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By J. E. Nesset, J. A. Finch, Rosenblum. F., S. Somot

"In a previous presentation at the CMP, evidence was shown for the formation of hydrogen sulphide (H2S) in self-heating experiments on pyrrhotite-rich samples (Somot and Finch, 2006). Oxidation of H2S is strongly exothermic leading to the proposition that H2S is playing a key role in the self-heating process. Subsequently, tests in two weathering apparatus (I and II) were run under varying oxygen levels to further examine conditions leading to self-heating. To characterise their resulting self-heating capacity the samples from the weathering tests were subjected to a modified Stage B test using the self-heating apparatus developed by Rosenblum and co-workers (Rosenblum and Spira, 1995; Rosenblum et al., 2001). Results showed highest self-heating after weathering occurs under low oxygen conditions, supporting the H2S hypothesis. It was observed that highest heating rates are not directly related to highest weight gains of samples.INTRODUCTION“Sulphides” refer to several types of minerals containing sulphur in its lowest oxidation state of - 2. Self-heating is the spontaneous heating of a material without external heat input. It is well established that some sulphides will self-heat on exposure to moisture and oxygen (Farnsworth, 1977; Good, 1977; Rosenblum et al., 2001; Wu and Li, 2005). This process is highly exothermic and if the heat generated is not dissipated, combustion may occur when the temperature reaches the ignition point of the sulphide (typically 350-400 °C). The hazards of sulphide self-heating range from handling hot material, to sulphur dioxide release, to fires. The literature documents self-heating incidents underground, on ships and trucks transporting sulphide concentrates, and in mine waste (tailing) disposal areas (Stachulak, 1990; Lukaszewski, 1969; Headley et al., 1977). Lukaszewski (1969), Farnsworth (1977), and Good (1977) note that sulphide minerals can act as fuel to promote underground mine fires. Based on such findings, sulphide minerals could become classified as hazardous materials, making transport of concentrates and storage of mine waste subject to stricter and more costly regulation. The problem is one the industry is keen to avoid."

Jan 1, 2009

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By F. O. Verret

Several grindability tests were developed over the years to design grinding circuits or optimize existing operations. Each test has its own strengths and weaknesses and it is imperative to select the proper test procedure(s) to meet project deliverables and minimize the risk of a project. Pilot plant testing of large bulk samples historically constituted the traditional approach for AG or SAG design, but was gradually replaced by small-scale tests. Nowadays, conducting grindability tests requiring only a few kilos of material on several samples is a more typical approach to grinding mill design. This paper summarises the requirements and deliverables of various bench-scale test procedures, their strengths and weaknesses, and cases where AG/SAG pilot testing should still be performed.

Jan 1, 2012

By J. A. Meech, R. J. Tucker

"Since the establishment of froth flotation as an effective method of mineral beneficiation there has been both academic and industrial interest in the levels of the various reagents required to perform the desired separations. Academic interest was spurred by a desire to understand the mechanisms involved - industrial interest by a need to improve the efficiency of the process. These efficiency improvements can take two forms: cost reductions due to reduced reagent consumption and/or improved separation efficiencies. The latter are indicated by either improved grade-recovery relationships for removal of a valuable mineral from gangue, or improved separation of two similar valuable minerals.The processing of lower grade ore bodies at higher tonnage rates has necessitated increased interest in both reagent consumption and metal recovery. Furthermore, the development of accurate and functional on-stream analysis equipment in the 1960's and 1970's has allowed for a better understanding of the dynamic processes involved in a flotation circuit and has required a more concrete statement of the relationships and reactions between the minerals and chemicals in the flotation pulp. Development of these relationships is necessary in order to make use of on-stream analysis to control the process at, or near its more efficient level."

Jan 1, 1984

By H. Cay, J. Zachwieja, T. Esplin, R. Ravenelle, T. Olsen-Tank

Barrick Goldstrike mine utilizes a carbon-in-leach (CIL) circuit to simultaneously leach gold into solution with cyanide and adsorb the gold-cyanide complex onto activated carbon for further refinement. If the gold bearing ore contains a significant amount of native carbonaceous material, gold cyanide can be adsorbed at these sites instead of onto the desired activated carbon and the gold is effectively lost to tailings in a detrimental process known as "preg-robbing." The preg-rob effect is considerably reduced by treating the ore with a surfactant, which is hypothesized to adsorb to and passivate the native carbon surfaces. Past laboratory and pilot studies have consistently demonstrated significant gains in gold recovery after treating carbonaceous ore with surfactant. With success in bench and pilot scale testing, a plant trial was conducted at Barrick Goldstrike to evaluate the feasibility of using an alkoxylated fatty amine surfactant (Ethomeen T/12) to aid in the leaching of high preg-robbing ores. This paper analyzes the performance of the surfactant during the plant trial in addition to the problems that occurred during the trial period. Suggestions for improvement are also discussed.

Jan 1, 2014

By G. Azimi, K. K. Varanasi1, A. T. Paxson, R. Dhiman, H. -M. Kwon

Hydrophobic materials that are robust to harsh environments are needed in a broad range of applications. Although durable materials such as metals and ceramics, which are generally hydrophilic, can be rendered hydrophobic by polymeric modifiers, these materials deteriorate in harsh environments. Here it is shown that a class of ceramics comprising the entire lanthanide oxide series, ranging from ceria to lutecia, is intrinsically hydrophobic. Their hydrophobicity is attributed to their unique electronic structure, which inhibits hydrogen bonding with interfacial water molecules. In addition, this work demonstrates that these ceramics sustain hydrophobicity even after exposure to high-temperature environment (1000 °C for 2 h in air). It is envisioned that this class of robust hydrophobic materials will have far-reaching technological potential in various industrial applications, where water repellency and dropwise condensation are desirable.

Jan 1, 2014

By Stefan Wallner, Andreas Filzwieser, Stefan Konetschnik, Reinhard Preiss, Iris Filzwieser

"Process Safety Management for METTOP means avoiding risks as far as possible - but also dealing with the residual risk by using all existing management tools or external assistance, if required. The presented paper has two parts. The first one introduces a new and very safe cooling technology for metallurgical furnaces. The second part shows how to deal with the residual risk as well as minimize it by using the tapping area of an electric arc furnace as an example.Today more and more intense furnace operations require effective cooling in order to achieve low refractory wear and good furnace lifetime, making cooling technology an important aspect of furnace operation. However, the use of water - today’s standard cooling medium - has some disadvantages, as it can cause problems both during furnace start up and operation, namely hydration problems, corrosion, and explosion.To overcome the disadvantages of water, a new cooling technology using an alternative cooling medium, namely ISIS B (a special kind of ionic liquid) was developed. The main advantage of ISIS B is the fact that no explosion occurs when this liquid comes in contact with molten metal. The working temperature range of ISIS B of 50 to 200 °C results in other advantages as there are no corrosion problems and no risks of hydration.The fact that no explosion occurs when ISIS B contacts molten metal leads to a revolutionary solution for the metallurgical industry in terms of safety. Especially in critical areas - like tap-holes - new safety standards can be achieved.Together with the TÜV Austrian Holding AG a risk analysis was done for a water cooled tap-hole as well as for a tap-hole cooled with ionic liquids. It is shown that using the new technology the risk can be decreased dramatically and the importance of a best available technology is described."

Jan 1, 2014

By S. Gorzalczynski

The recent trend in underground mine developments is “bigger is better.” This is most certainly evident in the mine shaft and conveyances that operate within its compartments. Today, there are several new installations requiring mine cages that can transport up to 170 passengers. The technology in mine hoisting is advancing to address a combination of higher capacity requirements, deeper hoisting depths and faster winding rates, however, some areas of the hoist plant have not changed in the past 50 years. The most notable of these areas is the shaft compartment guide string and the conveyance mounted safety arrest mechanism. The technology in use today for the protection of passengers in a shaft conveyance from a hoist rope severance incident remains conceptually unchanged from Elisha Otis’ design of 1850. The actual retardation components, the safety dogs, have taken on several forms since Elisha’s invention with the last major design change occurring in the late 1940s. The arrest of a free falling shaft conveyance requires that the shaft guides withstand the energy imparted on them by the safety dogs. There are some very real limitations presented by the use of wood for this application. The new hoisting era will most certainly continue to demand larger capacity equipment, but also an increased awareness toward safety

Jan 1, 2002

By Diankun Lu, Ganfeng Tu, Edouard Asselin, Feng Xie

A novel separation process for detoxifying cadmium-containing residues arising from zinc hydrometallurgical processes has been developed. An initial investigation indicated that a high concentration of zinc in the sulfate solution can be effectively separated from cadmium by solvent extraction with P204 (di(2-ethylhexly)phosphoric acid, D2EHPA). The mixture of sulfuric acid and ammonium citrate ((NH4)3C6H5O7) is thus used to extract metals from the residue at room temperature. Copper in the leachate is recovered by solvent extraction (SX) with LIX 973. Cobalt in the raffinate from the copper SX process is recovered by precipitation with a-nitroso-ß-naphthol. The results show that more than 50% of the copper and virtually all the zinc, cadmium and cobalt in the residue can be leached under the experimental conditions used here. Virtually all dissolved copper and cobalt can be recovered in the subsequent solvent extraction and precipitation processes. The presence of (NH4)3C6H5O7 could significantly facilitate the extraction of zinc by D2EHPA in the subsequent separation of zinc and cadmium. More than 97% of the dissolved zinc can be recovered through a two-stage counter current solvent extraction process. After separating copper, cobalt and zinc, cadmium can easily be recovered from the solution either by cementation with zinc powder or by electrowinning, while the purified solution can be recycled back to the leaching process.

Jan 1, 2014

By Mario Morin

The application of underground pre-concentration technology to narrow vein mining has the potential to change the entire economics of bulk mining methods when used in narrow vein situations. The rejection of waste at or near the face means that a higher-grade ore can be sent to surface. The waste rock can be reused directly as backfill. Swelling of the muck through blasting means that only 60 to 65% can be used as fill. Planning and scheduling of the fill usage is key to the success of this method. Through the use of simulation and system analysis, this paper examines the planning and scheduling implications of underground pre-concentration when applied to traditional narrow vein mining methods (cut-and-fill /drift-and-fill, longhole, AVOCA). It considers the logistical factors that represent potential system bottlenecks that are key to understanding the correct implementation and control strategies.

Oct 1, 2004

By Frédéric Flament, Luc Lachance

"The important task of metallurgical accounting that used to be done manually is being more and more automated. Currently available solutions can generate accounting reports without human intervention or almost. However, the practical conditions for fully delivering the promised benefits of those solutions are sometimes overlooked either by end-users or by integrators. The mere fact of filling reports with values satisfying several constraints such as mass conservation constraints does not, by itself, ensure a high quality metallurgical balance. Since managers make decisions based on these reports, it is logical that the metallurgical balance performance be monitored and retrofits be made if necessary. Such retrofits may involve modifications to the measurement strategy or the reduction of the spatial resolution of the material balance model. This requires an estimability and redundancy analysis (ERA) tool to assess the feasibility of the modified model. Since determining by hand the estimability and redundancy of a set of non measured and measured variables is not trivial, even for a medium-sized mineral processing plant, a dedicated ERA tool brings valuable assistance to the metallurgist in charge. The present paper aims first at explaining how a state of the art metallurgical balance is a key enabler for the adoption of a smart process plants paradigm (SPPP) in mineral processing. Then, the fundamentals behind the building of an ERA algorithm are introduced and illustrated by two examples. Finally, the role of an ERA tool in achieving state of the art metallurgical accounting and how it contributes to delivering additional value are discussed.INTRODUCTIONThe Smart Process Plants Paradigm (SPPP)Mineral processors have seen an increase lately in external pressures toward operating performance improvements. Indeed, the globalization of the mining business is a key driver to becoming more productive, more responsive to market changes, to improving corporate governance and reporting standards. Furthermore, mineral processors are also expected by their neighbouring communities to continuously improve their sustainability score. These current pressures differ somewhat from the past ones in leading to a larger than ever number of conflicting constraints that plant managers must concurrently satisfy while maximizing plant profitability. It is in turn not surprising that this context requires actions involving more real-time collaborative actions between more people in more places than ever before."

Jan 1, 2011

By M. Leroux, S. R. Rao, J. A. Finch

"Poor Pb-Zn selectivity during Pb flotation in laboratory tests on a Mississippi Valley-type Pb-Zn ore was traced to apH effect. In the pH range, 9.5 to 11.0 sphalerite floated readily without copper activation. Compared to sphalerite flotation with copper activation this procedure gave equivalent selectivity but reduced flotation rate.Possible mechanisms of this sphalerite flotation without copper activation are discussed. Activation by Fe(OH)2 is suggested, the Fe- + ions being derived from superficial oxidation of pyrite in the ore. IntroductionGalena and sphalerite commonly occur together. A typical procedure, using xanthate collectors, is to float the galena first, at pH - 8, followed by flotation of sphalerite after activation with copper (II) sulphate at pH - 10 (to depress pyrite).Flotation tests following this procedure in an undergraduate laboratory course with a Pb-Zn ore from Polaris failed to achieve consistent selective flotation of galena. Occasionally a considerable amount of sphalerite, even though unactivated with CUSO4, floated. This was traced to accidentally high pH. A systematic study was carried out which revealed that sphalerite floated readily in the pH range 9.5 to 11.0 without activation by CuSO4 This paper describes the results of the study and discusses a possible mechanism of this flotation of sphalerite."

Jan 1, 1987

By Derek Ettie

"In the Hydrometallurgical processes, the presence of the so-called "crud" is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design.The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the series-connected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation.The transfer of the organic phase into the electrolysis cell can result in a "burnout" of the cathode. The carryover of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show.To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl® by this means, we can guarantee our customers the maximum possible solvent recovery and minimize the solvent costs in this process step. This system is presented in detail in this paper."

Jan 1, 2014

By D. E. Calisaya, É. Poulin, A. Desbiens, R. del Villar, A. Riquelme

"A 15 cm diameter by 732 cm height, fully automated pilot column was installed in the Agnico-Eagle’s Laronde concentrator (Québec), for evaluating the performance of newly developed sensors and advanced process control algorithms. For eventual comparison purposes, the pilot column is continuously fed with the same slurry feeding the copper-circuit third cleaner column. It is equipped with electrical conductivity-based sensors for estimating the three variables used in the multi-variable control algorithm under evaluation: froth depth, fraction of wash water underneath the interface and gas hold-up. Froth depth is regulated using a PI controller while a predictive controller is formulated as the minimization of the tracking errors of gas hold-up and bias rate, keeping several operating constraints between their practical upper and lower limits. In particular, an unreachable high set point of gas hold-up can be selected in order to maximize the bubble surface area available for particle collection, while maintaining bias rate above a minimum value required for froth cleaning. The proposed strategy may indirectly help optimizing flotation column operation by using these secondary variables, without the implementation of a real-time optimization layer.INTRODUCTION Flotation columns have already been used for more than 30 years, mainly in cleaning stages, as a result of their froth washing capabilities. Despite their widespread usage, the measurement of some pertaining variables and their use for automatic control is rather scarce. Among the most important variables directly related to the process metallurgy (concentrate grade and recovery), froth depth (hf) is the only one normally monitored and controlled. Even though commercial sensors are available, gas hold-up (eg), a variable directly related to concentrate recovery, is seldom measured and never controlled. Another important variable, bias rate (Jb) responsible for concentrate cleaning, is simply not measured at all, as there is no commercial sensor available. Therefore, besides froth depth, continuous monitoring of process variables is limited to flow rates (gas, feed, tailings, wash water), i.e. to manipulated variables. Some new available sensors have been industrially tested, e.g. the Sonar-TracTM for eg (O'Keefe, Viega & Fernald, 2007) and the McGill hold-up sensor (Tavera & Escudero, 2002). Others, for bias rate and frother concentration, have been successfully validated at laboratory scale by Laval’s LOOP researchers (Maldonado, Desbiens, del Villar & Chirinos, 2008b; Maldonado, Desbiens, del Villar & Aguilera, 2010a). Some devices have been extensively used for monitoring bubble size and space distri-bution, e.g. McGill bubble viewer (Gomez & Finch, 2007) and others."

Jan 1, 2012

By Jarek Jakubec

The new euphoria in diamond exploration brings with it a need to understand the challenges that new projects can face in different stages of the development and risks that the commercial outcomes from the new projects fall short of expectations. In many cases, the problems are related to a poor understanding of the technical risks and a failure to adequately address them during the course of investigation. Failure to evaluate all disciplines to the same level of certainty could lead to a situation where the important issues are only identified late in the project development, resulting in costly delays and financial difficulties. The diamond projects located in Canadian Arctic, with its challenging environmental, geographical, social, political and geological contexts are especially sensitive to the high variability of the outcome. This presentation highlights some of the technical aspects that could be the leading sources of risk in diamond projects and could ultimately result in inappropriate mine designs, reducing the economic outcome.

May 1, 2006

By V. “Ram” Ramachandran

"In view of the increasing number of environmental regulations that have been promulgated all over the world in the last thirty years, non-ferrous smelters and refineries have had to learn and adapt to treating process bleed waste streams containing heavy metals. The result of such treatment invariably yields a gypsum-saturated solution containing salts such as alkali metal sulfates, chlorides and fluorides. Presence of anions such as sulfates, chlorides and fluorides in the discharge streams – presently not a major problem- are coming under increasing scrutiny and will have to be addressed in the near future. It is envisaged that discharge limits for sulfate ions will be in place in the near future. Treatment of brackish water to produce drinking water also results in brine streams containing alkali salts that have to be addressed for proper disposal. This paper reviews treatment options for such streams containing high levels of total dissolved solids with emphasis on sulfate removal. Areas covered would be: a) chemical treatment for removal of various constituents that make up the total dissolved solids b) processes for sulfate removal processes –thermal and non-thermal-to recover and reuse of treated water and c) brine use and treatment options.INTRODUCTIONThe rising cost of water and meeting the ever-changing stringent environmental discharge regulations make water recycling and reuse essential. The metallurgical industry has used water as a medium for dissolving and/or rejecting metals and chemicals in addition to removing thermal energy. Any excess process effluent is collected and sent to end-of-pipeline treatment and ultimately discharged to surface water for disposal under a permit. The conventional- and probably the cheapest way -of treating metal-bearing process effluent streams is lime neutralization followed by sulfide polishing for elimination of heavy metals to produce a stream that meets NPDES discharge limits. This results in a stream containing dissolved solids.These dissolved solids normally comprises of inorganic salts. The possible constituents are cations calcium, magnesium, sodium and potassium. The anions are sulfate, chloride, fluoride, nitrate, carbonate and bicarbonate. In addition to these constituents, the treated effluent streams contain very small amounts of heavy metals, oxyanions such as arsenites, arsenates, selenites and selenates. Process streams from gold operations contain residual cyanide. Small amounts of ammonium ions are also present in these streams based on the pH of the solution."

Jan 1, 2012

By Rocky (Yaokun) Wu

This paper introduces the development and application of a new cable anchor - Cable-Lok for pre-stressed cable bolting in mines. Cable-Lok is a spring-loaded cable anchor suitable for the drill hole diameter of 50 and 65 mm (2" and 2.5") in medium soft rock to hard rocks. The cable anchor is automatically set on installation and the cable can be tensioned immediately to provide active and primary support throughout its length. Post-grouting can be conducted independently. In comparison with the conventional cable bolting, Cable-Lok anchor will greatly speed-up the cable bolting circle and decreases the cost of cable bolting. Cable bolting anchored with Cable-Lok anchor has wide application in mines, e.g. pre-stressed cable bolting in large span drifts and intersections for permanent rock support, or in hanging walls or stopes for temporary support, or cable lace anchoring etc. This paper introduces the principle of pre-stressed cable bolting and the specifications of the Cable-Lok anchor, presented the testing results in laboratory and the application cases in mines.

Oct 1, 2010

"This generic study has been developed in response to the frequently asked question, ""That is the best treatment route for refractory gold ore?"". The study has developed operating and capital costs for many potential treatment routes and they are presented here in a generic form. All costs are in relation to the value of 1.00 given to the base case, a 1000 mtpd bio-oxidation plant, operating at 25% solids and 72 hours residence time.There is unfortunately no simple answer to the above quest ions. The treatment of refractory ores is a complex subject, with many variables, such as mineralogy, chemistry, environment and tonnage. However this study does offer information and relative numbers that we believe will be of assistance to gold metallurgists in obtaining a ""first shot"" at estimating costs.Equally, this technology is a rapidly evolving one. As more plants are commissioned, and test programs completed, better data is constantly being generated. For a generic study of this type to remain useful it will need regular updating and adjustment."

Jan 1, 1989

By Hiroaki Sakurai

Using batch reactors equipped with CO and CO2 gas sensor, CO oxidation over Au catalysts in room air has been investigated and compared with Pt catalysts. For both Au and Pt catalysts, the logarithm plot of CO concentration data during initial 10 min are well fitted by straight line, which mean the first order dependence on the CO concentration between 10 and 10,000ppm. The rate constant value (k) over Au and Pt catalyst generally decrease with increasing initial CO concentration above 100ppm. The value decrease especially rapidly between 100ppm and 1,000ppm over Pt catalysts, which should be due to the strong adsorption of CO on Pt. The k value over Au catalyst has become ten times or more as large as the Pt catalysts at 1,000ppm. Already for the initial concentration of 100ppm CO, the strongly adsorbed CO on Pt metal has been clearly observed by FT-IR during the reaction over Pt/Al2O3. A part of the strongly adsorbed CO has been remained on Pt after the disappearance of gas phase CO, and has gradually changed to gas phase CO2. Such strongly adsorbed species on Au has never been observed on Au/TiO2 under the same reaction conditions. These features of Au catalysts are favorable for indoor air purification.

Oct 1, 2003

By L. Flett, S. Woods, C. Deredin

"Following a significant reduction in world Imperial Smelting Furnace (ISF) capacity from 2003 to 2008, a major optimization initiative was successfully carried out on the lead upgrading and bulk (zinclead) flotation circuits in the Brunswick Concentrator.This paper describes the process improvements that have taken place in order to reduce the quantity of bulk concentrate:•,Increase in lead upgrading rougher flotation circuit capacity•,Installation of a closed-circuit bulk regrind utilizing MillPebs and 150 mm Cavex hydrocyclones•,Installation of two additional cleaner flotation stages on the bulk circuit•,Optimization of the manipulated variables in the lead upgrading and bulk circuitsINTRODUCTIONThe Brunswick Mine (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The planned closure of the mine will take place at the end of the first quarter in 2013. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.A simplified flowsheet for the concentrator is given in Figure 1. The overall flowsheet involves SAG milling, secondary ball milling, selective flotation, and dewatering by thickening, filtering and drying. The complexity of the flowsheet evolves from the requirements for fine grinding and the production of four concentrates: zinc (sphalerite), lead (galena), copper (chalcopyrite) and bulk (sphalerite plus galena).Primary hydrocyclone overflow feeds the copper-lead aerator-roughers for flotation at pH 9.0 with soda ash. Plant xanthate (80-20 sodium isopropyl and potassium amyl) and AP407 are used as collectors in the copper-lead circuit. The rougher concentrate is directed to the copper-lead regrind circuit and the tailings are fed to the secondary grinding circuit. The secondary hydrocyclone overflow from the secondary grinding circuit feeds the copper-lead rougher-scavenger banks. Rougher concentrates are reground to a P80 of 28 µm prior to three stages of copper-lead cleaning. The first stage of cleaning is done in an open circuit with the tail reporting to the cleaner scavenger. The cleaner scavenger concentrate reports to the regrind circuit and the cleaner scavenger tail combines with the rougher/scavenger tail to feed the zinc circuit. The second and third stages of cleaning are performed in closed circuit with the cleaner tail being recycled to the copper-lead regrind circuit. The average final concentrate grades 23% Pb, 3% Cu and 704 g/t Ag, and is fed to the copper separation circuit."

Jan 1, 2013