Search Documents

By I. M. Marshall

A review of technical literature covering Canadian mining emphasizes the advancement and changes that have been made in mining practice. However, current technical publications rarely outline basic principles or state definite rules that govern profitable mine operation. it may be argued that the broad principles of mining have long a go been outlined in various handbooks, text-books, and periodicals, and that these principles never alter. This is in great part true, but modern machinery, improved meta1-lurgical practice, and other advances, have in part modified these principles or changed the manner of their application. Many engineers hesitate to state specific rules, because it is so easy to quote an exception to a rules that any such statement appears to lose weight upon its very utterance. The exception to rules, and the reluctance to formulate rules, has forced such maxims as "the only rule in mining is the point of a pick," and "gold is where you find it". As an illustration of rules and their exceptions, one might quote the time-honoured maxim that a mill should not be built before a shaft has been sunk on a property in point of fact, Canadian mining history is replete with examples of wasted capital where a mill was built before a shaft had been bottomed. Y et this past year has seen a property enter profitable production whereon the building of the mill was started before the shaft was sunk. Instances such as this should not be accepted as evidence that a rule has been overthrown, but rather as an exception to the rule. The case cited pays tribute to the application of the diamond-drill combined with the correlation of sound geology. Incidentally, both these features emphasize a modern trend in the development of Canadian mining properties-a trend that is perhaps worthy of further comment. It is such trends that affect the principles of mining or modify their application. It is with such that this paper deals, at ]east in part. It is hoped that the statement of principles and the opinions herein outlined will be of sufficient interest to arouse discussion.

Jan 1, 1939

By S. A. L. Read

"The intact rock constant, mi, is one of the three basic input parameters required for the widelyused Hoek-Brown failure criterion. Values for the constant should ideally be determined by statistical analysis of laboratory test data. In this paper the influence of the inclusion or exclusion of tensile test data on derived values is discussed. We firstly investigate the relationship between direct tensile strength (DTS) test values and Brazilian tensile strength (BTS) test values based on a literature search, finding that the correlation between the two test types is DTS = 0.9*BTS, independent of the lithology being tested. Secondly, using the shear strength database of Douglas (2002), we examine the influence of confining pressure range and the inclusion or exclusion of DTS and BTS test values on calculated values of mi.Chief amongst the influences was the exclusion of tensile data in the calculation procedure, particularly when the Hoek triaxial confining stress range requirement (?3?max = 0.5?c) was not satisfied. Based on a reasonable 1:1 relationship between R (the ratio of unconfined compressive to tensile strength), use of actual tensile data in the calculations for the Hoek brown failure criterion is considered to be a simpler and more robust approach to the use of a tensile cutoff based on empirical criteria such as that of Fairhurst (1964). We advocate the fitting a failure curve using compressive and tensile test data as the most reliable means of calculating mi, while at the same time satisfying requirements as originally advocated by Hoek relating to the appropriate triaxial confining stress range (?3?max = 0.5?c) and sufficient (>5) evenlyspread data points. In the absence of triaxial data the use of R provides a practical means of obtaining estimates of mi that are more robust than guideline values."

Jan 1, 2015

By T. R. Stanley

Introduction The purpose of this paper is to interest mining men in the economic possibilities of sand deposits suitable for modern foundry work. Many members of the profession are constantly travelling over the country and it is felt that some knowledge of the necessary properties of foundry sands will enable these men t0 recognize such deposits. It is the experience of the writer that good sands suitable for the varied work of a foundry, such as that of the Consolidated Mining and Smelting Company, at Trail, are almost impossible to obtain from western Canadian sources. It is hoped that the following discussion may arouse some interest in the search for such sands. Sands are used in foundries for two purposes. The main use is for making moulds suitable for receiving hot metal. The mould must retain the? required shape until the metal has solidified. The second use of sand in the foundry is as an abrasive in sand blasting. This is a relatively minor use, and consequently will not be dealt with in detail. Any coarse sand with a high content of quartz will serve this purpose, but round-grained sands are superior to angular types, because they have not the same tendency to shatter on impact with the casting. Sand plays an extremely important part in the successful production of sound castings. This is more evident today than ever before, due to the greater variety of castings and alloys, each of which requires special sand characteristics. Poor sand is responsible for a great many foundry troubles which formerly were attributed to bad? metal; in fact, one investigator goes so far as to say that ninety per cent of bad castings can be traced directly to the sand. Very little of the vast amount of sand distributed over the earth's surface is suitable for moulding. It is the purpose of this paper to describe briefly the properties which are essential in good moulding sand. Sand for this work must be able to withstand the wash and hydrostatic pressure of molten metal, and yet be sufficiently porous to allow the gases generated in the mould to escape.

Jan 1, 1935

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By Paul W. Billwiller

Introduction In 1937, the Britannia Mining and Smelting Company, Limited, was carrying on an extensive exploratory diamond-drilling programme. Most of this drilling was done on the 4100 level, the lowest working level in the mine. One of the exploratory diamond-drill holes, at approximately 12,500 feet from the portal of the tunnel, encountered heavily mineralized stringers of chalcopyrite and sphalerite in silicified grey schist. The mineralization was encountered just to the hanging-wall of the green mottled schist at a point 350 feet south of the 4100 tunnel. To delimit this new orebody, drifts and cross-cuts were driven on 3500, 3800, and 4100 levels to the hanging-wall in the area of the projected mineralization. On the 3500 level, the top of the mineralized zone was encountered. The zone was thoroughly explored by drifting and diamond drilling. The mineralization, however, was not sufficiently concentrated to be of commercial grade. On the 3800 level, the zone was found to consist of disconnected stringers of chalcopyrite and pyrite. Drifting was continued to the west and a long lens-shaped area of grey schist containing fairly heavy stringers of chalcopyrite was delimited. This lens later proved to be very close to the top of the commercial mineralization of the No. 8 orebody. On the 4100 level, a diagonal cross-cut was driven to the footwall of the downward projection of the mineralized zone. Diamond-drill holes from this cross-cut indicated a zone of heavy mineralization. A drift was driven off the cross-cut parallel to the zone and some distance to the footwall of it. Further diamond drilling disclosed a mineralized zone approximately 300 feet long and 35 feet wide containing sphalerite, chalcopyrite, and pyrite. The foregoing development work indicated a fairly large lens of mineralization of sufficient concentration to be classed as ore between the 4100 and 3800 levels. To explore this mineralization at depth, long diamond drill holes, dipping at minus 57° and minus 80°, were planned from some point to the hanging-wall of the orebody. The 4100 level was not suitable for small development headings, due to wider gauge track and larger cars than on the levels above. Therefore, a raise was driven from the diagonal cross-cut on the 4100 level to a point some 70 feet above and just inside the footwall of the orebody. From the top of the raise, drifts were expanded east and west to delimit the ore zone. In addition, a long cross-cut was driven 350 feet to the hanging-wall, and drifts were opened east and west from the end of the cross-cut to provide diamond-drill stations for the exploration of the orebody at depth.

Jan 1, 1946

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By J. D. Clucas, D. B. Dreisinger

"The Starved Acid Leach Technology (SALT) has been developed by Search Minerals to extract nickel and cobalt VALUES (from nickel laterite ores (saprolites) and Caron plant residues. The technology consists of sulfuric acid atmospheric leaching of the ores or residues followed by neutralization and recovery of nickel and cobalt. The acid addition is carefully controlled to maximize nickel and cobalt extraction while minimizing overall consumption of acid by various gangue reactions. The final recovery processes can be tailored for maximum economic benefit. The use of resin-in-pulp processing is advocated as the most cost effective method for initial recovery of nickel and cobalt from lower grade materials. INTRODUCTIONCommercial processes for laterite ore treatment vary according to laterite type and local conditions. The two general categories of laterite ore are saprolites and limonites.Saprolites are generally treated by pyrometallurgical processes for reduction of nickel to matte or ferro nickel alloys. The high cost of drying, chemical reduction and electric furnace smelting requires that the saprolite grade for economic processing is of the order of 1.8% nickel or higher. There are of course large amounts of saprolite that fall below this “cut-off” grade that are not currently economic.Limonites can be treated by the Caron Process which involves drying of the ore, a reduction roast of the whole ore to reduce nickel and cobalt (and some iron) to the metallic state followed by ammonium – ammonium carbonate solution to leach nickel and cobalt. Nickel and cobalt recovery are low (70-85% for Ni and 20-50% for Co). The Caron plant tailings therefore contain high levels of unrecovered nickel and cobalt. Relatively few plants have used the Caron Process and new installations are not anticipated due to the high energy cost of drying and reduction roasting. Nevertheless, plants in Brazil (Niquelandia), Australia (Yabulu) and Cuba continue to operate.The high pressure acid leach (HPAL) process was pioneered at Moa Bay in Cuba in the 1960’s in the treatment of limonites. In the 1990’s the HPAL process was touted to revolutionize the nickel industry with low capital and operating costs for new installations. Murrin Murrin, Cawse and Bulong in Australia were started and in each case the technical difficulties of operating at extreme temperature and pressure conditions and the challenges in “ramping up” a complex hydrometallurgical facility conspired to cause these plants to fail economically. At present, Cawse and Bulong are closed and Murrin Murrin continues to operate after undergoing a financial restructuring."

Jan 1, 2012

By M. B. Shongwe, R. K. K. Mbaya, C. K. Thubakgale, P. Mendonidis

"A low-grade nickel-bearing ore was pre-concentrated on a SB40 laboratory model Falcon Concentrator. Three size fractions, -212+125, -125+75 and -75 µm were tested with the intent to upgrade the nickel content by reducing their content of fine silica, which becomes amorphous during leaching. Separation of silica from nickel-bearing magnesium silicate minerals; hornblende, clinochlore and talc, was more efficient in the finer particle sizes, -125+75 and -75 µm, and at high G-forces. For these two size fractions, nickel was upgraded from 0.06 to 0.07%, with a reduction in silica content from 52.12 to 50.71%. Leaching of feed samples prior to pre-concentration resulted in the formation of amorphous silica, indicative of the presence of fine silica in the samples. Leaching of nickel from the -125+75 µm fraction increased with increasing G-force and feed pulp percent solids, while that of -75 µm was not influenced. The optimum nickel recovery was 15.68% to the Falcon underflow, using the feed size fraction of -75 µm, 30 G and a feed pulp solids content of 10% solids, after 120 minutes of treatment.INTRODUCTION A low-grade South African nickel-bearing ore with about 0.06% Ni was previously studied for atmospheric pressure acid leaching using sulphuric acid. The study was motivated by the continuing search for methods to treat of low-grade ores, which appear to be an increasingly important source of valuable metals as a result of a declining production from rich sulphide ores. Nickel is a base metal that is used as an alloy in steelmaking and chemical industries because of its resistance to corrosion (Haudet et al., 2015). Nickel laterite ores with grades lower than 1.50% Ni are considered to be complex ores, accounting for 70% of the global nickel reserves (MacCarthy et al., 2016). Their complex nature may be attributed to the indefinite mineralogy of these ores, in which nickel may occur in more than one mineral host. In some cases, nickel may be finely disseminated in the ore. The grade of such an ore and complex mineralogy do not justify the application of pyrometallurgical methods for extraction of nickel (Zhu et al., 2012). This suggests that there is a need for less expensive alternative methods of extraction. This study investigates the application of centrifugal gravity concentration, using the Falcon concentrator, followed by leaching to determine the effect of pre-concentration of the ore prior to extraction by atmospheric pressure leaching with sulphuric acid."

Jan 1, 2017

By Claudio Acuña, Sergio Romo, Gerardo Fuentes

The leaching kinetics of a zinc concentrate in autoclave reactors were studied. A sample of concentrate from Bolivia, with typical mineralogical characteristics of the Andes region, was used. A concentrate containing 49% zinc and 145 ppm of silver from Minera Viacha was characterized chemically and mineralogically (atomic absorption, X-ray diffraction, and SEM microscopy) and tested in bench scale reactors. Two types of autoclave batch reactors were used at 40 bars of oxygen pressure and three levels of temperature (150°C, 200°C and 250°C). The solid to solution leaching ratio was 1:10 (10% sulphuric acid concentration). The effect of the particle size of the concentrate on the leaching kinetics was studied (P80: 145 and 45 µm). Iron from the leaching solution was removed by precipitation by increasing the pH in order to generate a clean solution for zinc electrowinning. The zinc solution was used to evaluate the feasibility of cathode production at the laboratory scale. Zinc extractions with higher liberation (P80 = 45 µm) reached up to 98%. Ground concentrate with finer sizes resulted in agglomeration and the use of dispersing agents did not improve slurry mixing. The leaching solution contained 55 g/L zinc and 7 g/L iron; it was purified by precipitating iron. The precipitation was evaluated using sodium hydroxide and ammonium hydroxide. In the first case, a colloidal suspension of ferric salts was formed while in the second case, different iron compounds were precipitated. The precipitate obtained with ammonium hydroxide had better filtering properties. Electrowinning was carried out using two types of cathodes (stainless steel and aluminium) and solutions purified with ammonium hydroxide. Zinc cathodes formed on stainless steel presented a better physical quality than those formed on aluminium.

Jan 1, 2015

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017

By A. Gronningsater

Introduction As is well known, the fight between the blast furnace and the reverberatory furnace in copper smelting during the second decade of the century ended with a victory for the latter, a result which must largely be attributed to the introduction of flotation methods. To my knowledge, no new blast furnace has been blown-in at any American copper smelter since the War. As the metallurgy of nickel, up to and including matte smelting, is generally considered a close parallel to that of copper, the introduction of reverberatory smelting in the big new smelter of the International Nickel Company at Copper Cliff, built in 1928-30, seemed a logical adherence to a well established trend. In view of these facts, considerable comment was made when Falconbridge Nickel Mines decided to retain the blast furnace in their smelter built about the same time, in 1929. A presentation of the reasons governing this choice should therefore be of interest. The basic principles underlying the Falconbridge practice, and the considerations guiding the successive steps in the operations, will be discussed in the following. To understand the problems involved, the character and mode of occurrence of Sudbury ore must be kept in mind. Large amounts of disseminated ore are generally present. Although the gangue usually runs only about 50 per cent Si02, the ore hoisted as a rule contains more silica than needed in the smelting operation; until recently this excess was removed entirely by hand picking (in later years supplemented by magnetic sorting methods), a difficult and not very satisfactory method, in which 'the border line between ore and waste is entirely arbitrary, and therefore too much depends on the judgment of the picker.

Jan 1, 1934

By Steve T. Laflin

Since the beginning of the nuclear era, there has never been a commercial solution for the large quantities of depleted uranium hexafluoride generated from uranium enrichment. In the United States alone, there is already in excess of 1.6 billion pounds of DUF6 currently stored. INIS is constructing a commercial uranium processing and fluorine extraction facility. The INIS facility will convert depleted uranium hexafluoride and use it as feed material for the patented Fluorine Extraction Process to produce high purity fluoride gases and anhydrous hydrofluoric acid. The project will provide an environmentally friendly and commercially viable solution for DUF6 tails management.

Aug 1, 2010

By D. B. Dreisinger, D. G. Dixon, G. Nazari

"The kinetics of chalcopyrite leaching in acidic ferric/ferrous sulfate media under atmospheric conditions in the presence of pyrite has been investigated. It has been found that pyrite samples from different sources affect the rate of chalcopyrite leaching differently. A strong correlation between the amount of silver associated with the pyrite and its effectiveness has been noted. In this study, improvement of the catalytic properties of pyrite such that all pyrite samples accelerate the rate of copper extraction regardless of their sources is demonstrated, and a detailed discussion of the mechanisms involved in the process of chalcopyrite leaching in the presence of silverenhanced pyrite is presented. INTRODUCTIONIt is well known that chalcopyrite resists leaching in sulfate media. It has been proved that pyrite facilitates the leaching of chalcopyrite (Berry et al., 1978; Dixon et al., 2008; Mehta and Murr, 1983; Muñoz et al., 2008; Nowak et al., 1984, Tshilombo, 2004). Considering the catalytic effects of pyrite on accelerating the kinetics of chalcopyrite leaching, Dixon and Tshilombo (2005) have developed a new process, known as Galvanox™, which has several advantages over other hydrometallurgical processes. Galvanox™ runs under atmospheric conditions, so it requires only low-cost leaching tanks. The sulfur yield at this temperature is high (>95%) which leads to low oxygen consumption and low sulfuric acid generation. The operating temperature is below the melting point of sulfur which eliminates the use of surfactants. This process also does not require fine grinding. Reaction 1 shows the overall leaching reaction in the Galvanox™ process.CuFeS2 + O2 + 2 H2SO4 = CuSO4 + FeSO4 + 2 S0 + 2 H2O (1)Complete copper recovery from the Galvanox™ process can be achieved at a considerably higher rate than other atmospheric ferric sulfate leaching processes (Dixon et al., 2008). Recycling pyrite and recovering copper from tailings with the Galvanox™ process have also been evaluated in continuous pilot leaching campaigns (Dixon et al., 2007)."

Jan 1, 2012

By V. S. Papezik

Pyrophyllite, an AI silicate used in the production of ceramic materials, is formed mainly by alteration of felsic to intermediate volcanic rocks, either directly (at temperatures of 250-300°C and pressures of 1-2 kbar) or by subsequent low-grade metamorphism of aluminous protoliths produced by thermal fluids or even by prolonged weathering. Most pyrophyllite deposits in North America are concentrated in a belt of Late Precambrian volcanic and sedimentary rocks, the "Avalon Zone ", which extends along the eastern flank of the Appalachian mountain system from Newfoundland to the southeastern U.S.A. The only producing pyrophyllite mine in Canada is an open pit located near the settlement of Foxtrap on the Avalon Peninsula of Newfoundland. It lies in a belt of rhyolitic flows and pyroclastics intruded by a granitoid pluton. The rocks have been leached along a shear- or fracture zone, depleted in silica, alkalies, Ca, Mg and Fe by the action of hydrothermal fluids, and recrystallized to a very fine-grained massive assemblage of pyrophyllite, muscovite ("sericite") and quartz. High-grade pyrophyllite lenses contain small nodules of diaspore with minor barite; rutile is present in trace amounts. The close proximity of all pyrophyllitized zones on the peninsula to the granite contact suggests that the alteration was produced by thermal fluids genetically connected with the granitoid pluton. The fine-grained pyrophyllite-bearing rocks, with their simple mineralogy, are suitable for quantitative modal analysis by X-ray diffraction. Chemically analyzed samples from the alteration zone were used for the construction of working curves by plotting calculated mineral content against the intensity of selected diffraction peaks. The accuracy of the resulting curves is ±4.5% for quartz, ±3.6% for pyrophyllite and ±2.7% for muscovite. Pelletized samples give best results. The XRD method is suitable for a rapid analysis of a large number of grab or core samples to outline higher-grade areas for more detailed sampling.

Jan 1, 1978

By Suman Giri

Non-Intrusive Load Monitoring (NILM) is a method of extracting appliance-level power consumption information from aggregate circuit-level data with the goal of giving users feedback regarding their energy consumption so they can take control of their consumption habits. In this paper, we present a novel algorithm for classification of on and off states of appliances. We compare the performance of our algorithm in on state detection with a pervious paper that evaluated the same dataset and show that it performs up to 13% better. We also present the results of a case study where we collected data for different modes of a cooktop, microwave and dishwasher and used our algorithms to perform power estimation. The error on ten different setups in the test bed ranges from 1% to 32%. We discuss our results and lay out ideas for future work.

Aug 1, 2013

By D. S. Rogers

"Throughout the history of mining at the Dome, gold has been found in a number of different rock types and in association with a number of different structural settings. Diamond drilling plays an important role in the evaluation of the stratigraphic and structural features which control ore deposition. The main function of diamond drilling is to locate favourable areas of mineralization.To date, over 20,000 diamond drill holes have been drilled from combined surface and underground programs. Needless to say, a great many significant intersections, carrying a wide range of gold values, have resulted from the total of over 756 miles of drill cores which these programs have produced.However, the term ""significant"" takes on new meaning in light of the experience of diamond drilling in a number of ore-type situations at the Dome Mine. Drilling through individual ore veins, such as the Fuchsite Vein or the Quartz-Tourmaline Vein, often intersect the vein structure; however, assays from the veins frequently fail to yield any ore grades. Similarly, drill cores through stringer-type occurrences such as dacite or conglomerate, when assayed, fail to indicate the true size or grade of the orebody ultimately mined.IntroductionOver the years, those who explore for gold and those who have the slightly less fickle task of actually mining gold have shared a common dilemma. That dilemma lies in the failure to relate the results of diamond drill information to a positive ore situation, or ultimately to reconcile ""diamond drill indicated ore"" to actual ore reserve tonnages.Drawing on the knowledge of more than 72 years of mining history at the Dome operation in the famous Porcupine Camp, this paper will review a number of drift and stope situations in which the grades of the ore material extracted will be compared with the anticipated grade of that same drift or zone as calculated solely on the basis of diamond drill assays."

Jan 1, 1982

By D. C. Peck, James. R. S., Chubb. P. T.

"Abstract -The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered matie intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendritic­ pegmatitic matie pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and mag­ matie breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to lOOJo within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that af­ fected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd :Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Severa! factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic inter­ action with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion .The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Com­ plex, U.S.A.) in terrns of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economie concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginal­ type POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By J. F. Wright

The cold, or Kississing, Lake area in northwestern Manitoba was the scene of considerable prospecting and mining activity last summer. At the Sherritt-Gordon property, four diamond drills were at work exploring a large deposit of copper and zinc ore, and underground work was in progress on this deposit from two shafts. Some preliminary diamond drilling was completed in five other deposits, and surface exploration work was in progress at a dozen or more additional localities where copper and zinc sulphides were known to be present. Many prospectors visited the area and spent some time in search for new deposits, but apparently few discoveries were made; consequently, last autumn some returned a little disappointed in the area as a prospecting field. Although many visited Cold Lake area last summer in the search for mineral deposits, it should be emphasized that this new prospecting field is a very large one, and that to date only a small proportion of the ground has been examined, except in a very general way. Within the past 18 months, a village of several dozen cabins, and with a population of l00 or more persons, has sprung up on the shore of Cold lake, just west of the Sherritt-Gordon mine. This at present is the business centre of the area, and two banks, a post office - named Kississing by the Postal authorities - a Mining Recorder's office, as well as several restaurants and stores carrying a fairly complete stock of groceries, dry-goods, and general prospecting equipment, are already established.

Jan 1, 1929

By C. M. Bartley

Fluorspar, in addition to its familiar uses as a metallurgical flux and as a source of the electrolyte for aluminum production, has become important as an essential raw material in the rapidly growing fluorine chemical industry. The unique ability of fluorine to react and form compounds with al-most all other chemicals has made it one of the important elements in modern chemistry. Research and development over the past thirty years have resulted in a current annual production of fluorine chemicals that is both technically and economically important to industry. Because many of these chemicals and products are relatively new, and most have properties that are not duplicated by other materials, the present uses are expanding rapidly and new applications are being reported continually. Fluorspar, the only immediate and practical source of fluorine, is therefore an important mineral. This fact has been recognized in major industrial areas such as the United States and Western Europe, but has received little attention in Canada.

Jan 1, 1962