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By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

By C. McCall, J. T. Knight, J. R. Ridley

Gold mineralisation in the gabbro sills is mainly stratabound to quartz- and Fe-rich, granophyric-textured units and is sited in undeformed, brittle quartz vein sets, which form pipe-like orebodies. Hydrothermal wallrock alteration consists of hornblende-plagioclase-calcite-quartz with minor biotite, garnet and chlorite and with arsenopyrite and pyrrhotite as the dominant sulphides. Geothermobarometric data suggest that gold was deposited at around 520 degrees C at 2.8-3.8 bar. Mineralisation is thought to have occurred during amphibolite-facies metamorphism. Fluid inclusion and isotope data indicate that gold mineralisation was the result of deposition from a low-salinity H2O-CO2-CH4 fluid of either metamorphic or magmatic origin. Although the Three Mile Hill deposit differs from others in the area in its wallrock-alteration assemblages, peak-metamorphic timing of gold deposition and distinct geochemical associations it forms a brittle stratabound ore body which suggests structural and gold-depositional mechanisms in common with those of the other gabbro-hosted gold deposits

Jun 18, 1905

By T. C. Alex, S Srikanth, Premchand

It has been suggested that reduction of the iron and manganese phases as far as FeO and MnO is preferred for the complete liberation and selective reduction of the copper, nickel and cobalt oxides in manganese nodules. The oxygen partial pressure/temperature regime suitable for this purpose has been delineated. Free-energy minimisation and thermogravimetric results indicate that the requisite conditions can be achieved if more than 10% of neutral oil is used at temperatures greater than 923 degrees C. Neutral oil content, temperature and roasting time have been optimised to maximise leaching recoveries of Cu, Ni and Co: up to 96% of Cu and Ni and up to 85% of Co can be recovered if 15% of neutral oil is used as a reductant at 973 K for 90 min

Jun 21, 1905

The Council of the Institution of Mining and Metallurgy submitted the report of the affairs of the Institution for the session 1970-71, and the Statement of Accounts for the year ended 31 December, 1970. The statistics given in the report refer to the calendar year 1970. Details are included of membership, officers, representation on other bodies, honours and distinctions, awards, meetings, publications, library, overseas activities, fellowships and grants, the revenue and expenditure account, the balance sheet, trust fund balances, contributing companies, and schedule of investments

Dec 1, 1971

By T Grenne, R. B. Larsen

Paper presented at the conference on Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. Paper originally entitled: Processes in a newly discovered sulphide-PGE mineralisation in Norway. The Stormyrplutten mineralisation is hosted by a minor tholeiitic metagabbro of low-Ti composition intruded at a high level in the volcanic lithology. It is thought to be the subvolcanic counterpart of submarine basalts generated during an extensional episode of ensimatic arc evolution. The sulphide-PGE mineralisation occurs as stratabound pyrite, pyrrhotite and chalcopyrite disseminations with average grades of 376 ppb Pd, 313 ppb Pt, 40 ppb Au, 0.5% Cu and 0.08% Ni in a deposit 15-25 m thick. Locally the PGE content peaks at 2 ppm over 1 m. Microprobe analysis isolated 14 different platinum-group minerals, dominated by sperrylite, temagamite and borovskite and occurring as 1-20 micron compounds embedded in the main sulphide minerals or along the sulphide/silicate grain boundaries. Mantle-normalised plots reveal strong depletion in Os, Ir and Ru and enrichment in Pt, Pd, Cu and Au. The general decrease in Pd and Pt and increase in S up through the stratigraphy is similar to PGE distribution in the Darwendale subchamber of the Great Dyke in Zimbabwe, and may reflect strong fractionation of Pd and Pt in favour of the first droplets of sulphide melt; two reversals of the trend at the 4 and 12 metre levels represent replenishment with fresh magma and repetition of the cycle. In contrast to the Darwendale system, Cu and Ni also show peak concentrations in the first-formed liquids and Pt appears to have fractionated more strongly into the sulphide melt than Pd

Aug 1, 1995

By G. M. Steed, A. O. Oyinloye

The deposit lies in amphibolite-facies biotite granite-gneisses of Proterozoic age, 4 km east of a major crustal break known as the Ifewara-Zungeru fault. Gold mineralisation is contained in a zone of quartz-carbonate (mainly calcite) veins and hydrothermally altered gneisses with associated small-scale intrusions along a steeply dipping second-order fault zone that roughly parallels the main fault. Gold is present mainly at grain boundaries between quartz and carbonate as discrete particles up to 100 micrometres in size, in general association with sparse, scattered pyrite, pyrrhotite and some base metal sulphides. Adjacent to the gold-bearing zone the granite-gneisses have been hydrothermally altered with minor volume increase, most notable enrichment being in K2O, S, Pb and Cu (and Au). High concentrations of Th, Y, Ce and Zr in the granite-gneisses imply derivation from S-type granites. It is likely that their high heat production capacity maintained the high temperatures needed to transport gold in the hydrothermal systems. It is most probable that the mineralisation dates from the Pan-African orogeny (650-450 Ma)

Apr 1, 1996

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

By A. Berckmans

The key variables in the financial analysis of a mining project include the metal price and the quantities of ore and metal. In general, if the metal price drops, the cutoff grade is increased so as to increase the average grade. This causes recovered tonnages of ore and metal to drop. Discussion is presented of the development of a new method to evaluate the relationship between the cutoff grade, z, the ore tonnage above cutoff, T, and the metal quantity above cutoff, Q. Detailed information is provided on the QTz curves for lognormal and inverse gaussian (Sichel's) distributions. Both these distributions are used as models for the grades in different types of ore bodies, and they are both T-symmetric. The geometry of the QTz curves is simplified, making it easier to work out the impact of minor variation in the parameter values for each distribution

Dec 1, 1996

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Phases of the Ir sub-group are present either as inclusions in or interstitially to chromite and are unaffected by (or only altered in situ during) hydrothermal processes. By contrast, almost all phases of the Pd sub-group are located in a secondary textural setting - in fractures in chromite or between fragments of brecciated chromite. The different settings indicate that the mineralisation episodes were associated with magmatic and hydrothermal stages respectively. The presence of an included Pd-group mineral in a hydrothermally Pd-group mineralised chromitite sample suggests that the hydrothermal Pd-group minerals were at least partly derived by remobilisation from magmatic deposits in the chromitite pod. These observations indicate that Pd-group elements are more mobile than Ir-group elements under hydrothermal conditions and point to the potential for hydrothermal platinum and palladium mineralisation in favourable environments

Apr 1, 1994

By P. J. Baguley

The model has been developed on the basis of the observation that the partitioning behaviour of a particle is related to its calculated terminal velocity. It utilises a theoretical calculation of the terminal velocity of each particle class. This is then correlated with the observed partition data for a plant separator using empirically-derived functions of operating conditions which take into account effects such as bath turbulence, holes in drum lifters and feed arrangements. The model successfully decouples the effects of medium density and viscosity and is appropriate for any bath-type separator. The correlation between calculated terminal velocity and actual partitioning behaviour was established and modelled using data obtained from two Wemco drums treating Fe and Mn ores. The model can be used to predict the prevailing size-by-size partition curves and the separation (product grades/recoveries) given the washability of the feed and operating conditions. Simulations are used to show that, for the treatment of Fe ore, there is a maximum medium density beyond which product grades fall and that this maximum decreases as the proportion of magnetite in the medium increases. This is attributed to the dominant effect of viscosity at higher medium solids concentrations

Jun 18, 1905

By B. Denby

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. The design and scheduling of open pit operations are consistent problems encountered by the surface mining industry. Numerous techniques and algorithms have been developed to assist the mining engineer in the creation of optimum development strategies. Virtually all the practical techniques that have been produced have concentrated on one of the aspects (limit definition or scheduling) at the expense of the other. It has long been recognised, however, that the two activities are intrinsically linked and thus solving either problem independently of the other can only ever produce sub-optimal results as a whole. This has been termed the "circular reasoning problem". It has also been recognised that, for all practical-sized situations, solving both problems simultaneously is virtually impossible using conventional techniques due to the massive size of the search space involved. A technique is presented which is based on a self-learning genetic algorithm, which provides a combined pit limit and extraction schedule simultaneously in order to maximise the NPV (net present value) of the extraction. The theory is developed in two-dimensions and a number of examples of its application are presented. It is proposed that this approach is a highly efficient, heuristic technique offering the potential to transcend the circular reasoning difficulties of separate pit limit and extraction scheduling systems. Extension of the technique into three-dimensions and its application to realistic problem sizes are discussed

Apr 1, 1994

By G. E. Pearse

Reports, discussions, a written contribution and two written replies are presented from 11 sessions on: Safety and compressed air; Ground movements; Geotechnical; Channel Tunnel (2 sessions); Machines; Case histories; Transport tunnels; Case studies; Site investigation; and Undersea tunnels

Jun 13, 1905

By Xuejing Xie, Tianxiang Ren

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Standardised stream-sediment sampling procedures have been used in mountainous and hilly terrains. Special sampling procedures were developed for application in remote environments, such as high mountains, desert, semi-desert, karst and loess-covered regions. The diversified analytical methods used in more than 20 analytical laboratories participating in the project have been unified into two multi-element, multi-method analytical systems. A unified data monitoring procedure was developed based on primary and secondary standard samples. To date the project has covered about 4 000 000 km2 and the aim is to complete the coverage within the present decade

May 1, 1991

By R. Patel, D. R. Taylor, P. M. Varley

In-situ measurements of ground stress were made from surface boreholes, using overcoring and hydrofracturing techniques, to obtain data for the detailed design of the underground works at Pergau. Unexpectedly low stresses were measured and appeared to correlate with apparent hydrofracturing observed during permeability testing. The low values of the minor principal stress had a major impact on design, particularly of the lining for the pressure tunnel and shaft. Additional hydrofracture tests were made underground during construction of the low- and high-pressure headrace tunnels and the pressure shaft, to define the vertical reduction in the minor principal stress with overburden. These data were then used to locate and design the steel and reinforced concrete linings

Jun 19, 1905

By A. P. Whittlestone, J. D. Johnson, R. J. Pine, M. E. Rogers

standpoint. The effect on efficiency of collisions

Apr 1, 1995

By P. Mousset-Jones, G. Danko

Variations of the temperature and steam/moisture content of the air with distance and time are modelled for a single airway. The input for the simulation is an air temperature that varies with time, together with the moisture/steam content that results, for example, from a fire with a given distribution of heat and of fume concentrations at the beginning of the airway. The transport of heat and moisture to the surface of the wallrock is assumed to be simultaneous. Such multiphase convection may result in evaporation from the moist wall close to the fire and recondensation downstream. The modelling of this non-linear effect is a unique feature of the new simulation. A new analytical solution is used to calculate the conduction of transient heat within the rock mantle, which, in the event of a fire, is typically a short-term process. This allows for an arbitrary variation of surface temperature with time - unlike that permitted by the age function solution, which is limited to stepped temperature changes. An iterative numerical scheme that has recently been developed to simulate mine climate is used to calculate the coupled transient heat conduction and multiphase surface heat transport in successive length increments along the airway. To demonstrate the simulation procedure a numerical example is presented in which a fire with a given distribution of heat and fume concentrations with time is located at the beginning of an airway

May 1, 1991

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

horizontal-type classifier prior to charging into a blastfurnace.

Apr 1, 1995

By J. Hurdley, J. A. Plant, H. Robotham, P. R. Simpson, G. C. Lalor

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results of orientation studies for a regional geochemical survey of Jamaica and the CARICOM countries of the Caribbean region are described. The survey is designed to provide systematic geochemical information for a wide variety of applications and, especially, to form a basis for agricultural development in the region

Jul 1, 1991

By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905