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By Kari Niiranen

LKAB (Luossavaara-Kiirunavaara AB) is operating iron ore mines, concentration plants and pelletizing plants in Northern Sweden. The largest of the apatite magnetite deposits and the mines are Kiirunavaara with annual production rate of approximately 27 Mt crude ore underground. LKAB produces two varieties of pellets: blast furnace pellets and direct reduction pellets (LKAB DR Oxide Pellets). Meanwhile the concentration process in a sequence of the low intensity magnetic separation (LIMS) and flotation at the concentration plant. In spring 2007 there were noticed great fluctuations of SiO2 grade in the crude ore. The high SiO2 grade is particularly problematic in the case of direct reduction pellets. In consequence, a project was started (called Silica in the Mine) to define exactly the problem related with silica and to find out, if possible, the reason for the great fluctuation of SiO2 grade in the crude ore going to the processing plant. A further target of this project was to develop a simplified method at the laboratory scale, to predict SiO2 grade in the magnetite concentrate in the future, but also predict the physical properties of the ore with respect to mineral processing. The essential stage of systematic characterization of the ore body for mineral processing properties is the estimation and simulation of different parameters from the laboratory scale to the large scale at the concentration plants using empirical data collected at the mineral processing by LKAB in Kiruna. Further a target was also to find useful physical parameters for mineral processing and implant those parameters into the existing geological 3D-model of the deposit. This information will be used for making prognosis of the future mining and the quality of the crude ore. It will also give better control and improve the production planning in the mine and the performance at the concentration plant in Kiruna concerning the decrease of the SiO2 grade of the magnetite concentrate.

Sep 1, 2012

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

Rotor speed is one of the key hydrodynamic parameters in froth-flotation and it plays an important role in bubble-particle attachment. Laboratory scale studies for optimizing the rotor speed to achieve maximum flotation rate constant (K) of quartz, ground by ball mill, are. Purity of quartz was 99.4 percent and d80 of ball mill product was 230 µm. Each size fraction was separately subjected to flotation at three different rotor speeds, namely, 1200, 1000 and 800 rpm, and the flotation rate constant was calculated. The results showed that the flotation rate constant was high at the rotor speed of 1200 rpm. The flotation rate constants achieved at 1200 rpm were 8.676, 8.232, 7.818, 7.248, 7.068 and 6.984 min-1forthesize fractions of +300, -300+250, -250+212, -180+150, -150+125 and -125+106 µm, respectively. Keywords: froth flotation, rotor speed, flotation rate constant, ball mill, quartz

Sep 1, 2012

By Gaom M. W.

The Mount Isa copper concentrator started operation in 1973. Its secondary grinding circuit consisted of two 5 meters diameter ball mills in closed circuit with 505 mm cyclones. At the design throughput of 800 t/h, the 80% passing size of the circuit product (P80) was about 140 µm. The then Mount Isa Mines Limited (?MIM?) installed two autogenous grinding (?AG?) mills in 1991 to replace two stages of crushing, a rod milling stage and one primary ball milling stage. One of the AG mills was later converted to semi-autogenous grinding (?SAG?) operation by the addition of a steel grinding medium to achieve the designed plant throughput of 800 t/h. The cyclone over-flow P80of the secondary ball mill circuit was reduced to 120 µm by the increased operating power in the AG/SAG mill circuits. The two secondary balls mills had a grinding power of 5.2 MW. A mineralogical study of the milled products indicated that half of this grinding power was sufficient for adequate chalcopyrite liberation. Eliminating one of the secondary ball mills could reduce energy and operating costs by more than A$2 million dollars per year. An optimisation project team was established to achieve the predicted power saving. Grinding circuit simulations were conducted for different circuit configurations. Ball mill parameters such as ball size, ball charge and feed slurry density were optimised. Cyclone body diameter, spigot and vortex finder sizes, and cyclone types were tested. The secondary ball mill circuit was redesigned and several proposed circuits were run as trial production campaigns to determine their operability and efficiency. The plant trials confirmed that one of the secondary ball mills could be decommissioned. Significant cost savings were achieved as a result. The success of the project demonstrates optimising grinding circuits can not only deliver the plant performance, but also a much lower unit operating cost through energy and maintenance savings.

Jan 1, 2014

By Nidhi Kumari

This work is based on surface chemical properties of bacteria during adaptation to high grade copper minerals and the projected consequences in Bio-Flotation process. The utility of bio-processing in the beneficiation of copper ore through bio-flotation is demonstrated. An autotroph Acidithiobacillus Ferrooxidans bacterium is adapted to high grade mixed copper ore sample by repeated subcultures. The surface characteristics were studies by analyses at different pH and time intervals. From the studies, it was established that the mineral-adapted cells became more hydrophobic as compared to unadapted cells during bio-flotation. It was also noticed that there was no significant changes in the surface charge of bacteria before and after adaptation. Keywords: bio-flotation, copper, Acidithiobacillus ferrooxidans, hydrophobic

Sep 1, 2012

By G. Rajesh

Mathematical modeling of bioremediation has gained importance as it is used as an optimization tool for the remediation process involved in contaminated sites. The bioremediation of Cr(VI) has been studied taking into consideration the initial Cr(VI) concentration Cr(VI)ini, bacterial growth substrate concentration (S), maximum growth rate (µmax), yield coefficient (Y), half saturation constant (Ks), and inhibition constant (KI). As the enzymatic reaction is also affected by initial substrate concentration (Sini) and Ks, different ratios of (Ks/Sini) are analyzed. As the inhibition constant (KI) is not constant for all the enzyme reactions and it varies with Cr(VI)ini, the correlation between (KI) and Cr(VI)ini is developed. A set of differential equations pertaining to bioremediation of Cr(VI) has been solved using FORTRAN 90 program adopting the model developed. The results are verified with the experimental data from the literature and a good correlation has been obtained between the experimental data and the model predictions. Keywords: bioremediation, hexavalent chromium, mathematical model, inhibition kinetics

Sep 1, 2012

By M. J. Lottering

Gold deposits in South Africa are invariably associated with uranium bearing minerals. Although it is low grade uranium by international standards, averaging around 0.3 kg U3O8 per ton of ore, recovery of uranium as a by-product improves the overall economics of gold extraction. Moreover, the current high uranium prices as well as increased demand due to renewed interest in nuclear power provide significant incentives for dedicated uranium production. An understanding of the uranium leaching response to changes in operating conditions is an important first step to-wards optimisation of uranium recoveries. In South African acid leaching plants, uranium dissolutions higher than 90% are difficult to achieve, and the chemical origin of this limit is not clear. To study leaching behaviour, an important consideration is the mineralogical characteristics of the ores. Typically, a diagnostic leaching approach can be followed. In this paper, a mineralogy-leachability explanation is presented to rationalise the difficulty in exceeding 90% dissolution from low grade uranium ores on the basis of a simple diagnostic leaching method. It was found that brannerite was the main reason for the existence of a dissolution limit in Witwatersrand ore and that chemical liberation was more effective to increase end dissolution compared to physical liberation. The findings from these investigations will form guidelines for developing economically viable flow sheets for improved uranium recovery, at least in a South African (Witwatersrand) context.

Jan 1, 2014

By C. V. G. K. Murty

Sillimanite, chemically named Aluminum silicate, 3Al2O3SiO2 is one of the three forms of alumino silicate polymorphs and commonly encountered in aluminous metamorphic, plutonic, and volcanic rocks and their weathering products. Most of the sillimanite deposits are granular and are of high grade available in coastal areas as associated mineral along with Titanium bearing minerals namely ilmenite, rutile etc. Sillimanite is one of the widely accepted raw materials for the manufacture of high alumina refractories (55-60 % alumina) or bricks. Sillimanite based refractory bricks are used for the lining of Blast furnaces, Arc furnaces, Soaking pits, Reheating furnaces of iron and steel, rotary kilns for cement manufacturing and general kilns for lime production. Considering the vast potential of unexploited sillimanite reserves in India, M/s Trimex Sands Pvt. Ltd., (TSPL)has set up a Mineral Sand Processing plant in 2010 at Andhra Pradesh with a capacity to produce about 50,000 tons of sillimanite per annum besides the production of various heavy minerals such as ilmenite, rutile, zircon and garnet. Traditionally in India, sillimanite is upgraded by froth flotation technique using Oleic acid as a collector cum frother, sodium silicate as depressant and soda ash as pH regulator. At TSPL, Conventional mechanical float cells are installed to float sillimanite. In addition to the usual problems associated with conventional cells, poor flow ability of the sillimanite concentrate is experienced in dry circuit due to the presence of sodium oleate. Fine garnet in the sillimanite concentrate contributes to high iron content in the final product, making sillimanite separation a nightmare for operators (lower recoveries coupled with inferior grades). Various efforts were made to improve the performance of the circuit such as introduction of additional frother like MIBC, optimizing the operating parameters such as pulp density, collector dosage, depressant dosage, air flow rate, pH etc., use of collector aids, stage wise addition of reagents etc. The challenges faced to produce a sillimanite product with stringent quality norms and the efforts made to improve the grade and recovery are described in this paper. Keywords: sillimanite, froth flotation, conventional mechanical cell

Sep 1, 2012

By L. W. Luo

Zeolite in some regions or countries of the world have been the subjects of materials for environmental remediation involving the use of removal to heavy metal ions and some organic pollutant as a sorbent because of its capacious ions exchange and huge surface area. This article addresses the equilibrium and kinetics for manganese adsorption using zeolite modified by hexadecyl trimethyl ammonium bromide (HTMAB) as a sorbent material over a range of pH between 3.4~7.2 with eight different Mn(?) solution concentrations. PHzpc (pH of zero point charge) of the sorbent was examined according to the method proposed by Tripathy and Kanungo, and a value of 6.91 was obtained. The experimental data fit langmuir?s model for the majority of pH and Mn(?) solution concentrations tested (0.92<R2<0.97). The maximal adsorption capacity, qm ascending with pH between 3.4~7.2, rise from 15.01mg?g-1 at 3.4 to 19.46 mg?g-1 at 7.2. Besides, the constant of Freundlich Kf have the same trend with qm, increases with pH ascending. And the sorption intensity, represented by parameter 1/n in Freundlich?s model, is favorable in entire range of metal ions concentration studied. Finally, kinetics data accurately fit to pseudo-second order which indicate that there must be sorption of Mn(?) behavior occurring on inner-sphere of the sorbent.

Jan 1, 2014

By Y. Q. He

The dynamic behaviors of the air bubbles in the dense gas-solid fluidized bed have a significant effect on the performance of dry coal separation. The combined method of experimental measurement and numerical simulation were conducted to conduct the research of the mean diameters and rising velocities of the bubbles in the fluidized bed. The calculation models of mean diameter and rising velocity of the single bubble were proposed. The results indicate that the models of the mean diameter raised by Rowe (1976) and the rising velocity raised in this work could be used to predict the bubble dynamic parameters in gas-solid fluidized bed. With the Geldart B type of magnetite powder as the medium solids and while the gas velocity of 1.5Umf=U=2.2Umf, the mean bubble diameter along the bed height is 36mm<Db<45mm, and the mean rising velocity of the single bubble is distributed in 40~65cm/s. The results of experimental measurement, numerical simulation and model predication provide well agreements finally. Based on the uniform fluctuations of air bubbles diameters and their rising velocities, the separation experiments of 50~6mm dry coal using the mixture of 0.3~0.15mm magnetite powder and <1mm fine coal as medium solids were carried out. The results show that the probable error, E is 0.06, which indicates a good separation performance by using the gas-solid fluidized bed. Keywords: dense gas-solid fluidized bed, bubble dynamic behaviors, numerical simulation, separation performance

Sep 1, 2012

By S. N. Shahcheraghi

Bioleaching method makes use of bacteria in solving metallic sulphides, so that these bacteria tend to convert insoluble metal sulphides into soluble sulphates. Since the kinetics description of this process is inevitable for better interpretation of relation between metabolism and growth of live organisms, as well as optimization of metals extraction processes, in this paper, this description is represented and designed in mathematic (kinetics) model for copper sulphide minerals based on Monod kinetics model. According to this model, special growth rate of bacteria (?) is a hyperbola function of restrictive substrate concentration (S). By Solving and developing of Monod kinetics model, a comprehensive kinetics model for bioleaching of copper sulphide minerals results. The designed is also applicable for other metal sulphides.

Sep 1, 2012

By P. Han

The preparation technological conditions and regeneration method of two novel granulated adsorbing materials of rectorite/fly ash composite (Material 1) and rectorite/water quenched - slag composite (Material 2) and the use of them to remove heavy metals from copper smelting plant wastewater have been studied. The experimental results showed that under the preparation conditions with the ratio of rectorite to fly ash or water - quenched slag of 1:1, the amount of the additive (Industrial Starch, IS) of 15% (Material 1) or 10% (Material 2), the addition of 50% water, and the calcination temperature of 500? (Material 1) or 400? (Material 2), the efficiency of heavy metal removal with the granulated materials was the best, whereas the ratio of disintegration loss was the lowest. Under the treatment conditions of natural pH, and with the addition of the granulated materials of 0.07g/cm3 (Material 1) or 0.05g/cm3 (Material 2), a reaction time of 60 minutes (Material 1) or 40 minutes (Material 2), and the adsorption temperature of 25?, the efficiency for the granulated materials to remove Cu2+Pb2+Zn2+Cd2+ and Ni2+ from the copper smelting plant wastewater was 98.9, 97.5, 96.7, 90.2, and 79.1, (Material 1) or 98.2, 96.3, 78.6, 86.2, and 64.2, (Material 2), respectively, and the quality indexes of the wastewater after treatment conformed with the first level of integrated wastewater discharge standard (GB8978-1996). When the adsorption of heavy metal ions on the surface attained saturation the granulated materials could be regenerated by washing with 1 mol/L sodium chloride (NaCl) solution and still with quite good heavy metal removal efficiency. The granulated adsorbing materials had the advantages of high efficiency of wastewater treatment, easy method of solid-liquid separation and regeneration, and a broad prospect of applications.

Jan 1, 2014

Considerable attention has been, and is being, given to the physics of water-films associated with bubble interactions at surfaces. In contrast, little information on the chemistry of such films has been reported. This communication reports a method using sum frequency vibrational spectroscopy (SFVS) to describe hydrogen bonding of interfacial water molecules in water films created with bubbles at hydrophilic and hydrophobic surfaces. The SFVS spectra of water films at hydrophilic silica surfaces differ significantly from the spectra of water at a hydrophobic silica surface. The SFVS spectra indicate that a very ordered water structure exists in water films at the hydrophilic silica surface during contact with a bubble and that the extent of hydrogen bonding increases with an increase in contact pressure. Such structural considerations as well as repulsive electrostatic and Van der Waals forces account for film stability for a bubble at the hydrophilic silica surface. In contrast, the SFVS spectra of water at a hydrophobic silica surface show a lack of hydrogen bonding and are characterized by a distinct absorption at about 3700 cm-1 similar to the spectrum of the air/water interface. These results suggest the presence of a water void, or water exclusion zone, at the hydrophobic surface, as supported by X-ray reflectivity measurements reported in the literature, by atomic force microscopy, and by the results from molecular dynamics simulations. Of course the water film at the hydrophobic surface is unstable with film thinning and rupture upon bubble contact. Under these circumstances it is shown that an attractive Van der Waals force between the bubble and the hydrophobic surface can be expected when the water exclusion zone is taken into consideration. As the thickness of the water exclusion zone increases to a thickness corresponding to the size of nano bubbles, the calculated attractive Van der Waals force increases. This analysis may help to explain the so-called ?short range? and ?long range? hydrophobic forces. Keywords: SFVS spectra, hydrophilic silica surface, hydrophobic silica surface

Sep 1, 2012

By M. Illikainen

Limestone is used for neutralization of acid leachates in a number of hydrometallurgical processes. The aim of this study was to clarify how limestone ground to different particle sizes can neutralize sulfuric acid. The laboratory scale ball mill was used in grinding experiments carried out using ball sizes of 20, 30 and 40 mm and volumetric slurry densities of 30, 40 and 50 percents. Varied grinding times were used in order to produce limestone samples with different particle size classes on which the neutralization potential and rate were determined. The results of the study showed that the neutralization potential of limestone is not dependent on its particle size between 5 and 120 µm. However, the particle size strongly affected the neutralization rate of sulfuric acid: The smaller the particle size, the higher the rate of neutralization. Thus, when optimizing the cost efficiency of the process, the optimal degree of grinding should be considered taking in account the required residence time in neutralization phase.

Sep 1, 2012

By L. Pan

As an air bubble approaches a mineral surface, a thin liquid film (TLF) is formed in between. The excess pressure (p) in the film determines the kinetics of drainage, which is of critical importance in flotation. We have developed a new method of monitoring the kinetics for both stable and unstable wetting films and analyzed the results using the Reynolds lubrication theory. It has been found that initially a TLF is thinned by the Laplace pressure (pcur) due to changes in bubble curvature and subsequently by the disjoining pressure (?) created by the surface forces present in a wetting film. In the present work, we have derived an analytical expression for determining ? from the temporal and spatial profiles of TLFs on mineral surfaces. The results show that ? > 0 in a film formed on a hydrophilic surface and ? < 0 in a film formed on a surface hydrophobized by collector. Thus, the role of collector in flotation is to create a hydrophobic force and hence a negative disjoining present in wetting films. It is also found that smaller bubbles can create higher Laplace pressure, which helps the TLF drain faster.

Sep 1, 2012

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By G. H. Lind

The Minerals Tertiary Education Council (MTEC), over the past decade, has worked closely with Australian higher education partners in metallurgical education to build capacity in this discipline to deliver high quality graduates for the Australian minerals-industry. This paper explores the benefits of industry engagement through a national innovative collaboration, the Metallurgical Education Partnership (MEP), and specifically the final year Process Design Project (PDP), over the four year period from 2008-2011. Some of the benefits discussed in this paper include outcomes of the student experience during an industry-intensive workshop, collaboration between higher education providers and aligning graduate attributes to meet industry requirements.

Sep 1, 2012

By A. K. Suri

India plans to increase the nuclear power share in overall energy-mix to about 30% by 2032 using both indigenous and imported reactor technologies. In the immediate time-frame, it is envisaged to generate 10000 MW electricity by PHWR technology by 2020 using indigenous uranium resources. This necessitates setting-up of new uranium mills and augmenting the existing resource, mining and milling capacities. This paper describes the current status and future R & D needs towards achieving the targeted demand of yellow-cake. Keywords: uranium, hydrometallurgy, leaching, yellow cake

Sep 1, 2012

By Y. Q. Yang

Jig is a kind of conventional and old gravity concentration equipment, which is mainly used in the preconcentration of medium particle fractions of low-grade nonferrous metal ore. In the past ten years, studies on jigs have made a great progress on separation of coarse and fine particle fractions. At the same time, pneumatic jigs have been widely used in processing of nonferrous metal ore. In this paper, pilot test study and commercial operation for several kinds of jigs used in Dachang con-centrator has been introduced. Dachang mining area of GuangXi province is rich in mineral resources, where many minerals exhibit various complex properties. Many elements such as Sn, Pb, Sb, Zn, S, As, Cu, In, Ag, Gd, Ag, Ga, etc, were found in the run-of-mine ore (ROM). At present, Dachang concentrator produces tin concentrate, lead-antimony concentrate and zinc concentrate. Other valuable elements get enriched and recovered in above concentrates. Dachang Mine with a mining operation history more than sixty years will end its mission on the rich ore resource exploitation. At present, low grade ores are porcessed in the concentrator, and the concentrator begins to run at a loss upon processing the low-grade and refractory ore. Heavy medium cyclones were used in the concentrator for processing 20-4mm fraction, Gongge jigs for 4-2mm fraction, and cone concentrator combined with spiral concentrator to discard the tailings of -2mm fractions. In order to minimize overgrinding, table flotation was used to recover some liberated cassiterites in a complex processing technology. Therefore, the concentrator is difficult to manage. Many years studies have shown that heavy medium cyclones and spiral concentra-tors can be replaced by sawtooth shaped wave jigs to discard 50% tailings to improve the grade of feed. And the feed was divided into rich one and poor one to minimize overgrinding of valuable cassiterites with different grinding mills. In this case, the recovery of the valuable minerals can get improved and the flowsheet was simplified. Moreover, the concentrator begins to make profit with reduction of cost. At the same time, pollution in the concentrator gets reduced and the working condition gets improved too. Sawtooth shaped wave jig was used in Changpo concentrator for replacement of cone separators and spiral concentrators to discard the tailings of -4mm fraction, and the yield of discarded tailings got improved from 30% to 50%. Grades of tin, lead and zinc in the tailings are lowered from 0.15%, 0.12%, 0.7% to 0.06%, 0.05%, 0.4% respectively, with a loss reduction of tin, lead and zinc from11%, 9%, 10% to 7.5%, 6%, 5% respectively, corresponding to the increasement of recovery of tin, lead, zinc from 52%, 50%, 55% to 56%, 56%, 62% respectively. Cost of the concentrator for processing one-ton ROM was therefore dropped from RMB155.28 to RMB119.74. Changpo concentrator lost RMB2.5 million in 2003, but it made a profit of RMB0.92 million in 2006 after the innovations. Batac jig was used in Tongkeng concentrator to discard the coarse tailings at 20-4mm, with a discarded yield of 35%, and the grades of valuable minerals got improved with a recovery above 95% for tin, lead-antimony and zinc.

Jan 1, 2014

The flotation behavior of kaolinite and diaspore using N, N-diethyl dodecyl amine (DEN12) and N, N-dimethyl dodecyl amine (DRN12) as collector have been investigated through flotation experiments. The mechanism of adsorption of two tertiary amine collectors on surface of kaolinite and diaspore were investigated by FTIR spectral, Zeta potentials measurements and calculation of molecular orbital energy. It has been found that DEN12 and DRN12 have stronger collecting power to kaolinite and weaker collecting abilityto diaspore than DDA. Kaolinite and diaspore in bauxite ores can be separated by using DEN12 and DRN12 as collectors at pulp pH below 8 and 6, respectively. The results of zeta potentials and calculation of molecular orbital energy indicated that the adsorption strength on kaolinite surface is in the order DEN12>DRN12>DDA and the adsorption strength on diaspore surface is in the order DDA>DEN12>DRN12. FTIR spectral analysis and Zeta potentials approve that the action between kaolinite and tertiary amine collector is strong electrostatic adsorption and that of diaspore is weak electrostatic adsorption in the range of pH 5~6.

Jan 1, 2014