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By K Saito, M Hasegawa

Removing sulfur and phosphorus from molten iron can be expressed by the following reactions, respectively. [S]Fe + (O2-)slag = (S2-)slag + [O]Fe [P]Fe + (3/2) (O2-)slag + (5/2) (FeO)slag = (PO43-)slag + (5/2) Fe(liquid) These equations indicate that desulfurisation and dephosphorisation have opposite oxygen potential conditions. If a small amount of desulfurisation slag not removed is carried over to dephosphorisation process, the reaction of sulfur mentioned above proceeds toward left hand resulting in increasing sulfur content in molten iron. For better understanding of such re-sulfurisation reaction in hot metal pre-treatments, the present study aimed at evaluating the effect of iron oxide on the sulfur distribution ratio between slag and hot metal. To measure sulfide capacities and FeO activities simultaneously at temperatures below the melting point of pure iron, CaO-SiO2-FeO and CaO-Al2O3-FeO ternary molten slags were brought into equilibria with copper-iron-sulfur liquid alloys, and the equilibrium oxygen partial pressures were determined with an electrochemical technique involving the stabilised zirconia solid electrolyte. The experimental results showed that the sulfide capacity increased with an increase in FeO content, and this trend was consistent with the fact that FeO was basic. Although the addition of FeO raised the FeO activity and oxygen potential, the calculated value for sulfur distribution ratio between slag and hot metal increased with increasing FeO content.

Jun 19, 2024

By R Yong, A McEwan, D G. Miljak, D Milinkovic, A Curtain, P J. Coghill, R Stefulj, B Lovric, G Roberts

The CSIRO has pioneered the development and use of certain classes of magnetic resonance (MR) for mining applications. The MR technique is a radio frequency-based spectroscopy that provides highly quantitative measurement of selected ore minerals. MR has many inherent advantages for bulk sensing in mining applications, including deep sensing penetration into most bulk ores with the use of non-contact sensors that are robust and tolerant of demanding mine conditions. The highly discriminating nature of the technique also provides the very desirable attribute of robust and simple calibration, that can often be performed prior to sensor installation. Rapid sensing (within seconds) at very low grade (few hundred ppm Cu) has been demonstrated, as well as sensing at high tonnage rate. Besides sorting applications, MR may also be applied to preconcentration applications involving very large volume sensing including: (i) haul truck sensing using portal arrangements, where truck destination assignment may be dynamically determined based on the truck grade, (ii) in-pit gantries used for loading trucks that may similarly be equipped with sensors for truck assignment and (iii) deep mine bench sensing, recently progressed through a CRC ORE project, where local bench grade is determined at the few-metre lateral scale and at depth prior to blasting, to aid selective blasting and ore extraction. MR sensor prototypes have been developed for each of these applications and have been tested in laboratory or limited field conditions. To inform the value proposition for truck or bench sensing, initial analysis of truck assignment improvement based on an analysis of in-situ mine bench grade has been performed for a porphyry style deposit. The prototype sensors, preliminary results and future technology development and objectives will be described.

Nov 10, 2020

Competition in the mining industry is the main driving force for both equipment manufacturers and end users to develop and apply the most cost efficient solution to a mining problem. Therefore the challenge to find new solutions is usually met by several suppliers under various factors of influence affecting specifications. Time and timing are particularly important, but all new developments ultimately have to successfully perform on site.Consideration of all aspects of planning, manufacturing, user liaison and ultimate satisfactory commissioning hinges on the necessities of assessing of all the expectations in the mining application and the requirements of the concept and layout team. To apply the maximum available technical competence with solid thorough workmanship is the best possible foundation for success of underground machinery development.

Jan 1, 1991

By K Williams, G M. Evans, S M. Iveson, K P. Galvin, C E. Loo

The Australian Research Council (ARC) has recently established an Industrial Transformation Research Hub in the area of iron ore, focused on iron ore characterisation, beneficiation, materials handling and end-use functionality. The research hubs are part of a new initiative aimed at building stronger relationships between industry and universities, while addressing issues of national significance. The ARC Research Hub for Advanced Technologies for Australian Iron Ore will focus its attention on developing innovative approaches for creating enhanced value across the full value chain through the characterisation of different ore types, beneficiation and materials handling and transport. This hub brings together five industrial organisations and a research team formed from well-established research groups based at the Newcastle Institute for Energy and Resources. These groups have a record of working closely with industry to create opportunities. Examples include new beneficiation technologies such as the Reflux Classifier for achieving gravity separation, the expertise of TUNRA Bulk Solids in materials handling and the Iron Making Centre at Newcastle, which is a capability maintained by BHP Billiton following the closure of its Technology Centre in 2009. The purpose of this paper is to provide an outline of the research hub and its objectives, some background on the research groups that now form the hub and an insight into the strategy adopted for developing and implementing new technologies. The paper also describes a range of novel technologies that have the potential to be developed and applied to iron ore beneficiation.CITATION:Galvin, K P, Roberts, A, Loo, C E, Evans, G M, Williams, K and Iveson, S M, 2015. Australian Research Council research hub for advanced technologies for Australian iron ore – an introduction, in Proceedings Iron Ore 2015, pp 7–12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By P Stewart, S Cowie, A Offer, J Carpenter, E Jones

The Ban Houayxai Gold-Silver Operation is a producing asset for Australian-based copper and gold producer, PanAust Limited. The Operation lies within PanAust’s 2600 square-kilometre Phu Bia Contract Area in northern Laos. Commencing production in 2012, Ban Houayxai is operated by PanAust’s Lao-registered company, Phu Bia Mining. PanAust owns a 90 per cent interest in Phu Bia Mining. The Government of Laos owns the remaining 10 per cent. The Operation mines an intermediate sulphidation epithermal gold-silver deposit and comprises an open-pit feeding ore to a conventional carbon-in-leach process plant. Metallurgical recoveries for gold and silver are approximately 75-85 per cent and 55 per cent respectively. To year-end 2017, the Operation had poured 0.65 million ounces (oz) of gold and 4.7 million oz of silver. The Ban Houayxai Ore Reserve supports a mine life of approximately four years from the end of 2017. The Ban Houayxai deposit is in an early Permian volcano-sedimentary unit which is part of a late Carboniferous to early Permian (310–270 million years ago) volcanic-plutonic sequence of the Truong Son Fold Belt. The deposit formed when hot saline (240–415°C, 2.7–13.0 weight per cent NaCl equivalent) fluids ascended from a geologically fertile island arc porphyry into overlying volcanics along a fault or faults in the early Permian (290–256 million years ago) (Manaka et al, 2014). CITATION: Carpenter, J, Cowie, S, Stewart, P, Jones E, and Offer, A, 2018. Machine learning at a gold-silver mine: a case study from the Ban Houayxai Gold-Silver Operation, in Proceedings Complex Orebodies Conference 2018, pp 82–85 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By P Odins

Traditionally, stratigraphic deposits have been represented by a large number of gridded surface and product analytical models, related to each other by naming convention. This approach, though suitable for structurally simple stratigraphic deposits, does not lend itself well to addressing the complex style of stratigraphic deposits which are becoming more prevalent. In addition, the sheer number of individual gridded models involved makes it very difficult to keep a consistent audit trail of the overall deposit model. Recently, a new enhanced block model structure known as Horizon Adaptive Rectangular Prism (HARP) models was introduced to address these issues. An HARP model is specifically designed to allow stratigraphic units to be represented with virtually no loss of structural integrity, by allowing the tops and bases of the individual HARP blocks to ‘bend’ in concert with the input surfaces. By bringing together the best of grid modelling, triangulation modelling, block modelling and grade estimation, the HARP model opens up many exciting new opportunities for the stratigraphic geologist or engineer to take their model further than was previously possible. Examples of improvements in modelling methodology using a HARP model include: the ability to represent complex normal, reverse and thrust faulting; the ability to store thousands of additional analytical, geotechnical or calculated variables in each individual block; advanced visualisation, manipulation and plotting capabilities; and the ability to calculate volumes and resources against complex, three-dimensional (3D) solid pit designs. Finally, several ‘real world’ scenarios, illustrating how this advancement in modelling technology can benefit a wide range of mining professionals are detailed. These examples demonstrate how productivity gains can be made in both long-term resource modelling and short-term ‘week by week’ geological modelling as an adjunct to mine planning.

Aug 22, 2011

By Mantsevich M, Ivanov V, Volkov V, Ponomarov G

A new ecologically promising technology for the copper-nickel ore benefication using insert gases and pyrrhotite depression is under consideration. The finely dispersed nickel-containing sulphides and the pyrrhotite are easily oxidised during the process of flotation resulting in deterioration of selectivity and valuable component loss in the tailings. One of the ways to improve the benefication is the flotation of easily-oxidising minerals in an inert atmosphere. In the experiments nitrogen was taken as the inert gas supposing that in the industrial scale operations nitrogen generating, as a by-product of the oxigen production. will be used (Rybas et at, 1989). The most wide-spread mineral in the Norilsk rich sulphide copper-nickel ores is pyrrhotite containing iron, sulphur, nickel and platinum group metals. Up to 30 per cent of the pyrrhotite sulphur is recovered into the nickel concentrate causing the high sulphur dioxide emission in the further pyrometallurgical process of nickel production. This is the reason why the problem of the pyrrhotite removal during the ore concentration should be solved, the critical factor of the problem being the lowest possible nickel content in the pyrrhotite. According to the data of the geological and mineralogical mapping the nickel content in the pyrrhotites of rich ores varies from 0.3 to 1.8 per cent, with the mean value equal to 0.6 - 0.8 per cent. This assures the technological and economical effectiveness of the low-grade pyrrhotite removal during the flotation process.

Jan 1, 1993

Ore textures in Australian BIF-derived ores are quite complex and have formed the basis for ore genesis models, which includes hypogene upgrading or supergene upgrading then regional metamorphism for the microplaty hematite ores and supergene upgrading for the martite-goethite ores. Despite a high level of ore texture knowledge, little is known about the spatial distribution of ore textures within deposits or their relationship to downstream processing. This paper describes a new iron ore texture classification system to better understand the vertical textural zonation characteristics of Australian BIF-derived deposits, the interpreted role of recent supergene upgrading processes on modifying primary ore textures and their implications for downstream mineral processing. The iron ore textural classification scheme presented uses textural groupings defined on the basis of similarities in mineralogy, ore texture, porosity, mineral associations and hardness. The scheme is non-genetic and has been successfully applied to deposits in the Pilbara, Yilgarn and Gawler cratons. The main ore texture groups include dense martite/hematite, microplaty hematite, microplaty hematite-goethite, martite-goethite, goethite-martite and goethite-rich. Each group can be further subdivided into physically hard to softer subcategories. The ore textural groups can be divided into those interpreted to be associated with primary replacement of BIF and secondary textures resulting from more recent modification by near-surface hydration or dehydration processes. A schematic vertical section through BIF-derived deposits consists (from surface) of detritals underlain by a carapace, both of which may have been eroded, followed by a hydrated zone with replacement of primary ore martite and microplaty hematite by vitreous goethite. The hydrated zone is underlain by 0.2 - 6 m thick zones of intense dehydration and textural infilling of porosity with hematite and hydrohematite. Immediately below the dehydration zone is a strong zone of leaching, where more porous and friable ore textures occur, followed underneath by a gradational contact with primary ore. Secondary supergene processes can impact on beneficiation with hydration and leaching resulting in more difficult density separations at the concentrator stage due to reductions in density differences between ore and gangue and loss of heavy media into pores. Supergene modification of primary BIF-derived ore textures can substantially change lump metallurgical properties, with hydration and dehydration favourably increasing lump yield but reducing resistance to thermal shock whilst leaching will give the opposing outcome. The lump properties of ore textural groups appear to be relatively consistent within and between the iron ore deposits examined.

Jan 1, 2002

By D Duan

In this study, aimed at two kinds of ore (lump ore and iron ore fines) and four types of Australian iron ore resources (haematite iron ore, Mara Mamba iron ore, limonite iron ore, and mixed iron ore, such as Newman, MAC, Yandi and Pilbara iron ore), the physical and chemical properties and high-temperature properties were investigated in detail, to master their behaviour and effects in sintering, blast furnace, and non-blast furnace processes. Then, according to the individual properties of Australian iron ores, Chinese domestic iron ores and Brazilian iron ores, etc, the optimisation of ore-proportioning for sintering, blast furnace, and non-blast furnace processes was studied based on the interaction of the individual iron ores and their complementary properties, and the corresponding tests were carried out. The test work results indicated that this method not only improved the technical and economic indexes of sintering, blast furnace, and non-blast furnace processes, but also increased the addition of Australian iron ore. All of these provide the theoretical basis and technical support for highly effective use of Australian iron ore resources in iron and steel enterprises in China.

Jul 11, 2011

By L Mariano

Three selected iron ore samples from the major bedded and channel iron deposits of Western Australia were analysed using a scratch test commonly used in the oil and gas industry. The portable commercial equipment dubbed Wombat cuts a groove on the surface of the sample with a cutter under imposed depth of cut and cutting velocity. The normal and tangential components of the force acting on the cutter are recorded with a high degree of precision (about 1N) at fine spatial resolution of about 20 measurements per millimeter.The intrinsic specific energy inferred from the scratch test measurements is found very well correlated with a classical measure of strength such as the uniaxial compressive strength, for over 300 sedimentary rock samples.The results obtained on the iron ore samples are comparable to those obtained on oil and gas sedimentary rocks. This method could provide an objective and semi-automated measurement of material strength and brittleness in iron ores that can possibly be correlated to the lump to fines ratio.

Jul 11, 2011

By A Winchester, D Grant

The massive 1100 Orebody in Mount IsaÆs X41 Copper Mine has been extracted over the last 40 years form north to south utilising sublevel open stoping methods.De velopment has continually stepped ahead of production to provide access to new primary stoping blocks. The remaining secondary pillars contain stopes with one, two or three fill mass exposures and were constrained by access requirements and stope extraction turnaround time.The remaining southern mining areas consist of large 40 m wide by 300 to 400 m long east-west transverse pillars that have been left to provide access for ventilation and service requirements. Three large transverse cross-cuts or transverse pillars û 4180 x/c, 4010 x/c and the Panel pillar now remain. The 4180 x/c was the last major transverse pillar to be successfully broken.This transverse pillar is being extracted in a retreating sequence, creating 3SLOS stopes due to the surrounding backfilled stopes.In recent years the extraction of the first, and most critical, stopes in the transverse pillars have resulted in large changes to the induced stress field. This paper describes the extraction of the 1.1 million tonne stope P418 in the 4180 x/c pillar.T echnical challenges that were faced and how they were overcome to allow for the successful extraction of the stope are described.Critical to the success of the P418 stope extraction were the rehabilitation methodology used; extraction strategy modifications to address deteriorating ground; mass firings with multiple directional changes; managing the exposure of backfill of variable strengths; and geotechnical monitoring prior to, during and after extraction.

Jan 1, 2005

By T Hill, J Everingham, P Clark

Currently, social impact assessment (SIA) is used to determine social impacts across the life-of-mine (LOM) to closure. This paper draws on recently completed SIA reports from the Martha gold mine in Waihi and qualitative interviews in the community that explored post-closure options, to review the challenges mining companies face when engaging with iwi4 through the SIA process and what that may mean for closure planning. The Maori of New Zealand consistently lobby to have a distinct voice in resource management issues. This is in line with the evolution of indigenous participation in SIA globally and with New Zealand policies, not least of which, the Treaty of Waitangi (the founding document of New Zealand) makes provision for Maori self-determination with regard to natural resources. Land use for mining has been a source of conflict for Maori and mining can have profound cultural and social impacts on the Maori community, yet despite Treaty intentions their representation in SIA has been comparatively limited. With this in mind, the Waitangi Tribunal has released the Ko Aotearoa Tenei (Wai 262) report, which recommends far reaching reforms to laws and policies affecting Maori culture and identity including natural resource management. This landmark report seeks to move the Maori-Government relationship beyond grievance to partnership. Given suggested policy changes in Wai 262 and the risks of poorly conceived closure planning, it is timely to review where Maori currently fit into the SIA process. The findings of this research suggest that improvements to the outcomes of this process will require companies to act beyond compliance. However, these improvements may also ensure mining companies maintain their social license to operate and to ensure continued influence across the life of a project to closure.CITATION:Hill, H, Clark, P and Everingham, J, 2012. æThere is an emptiness for Maori here in WaihiÆ - Understanding indigenous perspectives on post-mine land uses in closure planning, in Proceedings Life-of-Mine 2012 , pp 153-160 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By A Dal-Corobbo

Traditional acid and metalliferous drainage (AMD) wastewater treatment focuses on the iron co-precipitation/adsorption process as this is a very effective method of reducing heavy metals, including copper, lead, zinc, arsenic, etc, to parts per billion (ppb) levels in AMD wastewater streams. One of the drawbacks to this method however is the large volume of sludge produced and subsequent disposal costs for the mine site concerned.A proprietary metals treatment system called high density sludge (denoted HDS) which significantly reduces the quantity of waste generated is described in this paper. This process generates a dewatered sludge that contains in the order of 50 to 55 per cent solids. This sludge is denser than conventionally dewatered sludge, which typically contains only 20 to 30 per cent solids. This advanced process has a wide range of applications and can be easily retrofitted into existing AMD treatment systems. It has been successfully installed at several mine sites to treat AMD wastewaters. This paper discusses the high density sludge process, its benefits and provides data and operating results from pilot test installations.CITATION:Dal-Corobbo, A, 2013. High-density sludge process for treating metal bearing acid and metalliferous drainage wastewaters, in Proceedings Water in Mining 2013 , pp 217-220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By White A. H, Gillies A. D S

In recent years the Australian gold industry has gone through a major expansion phase. The need for finance has led to adoption of different approaches such as the well known gold loan, forward selling, equity participation by suppliers and equipment leasing. During early periods of the expansion, significant new equity was raised chiefly for high risk exploration ventures. The major form of new equity finance was ordinary shares, often in 'No Liability' companies. The increasing capital requirement of the huge new development projects of the 1980s also spurred the use of debt finance. This trend was accelerated as high inflation and the taxation advantages of debt finance made borrowing attractive. This paper reviews major financing techniques used by the Australian gold industry with particular emphasis on the innovative financing techniques initiated recently. An analysis has been undertaken of the effects on the industry of issues such gold loans, forward selling, equity participation by suppliers, fly-in fly-out operations, contractor mining and equipment leasing. In order to achieve a better understanding of the innovative financing techniques, a survey of already published financial data from well known Australian gold mines was carried out. Data was collected from various published financial reports of gold mining companies. In addition, a questionnaire survey was sent to gold mining companies to assist the collection of further information. The results of this study show that there are a significant number of gold mines variously using gold loans, forward sales, contractor mining and fly-in and fly-out arrangements to finance their projects. Only four operations have vendor suppliers investing capital funds in their projects. Based on the findings of this study, conclusions and recommendations are drawn that these approaches are likely to be with Australian gold industry for some time in the future and will continue to be intensively applied to finance gold projects.

Jan 1, 1994

By P Luo, J E. Danoczi, P Nakutnyy

Sensor-based sorting methods to remove waste or for upgrading ore prior to downstream metallurgical processing is becoming more prevalent for mining operations. X-ray transmission (XRT) sorters are a popular choice for mineral processing plants since they can sort a wide variety of minerals. XRT sorters pass high intensity X-rays through particles to generate images of varying greyscale, based on their effective atomic density. The ore sorter then mechanically separates the particles using algorithms based on the images. A popular test currently used to evaluate the amenability of the ore to XRT sorting is to pass the particles through the sorter and obtain the greyscale images showing mineralogical differences. This test provides information on the mineralogical heterogeneity between ore particles for their separation. However, it does not provide an understanding of the actual mineralogical composition of the ore or information pertaining to which other minerals may respond in a similar manner, nor does it provide liberation information. This paper describes a test that combines high resolution X-ray micro Computer Tomography (CT) combined with QEMScan to obtain information about amenability of ore to XRT sorting and to obtain valuable information that can streamline metallurgical testwork programs. This test also provides information relating to particle thickness and associated X-ray attenuation coefficients, desired mineral presence and mineralogical information relating to associated minerals and clays to assist with developing sorting algorithms. Combining the CT and QEMScan can address many limitations of the current method to determine whether XRT sorting technology is appropriate for particular ores. Mineralogy information from QEMScan can identify incidences of; mineral encapsulation, problematic clays, detrimental minerals as well as calibrate the greyscale values of CT data. Additional 3D CT imaging carried out on cores provides spatial information of the minerals within the ore and mineral grades.

Nov 10, 2020

By C J. Unger, T Baumgartl, C J. Bond, P Sabourenkov, V C. Glenn

Social licence to mine is influenced by society’s perception of the mining sector’s ability to effectively rehabilitate mined land and for governments to appropriately regulate that process for the broader community benefit. In Queensland, Australia, many mine rehabilitation personnel working for active coalmines, as either staff, consultants or contractors, belong to the Central Queensland Mine Rehabilitation Group (CQMRG). The CQMRG was established 23 years ago with the aim of sharing informal knowledge related to practical aspects of rehabilitation in order to leave as positive a legacy as possible from mined land. This voluntary group of professionals also includes members from regulatory agencies and civil society. Within the dynamic regional mining environment, mine rehabilitation professionals benefit from sharing their informal knowledge.CQMRG is currently a group in transition. Mining boom and downturn cycles have exacerbated the loss of accumulated knowledge in the core CQMRG membership due to rapid changes in personnel at mines in the region. Additionally, some of the most experienced CQMRG-affiliated rehabilitation practitioners are approaching the end of their careers and want their valuable and less formal knowledge retained. This paper discusses the development of a research project that emerged in response to the anticipated loss of several decades’ worth of valuable knowledge as rehabilitation practitioners in CQMRG left the region or the workforce.CITATION:Unger, C J, Bond, C J, Baumgartl, T, Glenn, V C and Sabourenkov, P, 2016. ‘MRC-wiki’ – a mine rehabilitation and closure knowledge management tool for Central Queensland coalmine practitioners, in Proceedings Life-of-Mine 2016 Conference , pp 39–42 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

A brief history of the significant haulage truck feature changes and the factors that influenced those changes during the 60's and 70's provide a basis for forecasting the changes that can be expected in the 1980's. A review of the impact factors and changing requirements that currently exist that will create changes. Define the critical requirements of a successful haulage truck design and discuss the availability of bigger engines and better electric drive componetry to provide deeper pit capability and improve reliability. The Unit Rig Trolley Assist System to provide improved productivity and diesel fuel savings and an economic analysis to evaluate the Trolley System is covered. The Unit Rig Automatic Truck System for a driverless truck is covered in concept and discussed from the point of view of the experience in a test in a New Mexico mine. INTRODUCTION A good basis for trying to forecast what is going to happen in the future is to go back a little bit in history, to see what the influencing elements were in different periods of time as a foundation for the forecast. INFLUENTIAL FACTORS IN THE 1960'S If you look at the truck development that occurred in the 1960's, there were some identifiable factors that give us insight. (See Fig. 1) Several things happened at the beginning of the 1960's. Mechanical drive haulage trucks were introduced that were

Jan 1, 1982

By Hermann J. A

Over the last few years enormous dapooits of high-grade bauxite have been discovered in Australia, ;_ d an alum .nium smelting industry based on them is rapidly being developed,, This industry requires large amounts of carbon, as about 60 pounds of carbon anodes are consumed for every 100 pounds of aiumin.'.'-n produced. Tie anodes are usually made by mixing finely ground petroleum coke with coal tar or petroleum pitch, forming the mix into shapes under pressure, and baking them at around ?.200¦C0 Petroleum coke is ussd uecause its high density gives good strength and conductav_ty to the finished electrode, and its purity ensures that contamination. of the alumin- ium by extraneous i,iorganic material from tho carbon is low,

Jan 1, 1969

Extraction under very mild conditions - a few minutes at room temperature with poor solvents - yields results characteristic of surface properties for a variety of coals. Such superficial extractions preferentially remove long-chain aliphatic compounds. As coal becomes more oxidized, less of these yellow- colored compounds is extracted, forming the basis for a simple colorimetric test for coal surface quality. The fact that these aliphatic compounds are responsible for surface hydrophobicity is supported by good correlation between extraction results and floatability, which decreases with decreasing extractability. This extraction test is very sensitive to oxi dationb even the effect of heating for an hour at 100 C can be detected. A second extraction test using mild alkali conditions has shown good correlation with plant dewatering Operations.

Jan 1, 1986

By S A. Ravishankar, W Perez

Flotation is one of the main concentration processes to purify kaolin clay via the removal of naturally occurring impurity minerals containing Ti and Fe. Currently, there are two types of collector chemistries used in the industry to float coloured impurity minerals. These are traditional tall oil fatty acids (TOFA) and specialty hydroxamate (AHX) based collectors. AHX based collectors have long been known to be the most selective collectors to float Ti and Fe based coloured impurity minerals (CIMs) as compared to TOFA based systems. AHX based collectors provide, not only improved selectivity and simplified process, but also more importantly, make it possible to treat certain kaolin resources that do not respond to standard TOFA systems. However, the relatively higher cost of straight AHX collectors has restricted broader application of these collectors in kaolin clay and other oxide flotation applications for a long time. Recent technological advancements, in both making and formulating AHX products more economically, increased the usage of these collectors in kaolin applications. Modified AHX products offer more economical alternatives and process options to provide high purity kaolin clay products for specialty applications based on cost-performance criteria. In this paper, the flotation performance of a series of newly developed AHX formulations is provided along with the characteristics of AHX flotation in general. In addition, flotation performance of earlier AHX collectors is provided based on published literature as background data.

Jan 1, 2005