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By P C. Hagan, J Chen, S Saydam

Fully grouted cable bolts have been used in underground mining industry for more than 40 years and are becoming more and more popular especially when severe geological conditions are encountered, such as high stresses and large cross-section excavations. The axial performance of cable bolts are mainly relied on the load transfer process between the cables themselves and surrounding rock masses via grout annulus. Therefore, the selected grouts play a significant role in determining the reinforcement quality for underground openings. In order to better understand the mechanical properties of Stratabinder HP grout, which is one type of cementitious grouts commonly used in Australian underground coalmines, plenty of unconfined compressive tests are conducted on it. Following diverse standards, two different kinds of samples are prepared and tested with the w/c ratio ranging from 0.35 to 0.45. During the test important mechanical properties including uniaxial compressive strength (UCS) values, Young’s modulus, Poisson’s ratios and so forth are recorded. Based on experimental results, the effect of w/c ratio on the mechanical properties of Stratabinder HP grout is studied. Beyond that, influences of sample size on the failure mode, peak strength as well as residual strength of this kind of grout are summarised and analysed.CITATION:Chen, J, Hagan, P C and Saydam, S, 2014. Mechanical properties of cementitious grout serving in fully grouted cable bolting systems, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 269–276 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By D Kilkenny

This paper discusses the use of a mechanised shaft sinking machine Herrenknecht Vertical Shaft Sinking Machine (VSM) – to conduct the 93 m presink for the Wira Hoisting Shaft at the Prominent Hill Mine in South Australia. This technology has been widely used in the global construction industry, however, this was the first time it had been used in Australia and the second time in a mining application. The non-entry shaft sinking system eliminates risks associated with a traditional manual method and allows all shaft construction operation to take place from surface. The geology in the upper 100 m at the Prominent Hill mine is conducive to mechanical excavation, with expected rock strengths below 130 MPa. This enabled an alternative shaft construction methodology to be considered. The Herrenknecht VSM system was selected due to its extensive work history and demonstrated performance in similar ground conditions. In collaboration with the operations and design team, the shaft collar and surface configuration were modified to suit the requirements of the VSM, additional equipment, and loading jacks that support the pre-cast lining. Dedicated concrete moulds were designed in Germany and built in Italy. The concrete segments were cast in Adelaide and road freighted to site. This paper outlines each stage of the presink – refurbishment, transportation, logistics, establishment, operation and demobilisation. Selecting this shaft presink excavation methodology, delivered through positive collaboration and communication despite some challenges, shows the benefit to the mining industry of applying new technology and innovation to improve safety and productivity.

Mar 29, 2023

By N Clarke, A Barros

Preconcentration of run-of-mine subgrade and marginal ore by screening has the potential to substantially improve the economics of mining, particularly for large, low-grade orebodies, and to reduce environmental impacts. It has recently been the subject of a major research effort by a joint public-private research body, CRCORE. Yet despite this, there appears to have been only one fully commercial installation, at Bougainville Copper Limited in the late 1980s. Two reasons for the limited application are that not all ores have suitable properties and the economics of all pre-concentration processes on low-grade materials are highly sensitive to the precise balance of mass and value recovery and to the pre-concentration process cost, including materials handling. These factors make it imperative to have good test data on the process response of feedstock across the orebody. Collecting that data presents major challenges, which differ for green and brownfields operations. This paper first discusses the approach to preliminary evaluation developed by CRCORE, which relies on testing of coarse rejects or drill chips available from exploration drilling programs. This method is an efficient first step in evaluating an orebody which is deemed geologically to be potentially amenable to screen upgrading, but it does have limitations and must be followed by larger scale work. A suite of methods have been developed by the authors as a result of test work since the 1990s on several projects, supplemented by published data, which aim to provide statistically robust data at lower cost than large scale bulk sampling tests. For greenfields projects, the upgrade response measured on material crushed to -53 mm has been found to correlate closely with ROM ore, with no scale-up required for material with upgrade responses in the range of commercial interest. Large diameter whole drill core, such as PQ, is expected to be suitable for this method. As drilling such core is costly, the aim should be to establish relationships between upgrade performance and proxy measurements such as multi-element chemical or hyperspectral analyses. This approach was successful at the Gramalote gold project in Colombia. The method is not applicable for ores with thick vein material comparable with the crush size, but such material is not suitable for upgrading by screening and would be eliminated by the preliminary testing. For brownfields projects where blasted material can be sampled, the upgrade response can be accurately measured by sampling only the finer fraction of the ore, selecting a top size which represents 30–50 per cent or more of the ROM size distribution. This is likely to be between 50 and 100 mm. The much finer size compared with the full ROM ore greatly reduces the sample mass required to achieve a given intrinsic sampling error and enables sample preparation to be undertaken with large-scale laboratory equipment rather than mobile crushing plant. The accuracy of the method can be improved by measuring the approximate mass of oversize rejected during sampling. Some ores do show a systematic deviation from the assumed model fit which results in this method slightly underestimating the upgrade response, and it would therefore still be recommended to take one or two full bulk samples to confirm results before a final investment decision.

Aug 24, 2022

By G Phillips

The Merlin project is situated 130 km south of Cloncurry in North West Queensland, Australia. It is located within the Pre-Cambrian Mt Isa Inlier and is grouped within the Eastern Fold Belt. The host rocks are metasedimentary rocks of the Proterozoic Kuridala and Staveley Formations adjacent to the Mount Dore Granite.Merlin zone represents part of the Mount Dore polymetallic deposit containing copper, zinc, silver, gold, lead, cobalt and most recently has been found to host molybdenum mineralisation. This is intimately associated with economic grades of rhenium, a naturally occurring metal that is an important component of high temperature aircraft engines. The host rock sequence is a 200 m thick zone of metasediments sandwiched between competent granite in the hanging wall and brittle quartzite in the foot wall. A distinct shear marks the contact between the granite and metasediments. The host rocks are comprised of three main rock types: black shale, phyllite and altered banded calc-silicate.Mineralisation dips to the east at approximately 45° in a package of fine grained pelites and banded calc-silicates. The top 150 m of the sequence is typified by black shale and phyllite. The lower 50 m is typified by pink banded calc-silicate. The main molybdenite zone is located at and parallel to the pelite-calc-silicate contact. Down dip, the zone splits into two or three veins hosted by the calc-silicate rock suite and haloed by thin, steep dipping, stylolitic molybdenite veinlets.The deposit was discovered in 2008 by routine infill reverse circulation sampling conducted for the Mount Dore copper deposit. One hole penetrated below the main target Cu horizon and intersected visible molybdenite. During 2009 and 2010 a 50 × 50 m diamond drill pattern delineated a total mineral resource of 6.7 Mt @ 1.3 per cent Mo, 23g/t Re, 0.3 per cent Cu (mostly Indicated Mineral Resource with minor Inferred Mineral Resource). The resource has been estimated using ordinary kriging within grade domains. Access to the deposit has commenced via a decline and production through the nearby Osborne flotation concentrator (70 km south) is expected in 2012. All facilities and resources are fully owned and operated by Ivanhoe Australia Limited, a public listed company on the Australian and Toronto stock exchanges.

Aug 22, 2011

By A Trench, S Ulrich, S Hagemann

A synthesis of reported All-In Sustaining Costs (AISC) for 57 Australian gold mines in the period 2014–2016 reveals for the first time the clear influence of grade upon cost performance, most evident in gold-only underground mines. Past syntheses of costs on a single quarter basis have viewed grade as potentially subordinate to other factors such as production scale, mine geometry, mineralisation style and a combination of other mining-related costs. Better understanding of the grade to cost relationship on both an individual mine and whole-of-portfolio portfolio basis is needed. Insight into the roles and trade-offs between other cost-determining factors will aid the future sustainability of the gold mining sector in Australia and assist in targeting prospects for future resource growth and development. While the overall trend is toward higher-grade mines displaying lower costs and vice versa, the grade to cost functions appear radically different between mines based on time-series data. The median cost of Australian gold production in the final quarter of 2016 was A$1081/oz. The threshold for lowest cost quartile production was A$965/oz. Underground production now dominates Australian gold output – with 71 per cent of ounces originating from operations that are either entirely underground or hybrid pit/underground mines. Scale economies are evident, with smaller mines predominately among the higher cost producers. For mines of equal grade, open pit mines are lower cost than underground operations. Reserves are modest, with a median mine life for underground operations of 4.7 years based on current production rates. Reserve additions at mines are likely constrained not only by the finite nature of mineralisation at each mine but also by the geometrical difficulty of accessing suitable drilling locations to test for reserve extensions.CITATION:Ulrich, S, Trench, A and Hagemann, S, 2017. Towards an understanding of production costs at Australia’s underground gold mines, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 241–250 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

The role of a project metallurgist is diverse and covers input into the resource definition, mining studies, metallurgical test program development, process engineering and plant design, cost estimate preparation and financial analysis aspects of project feasibility studies. Mining project schedule and cost overruns can often be attributed to cutting short metallurgical test work, engineering and cost estimating leading up to commitment to development. In a significant number of cases this may result from the lack of understanding and commitment by the project proponent to the requisite metallurgical and processing studies required during the various pre-commitment stages of a mining project. Metallurgical test work, process development, engineering and cost estimating requirements for each stage of pre-commitment development are described together with a summary of the ongoing role of the project metallurgist during detailed engineering and commissioning of a process plant.

Jan 1, 2008

By D Johansson, C Yi

Blasting techniques are widely used to fragment rock masses into smaller pieces. Numerical modelling is an efficient method employed by many researchers in the blasting field. It is difficult for a conventional continuum-based approach such as the finite element method (FEM) to model the rock fragmentation by blasting and the expansion work on the rock by explosive and its detonation products. In this paper, the particle blast method (PBM) was employed to model the behaviour of the detonation and a bonded particle model (BPM) was used to model the brittle material to be blasted. A mortar cylinder with a centrally placed hole for the explosive was modelled and the results were compared to the experimental data. The blast process from crack initiation to fragment formation was analysed. The influence of coupling ratio on fragmentation was also investigated.CITATION:Yi, C and Johansson, D, 2015. Discrete element modelling of blast fragmentation of a mortar cylinder, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 793–798 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By N Haque

Base metal ores contain low levels of toxic/hazardous elements such as arsenic, antimony, bismuth, cadmium, lead and mercury. Given the large tonnage of base metal ores mined and processed each year globally, the accumulated mass of minor elements introduced into the biosphere is large and could be expected to have a significant environmental impact. Life cycle analysis (LCA) is a methodology that has been developed to assess the environmental impacts of material supply chains over their entire life cycle. Assessing the toxicity impacts of metallic wastes and incorporating these impacts into LCA methodology is not a simple task given the complexity of the issue. However, research and methodology development is in progress internationally to address this. Despite limitations concerning the lack of a coherent framework for characterising the toxicity impacts of metals, including issues such as bioavailability, a study was carried out to give first estimates of the relative toxicity impacts of various waste streams from metal production processes. The wastes considered were: red mud; sulfide tailings (copper, nickel, lead/zinc); lead/zinc slags; synthetic rutile residue; iron oxide residue; and copper slags and anode slimes. These toxicity estimates can be considered the æworst caseÆ scenario for these wastes, where all the metals present are bioavailable. Combining estimates of the amounts of the various waste streams produced in Australia each year with the toxicity results showed that despite their relatively low human toxicity impact per unit mass compared to some other waste streams, red mud and the various sulphide tailings had the highest annual human toxicity load on the environment, along with copper smelting slag and dust. Data from the pH dependent leaching test reported in the literature were assumed to represent first approximations of metal bioavailability and used to compare the two approaches to estimating the toxicity impacts of red mud.

Jan 1, 2009

By J Kwak

Driving sustainability concepts and practices into the heart of the design process is the key to achieving a successful, sustainable plant design. Engineering design practices, tools, systems and methodologies should be prepared around true eco-efficiency parameters, adopt wholesystems-thinking and consider life-cycle impacts for the design task. Experience dictates that the application of sustainable plant design practices is most likely to succeed if: The principles are well documented and explained. All stakeholders agree on what sustainability means. Sustainable plant design is treated as a core process. The principals of sustainable plant design are equally applicable in brownfield and Greenfield environments. Although brownfield situations provide the designer with less latitude for change, these types of projects do allow easier measurement and demonstration of relative impacts. This paper further develops the above points by drawing on case studies from HatchÆs repertoire.

Jan 1, 2004

By S J. Hawke, L A. Dominguez

In non-ferrous metal mining operations, it is generally necessary to crush and grind the ore to a very fine particle size to effectively liberate the contained mineral from the host rock. Fragmentation by blasting is the first stage of this comminution process.Numerous studies and independent modelling of the Mine to Mill process have demonstrated the potential for significant downstream productivity improvements from improved blast fragmentation. However, safety and environmental constraints associated with the blasting process usually limit the extent to which blast energy or powder factor can be increased.An effective blasting solution has been identified that enables the safe utilisation of powder factors several times higher than those used conventionally to provide significant improvements in fragmentation. The solution uses a static ‘blanket’ of broken rock overlying the blast to contain this increased blast energy and control rock movement. To produce this broken layer of rock, the subdrill in each blast is significantly increased to preblast (or precondition) the entire stemming region of subsequent blasts on the next mining bench.The solution has been evaluated at a large open cut poly-metallic mine in Mexico. Results from the application of this technique have shown significant improvement in run-of-mine fragmentation, with subsequent downstream productivity improvement indicated.CITATION:Hawke, S J and Dominguez, L A, 2015. A simple technique for using high energy in blasting, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 321–326 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By E de Necker, F D. I Hodg, L-M Cruywagen

The acid mine drainage (AMD) situation at three opencast collieries in the Witbank Coalfield, South Africa, was evaluated from different perspectives. Twenty-seven test pits were dug into the spoils of these collieries to characterise the in situ conditions of spoils of varying age. Detailed static testing was done on surrounding drill holes and additional samples were taken from the test pits. Selected samples were tested using different techniques, namely ABA, mineralogy and kinetic tests. Groundwater monitoring boreholes from the areas surrounding these spoils were also used for characterisation. The ABA results compared favourably with the in situ determinations; acidic test pits proved to be potentially acid-generating from ABA, even when the samples had neutral paste pH. Kinetic test results showed these samples to yield low pH leachate over the test period. In several of these results, the theoretical depletion of neutralising potential and the onset of acidity were well matched. NAG pH-values and final observed water chemistry corresponded for the cells predicted by ABA to acidify, but compared poorly in cells that did not acidify. Results from the non-acidic spoils were consistent with the in situ observations. Alternative kinetic test methodologies were also employed. Duplicate samples were tested in humidity cells and in aerated trays that were manually wetted on a regular basis. Results from these tests showed an excellent correlation. Detailed mineralogical determinations using XRD and XRF were used for comparison to the ABA and, in some cases, humidity cell results. These comparisons show that the ABA results are consistent with the results expected from the mineralogy. The conclusion from these assessments is that ABA, in most cases, provides information that can be correlated to the field, mineralogy and to humidity cells. The use of multiple techniques leads to a higher degree of confidence in the use of the data.

Jan 1, 2003

By G J. Halstead, R C. Steinhaus

The True Pipe® in-line sampler was developed in an attempt to address the need for a mechanically reliable and correctly designed sampler to suit one-dimensional pressurised slurry pipelines, often found in metallurgical process plants but for which no reliable and representative sampling solution as yet exists.The design, whose operation is based on the principle of symmetry, is described by Dominique François-Bongarçon (2005) with the synchronous opening and closing of relevant valves. It representatively isolates portions of the particulate material stream at predetermined intervals for effective extraction of primary increments for subsequent sample compositing.Theory of Sampling applicable solutions have proven elusive in flowing pressurised particulate material streams, with various attempts to date not having formulated a viable, mechanically reliable and acceptable design.Compliance to sampling theory is critical, and a number of tests were conducted where certain operating parameters were altered to determine their influence and sensitivity on sampling representativeness.The results of the initial series of tests performed on a carefully designed rig are presented, with additional work discussed for necessary investigation in the near future.Getting closer to a robust, economic and correct design for this challenging application in the minerals industry may now not be that far away. Plant management staff will see improved metallurgical mineral balances around their process plants and significantly reduced sampling discrepancies, particularly in tailings applications. Improved quality control is now possible where, due to plant head room constraints, classical cross stream sampling methods cannot be employed.CITATION:Steinhaus, R C and Halstead, G J, 2014. True pipe sampler – a correct design utilising the principle of symmetry in pressurised slurry particulate streams, in Proceedings Sampling 2014 , pp 127–134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By G N. Phillips

No new goldfields have been found in the Witwatersrand Basin for over 60 years, and one consequence of this is a long-term decline in gold production. Exploration throughout this period has been based on the placer model that infers alluvial transport of gold grains and then sedimentary sorting in the basin; however, there is no viable source for so much alluvial gold and no single sedimentary setting that hosts the gold.An alternative genetic model can now provide a quantified explanation for the source of the gold, and it does not rely on alluvial gold processes. The hydrothermal model can easily explain the source of the Witwatersrand gold as being derived from the background gold at parts per billion (ppb) level throughout the Kaapvaal craton of South Africa. This gold is involved in metamorphic processes, available for solution in metamorphic fluids, and hence may be transported whilst dissolved in fluid into the Witwatersrand Basin. The hydrothermal model warrants consideration as it can explain the source of gold, the large alteration halo in the goldfields, the mineralogy, and especially the gold-carbon association.Working on the premise that if one model (placer) is not giving the desired results (discovery of new goldfields), then it may be prudent to consider alternatives. Application of a hydrothermal model to guide exploration would place importance on large and small early structures in and around the Witwatersrand Basin; it would also emphasise the geochemical nature of potential host rocks (especially C and Fe) rather than their sedimentary origin.CITATION:Phillips, G N, 2013. Origin of Witwatersrand Gold - a viable source region and source process for gold, in Proceedings World Gold 2013 , pp 175-180 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Roberts T, Firth B. A

A series of flotation experiments was carried out to study the interaction between the parameters of pulp density (mass per cent of solids in feed slurry) and frother addition (on the basis of solid mass feed rate). It was found that certain combinations of pulp density and frother additions caused large losses in yield. The interactive effect of these parameters can be primarily attributed to the total amount of frother added per unit of water. Consequently it is suggested that frother additions be made on the basis of water flow rate. As frother addition increased, in terms of the amount of frother per unit of water, yield increased rapidly but above an addition rate of about 10 g/tone it reached a plateau. Such results correlated well with qualitative visual observations of changes in bubble size and dispersion, with increasing levels of frother addition.

Jan 1, 1984

By L Torckler, J Hobbins

Favona is a blind low-sulfidation epithermal vein deposit in the Waihi Vein System approximately two kilometres east of the world class Martha Hill deposit that has produced nearly 6.8 M oz Au to date. The Favona epithermal system has surface expression in variously altered and mineralised hydrothermal eruption breccias forming a series of low hills that are windows through post mineral dacites and ignimbrites. The tip line of the Favona vein is about 50 û 100 m below surface with a steeply east dipping principal vein structure carrying numerous hanging wall splays in the upper flatter section and thickening down dip where the vein steepens. Host rocks comprise feldspar phyric andesite flows with minor pyroclastics. Although Favona has a strike length in excess of 1000 m and vein widths up to 25 m over a vertical range in excess of 400 m it was only recently discovered after nearly thirty years of exploration by various companies involved in the Martha Hill joint venture that operates the Martha Mine. Since discovery in 2001 a feasibility study based on 27.5 km of diamond drilling in 83 holes has been completed reporting a reserve of 1 Mt @ 10 g/t Au against a resource of 1.8 Mt @ 10.3 g/t Au. Exploration is continuing with a further 20.5km of diamond drilling completed to date on nearby prospects.

Jan 1, 2004

By M Kim, J Park, I-K Suh, E Kim, J Lee

One of the key technologies in developing hydrogen-enriched ironmaking operations is the control of the carburisation, melting, and dripping behaviour of the iron ore burden materials. When a hot compacted iron (HCI) is charged in the blast furnace or the FINEX Melter-Gasifier, iron oxide reduction, the reduced iron’s carburisation, and the melting of iron and slag occur successively. This study investigated the reduction, carburisation, melting and dripping behaviour of HCI under a COH2 gas mixture using the high-temperature X-ray radiographic technique. Under 100 per cent CO gas atmosphere, the dripping temperature was 1410°C. When 5 per cent H2 was introduced, the dripping temperature slightly decreased to 1400°C. Furthermore, the dripping temperature gradually increased as the H2 gas composition increased. As 30 per cent H2 was introduced, the dripping temperature reached 1414°C. The carbon concentration in the drained metal samples gradually increased with increasing H2 composition. It is considered that H2 decreased FeO content in the slag, yielding the increased melting temperature and viscosity of the slag. On the other hand, H2 accelerated the carburisation of the reduced iron by CO gas, enabling the homogenisation of the oxide materials to form a liquid phase. Therefore, it is considered that introducing H2 in the reactor is helpful to increase productivity and energy efficiency by accelerating the liquid phase’s formation.

Aug 21, 2024

By R Fanni, D Reid, M Kulessa

Recent updates to Australian industry guidelines emphasise the importance of the assessment of liquefaction potential of tailings. This includes assessment of the cyclic liquefaction potential, and the post-seismic strength of tailings expected to undergo strength loss from seismic loading. Despite this increase in focus, a relatively small number of Australian tailings appear to have been characterised through cyclic and post-cyclic testing. This paper presents the cyclic characterisation of four Australian tailings, consisting of iron ore, lateritic nickel, vanadium and bauxite residue. Material was obtained either from surficial tube sampling or through remoulding samples in the laboratory from slurries. Testing consisted of monotonic, cyclic and post-cyclic tests for each material. For three of the materials, laboratory-scale shear vane testing was also performed to provide a comparison to post-cyclic strengths from direct simple shear.The results indicated cyclic resistances consistent with the results of other tailings presented in the literature. The lateritic nickel tailings provided the greatest cyclic resistance of the four materials tested, followed by the vanadium tailings. This was somewhat consistent with expectations for material behaviour based on index properties. Post-cyclic strengths were seen to decrease as cyclic strains increased, consistent with typical observations in the literature. Following significant cyclic straining, in some instances the post-cyclic strengths approached those obtained through residual shear vane testing. This provides further insight into the strain-dependent nature of post-cyclic strengths for some materials. The implications of these observations on the post-seismic stability condition are discussed.CITATION:Reid, D, Fanni, R and Kulessa, M, 2015. Cyclic and post-cyclic behaviour of four Australian tailings, in Proceedings Tailings and Mine Waste Management for the 21st Century, pp 207–214 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By X L. Liu, W Huang, J M. Zhu, S L. Wu

The shape, position and thickness of the cohesive zone have a great influence on the operational performance of the blast furnace. Many researchers have found that the high temperature properties of iron ores determine the formation of the cohesive zone. The results of this work show that sinter of high basicity interacts with lump ores and acid pellets due to the difference in chemical compositions. The softening and melting properties and the primary slag formation behaviours in the cohesive zone are improved by the high temperature interactions. The high temperature interaction is mainly influenced by the chemical compositions, porosity, interfaces and so on. Although the softening and melting properties and primary slag formation behaviours of lump ore A (a typical limonite lump ore from Australia) is the poorest of the iron ores studied, the high temperature properties of integrated burden A (consisting of sinter and lump ore A) is no worse than the other integrated burdens due to the high interaction between the sinter and lump ore A. It is useful to apply the results in the optimisation of blast furnace burden.CITATION:Liu, X L, Wu, S L, Huang, W and Zhu, J M, 2015. High temperature interactivity of iron ores in the cohesive zone of the blast furnace, in Proceedings Iron Ore 2015, pp 363–366 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By I Ametov, S Harmer, R Alford

A process that allows selective flotation separation of low Cu/S ratio minerals (chalcopyrite and pyrite) from high Cu/S ratio minerals (bornite and chalcocite) from a mixed copper mineral concentrate under controlled oxidative-reductive potential conditions has been developed. The process has been extensively tested on samples with varying mineralogy using laboratory batch flotation tests and mini pilot plant trials.In this process, the mixed final copper mineral concentrate is purged with nitrogen, and then treated with sodium dithionite to achieve a slurry Eh in the -200 to -100 mV standard hydrogen electrode (SHE) range. Flotation was then carried out using nitrogen gas. As a result, a low Cu/S ratio concentrate (<1.3) and a high Cu/S ratio (>1.6) tailing stream were produced. QEMSCAN analysis of the flotation products showed that more than 85 per cent of the chalcopyrite and 95 per cent of the pyrite reported to the froth concentrate. Chalcocite and bornite were almost evenly distributed between the concentrate and tailing streams.Surface analysis studies, focused on the mechanism of separation, showed that at a negative redox potential xanthate and possibly dixanthogen are the dominant hydrophobic species on the surface of chalcopyrite and pyrite. As a result, the flotation of these minerals remained unaffected. In contrast, a much lower concentration of xanthate species on the surface of chalcocite and bornite particles was observed. Therefore, it is likely that at low Eh the copper xanthate complex desorbs from the chalcocite and bornite surfaces, causing a decrease in surface hydrophobicity and the diminished floatability of chalcocite and bornite.CITATION:Ametov, I, Harmer, S, Grano, S and Alford, R, 2014. Selective flotation of chalcopyrite and pyrite from a mixed copper mineral concentrate under controlled redox potential conditions, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 131–140 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By J S. J van Deventer, D C. Shallcross

New developments are taking place in the recovery of gold from leached pulps that are based upon the adsorption of the metal cyanide species onto ion exchange resins. Despite the success of several resin-in-pulp pilot plant operations in the Western World and large-scale plants in the former Soviet Union, the process is yet to gain recognition as a viable alternative to the carbon-in-pulp process. An experimental research program has investigated the use of a variety of different types of resins for the recovery of gold, but to-date no resin studied has the desired properties of high selective loading capacity for gold cyanide and a simple inexpensive elution procedure. In addition very little is known concerning the physical strength of resins and their ability to resist shattering due to osmotic shock during cycles of adsorption and elution. The ability of ion exchange resins to enhance the leaching of refractory and re-adsorbing ores has not been investigated. This paper highlights the necessary factors that need to be addressed before commercialisation of ion exchange technology for gold extraction is feasible.

Jan 1, 1998