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By C. Guo, R. J. Chalaturnyk, M. MacKinnon, J. D. Scott

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd. oil sands plant. Over the past years (since 1996), there has been a marked change in the densification behaviour of MFT in the MLSB. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings) at the area with intense microbial activity. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. It may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program was carried out to study the mechanism leading to the rapid densification phenomenon. A review and discussion of the research program is given and some results from the field investigations and small-scale column tests are presented in this paper.

Jan 1, 2007

By D. A. Le, T. S. Nguyen

"In Canada and other countries, several types of rock formations are being considered for the geological disposal of radioactive wastes. In order to better understand the ability of these rocks to contain and isolate the wastes, the Canadian Nuclear Safety Commission collaborates with different international research organizations and has access to experimental data from Underground Research Laboratories (URLs) in the world. Such an URL is situated in Opalinus Clay, at Mont Terri, Switzerland. An experiment, consisting of the excavation of a tunnel followed by water and gas injections in a test section of the tunnel, was performed at the URL. The authors have developed a mathematical model, based on the poromechanics theoretical framework, to simulate those phases of the experiment. The constitutive relationship for the stress-strain behaviour of Opalinus Clay takes into account its inherent anisotropy due to bedding. The model was able to capture the main features of the experiment such as the prediction of the shape and extent of the excavation damage zone and its influence on water and gas migration.INTRODUCTIONIn Canada and many other countries, several types of rock formations such as crystalline rocks and sedimentary argillaceous rocks, are being studied for the disposal of used nuclear fuel from nuclear power plants. Geological disposal relies on multiple natural and engineered barriers for the long-term containment and isolation of the wastes. The host rock is a major natural barrier and is the subject of extensive research. The Canadian Nuclear Safety Commission (CNSC), Canada’s nuclear regulator, will be responsible for the licensing of future deep geological repositories. In order to evaluate the safety of deep geological repositories, CNSC staff keep abreast of scientific developments by collaborating with national and international partners on experimental and theoretical research on the long term performance of those engineered and natural barriers. Through that collaboration, the CNSC has access to data resulting from experiments performed at different Underground Research Laboratories (URLs)."

Jan 1, 2015

By M. Drozd, M. Somppi, Z. F. Yamak

"Activated carbon is used to recover gold in solution from various gold circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes; however, the characteristics and durability of the activated carbon can vary. Handling this medium poses challenges when fine carbon losses occur in the CIP, CIC, and CIL circuit discharge. Additionally, adsorbed gold on carbon fines can be lost to the discharge. The studies in this paper aim to standardize laboratory methods for testing activated carbon qualities specific to the gold industry. The investigation focused on size distribution, platelet content, wet attrition resistance, gold kinetics, and gold loading. The results demonstrate that a 96 h attrition test and a gold loading test form a basis for ranking carbon samples based on expected economic performance of the plant. ¦ KEYWORDS Activated carbon, Carbon attrition, Carbon ball-pan hardness, Carbon evaluation, Carbon fines loss, Carbon turnover RÉSUMÉ Le charbon actif sert à récupérer l’or en solution dans diverses conceptions de circuits de broyage d’or, notamment les procédés de charbon en pulpe (CIP, de l’anglais carbon-in-pulp), de charbon en colonnes (CIC, de l’anglais carbon-in-column) et de lixiviation au carbone, ou charbon au lixiviat (CIL, de l’anglais carbon-in-leach). Toutefois, les caractéristiques et la durabilité du charbon actif varient. La manipulation de ce milieu pose des problèmes dès lors que se produisent des pertes de carbone à grain fin dans la décharge des circuits CIP, CIC et CIL. Par ailleurs, l’or adsorbé sur les fines de charbon peut se perdre durant la décharge. Les études réalisées dans le cadre de cet article visent à normaliser les méthodes de laboratoire pour tester les qualités du charbon actif spécifiques au secteur de l’exploitation aurifère. L’étude portait sur la composition granulométrique, la teneur des plaquettes, la résistance au frottement humide, la cinétique de l’or et l’adsorption de l’or, à savoir la capacité du charbon actif à adsorber l’or sur une période spécifique. Les résultats ont montré qu’un test de frottement de 96 heures et un test d’adsorption de l’or constituaient le fondement d’un classement des échantillons de carbone du point de vue économique en vue de trouver l’échantillon générant le meilleur rendement des usines. ¦ MOTS CLÉS charbon actif, dureté de la batée des billes de carbone, évaluation du carbone, perte de fines de charbon, renouvellement du carbone, résistance au carbone INTRODUCTION The use of activated carbon for gold extraction is among the most common processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on reducing gold loss to tailings. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes. Granular activated carbon (Figure 1) is widely used for gold extraction from slurries containing gold-cyanide complexes. This activated carbon—produced from charred coconut shells—is well suited because of its adsorption kinetics, gold-loading capacity, attrition resistance, and ability to be reactivated. The extraction process using activated carbon technology involves adsorbing gold from an aqueous leachate; the gold is dissolved using a cyanide salt and consequently a dicyanoaurate(I) ion (Au(CN)2–) is formed, as noted in equation 1."

Jan 1, 2019

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By H. Thalenhorst

For an advanced mineral exploration project that has a ?nugget? issue making the assessment of the deposit grade difficult, a bulk sampling program using a sample tower can provide information that is otherwise not obtainable prior to actual production. This information includes the verification of predicted resource grades for the bulk sample tonnage (and, indirectly, of the methods and parameters used for the grade estimate), confirmation of the physical and grade continuity of the mineralization, and geotechnical data for a future mining operation. The information gathered will improve the input of a feasibility study, particularly with respect to expected mining grades, which are the key economic parameter for most mining projects. The bulk sample rejects can be used for pilotscale metallurgical testwork. Bulk sampling is also useful in cases of potentially biased drill-hole assay results and in the reliable determination of ore grade before shipment of ore from production or development operations to an external beneficiation plant. This paper presents a practical bulk sampling and sample preparation protocol, lists design features for the sample tower, examines the sampling errors that will be encountered, provides information on quality control procedures, and looks at the costs and benefits of such a program, based on the experience of undertaking bulk sampling programs during the period of 1985 to 2008.

May 1, 2010

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By T. Plikas, L. Gunnewiek

Computational fluid dynamics (CFD) modeling was used to evaluate the performance and optimize the design of a potroom ventilation system in an aluminium smelter facility. The ventilation system must ensure the inflow of fresh air to the workplace by natural draft and the removal of heat and hazardous emissions generated from the pot cell process. A full-scale, three dimensional CFD model of the potroom was developed to predict the air temperature distribution and contaminant concentrations throughout the potroom for the purpose of verifying that the industrial workplace hygiene standards will be met by the proposed ventilation system design. The modeling work was used to optimize the size of the floor gratings around the pot cell and roof ventilator, as well as determine damper settings in the roof ventilator. The effects of outside air temperature and external wind on the performance of the ventilation system was evaluated to ensure the design performs adequately in response to seasonal variations in climatological conditions.

Jan 1, 2006

By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By E. M. Stiles

Introduction The papers that follow deal with recently completed major improvements in practices at the Sullivan operations in Kimberley. The papers have been prepared by members of the Consolidated Engineering Staff and outline the construction programme which has been in progress for the past three years, entailing an expenditure of some millions of dollars. Four major operational changes have been brought about in the mine and concentrator. They are: (1) A change in backfill procedure for filling stopes below the 3900 level. (2) A 12,000-ton,per-day sink-float plant at the concentrator. (3) A new haulage system from the mine to the concentrator. (4) A completely new crushing plant and ore storage facilities located underground. A brief outline of the background and history leading up to this overall project will be given to show how each started as an independent betterment and how they were finally co-ordinated into one major programme. The first of these, namely, the necessity for backfilling stopes below the 3900 level, was the most pressing problem. All filling to date bad been done above the 3900 level, where mining was carried on in an irregular pattern of open stoping. Stopes below the 3900 level were first opened in 1940 and are being worked on a regular pattern of panel sub-level open diamond drill stopes. The two areas are separated by a sill pillar traversing the entire length of the vein at the 3900 level elevation.

Jan 1, 1950

By Neil J. Sullivan, Goode. George E.

"The Adams mine, operated by Jones & Laughlin Mining Company, Ltd. and located near Kirkland Lake, Ontario, produces one million tons of iron ore pellets per year. This paper briefly describes the mining and concentrating operation and deals mainly with the operation of the pellet plant. The orebody consists of fine-grained magnetite and some hematite, with alternating layers of chert, and is mined by conventional open-pit methods. After crushing and grinding, the ore is concentrated by magnetic separation and flotation. Agglomeration is accomplished by the grate-kiln pelletizing process. The plant layout and general operation will be discussed in detail."

Jan 1, 1968

By D. Ling, Santos. R. M., T. Van Gerven, M. Guo

The valorization of alkaline waste materials from thermal processes utilizing intensified mineral carbonation routes is investigated. The principal advantages of this approach are the chemical stability and storage safety of mineral carbonates, the opportunities for process integration presented by the technology, and the potential for conversion of low-value materials into useful products. Treatment and disposal of steel slags are a costly burden on steel plants. Sustainable solutions for Argon Oxygen Decarbonisation (AOD) and Continuous Casting (CC) stainless steel slags and Basic Oxygen Furnace (BOF) steel slag are desired. An integrated on-site mineral carbonation approach is envisaged as a favourable solution.

Jan 1, 2011

By Mary Kama, Kaul Gena

"Magnetic skarn ore (MSO) is one of the major copper bearing ore extracted by the Ok Tedi Copper Mine in Papua New Guinea. Copper minerals are recovered by flotation while the iron not associated with copper are discarded as tailings. The objective of this investigation was to determine the iron ore reduction kinetics for the Ok Tedi MSO and ascertain if it can be processed to produce sponge iron for a mini steel plant in Papua New Guinea.SEM-EDAX analyses of the Ok Tedi MSO indicated 10.1% C, 30% O, 0.6% Mg, 1.1% Si, 21.1% S, 0.8% Ca and 36.2% Fe. Most of the iron is in sulfide form. Both naturally occurring and roasted sinters of Ok Tedi MSO samples of different particle sizes were reduced by charcoal carbon at three different temperatures and seven different reduction times. Analyses of the reduced products indicated a metallic iron content of more than 65 wt.% on average.Results showed that there was no significant difference in reduction between fluxed and control materials. Only a slight increase in kinetics with reduced particle size, hence the reaction rate constant (K) did not vary much within the temperatures investigated. Reaction kinetics increases with increasing reduction time at 900°C. Therefore, more iron reduction is observed with particles of 106 µm size. In addition, the results also confirmed that the reduction energy used was higher at 800°C and lower at 1,000°C. In summary, iron reduction can be improved but close monitoring of temperature and reduction times are essential to determine the reaction kinetics of the Ok Tedi MSO. INTRODUCTIONMost mines in Papua New Guinea mine large quantities of iron in the form of sulfides, carbonates, oxides and sulfates that are eventually disposed off as tailings. The Ok Tedi magnetic skarn ore (MSO) contains a significant amount of hematite, magnetite, siderite, ilmenite and pyrite that can be a source of iron. The mineralogical compositions of Ok Tedi MSO reveals more iron minerals than copper, yet all iron containing minerals are collected in the tails from the main copper production stream. Therefore, this study is conducted to investigate the possibility of producing direct reduced iron (DRI), or sponge iron, from the MSO. Such sponge iron may serve as the feedstock for electric arc/induction furnace based mini steel plants in Papua New Guinea."

Jan 1, 2016

By H. D. B. Wilson

THIS PAPER has resulted from a preliminary draft of a background paper prepared anonymously for the Science Council's Special Study of the Solid-Earth Sciences in Canada. The draft was circulated to eighty-four Canadian geologists; forty-eight of these responded with criticisms of the draft. All critical re-marks were considered carefully and most have been incorporated in the final paper in an attempt to balance the author's bias, although this bias undoubtedly still appears. Indications of support for a particular statement or section were also helpful, because many of these contradicted criticisms and enabled the author to judge the consensus. Thus, all criticism could not be incorporated because the referees did not agree. It is interesting that some remarks were con-sidered overstatements by some and too bland by others. The most perplexing critical comment was one which suggested a new author was needed, and went on to name the existing author as the most likely candidate.

Jan 1, 1970

By G. Anger, J. Enser, H. Antrekowitsch, S. Koch

Homogeneous chemical composition and microstructure are always necessary, but not always attained in practice. As-cast aluminium alloys tend to have a segregation microstructure. Features of the cast structure, which affect subsequent processing or properties, can be altered by the homogenization. The main task of the Department of Nonferrous Metallurgy was to investigate the effect of homogenization treatment on precipitation hardening of aluminium alloys 6061 and 6082. The effect of the solution heat treatment (SHT) temperature on the mechanical properties was also analyzed. The homogenized and non-homogenized rolling slabs were produced according to the usual conditions and methods. The metallographic investigations were carried out on the as-cast samples, after homogenization, after the hot and the cold rolling mill, and after natural and artificial ageing. Then, Brinell hardness measurements and tensile tests were conducted on both alloys in order to examine the influence of the homogenization.

Jan 1, 2006

By R. M. Giegerich

"This paper begins with a brief history of Madawaska Mines, a brief description of the geology, mining methods and equipment, and the historical development of 7/8-in. tapered drilling equipment. It then outlines the performance characteristics and inherent problems of the traditional 12-degree, tapered connection, blade-type insert bits. Service-free (Unipass) button-type insert bits are presented as a possible solution to these problems. The paper concludes with an analysis of button bit performance to date.Brief History of Madawaska MinesMadawaska Mines Limited, near Bancroft, Ontario, is in Faraday Township, Hastings County, approximately 100 miles northeast of Toronto and 100 miles west of Ottawa.The mine re-opened in 1976committed to 1,500 tons per day to provide approximately 600,000 pounds of yellowcake (U3O8) per year to A.G.I.P. (an Italian government agency) under the joint ownership of Federal Resources Corporation, Salt Lake City (51%), and Consolidated Canadian Faraday Limited (49%). At present, the mine is producing approximately 2 pounds per ton (.1% U3O8) at the rate of 60,000 pounds per month. The mine employs about 400 employees.Brief Description of Geology, Mining Methods and EquipmentGeologyThe Grenville metasediments of the mine area are chiefly paragneiss, amphobolite and some carbonate (marble) rocks, which were intruded by a basic rock, altered to a metagabbrometadiorite. These formations are generally concordant, striking east to northeast and dipping 45 to 60 degrees to the south. Locally, the metagabbro is often discordant. The above group of rocks (mixed hybrid gneisses) forms the hanging wall of the south-dipping Faraday granite sheet and was intruded by nepheline syenite, syenite and granite. The ore occurs in the granite-syenite-pegmatite dykes that are probably genetically related to the Faraday granite. The ore shoots are erratically distributed within the pegmatite bodies, mainly on the hanging or footwalls but also medially. Their size varies from 50 to 350 feet in length, 5 to 40 feet in width and 50 to 200 feet in height. The ore occurs most frequently in a medium-grained granite or syenite, well hematized with 10 to 30% mafic crystals of pyroxene, amphibole and/or relics of the host rock."

Jan 1, 1982

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

By Matej Petružálek, Václav Vavrycuk, Tomáš Svitek, Tomáš Lokajícek

The most common type of waves used for probing anisotropy of rocks in laboratory is the direct P wave. Information potential of the measured P-wave velocity, however, is limited. In rocks displaying weak triclinic anisotropy, the P-wave velocity depends just on 15 linear combinations of 21 elastic parameters, called the weak-anisotropy parameters. In strong triclinic anisotropy, the P-wave velocity depends on the whole set of 21 elastic parameters, but inversion for 6 of them is ill-conditioned and these parameters are retrieved with a low accuracy. Therefore, in order to retrieve the complete elastic tensor accurately, velocities of S waves must also be measured and inverted. For this purpose, we developed a lab facility which allows the P- and S-wave ultrasonic sounding of spherical rock samples in 132 directions distributes regularly over the sphere. The velocities are measured using a pair of P-wave sensors with the transmitter and receiver polarized along the radial direction and using two pairs of S-wave sensors with the transmitter and receiver polarized tangentially to the spherical sample in mutually perpendicular directions. We present an inversion method for elastic parameters describing general triclinic anisotropy. We demonstrate on synthetic tests that the inversion becomes more robust and stable if the S-wave velocities are included. This applies even to the case when the velocity of the S waves is measured in a limited number of directions and with a significantly lower accuracy than that of the P wave. Finally, we analyze velocities measured on a rock sample from the Outokumpu deep drill hole, Finland, including the error analysis for several levels of confining pressure.

Jan 1, 2015

By M. Rudolph, T. Leißner, TU Bergakademie Freiberg, C. Mämpel, R. Möckel, M. Embrechts, T. Leistner

Tin-mining activities have taken place in the region of the German Erzgebirge (Ore Mountains) for over hundreds of years up until 1991. For long times, gravity separation processes used to be the dominating beneficiation approach in those mining districts to recover cassiterite, the main tin-bearing mineral. For fine (< 100 µm) and very fine (< 20 µm) particles these approaches might not represent effective techniques, significant valuable materials could not be recovered and reported to tailings, where it was subsequently disposed. Thus, there are substantial amounts of cassiterite still present in these tailings disposals, most of it as very fine particles with already high degrees of liberation. That fact brings these tailings disposals into focus for potential reprocessing using beneficiation approaches, which are more sensitive to fine and very fine particles. In this paper we present results concerning the laboratory-scale treatment of material from exemplary heaps of the former Altenberg and Ehrenfriedersdorf mining sites using various flotation methods (including conventional froth flotation and oil-assisted flotation). Different size ranges of the material were previously prepared in order to investigate their response to the different techniques. For the study, special emphasis is put on agglomeration flotation, an oil-assisted flotation method. Therefore, an aliphatic oil phase of alkane basis is used to either selectively aggregate or collect the cassiterite particles. Recovery and flotation performance results are presented with respect to different process parameters: various collectors (including sulphosuccinamates and phosphonic acids) and depressants (including sodium fluorosilicate and oxalic acid) regime, oil dosage, agitation time and pulp density during oil/pulp agitation. Furthermore, the oil/particle aggregation behavior is analyzed via particle image analysis and, additionally, collector adsorption characteristics are investigated by contact angle measurements and zeta potential analysis. The data obtained is correlated with the testwork results achieved in order to interpret the flotation response of very fine cassiterite particles.

Jan 1, 2016