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By B. Friedrich, N. Anastasijevic, S. Stopic

The extraction of nickel from Serbian and Western Australian lateritic ore by sulphuric pressure acid leaching (PAL) has been studied. The following parameters were tested: stirring rate, acid to ore ratio, reaction time, pressure and temperature. These studies were performed with ore samples from the Rudjinci, Serbia and Silcrete, Australia, both belonging to the laterite-silicate group of deposits. An increase of the reaction temperature and the stirring speed at a fixed acid/ore ratio showed a positive influence on nickel extraction. The decrease of the oxidation potential with time correlated with the increase in Fe(II) in solution and nickel extraction as the reaction went to completion for both ores. The target values of 95 % Ni extraction and 60 % Co extraction were attained in 5 min at 250°C for the Serbian silicate ore, at an agitation rate of 1500 rpm, 10 % solids, and acid/ore ratio of 0.40. Under similar conditions only 60 % Ni, but 69 % Co could be extracted from the Australian Silcrcte ore due to different mineralogy. The nickel extraction was shown follow a diffusion-controlled reaction model.

Jan 1, 2004

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By G. A. Pinsky, Pickard M. K

"IntroductionTWO METHODS of mucking have been used in sinking C shaft, the five-compartment production shaft of the Yellowknife property of Giant Yellowknife Gold Mines, Limited:(a) Band mucking during the original sinking in 1949 and 1950 (l); and(b) Mechanical mucking with the Cryderman shaft mucker during the recent deepening in 1954.This paper briefly describes the recent deepening and compares the performance figures of the two sinking operations.PlanningProduction planning in 1952 showed that it would be advisable to deepen C shaft in 1954 to provide for three new production levels and the installation of an underground crusher. To complete the required shaft work it would be necessary for a shaft crew to deepen the shaft about 500 feet, to partly excavate three level stations and a crusher station, and to cut a station for the loading pocket. Figure 1, a vertical section of the lower part of the shaft, shows the details of the deepening programme.During the planning period, Giant had a rather small supervisory staff and at the same time was experiencing a heavy labour turnover. As it was obvious that production would suffer if the sinking crew were recruited at the mine, it was decided that the merits of contracting-the shaft sinking to an independent contractor should be investigated."

Jan 1, 1955

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By G. Lodewijks

This paper explores the savings that can be achieved in the energy consumption of belt conveyors used in mines by changing the conveyor components, the operational parameters of the system or the belt properties. First the concept of energy savings is introduced by looking at the energy consumption of belt conveyors from a theoretical point of view. Also methods for the calculation of the power consumption of a belt conveyor and the associated emissions are presented. Two case studies are presented in which the effects of the change of the operational parameters of the system, in this case the belt speed, and the belt properties, in this case the application of aramid products in the belt, are presented.

Aug 1, 2013

By X. Xu, J. K. -W. Wong, J. -Y. Delenne, K. Soga

Hydraulic fracturing (HF) is a mulit-scale and multi-physics process which makes numerical modelling challenging. Conventional numerical models focus on multi-physics nature of HF but the multiscale nature is compromised by idealization of reservoir to be continuous, homogeneous and isotropic. However, natural fractures take a significant role in the success of HF for exploration of unconventional resources like Shale gas. Advancement in microseismic monitoring provides useful data for simulation in a much greater details. There is an urgent need to develop a suitable numerical tool for multi-scale threedimensional simulation to better understand the roles of discontinuities and heterogeneity in reservoir and its interaction with HF, especially to address the environmental concerns such as induced seismicity. In this paper, a simple discontinuum numerical method – Lattice Element Method (LEM) is proposed to model HF in a large scale three-dimensional model. A reservoir is modelled as a lattice network composed of 1D Hookean’s spring. Fracturing is modelled simply by removing lattices that meet a specified threshold as determined by the critical energy release rate of the rock. By introducing disorder in the model, mesh dependency in modelling fracture growth is minimized. Fluid flow is simplified as flow in pipe network and the permeability of pipe is related to fracture aperture by cubic flow law. Therefore, fracture flow and rock deformation are fully coupled. In this paper, four simulations of the same configuration except with different degrees of reservoir heterogeneity are presented. Fractures formed are diffusive and two groups of fracture are identified – connected fractures and isolated fracture without clear spatial correlation. The former forms a ‘fracture cloud’ and contributes to fluid flow and modeled by pipe network. The flow of fluid is highly tortuous and pipe network is sparely connected. The degree of reservoir heterogeneity controls the growth of ‘fracture cloud’ and pipe network. Microseismic monitoring often shows diffusive fracturing during HF on site and hence the outcome of the proposed model can be compared to such monitoring results.

Jan 1, 2015

By K. Soldenhoff, D. Wilkins, E. Ho

In the processing of rare earth ores, a pure, mixed rare earth chloride solution is usually produced and used as the feed to solvent extraction circuits to separate the individual rare earths. Cerium(III) may be separated from the other rare earths by oxidising it to cerium(IV), which precipitates as cerium(IV) hydroxide in chloride liquors. This oxidation step may be inserted either before rare earth separation by solvent extraction or between solvent extraction circuits. Although oxidation of cerium by sodium hypochlorite has been known for many years, detailed conditions for oxidation are not readily available. The effect of hypochlorite addition, temperature, pH and cerium concentration on oxidation of cerium(III) from synthetic solutions was investigated

Jan 1, 2014

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By D. J. MacKinnon, Kazi E. Haque

Ammonia present in a variety of mine/mill waste waters was almost completely oxidized to nitrogen by chloride mediated electro-oxidation. A closed circuit operation of preconcentration of ammonia on a suitable adsorbent (e.g. zeolite or a resin) followed by brine stripping of ammonia and electrolysis of the strip liquor seems to have sound technical, economic and environmental merits. The removal of ammonia, cyanide, cyanate or thiocyanate from a mine/mill waste water (e.g. gold mill), either individually or collectively, is also feasible by chloride mediated electro-oxidation technique. Further R&D investigations are necessary for the development of a closed circuit operation for the removal of ammonia, cyanide and thiocyanate; and also to obtain technical data for process cost estimates

Jan 1, 1996

By Trevor R. Ellis

"The valuation of mineral properties in the U.S. is only partially regulated. The regulations which have jurisdiction or impact appear to have such mainly as a consequence of unintended fallout, since the regulations were designed for other purposes. Court case history can also be important. The combined results are a mixture of bad and good, with important lessons to be learned.Since 1981, the Securities and Exchange Commission has prohibited U.S. listed companies from reporting quantitative estimates of mineralization and the value of mineralization, other than proven and probable reserves. This results in the minerals appraiser (valuator) working with a shortage of data in his everyday work, both on the subject property and in sales analysis.Between 1989 and 1995, all 50 states and essentially all Federal agencies adopted the Uniform Standards of Professional Appraisal Practice (USPAP) for real property appraisals (valuations). The major national appraisal societies also require their members to abide by USPAP. A significant portion of minerals appraisals must now follow these standards. This paper will discuss the content of USPAP. It provides a very good framework for the valuation of a minerals property or a mine, both as real property and as a business. However, the credentialing standards for real property appraisers are now prohibitive for minerals appraisers."

Jan 1, 2003

By A. Gakwaya, P. Vachon-Joannette, P. Gagnon, J. Lévesque

"Predictive numerical methods are essential tools for reduced development cost and improved high performance designs of modern aircrafts. Their use leads to savings in terms of design cycle time and experimental trials. Composite materials subjected to impact loadings demonstrate various damage modes such as matrix cracking, fiber breakage, delamination and, ultimately, fabric fracture. Composite laminates are extensively used in the aerospace industry, and their damage modeling is complex due to their inhomogeneity and anisotropic behavior. Damage evolution affects both in-service properties and performance of these composites. In this work, the drop-weight impact test has been simulated. Using a material model that accounts for both delamination and intralaminar damage, laminates response is analysed using numerical simulations based on 3-D finite-element models of the commercial code Abaqus/Explicit. Experimental and simulation results are compared, in terms of energy absorption and contact force. The obtained numerical results show good agreement with experimental data.INTRODUCTIONAs primary aircraft structures are increasingly being made from advanced fiber-reinforced polymer matrix composites and are in general exposed to a variety of impact scenarios (bird, hail, debris etc.), an understanding of the impact event and the performance of composite materials during impact is important in the development of new structures. This work is focussed on low velocity impacts that typically occur when foreign objects hit the aircraft during maintenance or other on-the-ground operations. These impacts can cause non visible damage that affect the structural integrity of the composite components. While for metallic structures, damaging impact events typically leave noticeable dents due to plastic deformation, in contrast, for high strength carbon fiber reinforced composites, they can deform elastically to strain levels exceeding 1% and the internal damage can often occur without the formation of a visible dent. The identification and effect of impact damage on the performance of the structure is thus of great concern to the aircraft industry as the durability and damage tolerance of these composite structures are strongly influenced by the size of detectable internal damage."

Jan 1, 2016

By Morris Wong

"An antimony-bearing gold ore was studied in a cyanide slurry containing 7 -20 ppm dissolved oxygen. 1 g/L NaCN at pH 9.5 and 48 hours retention time is required to extract 94 % of the gold from the 90 % minus 200 mesh ore by conventional cyanidation at a 7 ppm O2. As oxygen concentration was increased to 20 ppm, the conditions required to extract the same amount of gold were: 0.25 g/L NaCN, 16 hours retention time and 80% minus 200 mesh. Compared to conventional cyanidation, oxygen-enriched leaching was shown to reduce retention time by three times and cyanide consumption by four times. The kinetics of gold dissolution related to the dissolved oxygen concentration in slurry was expressed by following equation:XAu = 100 * (Kt + I0) / (1 + Kt + I0)where XAu is the percentage gold extraction; t is the retention time; K and Io are the slope and the intercept of the plot of XAu I (100 -XAu) vs. t respectively. The values of Kand Io depend upon the concentrations of cyanide and oxygen, the fineness of grind and the origin of ore sample etc.. A preliminary cost analysis was also performed to justify the use of oxygenating slurries.IntroductionGeneral:It was proposed almost 149 years ago (Elsner 1846) that oxygen is required for the dissolution of gold in cyanide solution. However, little attention were paid to oxygen application in the gold milling industry during the following one hundred years. Due to the constraints of gold price, reagent costs, refractory ores, and environmental issues in the past decade, the oxygen enhancement in the cyanidation process was introduced to the gold milling industry for increasing operation efficiency, reducing production costs, and meeting the requirement of environmental standard.The advantages of oxygen-enriched cyanidation have been reviewed by several investigators (Hague 1992, Jara et al 1992, Henderson 1989, Loroesch et al 1988, Elmore 1987, Cathro 1963). Common to all conclusions are the following advantages."

Jan 1, 1995

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By Andrea Lisjak

The mechanical behaviour of Opalinus Clay, an indurated over-consolidated argillaceous rock, is heavily influenced by the presence of preferably oriented bedding planes. The objective of this study is to illustrate a new modeling approach aimed at capturing the bedding-induced anisotropy of Opalinus Clay as observed in the laboratory and in situ. The combined finite-discrete element method (FEM/DEM) is employed as the main simulation tool. FEM/DEM is a numerical method that models material damage processes by explicitly considering fracture nucleation and propagation. A transversely isotropic elastic constitutive law is used to account for different elastic property values in the direction parallel and perpendicular to the layering, while strength anisotropy is captured using a directional cohesive fracture model. Quantitative calibration and validation of the model is based on laboratory results of indirect tensile tests and uniaxial compression tests. Emergent strength and deformation properties, together with the simulated damage mechanisms, are shown to be in good agreement with experimental observations. Preliminary results relative to the analysis of a circular tunnel show that the approach is able to reproduce the main Excavation Damaged Zone (EDZ) formation mechanisms as observed in the field.

Jun 1, 2012

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By Mario A. Morin

Mine design, planning and scheduling is a very complex, iterative process comprising several interrelated and interdependent activities. Understanding how this process works, identifying the critical pieces of information and the decisions to be made is key to initiating business process improvements (BPI) or business process reengineering (BPR) activities. Fundamental to most BPI and BPR work is some form of systems analysis. Structured Analysis is a powerful systems analysis technique that is well suited for modeling and analyzing complex process activities. Through a series of diagrams, this paper presents a vertical slice through the analysis work performed for formally describing the underground hardrock mine design and planning process. These diagrams illustrate how simple graphic constructs can be used to decompose the most complex situations into easily understandable diagrams that facilitate understanding, communication, improvement and reengineering.

May 1, 2002

By L. Li

Backfill is increasingly used in underground mines, as it can help reduce the environmental impact from mining operations. However, the primary objective of backfilling is to provide safe working space for miners, by improving ground stability conditions. As cement is often added to the backfill, a critical issue is the determination of the required backfill strength (cohesion) due to the binder. This value is usually obtained from a solution proposed by Mitchell and co-workers, in the early 1980?s, for stopes with an exposed backfill face. This paper presents a brief review of the Mitchell et al. solution, with some of its main limitations. Some of the recently developed solutions for backfill design are then summarized and discussed.

Aug 1, 2013

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By J. B. De Hart

This paper has been confined to the consideration of the working of thick seams, from six feet to sixteen feet, which are pitching at about thirty degrees to the horizontal. The discussion has been limited to these set conditions because they are the ones of commonest occurrence in the Southern Alberta bituminous coal district, because, from the point of view of safety, thin seams are more easily worked, and because a discussion of all the possible combinations of thick and thin seams pitching at angles varying from zero to ninety degrees with the horizontal would involve a task impossible in the time available. It has been assumed that the mine makes gas freely and that the coal is friable and tends to make inflammable dust which is highly explosive. Since the problem requires the taking into account means of maintaining a high proportion of lump coal, it is further assumed that lump coal commands a price considerably higher than the price which can be obtained for run-of-mine or for slack coal. Figure 1, tabulating the various factors which must be considered and their relation to each other, indicates diagrammatically the complexity of the problem. Any method of working becomes divided into two distinct components, the active workings of the mine and the old abandoned workings. While these are in a measure distinct, they are nevertheless inter-related, as shown in the diagram.

Jan 1, 1930