Search Documents

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By J. C. Keenan

Company-community agreements are widely considered to be a practical mechanism for recognising the rights, needs and priorities of peoples impacted by mining, for managing impacts and ensuring that miningderived benefits are shared. The use and application of company?community agreements is increasing globally. Notwithstanding the utility of agreements, the gender dimensions of agreement processes in mining have rarely been studied. Prior research on women and mining, however, does show that women are often more adversely impacted by mining than men, and face greater challenges in accessing development opportunities that mining can bring, however there is currently little to no guidance for companies, government or communities in terms of bringing a gender perspective to the fore in mining and agreement processes. While it is undisputed in human development literature that investment in women and sensitivity to gender delivers long-term health, education and local development outcomes, a number of key factors remain unexplored in debates about mining and development. These include: women?s participation in agreement processes, the gendered distribution of agreement benefits, and the extent to which impacts and benefits influence (either positively or negatively) women?s development and economic inclusion. This paper presents the results of an applied research project undertaken by the Centre for Social Responsibility in Mining (CSRM) at The University of Queensland and funded by a partnership between the Minerals Council of Australia (MCA) and the Australian Agency for International Development (AusAID). The project sought to connect with practitioners who had been directly involved in agreement processes to hear grounded perspectives on the interaction of gender dynamics and agreements, and connect those experiences with the broader literature. Findings from this study have implications for the role of companies and governments in promoting gender equality and empowerment as part of their commitments to sustainable development. A key challenge for companies will be navigating the territory of cultural norms and gender equality. The authors argue that without consideration of the gender perspective, and appropriate responses, mining agreements may not be inclusive or representative and may exacerbate gender inequalities and fail to contribute to long-term sustainable development.

Aug 1, 2013

By F. Barriga-Ordonez, J. A. Finch, L. Calzado, S. R. (Ram) Rao

Sludge, formed by lime treatment of acidic drainage and stored in tailing ponds of the Sudbury region, contains 5-7% Ni, mostly in a mix of hydroxides with Fe (~ 10%), Mg (~ 10%) and Cu (-0.5%), and Ca (-3.5%) as sulphate. Investigations were conducted to recover nickel by a 2-stage process. In the first stage, the sludge was leached with sulphuric acid at pH 3.2. About 90% of the nickel was extracted, producing a solution, which contained mainly nickel (2 g/L) and magnesium (3.7 g/L). In the second stage, nickel was separated by treating with ozone which recovered 99% of the nickel in the Ni(III) oxidation state as -85% pure nickel oxide-hydroxide (NiOOH) precipitate. The oxide settled and filtered readily. A potential use of the product in battery making is suggested. The leach residue contained 0.5% Ni making it less toxic for disposal. Some physical properties of nickel oxy-hydroxide and process parameters including ozone consumption will be discussed.

Jan 1, 2005

By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By T. G. Ewart

INTRODUCTION FOR THE purpose of this paper, western bituminous coal is defined as steam coal produced in Alberta and southeastern British Columbia for sale primarily to railways and industries. Before examining present and future markets of this industry, it is proper to review briefly financial and operating conditions within the industry. The report of the Royal Commission on Coal, 1946, supplies financial data from which some conclusions may be drawn. In 1944, the industry as defined above had share capital of $24,886,696. In the fifteen years 1930 to 1944, inclusive, the industry produced: 44,364,211 tons of coal. The profit on this tonnage amounted to $4,678,382.58, which represented 10.6 cents per ton of production. Miscellaneous earnings increased the amount available for dividends to shareholders to a total of $8,487,952.41, which is equal to, 19.1 cents per ton of production. Dividends actually paid in this fifteen-year period amounted to $12,332,040.64, which represented an annual average rate of 3.40 per cent on share capital. It is worthy of note that, in 1944, the net current position of the industry, including investments, was $8,753,874.51. The writer believes that the financial position of the industry with respect to capital, current financial position, and net earnings, has not significantly changed from the fifteen-year period out-lined above. The figures quoted indicate the following situation: (1) The western bituminous coal industry is adequately financed. (2) The industry has followed a conservative dividend policy and has accrued funds for contingencies. (3) The industry has sold its production at very reasonable prices as evidenced by its moderate earnings per ton of production.

Jan 1, 1951

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By Pravin Mathur

"Praxair's CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

By W. J. Blackstock

Introduction To The great majority of people, the term 'strip coal' has little or no meaning, or if it has any significance it is thought to refer to a poor grade of coal that had to be accepted during the war because no other fuel was available. Few people in the Province of Alberta realize the magnitude of our coal stripping industry, and fewer realize that strip coal has been available to domestic consumers for at least forty years. Among the first in the field of strip coal mining in Alberta were the Tofield Coal Company, Ltd., and Sterling Collieries Company Ltd. It was not until the advent of World War II, with its huge drain on industrial and domestic coal sup? plies produced by the underground mines, that some other source of coal was seriously sought. The tremendous shortage of manpower du ring this period of National emergency made it imperative that any increase in the coal production must be procured on a high tonnage per man-hour basis. It was therefore natural that the highly mechanized strip mine should be eagerly encouraged and subsidized by the Governmental agency - the Emergency Coal Production Board - under the very able direction of Mr. G. A. Vissac.

Jan 1, 1949

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

By S. Sundararajan, Z. Lin

ABSTRACT Fierce market competition and demand have made it imperative for mining companies to achieve higher productivity and operational efficiency. The selection of the best mining method and equipment combinations will enable companies to meet production and efficiency targets. Continuous mining is increasingly preferred by companies for its high efficiency and low unit costs. We developed simulation models for two continuous mining systems: the continuous surface miner (CSM) system and the at-face slurrying (AFS) system. Considering two different case studies, the paper discusses application of developed models to determine the optimal number of trucks and equipment capacities for the two systems.

Jan 1, 2013

By Magdy Ibrahim

This paper presents experimental design and development of a low-cost remote sensing hardware designed to support automated site data acquisition for near real-time progress reporting of construction operations. The developed hardware utilizes open source microcontroller equipped with multiple sensors that include 3D accelerometer, GPS, Data logger and Bluetooth. The use of open source microcontroller makes the developed design cost effective; freeing it from the need for costly license fees. Its platform configuration is flexible; enabling the addition of temperature, weight and other sensors, Wi-Fi and Xbee capabilities to suit individual field applications. Pilot tests have been carried out in laboratory and outdoor environments. The results prove effectiveness and robustness of the developed configuration. The paper provides description of the individual components used in the development of this prototype hardware. It also describes the technical characteristics, capabilities and limitations of the developed hardware. The findings of comparison with alternative technologies used for outdoor tracking of construction operations are presented. The comparison is carried out with respect to range, cost and suitability for outdoor environment. The developed hardware is expected to support a wide range of applications including tracking of earthmoving operations, highway construction and onsite resources. As well, it is expected to enhance safety on construction jobsites.

Aug 1, 2013

By Olav Mejia

The rising energy costs and environmental considerations in mining necessitate the development of energy-efficient copper and gold processing plants. This paper presents an analysis of technical strategies aimed at reducing energy consumption in these plants. Key approaches include the integration of advanced ore sorting technologies, High Pressure Grinding Rolls (HPGR), Coarse Particle Flotation (CPF), and high-intensity flotation. Ore sorting enables early-stage waste removal, reducing the downstream processing load and associated energy use. HPGR technology, recognized for its energy efficiency, contributes to significant energy savings in comminution circuits by reducing reliance on traditional grinding methods. CPF technology further optimizes flotation performance by enabling the recovery of larger particles, thereby decreasing the need for fine grinding and reducing overall power demand. High-intensity flotation units enhance separation efficiency and mineral recovery in a compact footprint, offering further reductions in energy consumption. Together, these technologies provide energy saving opportunities to achieve a more sustainable and economically viable processing operation. This paper evaluates the effectiveness of each method, highlighting their potential impacts on energy consumption, operational efficiency, and cost-effectiveness in copper and gold processing

May 4, 2025

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

By Marc C. Bétournay

A number of successful proof-of-concept projects have been carried out to replace conventional power application, such as diesel and rechargeable batteries, in underground mine vehicles. This has led to the development of the world?s first fuelcell production vehicle, a mine locomotive. A mine loader project has also started and several other projects are planned. These projects are providing the mining industry with the required information to make this technology shift possible. The application of fuelcell power will yield several important benefits such as the elimination of underground diesel emissions, significant reduction in the primary extraction?s sector greenhouse gas emissions and support for a more productive scenario. This article reviews these successes, discusses ongoing and potential projects and presents the technology application benefits that could be possible for mining operations.

May 1, 2003

By Roger T. Laine

"The Carswell structure, located in the western part of the Athabasca Basin, northern Saskatchewan, has been extensively explored since 1967. This exploration has been successful and lead to the discovery, in 1970, of the D sandstone-hosted unconformity related deposit. By the end of 1984, five additional basement-hosted unconformity related deposits had been delineated: the OP and N discovered in 1970, the Claude in 1971, the Dominique-Peter in 1981, and the Dominique-Janine in 1984. The D deposit has been mined out; the Claude open-pit has already produced more than 500 tonnes of uranium, the development of the Dominique-Peter underground mine (first phase) has been completed, and production from the latter started in 1985.All six deposits are located in the southern part of the Aphebian metamorphic core, 18 km in diameter, which has intruded at least 1250 metres of Helikian Athabasca Group sediments during a cryptoexplosion event at 480 Ma, unrelated to the emplacement of uranium mineralization. The metamorphic rocks, affected by the Hudsonian Orogeny, are divided in two lithostratrigraphic units: the Peter River gneiss, aluminous gneiss series, and the Earl River complex, mixed quartzofeldspathic and mafic gneiss series. A well developed regolith profile is recognizable in the south along the contact with the sandstone and inside the metamorphic core sometimes associated with conformable sandstone beds.Basement and sandstone-hosted uranium deposits show many similarities:-linkage to unconformity;-mineralogy and geochronology with a first phase mineralization characterized by a polymetallic sulphide-uraninite-brannerite assemblage dated at 1150 to 1050 Ma, a second phase characterized by a simple sulphide-uraninite assemblage dated at 890 to 820 Ma, and a third phase characterized by a pitchblende-hematite dated at 380 Ma; and,-linkage to early Hudsonian structures with remobilization of these structures during intense hydrothermal alteration resulting in Mg chlorite-illite halos."

Jan 1, 1986

By L. Vinnett, T. Ledezma, F. Contreras, F. Díaz

"Mass balances in secondary grinding are subject to critical constraints mainly because of the unknown load distribution from the SAG mills, the uncertainties in the hydrocyclone split estimations and the lack of flowmeters in the key streams. In this paper, a methodology to support mass balances based on the use of radioactive tracer is presented. This approach was successfully implemented in two secondary grinding circuits of Minera Los Pelambres, which operate with ball mills of 21’ x 33.5’. The method allowed the load distribution of the SAG product (secondary grinding feed) to be determined. This load distribution was used as an input in the mass balance data reconciliation.The effective residence times of solid tracers were obtained in the secondary grinding equipment, where irradiated solid was used as a tracer. The residence times were obtained from the parametric deconvolution between the input and output tracer signals. The model fitting was performed to reconstruct the normalized output tracer concentration. Effective residence times of solid tracers in the ball mills ranged from 1.9 min to 9.5 min. The use of radioactive tracer measurement in grinding circuits is a powerful tool to consolidate mass balance results as well as to characterize grinding mills.INTRODUCTIONGrinding is the last stage of the comminution circuits. At this stage, the ore particles are reduced in size by a combination of impact and abrasion, either dry or wet (Austin & Concha, 1994). The grinding equipment mostly used in industrial operations correspond to horizontal tumbling mills (Wills & Napier- Munn, 2006). Tumbling mills employ steel balls or rods as grinding media. Ball mills, which are a type of tumbling mills, use steel grinding media with greater surface area per mass unit than SAG (semiautogenous grinding) mills or rod mills (primary grinding). Hence, the ball mills are suitable to obtain the particle size required in the next separation stages (Napier-Munn et al., 1996; Wills & Napier-Munn, 2006)."

Jan 1, 2016

By Saba Gharedash

In this study the results of a series of numerical simulations which are conducted for one of the tunnels of the Mashhad metro line 2 project are presented to evaluate the role of tunnel face support pressure and soil strength parameters on deformation of tunnel lining and face deformation. To achieve this goal, comparative numerical simulations of a mechanized tunnel advance in soft non- homogeneous soil on top of the ground water table and beneath the building are conducted and sensitivity analysis is performed. Development of a step by step tunnel construction process is modeled using a three dimensional finite difference model (FLAC3D) taking into account all the relevant components of shield tunneling. In order to understand the mechanism of the effects of a variety of support pressures on face deformation and lining stresses, numerical simulations are conducted. It is found that the use of different face supports causes a considerable influence on the forces of tunnel lining. In addition, it is revealed that building weight help to change the stress paths and the stress distributions in the tunnel lining.

Aug 1, 2013

By W. Lin, Z. Z. Dong, C. L. Zhou, Y. C. Kuang

The inversion of rock mechanical properties based on well-logging data is a common method to drillbit selection in petroleum engineering, the basic principle of which is to use deep-well logging data and experimental regression model to calculate rock mechanical properties. The profile of rock mechanical properties can be established. According to the profile, the type of drillbit can be selected in different formations, which will improve the economic benefit of bit use indicators. Compressive strength of rock is one of the most important parameters. Conventional method to establish regression models of acoustic velocity and uniaxial compressive strength is on the basis of rock core sonic experiments and uniaxial compressive experiments. However, with the increase of deep drilling operation, triaxial compressive strength prediction model will play a more vital role in drillbit optimization selection in deep wells and improving ROP (Rate of Penetration). Triaxial compressive strength is an important parameter to evaluate the formation strength property. In this paper, to the sandstone commonly encountered in oil drilling, combined the rock mechanical experimental results with the changing porosity experimental results under confining pressure, a new interpretation model of triaxial compressive strength based on well logging data is proposed. Firstly, three types of sandstone samples are collected. Then measured components, uniaxial compressive strength, triaxial compressive strength and porosity. Experimental results show that: confining pressure has a significant influence on sandstone strength, with the increase of confining pressure, triaxial compressive strength increase; furthermore, the triaxial compressive strength of different porosity sandstones have different change rules when confining pressures changes; sandstone porosity decreases with the increase of confining pressure and it obeys logarithmic function. According to the results, regression models of sandstone, in-situ uniaxial compressive strength model and uniaxial compressive strength model under normal pressure are generated. Meanwhile, using well logging data in the acoustic velocity, density and gamma value can derive in-situ rock formations uniaxial compressive strength and in-situ porosity. Eventually, a new model established in this paper, containing in porosity, uniaxial compressive strength, lateral pressure and power exponent of regression, can predict triaxial compressive strength which will guide drillbit selection.

Jan 1, 2015

By M. Xian, M. Jahazi, Y. L. Lin

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded at different defocusing distances on two surface conditions (as-cast or machined) using a continuous wave 4 kW Nd:YAG laser system at a power of 2.5 kW and a welding speed of 6.0 m/min. Two welding modes (conduction or keyhole) have been observed. The adjustment of defocusing distance can greatly influence the establishment of conduction or keyhole modes. On the machined surface conditions conduction welding is obtained at a power density of 4.0 x 105 W/cm2. In contrast, keyhole welding is reached at a threshold irradiance of 1.5 x 106 W/cm2. Neither conduction nor stable keyhole modes have been established at a range of power density from 7.7 x 105 to 1.2 x 106 W/cm2 on the machined surface conditions. On the as-cast surface conditions keyhole is obtained at a power density as low as 4.0 x 105 W/cm2 but good surface quality is obtained at a defocusing of +2 mm. The as-cast surfaces require lower power irradiance for the formation of keyholes indicating that they have higher energy absorptivity for Nd:YAG laser beams probably due to coarse surface morphology.

Jan 1, 2004

By Y. Mudryk, D. Paudyal, K. A. Gschneidner, V. K. Pecharsky, M. Khan

"Rare earth intermetallic compounds are utilized commercially as magnetic and battery materials, electron gun electrodes, etc. Several of these intermetallics will be briefly discussed. There are many other rare earth intermetallic compounds which are not utilized industrially but have unusual properties which are of fundamental interest and may have future technological applications. Several of these materials are discussed as well.INTRODUCTIONTens of thousands of rare earth intermetallic compounds exist, but physical properties (primarily their magnetic behaviors), other than their crystal structures have been measured for only a small percentage of these materials. Among these are the commercially important compounds: Nd2Fe14B, and the SmCo5 – Sm2Co17 family – well known high strength permanent magnets; (Tb0.3Dy0.7)Fe2, Terfenol-D, a giant magnetostrictive material; LaNi5Hx a critical component of the rechargeable Ni metal hydride batteries; and LaB6 an electron emitter. There are, however, many other intermetallic compounds which are not utilized industrially, but none-the-less, exhibit interesting, and sometimes, exotic physical properties which are of fundamental interest and may have some future technological significance. These include: the giant magnetocaloric effect compounds Gd5Si2Ge2 and La(Fe13-xSix)Hy; the RCu and RAg families of ductile intermetallics; the mixed intra-lanthanide (R,R')Al2 compounds in which magnetic transitions disappear and reappear as one R is substituted for by R'; and GdNi which exhibits large dilations along two crystallographic directions and a larger contraction in the third direction at the Curie temperature resulting in zero volume change as GdNi orders magnetically via a second order phase transition.COMMERCIALLY IMPORTANT INTERMETALLICSNdFeB Permanent MagnetsThe Nd2Fe14B permanent magnets were discovered in 1984 independently in the USA and Japan. It is a ferromagnet and with proper heat treatment and processing Nd2Fe14B is the strongest near room temperature permanent magnetic material known today. This intermetallic compound is utilized as a permanent magnet in many applications, such as electric motors (e.g. the modern automobile contains up to 35 electric motors), spindles for computer hard disc drives, microphones and speaker magnets for cell phones and other audio equipment, direct drive wind turbines, actuators, and Magnetic Resonance Imaging (MRI) units. There are two kinds of NdFeB permanent magnets – bonded and sintered. The bonded magnets have a lower magnetic strength than the sintered magnet. The highest strength magnets are obtained by small substitutions of Dy (up to a maximum of 10%) for Nd, because Dy can significantly increase the coercivity and thus the energy product (a measure of the magnetic strength or hardness). The bonded magnets account for about 12% of the NdFeB market (~82 metric kt per year, containing ~20 kt/a of Nd). The NdFeB permanent magnet market is growing at a rate of about 15% per year. (Burzo & Kirchmayr, 1989; Kobayashi & Hirosawa, 2001; Coey, 2011)."

Jan 1, 2012