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By Katarina Theander, Robert J. Pugh

The generation of froth with a critical degree of stability and height is an important aspect of the froth flotation. In this paper we have studied the synergism and anti-synergism in frothing behaviour in a mixed flotation collector/frother mixture (a model fatty acid; sodium oleate and a model frother; nonionic (polyethyleneoxide alkyl C14E6). Values of the collector / frother molecular interaction parameters (the ß-parameters) were determined from the surface tension data using regular solution theory. The frothing characteristics of the system were evaluated using a glass column equipped with a series of conductivity electrodes, which enabled the water content of the froth to be determined. From these measurements, the dynamic frothability and static froth stability were determined. It was concluded that the synergism/anti-synergism in frothability was depended on the molecular composition of the surfactant system, the diffusion of monomer to the thin film interface and on the breakdown of the mixed nonionic/anionic micelles.

Jan 1, 2003

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By Paul W. Weiblen, Louis J. Cabri, Rolando Lastra

"Preliminary tests were done to determine whether comminution by electric-pulse disaggregation, or E-PD (cf. Rudashevsky et al; 1995), was more effective than using conventional crushing for Merensky Reef ore. A hand sample of the Merensky Reef was sawn in two: then one sub-sample was comminuted to .2 mm using E-PD at the University of Minnesota, and the other sub-sample was crushed to .2 mm using a conventional jaw crusher at CANMET.The products of the electric-pulse disaggregation and jaw crusher were fractionated by sieving and by a separation using a heavy liquid with a specific gravity of 3.3, because the proportion of platinum-group minerals (PGM) and sulphides to silicate minerals is very low. Thus, four mineral separates were produced: .2000 + 833 µm, -833 +208 µm, -208-µm float and -208-µm sink. All the mineral separates were studied by image analysis (Lastra et al; 1998). The main objective was to determine the liberation of gangue (silicate minerals), chromite, pyrrhotite, chalcopyrite, pentlandite and PGM. In the case of the PGM, a specific image analysis program was written to search and measure these minerals.The results show that the liberation obtained for gangue was similar (~99%) using either method of comminution. However, the liberation obtained for chromite (~89% vs. ~38%), pentlandite (~50% vs. 1%), pyrrhotite (~56% vs. ~38%), and PGM (~56% vs. ~1%) by E-PD was higher than that obtained by conventional jaw crusher, whereas the liberation obtained for chalcopyrite (~20% vs. ~71%) by E-PD was lower. Nevertheless, the image analysis of the products also showed that the PGM are strongly associated with pentlandite. Thus, for the Merensky Reef, liberation of pentlandite from the gangue minerals and chromite is important to recover more of the PGM. This maybe be significant because, in addition to increased recovery of platinum-group minerals (PGM), Merensky Reef pentlandite also contains significant quantities of valuable platinum-group elements like Pd and Rh (Cabri, 1981; Cabri 1988, Kinloch 1982, Peyerl 1983). Hence, the results indicate that for the Merensky Reef, electric-pulse disaggregation would represent a better comminution operation than a conventional jaw crusher would. In addition, the greatly improved liberation for chromite may find application for the PGM-rich UG2 chromitite."

Jan 1, 2003

By Luis Bergh, Iván Rojas, Juan Yianatos, Luis Vinnett

"At present, flotation rate characterization follows standard measurements to identify the overall flotation performance looking at the feed, tailings and concentrate in flotation cells or banks. This classical approach does not take into account the evolution of the true collection rate down the flotation banks explicitly. The potential for identifying the impact of the mineral characteristics (size and liberation) as well as the effect of different manipulated variables (reagents, froth depth, gas dispersion) on the true flotation process remains hindered. Top-of-froth (TOF) measurements, which consist of sampling the first layer on the froth surface, have been used to characterize the mineral collected by true flotation in rougher banks. The information provided by TOF samples allows evaluating the floatable mineral evolution (grade, particle size, liberation) down the bank. In this work, an indirect approach to estimate the flotation rate along rougher flotation banks is proposed. The new approach is based on the decreasing of collected mineral grades (on top of froth) and the feed characteristics. Flotation rates per liberation classes were used to reconstruct the TOF grades from the feed information. This approach requires a simple froth surface sampling, without constraints typically observed during mass balance surveys and uncertainties on the mineral recovery estimation. The proposed methodology was successfully applied at industrial scale using TOF measurements together with QEMSCAN information."

Jan 1, 2014

By Dmitriy Makarov

The paper presents the modeling and analysis of oxidation of pyrite copper-zinc ore samples from the Letnee, Yaman-Kasy and Valentorskoye deposits. It is found, that the oxidized samples contain copper and zinc sulfates that are leached under the sample and water contact. It is shown, that sulfide floatability is decreased by the longer-term oxidation.We advise to improve nonferrous metals recovery by joint leaching and ultrasonic treatment of oxidized compounds. Study of the geotechnological processes of non-ferrous metal extraction, on the basis of two copper-zinc ore deposits shows, that heap leaching is of little use for the ores of the Letnee deposit. Leaching results for the Yaman-Kasy ore showed more promise.

Sep 1, 2012

By N. N. Orekhova, I. V. Shadrunova, N. G. Novikova, N. ?. Volkova

The purpose of the research is scientific substantiation and formulation of strategy and technical solutions of handling liquid wastes of plants producing and refining copper-zink pyritic ores. In the course of research studied are chemical composition of technogenic waters of mining plants as well as water and alluvia of intake river within and outside a sanitary zone of Southern Ural mining plant using inductively coupled plasma mass-spectrometry and X-ray fluorescence analysis techniques. A particular focus is made on microcomponent composition. Novel data on Cd, Li, Be, Mn, Co, Cu, Zn migration with technogenic flows and accumulation of these elements in alluvia is obtained. It is showed that extraction of valuable components from technogenic waters is a novel problem for refiners that can be solved only in cooperation with mining industry ecologists. Laboratory research of selective copper and zink extraction into corresponding practical products by galvanocoagulation and sulphide precipitation is carried out. Common factors of phase formation are studied using physicochemical modeling, X-ray phase analysis and electronic microscopy. Methods of intensification of processes and increasing of extraction ratio of metals in products are elaborated. A technology of comprehensive processing of undersoil waters is proposed. Enlarged laboratory and pilot plant tests of technological solutions for protecting hydrosphere and extracting metals from mine waters carried out on several plants of UMMC-Holding Corporation showed a possibility of obtaining additional products having weight content of metal which is profitable for consequent metallurgical processing and purification of waters to comply with quality standards. A possibility of transformation of technological chain depending on season variability of water quality is put behind the designed technological schemes.

Jan 1, 2018

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By P. V. Ramesh Babu

India has sizeable number of small deposits of rare metal bearing minerals namely columbite-tantalite, pyrochlore, beryl, lepidolite, spodumene and rare-earth element bearing minerals monazite and xenotime in different parts of India. Pegmatites, alkali granites, syenites, and the derived gravel and soils are the main source for rare metal and rare earth (RMRE) minerals. The RMRE minerals are classified as prescribed substances under Atomic Energy act of 1962 keeping in view the uses in the nuclear industry. Atomic Minerals Directorate for Exploration and Research (AMD) of Department of Atomic Energy (DAE) is the sole agency responsible for exploration and exploitation of RMRE minerals in India since 1962. The latest technological advancements and applications in the field of space, electronics, communication and nuclear industry using these metals and their products have necessitated to augment the production and resources of RMRE minerals. These minerals play a significant role in the technological and economic development of the country. The light rare earth element bearing mineral monazite is abundant in beach sands and is being commercially exploited by Indian Rare Earths Limited (IREL). Columbite-tantalite, the chief source for niobium and tantalum (Nb-Ta) metals present in the pegmatitic gravel are recovered by small mobile beneficiation plants. The cut and fill method of mining adapted is eco-friendly. The processing flow-sheet consists of wet sizing at ½ in and 1mm followed by gravity concentration of sized products utilizing the methods of jigging and wet tabling. The sizing equipment include revolving and vibratory screens and the gravity concentration equipments used are fixed sieve jigs and movable screen jigs for final upgradation. The gravity concentrates are further upgraded by magnetic separation to remove magnetite and ilmenite. The mine areas are reclaimed by filling with coarse size tailings and new plantations. These mobile pilot plants were earlier operated in Bihar mica belt, Jharkhand, pegmatitic areas of Karnataka and Nellore mica belt of Andhra Pradesh and are currently being operated in Bastar-Malkangiri pegmatite belt of Chhattisgarh and pegmatites of Jharsuguda district of Orissa. Beryl, lepidolite, spodumene and cassiterite minerals are the by-products from the pegmatite ores. Fergusonite, samarskite and microlite are the other niobium and tantalum bearing minerals which are also found in pegmatites. Xenotime, the chief mineral of yttirium generally occurs in granites and pegmatites. The rare earth minerals monazite and xenotime get concentrated in the placer sands of rivers and beaches. The occurrence of xenotime in the sands of Siri River and Deo River in Chhotanagpur granitic terrain in parts of Chhattisgarh and Jharkhand are an example. These sands containing 1-2.5% heavy minerals were processed by a mobile plant consisting of sizing equipments like trommel and vibratory screen followed by separation of heavy minerals from -1mm sands with the help of gravity concentration equipments like spirals/shaking tables/sluices. Xenotime and monazite from the pre-concentrate are further separated by magnetic and electro-static methods. The present paper illustrates the pilot plant set up for the recovery of rare metal as well as rare earth minerals. Keywords: small deposits, rare earths, rare metals, pegmatite, Nb-Ta, xenotime, India

Sep 1, 2012

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By Yuhua Wang, Huilan Yang, Yanqing Jiang, Dongfang Lu

"Generally, the concentration of bauxite flotation tailings is around 10%, a large amount of water in tailings needed to be recycled in the flotation process. Sedimentation and dewatering properties of tailings were investigated under different conditions. Surface high negative charges on mineral particles are the key factor to destroy the settlement of tailings when the pulp pH is around 8.9. Hence, the modification of pulp pH around 7 is necessary to the diminution of the repulsive force between mineral particles and then the acceleration of sedimentation of tailings. Anionic polyacrylamine with molecular weight of 14 million is the best flocculant for the settlement of tailings in all tested polyacrylamines. P-toluene sulfonic acid shows better properties than hydrochloric acid for pulp pH adjustment when anionic polyacrylamine with molecular weight of 14 million is used as flocculant. Although the flotation of diaspore is depressed in the presence of polyacrylamine using sodium oleate as collector, but the recycling water traded by the combination of ployacrylamine and p-touenesulfonic acid does not show the depression effects on the flotation of bauxite ore. The lower residual content of polyacrylamine in recycling water treated by the combination of ployacrylamine and p-touene sulfonic acid plays an important role. INTRODUCTION Generally, the waste water generated from mineral processing plant is usually treated by sedimentation, oxidization, electrodialysis, ions exchange, active carbon adsorption and flotation technology, and the treated water is also used again in the industrial process. Flotation was adopted widely to improve the quality of bauxite from low grade diasporic bauxite in China. For flotation, the grinding fineness of bauxite is over 90% -0.074 mm, sodium carbonate and sodium hexametaphosphate were used as regulators, so the tailings pulp is very difficult to settle and be dewatered (Y. Wang et al., 2004; Y. H. Wang et al., 2007; Wang Yu-hua et al., 2008; Wang Yuhua et al., 2011). The water recycling of bauxite tailings are becoming the highlight for the industrial application of the flotation process for bauxite ore. Researchers in China shift their attentions onto this topic."

Jan 1, 2018

By V. E. Dementiev, V. I. Kulikov, G. I. Voiloshnikov, Yu. O. Fedorov

"The report presents the summary of the JSC Irgiredmet’s activities in the field of preconcentration of ores. As of 2018, the Institute has almost 40-years’ experience in this area. Over the years, Irgiredmet has done a lot of work – from development to implementation of new technologies of ore piece sorting and concentration based on X-ray radiometric separation (XRRS). INTRODUCTION Preconcentration has been a challenging issue of the mining industry over the last decades. The implementation of this technology can significantly increase mining efficiency. The main application of preconcentration is improvement of mined ores quality, however new and more complex issues have arisen with the evolution of the technology. Irgiredmet has started to develop an efficient preconcentration technology for gold-bearing and rare-metal ores 40 years ago. The X-ray radiometric method widely used at that date as a method of elements determination in geology and geophysics become the ground for this work (1). Since that time, the Irgiredmet Institute has developed and significantly improved the technology of piece ore sorting, or XRRS (2-5), that is currently also known as the X-ray fluorescence method. The progress of the XRRS development achieved by Irgiredmet in cooperation with Rados LLC, Tekhnoros LLC (Krasnoyarsk), Rados-Service LLC and CJSC Tekhnogen (Ekaterinburg) has proved efficiency and applicability of the XRRS technology for processing a wide range of minerals and solving of various technological problems (7-9) compared to other radiometric methods (6). Furthermore, obtained results are supported by numerous studies, trials and implementations. The significance of ore preconcentration for greenfield and brownfield projects determined the establishing a new subdivision of Irgiredmet, the XRRS Technology Center (XRRS TC), that has provided the Institute with a completed range of processing technologies, from preconcentration to producing final products. Over the past few years, the XRRS Technology Center has carried out studies and testing of a numerous (more than 100) projects, mines and deposits of gold-bearing ores, rare metal ores (Be, Ta, Nb, W, Mo), base metal ores (Cu, Sb, Zn, Pb), ferrous metal ores (Fe, Ti, Cr), rough diamonds and coal. The XRRS Technology Center performs various specific studies and testing not only in Russia, but as well as in Kazakhstan, Georgia and Mongolia. Mines and companies from Chile, India, China, Iran and other countries also take an active interest in the XRRS technology."

Jan 1, 2018

By J. Y. Tian

In view of the fact that many domestic iron ore-dressing plant applying flotation cells in the re-verse flotation, to improve the technical level of magnetite reverse flotation, we apply such a technological process of one stage rougher and two stages scavenger flotation column respectively. The middling from the two stage scavenger process are returned to magnetic separation for condensing. By contrast, the technological process of one stage rougher and one stage cleaning flotation cells is made up of by multi-magnetic separation and magnetic middling regrinding separations. It has been proved that the flotation column we offer can simplify the technological process structure, obtain advanced technical indexes, run the system smoothly, reduce energy consumption, and be environ-mental friendly.

Jan 1, 2014

By F. Z. Dong

The paper is mainly about a study on the techniques of separating iron from pyrite cinder of a certain sulfuric acid plant in Shandong province. The main components of the cinder are Fe2O3 and SiO2, and the degree of liberation of iron mineral and gangue is very high. So the iron concentrate with higher degree of iron and lower grade of silicon and sulfur can be achieved by reverse flotation. The iron grade of the concentrate reaches 63% and the recovery of iron is no less than 63%. And the most important influencing factor of the flotation is the temperature of the pulp. A better guideline can be achieved by magnetic separation. The cinder is magnetizing roasted for 15 minutes with temperature of 800?, and the concentrate with the iron grade 64%, sulfur grade 0.2% and iron recovery 85% can be obtained by two stage magnetic separation. A rotary kiln has been built to deal with the pyrite cinder, and the result of the industrial magnetizing experiment and magnetic separation is satisfying.

Jan 1, 2014

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By Willis Forsling, Prabhakar Swarna, Hanumantha Rao Kota

The solubility of wollastonite and its Hallimond flotation behavior as a function of dodecylamine concentration and pH are examined. The flotation response is characterized by adsorption and surface energy in the presence of amine. The methods of UV-Visible and FT-IR spectroscopy for adsorption and sessile-drop contact angle for surface energy estimation are employed. The results of wollastonite dissolution clearly showed its non uniform dissolution. The surfaces are depleted with calcium ions and became rich in silicon within 10 min of flotation time. Maximum flotation of wollastonite corresponds to a half monolayer coverage of amine, which is substantiated by the surface energy parameters. A good correlation between flotation, adsorption and surface energy as a function of amine concentration and pH was observed. The sudden increase in wollastonite flotation and amine adsorption at and above 5x10-5 M initial amine concentration is thought to be due to two-dimensional precipitation of amine on surface in accordance with the recent 2D-3D precipitation model of amine adsorption on silicate minerals.

Jan 1, 2003

By D. Steele, B. Ndlovu

"Adequate characterisation of clays is becoming increasingly important as operating mines move into areas of more complex ores. The processing therefore needs better mineralogical characterisation to identify problematic ores for better planning before issues arise. While a number of instrumental mineral characterisation methods are available, X-ray Diffraction (XRD) is widely recognised as perhaps the best technique for the identification and quantification of minerals, particularly clays. When an appropriate sequential and systematic sample preparation and treatment protocol is employed with instrumental XRD analysis individual clays can be uniquely identified, and the proportions of interstratified clays can also be quantified. The effect of sample preparation on the XRD analysis and identification of clays was investigated in this study. The results showed that sample preparation protocol is indeed critical to accurately analysis and characterisation of clays. For example, both dry grinding and micronizing affected the degree of crystallinity of kaolinite leading to the formation of reactive surfaces or changes in the physicochemical behavior. It was also found that the apparent degree of preferred orientation in platy minerals correlates directly with the amount of force/pressure applied during the preparation of backfilled powder samples. This work showed that manual preparation can produce highly variable peak intensities especially with minerals that show any preferred orientation. KEYWORDS Clay; XRD; kaolinite INTRODUCTION Clays are important in our life and they have numerous applications in modern world from cosmetics to environmental remediation. Therefore, clays have been extensively investigated for many years. Adequate characterisation of clays is becoming increasingly important as the mineral processing industry faces more complex mineralogy with the need for better mineralogical characterisation to identify problematic ores and plan accordingly. In most studies, X-ray diffraction (XRD) method has shown the unique capability to characterise mineralogy, especially for the fine grained size materials. The XRD technique is particularly diagnostic for clays. It is known that under ideal conditions, the peak intensities of an XRD diffractogram are proportional to the concentrations of individual minerals present in the sample. Hence, the qualitative mineralogical data obtained from XRD can be quantified, using either the internal or external standard methods. However, it is also known that clays are particularly sensitive to the influences of sample preparation method due to their physical characteristics (e.g. fine grain size, morphology, relative physical softness, crystallinity, thermal sensitivity) that could be destroyed by inappropriate preparation prior to the analysis. Thermal and mechanical treatment and grinding of clays can change their crystalline structure, and consequently, their characterisation results by XRD analysis. The behaviour of clays in grinding has been widely studied, especially for kaolinite (Miller and Oulton, 1970, Milocevic et al., 1992, Tomasevic-Canovic et al., 1992). With prolonged grinding time, the crystallinity of the clays can decrease (Filipovic-Petrovic et al., 2002). It has been shown that grinding may gradually cause the loss of hydroxyl ions of kaolinite (Gonzalez Garcia et al., 1991)."

Jan 1, 2018

By L. K. Smith

Flotation work conducted by CSIRO on both single minerals and high-arsenic copper ores from a number of sources, has shown it is possible to produce separate low-arsenic copper concentrates and high-arsenic copper concentrates from high-arsenic copper ores. The procedure involves controlled separations at high or low pulp potential regions exploiting subtle differences in the flotation behavior of the arsenic-bearing and non-arsenic-bearing copper minerals. An overview of several case studies investigating the applicability of the controlled potential flotation approach to the separation of copper and arsenic from sulfide copper ores is presented. It highlights the variables which influence the efficiency of the separation which include mineralogy, liberation and reagent selection. The procedure can produce a saleable low-arsenic copper concentrate, which can be directly smelted without penalty, and a high-arsenic low copper concentrate, which will require further processing. Keywords: flotation, copper, arsenic, controlled-potential flotation

Sep 1, 2012

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Automatic identification and characterisation of mineral raw materials and beneficiated products are of major importance in mineral processing. However, minerals show great variety in their composition and physical and chemical properties. Industrial minerals may contain the same elements in about the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. By means of EBSD, diagnostic mineral information can be achieved if indexible patterns are provided.Until now EBSD has not been used frequently on geological samples for mineral and micro structure discrimination.The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques."

Jan 1, 2003

By M. Saghaeian, R. Hejazi, M. Farahani, M. Dehghani, A. Tohry

"Wet tailing dams of iron ore processing plants typically contain a significant amount of valuable minerals. In more recent years, due to the increase in iron’s prices and technological innovations, as well as the low energy consumption which required for processing of materials from tailings, dams can consider as potential valuable deposits. However, the production of iron concentrate from tailings is usually complicated where the high moisture content of the material, the high clay content and the presence of chemicals of processing such as flocculants, acids and flotation reagents, all make materials highly sticky which can be easily swollen. In the present paper, the optimization of operational parameters to recover ultrafine hematite iron ore from the wet tailings dams of the Chador-malu iron ore mine was investigated. The optimization of operational parameters, showed that with modification of the washing unit components for slurry making, the challenge of constraints from feeding the plant could be overcome. To decrease the magnetite content in the tail stream of the medium intensity magnetic separation (MIMS) and subsequently increase the efficiency, the orifice of the cleaner tail flow exit pipe was changed from 7 inches to 3 inch and yoke angle changed from 14 to 8 degrees. These changes increased mass yield by 3% and decreased the magnetite content in the final tailings to 1.2%. By recirculating the cleaner SLons of final tailings within the circuit, the solid percentage of the feed to rougher SLons decreased to around 15%, and as a result the matrices were not overloaded that easily, and mass yield increased to about 13% from 7%. All the above mentioned optimizations were achieved without significantly affecting the concentrate Fe grade."

Jan 1, 2018

By V. A. Luganov

Methods of treatment of pyrite concentrates differ, depending on the content of pyrite and non-ferrous metals: oxidation roasting, sulphatization roasting, smelting, direct hydrometallurgical treatment and so on. Existing technologies do not provide for high recovery of metals, expenses associated with existing technologies are high, and environmental issues, associated with the existing technologies need serious attention. We have developed universal technology of the activating-dissociating autogenous roasting of pyrite concentrates using air based, or air, enriched with oxygen, blow. The basic process is taking place in accordance with the following reaction: (1-x)FeS2 + (1-2x)O2 = Fe1-xS + (1-2x)SO2 +Q The products of this reaction are pyrrhotinized cinder and roasting gases, rich in SO2 (up to 18 % in case of air blow) and poor in SO3, that contain up to 1 % of elemental sulphur. Cinder contains different forms of pyrrhotite. These forms of pyrrhotite differ by its content (from Fe0.843S to Fe0.945S), thermodynamic, magnetic (from 4.10-1 to 3.6 SI units), flotation properties (with pyrite dissociation the ?-potential of the product is moving towards more electrically positive charge, from 0.95 for pyrite to 0.2 for dissociation products) and other properties that depend on the conditions of roasting. The combination of pyrrhotizing roasting with different methods of cinder treatment allows to increase the level of sulphatization of non-ferrous metals during the roasting; reduce the amount of blow used during the processing; reduce dust losses to the gas phase; reduce the capacity of gas cleaning system and increase resistance to corrosion of the gas-treatment system, used for the production of sulfuric acid from pyrites. This combination of treatments also allows to use magnetic separation and flotation for separation of ferrous and non-ferrous metal compounds during cinder treatment; perform de-arsenation of arsenic containing concentrates and by-products. Pyrrhotinized cinder may be treated by oxidizing and non-oxidizing hydrometallurgical methods. Keywords: Pyrite, polymetallic ores, sulphidization roasting, pyrrhotite, magnetic separation, arsenic sulphide

Sep 1, 2012