed points was used to model the mineralogy of the specimens. Results showed that pre-existing cracks resulted in a decrease in the fracture force as the crack density increased. Additionally, the irregularity of fracture patterns within rock specimens after impact became more apparent as the crack density increased. The findings were used to emphasise some of the attributable causes of the variation observed between ore hardness characterisation tests and in situ ore behaviour. Keywords: Element Method; Bonded Particle Model, synthetic rock sample; rock fracture, preexisting cracks

Jan 1, 2020

By A. G. Royle

The reasons for constructing a model of an orebody for which both the parent population and the sampling distribution are known are discussed and details of the model are given. A brief summary of Matheron's theory of regionalized variables is included, with particular reference to his kriging estimators and their variances. Using the model, a comparison is then made between these kriging estimators and other commonly-used estimators. These are compared to find the one with the minimum variance, and an analysis is included to investigate whether any of the estimators is biased. Also included is a comparison between theoretical and experimental variances for some of the estimators.

Jan 1, 2014

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

A brief overview is given of the issues regarding the processing of waste electrical and electronic equipment (WEEE). The printed circuit board component of WEEE is an exceptionally complex feed to possible recycling processes. Scrap printed circuit boards were selectively smelted at 1 200°C to produce a metallic alloy. Iron and aluminium were found not to be part of the alloy. The alloy was characterized by SEM-EDS, and three phases were identified: alpha and delta bronzes, and a lead-rich phase. Calculations show that about 56 mass per cent of the alloy is the alpha phase, 35 per cent delta phase and 9 per cent lead phase. A simplified approach using appropriate binary phase diagrams was used to derive a phase composition for the alloy. This was further backed by FactSage calculations, which showed that the simplified approach was appropriate for this alloy. The experimental findings and theory were found to agree well.

Jan 1, 2009

By M. Andersson, R. Elsrud

The quality and the production rate for the mining operations in the Garpenberg mine has been much improved due to a new system, that presents the latest exploratory and planning data for the driller at the moment he deploys the drill rig at the face. Other components in this improvement work are better planning procedure, large-scale production system with longer rounds and introduction of new drill rigs in the mine. The new Rig Control System (RCS) for the new series Atlas Copco Boomers L2C has made it possible to develop this system for production drilling in the Garpenberg mine. The ABC Regular has been extended with map navigation and drill plan generator. The driller will have the best estimate of the orebody in front of him and the best drill plan for that orebody. The customer’s specific system will also become a standard Atlas Copco product for the Boomer ABC drill rig family.

Sep 1, 2001

Prediction of the performance of explosives In bench mining by C. M. LOWNDS, B.Se. Hons (Rhodes), Ph.D (Cape) (Visitor) Some of the problems encountered in the calculation of the relative weight strength of explosives are discussed, and a realistic model of the behaviour of explosion products in a borehole is proposed. The heat flow from condensed to gaseous products is calculated as a function of time, and the relationship between the pressure and the volume of the product gases is found by a consideration of the compression of the rock between radial cracks. Work done on the burden is assumed to cease when the cracks first appear at the face. Reasonable values of burden and crack velocities are obtained from the model. Calculations of the relative weight strengths of aluminized mixtures of ammonium nitrate and fuel oil show that the increased density resulting from the addition of aluminium is the main advantage to be gained.

Jan 2, 1975

By G. Gafner

The paper gives the reasons for the development of a gold alloy of 990 fineness with good colour, durability, and mechanical properties, and explains why titanium was chosen as the alloying metal. Methods are described for the alloy?s production, solutionizing, and age-hardening. Mechanical properties are given as a function of deformation, age-hardening time, and temperature for three different starting states, and these properties are compared with those of some standard 14 and 18 ct jewelery alloys and pure gold. The effects of various salts and fluxes on the composition of the alloy after heat treatment at 1150, 800, and 500°C are discussed. These indicate how alloy scrap can be refined to pure gold, and how solutionizing and agehardening can be conducted without the use of vacuum equipment. The results of wear tests indicate that the alloy is more durable than normal coinage and jewelery alloys. Tips are given on the grain refining, soldering, and casting of the alloy.

Jan 1, 1989

As a token of their gratitude, former pupils of Professor Lucien Denoel, a lecturer on coal-mining in the University of Liege, over a period of forty years, have founded the LUCIEN DENOEL prize. It is awarded, regardless of nationality and diplomas, to the author of a thesis dealing with coal-mining, ventilation, mine-draining methods, the use of explosives in the mine or coal-preparation. The thesis must show a truly scientific approach and considerable originality, and must not have been dealt with in a previous publication. The prize is 60.000 Belgian francs. The articles must be written in French, Dutch, German or English, and contain not more than 10,000 words, figures included. They must be forwarded, in triplicate, to the 'Jury du Prix Lucien DENOEL, c/o A.I.Lg., 22, rue Forgeur, Liege, Belgium,' before 1st July, 1970. The examining board reserves the right to publish the winning thesis in a Belgian magazine.

By C. Chapman, M. G. Reading, M. P. Amsden

Computer control of flotation at the Ecstall concentrator By M. P. AMSDEN, C. CHAPMAN, and M. G. READING Ecstall Mining Limited, a subsidiary of Texas Gulf Sulphur Company, operates the Kidd Creek Mine, a 10000 tons per day base metal producer, near Timmins, Ontario. Two different types of ore are mined and milled: copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous on-stream X-ray analysis. Recently this system was automated further by the addition of computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery by 1,1 per cent, zinc recovery by 1,4 per cent, and have reduced reagent costs by 16 per cent. Although not expected, copper and zinc concentrate grades were improved slightly as well.

By P. R. Jochens, D. D. Howat, M. S. Rennie

The slags arising from ferrochromium plants were simulated by additions of CaO and Fe2O3 (6 per cent each), Cr2O3 (7 and 12 per cent), and Fe2O3 and Cr2O3 together (6 and 12 per cent respectively) to slags in the MgO-Al2O3-SiO2 system. These additions were made to slags having an SiO2 content of 45 per cent and an MgO-to-Al2O3 ratio of 4 to 3 or 3 to 4. The effect of these oxide additions on the liquidus temperatures, electrical conductivities, and viscosities was determined. The additions of CaO and Fe2O3, although having little effect on liquidus temperatures, decreased viscosity and increased electrical conductivity. The addition of Cr2O3 raised the liquidus temperatures considerably, and tended to decrease viscosity in the temperature range 1 700 to 1 800°C and to increase electrical conductivity.

By T. Groenewald

Potential applications of thiourea In the processing of gold by T. GROENEWALD, Ph.D. (Rand), D.I.C. (Imperial College) (Visitor) The aqueous chemistry of gold(l) that has found practical application is mainly the chemistry of the anionic complexes involving ligands such as cyanide. sulphite, and the halides. The one potential exception is the cationic gold(I)-thiourea ion. While many laboratory studies have been made during the past decade. the application of thiourea in the processing of gold is only now reaching the development stage. While thiourea is relatively inexpensive. recent interest has probably been spurred mainly by the novel technology that could arise out of the cationic properties of the gold-thiourea ion. This review outlines the chemistry of gold and thiourea. and discusses the possible use of thiourea in the processing of gold with respect to dissolution. solvent extraction. ion exchange, electrowinning. electroplating. electroless deposition. electro-etching, and electropolishing.

Jan 6, 1977