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By PC Pistorius, DR Groot

The South African base metals industry has been one mainly focused on the production of metals or metal compounds from primary ores. This is true for metals such as titanium, vanadium, chrome, manganese, cobalt, nickel, copper, zinc and aluminium. The steel making industry has traditionally used a substantial portion of scrap steel, and could thus be considered to be somewhat of an exception. Secondary sources have played much less of a role, possibly due to at least some of the following factors. Scrap material is often of unknown composition, and thus it requires additional chemical analysis, and possibly special treatment. Tonnages are relatively small, and the incorporation of secondary materials is possibly seen to carry undue risk and inadequate benefit. South African consumers are still not very conservation and recycling conscious, which limits the amount of scrap made available. This attitude might also be expected to influence decision makers in these industries. Finally, pressure from environmentally motivated activists locally has not been unduly large. This landscape has been changing, and is continuing to do so. Various municipal authorities such as those of Pretoria, Johannesburg and Cape Town are reporting increasingly limited landspace for waste (Bondolfi, 2007). There are increasing concerns regarding the leaching of hazardous metals such as chromium, mercury and cadmium from landfill waste, especially electronic and electric wastes ? the so-called eWastes. In more developed countries such as the United States of America and Western Europe the problem of eWaste has grown to the extent where legislation has been enacted, such as the Waste Electrical and Electronic Equipment (WEEE) legislation of the EU (European Union Directive 2002/96/EC). The 19th and 20th centuries have seen major technological advances. Relevant to this paper is the availability of centrally generated electrical power, telecommunication, entertainment through recorded and transmitted music and images, the growth and pervasive influence of electronics, and the handling of digital data by computers and microprocessors. These developments have placed ever increasing demands on resources for the manufacture of electrical and electronic equipment, as well as on the generation of electrical power. Most of the resources required are non-renewable: copper, steel, aluminium and other metals, various thermoplastic polymers such as PVC (polyvinyl chloride), polyethylene and ABS ( acrylonitrile-butadiene-styrene), thermosetting polymers such as epoxies, elastomers such as butyl rubber, glasses and ceramics, and composites such as fibre reinforced plastic (fibreglass). The conservation of non-renewable resources inevitably includes recycling. To a certain extent, recycling of materials locally is well established. Thus glass, paper, used oil, car batteries, ferrous scrap such as beverage cans and non-ferrous scrap such as

Jan 1, 2007

By Richard F. Link, Jr. Koch

"A mathematical simulation model has been devised to guide the layout of surface or underground mine workings, drill stations, and drill holes that are established in order to search for tabular ore bodies. The ore bodies may be contained within veins, sedimentary beds (including reefs), or other tabular structures.Programmed for a time-shared digital computer, the model contains both stochastic and deterministic variables. Stochastic or natural variables include the number of ore shoots and their sizes, orientations, locations and values. Deterministic or controllable variables include (i) locations and costs of workings (for underground exploration); (ii) drill station locations and costs; and (iii) drill hole azimuths, inclinations, lengths and deflections (if any).For various assumptions about the natural variables, the model is run while the controllable variables arc changed deliberately. Thus, layouts are devised to determine the percentages of the total number of assumed ore shoots found at different costs. In order to choose among the various layouts, cost-effectiveness measures are calculated."

Jan 1, 2014

By F. S. Hoseinian, B. Rezai, E. Kowsari, M. Safari

In order to remove heavy metal ions from a large volume of wastewater with a low ion concentration, ion flotation appears to be promisingly effective. In the ion flotation process, because of the high ion removal percentage, the amount of water recovery percentage is a very important factor which determines the process efficiency. However, ion flotation suffers from relatively high collector concentration to achieve the high removal percentage to the desired limit, which subsequently increases the water recovery. In this study, functionalised graphene oxide (FGO) was synthesised, using a chemical method in the ion flotation process, applied as a collector for increasing process efficiency by reducing the collector consumption and water recovery. The high ion removal was achieved with both collectors of sodium dodecyl sulfate (SDS) and FGO, while the water recovery with a collector of SDS was 3.4% higher than that with a collector of FGO. The results indicated that the FGO could be effectively used for high ion removal and low water recovery in the ion flotation process. Keywords: Ion flotation, synthesised collector, ion removal, wastewater, water recovery

Jan 1, 2020

By P. G. Toledo, R. I. Jeldres, G. R. Quezada

Chile is the main producer of copper in the world and lately the mining industry has suffered challenges due to the lack of water in the north of the country, along with the new policies of not using fresh water for the industry. This has prompted the use of seawater as an alternative source for mining. Several studies have been driven due to this new scenario, which have shown that seawater can be beneficial, if certain ions are removed from the process. This is the Mg that generates precipitates at high pH, that have been shown to make mining operations difficult. In particular, thickening operations are impaired by the presence of Mg ions, where aggregate formation and sedimentation decreases substantially. Our studies suggest the competence of the precipitates in adhering to the polyacrylamide (HPAM) flocculant and not towards the surface of the quartz minerals. This motivates the present work to use molecular dynamics to study the adsorption of a HPAM molecule on quartz surfaces and the surfaces formed by Mg precipitates. The surfaces are immersed in a saline solution or seawater that includes the HPAM molecule. Results are obtained by measure the adsorption frequency and duration. We obtained that the HPAM molecules are preferably absorbed on the surfaces of magnesium hydroxide. This gives us a good agreement with what is observed experimentally and strengthens the premise of the competition of hydroxide with the flocculant. Keywords: Molecular dynamics, adsorption, tailing flocculation, magnesium removal

Jan 1, 2020

By N. Naude, L. S. Leal Filho, M. P. Tshazi

In this paper, the authors performed experiments in the Denver and Leeds laboratory flotation devices at the University of Pretoria at various particle sizes to evaluate the performance of the devices. Quartz was used in a single mineral system at discrete sizes fractions, -25 μm, +25- 45 μm, +45-75 μm, and +75-106 μm. Hydrodynamic analysis, based on dimensionless power and Reynolds numbers, indicated that the Leeds cell required higher power input to achieve comparable flow conditions. Specifically, the Leeds cell exhibited an average power number of 1.03, whereas the Denver cell averaged 0.77 within the same impeller speed range of 1000 rpm–1500 rpm. For comparative flotation performance, impeller speeds were calibrated, resulting in operating speeds of 1200 rpm for the Denver cell and 1400 rpm for the Leeds cell. The cells performed similarly at two coarser-sized fractions. However, some deviations were observed in the finer particle size range. The -25 μm (fine) fraction initially achieved a recovery of only 15%. An additional reagent dosage was required to enhance the recovery of this fraction significantly. These findings highlighted the influence of particle size on flotation recovery. For all experiments, the Denver laboratory flotation cell outperformed (defined by higher recovery) the Leeds device, while still operating at a lower impeller speed. This advantage can be attributed to its impeller-stator design and air dispersion features, effectively overcoming slurry resistance and resulting in superior flotation performance compared to the Leeds cell.

May 27, 2025

By E. J. Y., G. J. McLachlan, E. Amini, Koha

Inferring individual component flotation rates from recovery-time data of ore complexes is important in optimising and designing minerals processing plants. However, existing two-component first-order flotation models are computationally intensive to solve using conventional non-linear least squares regression. In this paper, a Convolutional Neural Network (CNN) is used to approximate the inverse function which predicts the two-component first-order model parameters using recovery-time data. This paper compares the accuracy and computation speed of the proposed CNN against traditional non-linear least squares regression on 1 million generated data based on a known two-component firstorder kinetic model. It is shown that using a CNN is possible to approximate the inverse function for the non-invertible two-component model with recovery-time as an input matrix for convolution operations. The CNN method is 450 times faster to compute than the Trust-Region (TR) non-linear least squares regression algorithm. However, the CNN model is less accurate compared to the TR algorithm overall. Keywords: Flotation kinetics, convolutional neural network, inverse problem, modelling and simulations

Jan 1, 2020

By Roger A. Blais, Michel David

"Matheron's geoslalislical method for the estimation of ore reserves has been developed to the point at which real-life problem may be handled effectively. The steps involved in the method are:(i) obtalning the variogram,(ii) fitting a model, and(iii) producing block estimates.All three steps may cause difficulty, and would-be users need a deep understanding of the theory if failure is to be avoided.To illustrate these points, specific cause are considered:(i) two almost equidimensional porpbyry deposits, one drilled randomly and the other regularly; and(ii) two iron formation, one drilled extensively and being mined, while the other is still at the stage of early estimation."

Jan 1, 2014

By C. Ntsele

Stirred milling technologies have firmly established themselves in concentrator circuits as energy-efficient alternatives to tumbling ball mills. High and continued increases in electricity costs, coupled with the ever-increasing power consumption by primary grinding circuits due to declining head grades of ore-bodies, provides a compelling case for these technologies. Additionally, the ability to successfully deploy stirred milling in coarse grinding applications extends the range of use in concentrators, thus increasing the opportunity matrix for energy optimization in a flowsheet. This paper therefore details methodologies and strategies that can be applied to evaluate the optimum stirred milling solution for different concentrator applications. These methods and strategies will focus specifically on the two major stirred mill machine types; namely, gravity-induced (VERTIMILL? grinding mill and Nippion-Eirich tower mill) and fluidized (SMD, Isamill?, Knelson-Deswik mill, etc. ). Finally, case studies from circuits across industry and laboratory tests will be used to illustrate the energy benefit from the use of stirred mills.

Jan 1, 2012

By M. Dworzanowski

Beneficiation, in the context of this paper, has two distinct definitions. From an economic perspective, beneficiation relates to adding value to a mined raw material. From a metallurgy perspective, beneficiation relates to processes used to upgrade the mined raw material. Clearly then, ?economic beneficiation? is dependent on ?metallurgical beneficiation?. South Africa possesses the world?s largest mineral resources by value and is a significant global producer of many mined commodities. Significant metallurgical beneficiation of ores does occur in South Africa. The role of metallurgy in economic beneficiation will be examined in terms of current practice and the potential for expansion. South Africa?s main mining commodities will be covered ? namely gold, platinum, coal, iron ore, manganese, chromium, vanadium, copper, nickel, titanium, zirconium, uranium, and diamonds.

Sep 1, 2013

By B. Aydin, A. S. Aloglu, S. Kahraman, E. Saygin

"The coal strength parameter is used in operations such as the selection and design of mechanical excavators and coal crushing/grinding equipment. However, coring or cutting prismatic specimens from coal for the standard strength tests is difficult, and sometimes not possible. For this reason a method for the indirect determination of coal strength from easy tests would be useful. In this study, the predictability of coal strength from the needle penetration test was investigated. This is a very easy and practical test method. Point load and needle penetration index (NPI) tests were carried out on coal specimens from Çayirhan coalfield in Turkey. The point load indexes were converted to the uniaxial compressive strength (UCS) values by using the general conversion factor. The UCS and NPI values were evaluated using regression analysis. A strong linear relationship was found between the two parameters. The conversion factor for the UCS-NPI ratio is 0.35 for the tested coal samples. It is concluded that the UCS of coal can be predicted from the NPI.IntroductionKnowledge of coal strength is important for the selection and design of mechanical excavators and coal crushing and grinding equipment. Uniaxial compressive strength of coal is used in designing pillar dimensions in room and pillar mining. Coals always contain bedding planes and cleats; they are also brittle and fragile. Therefore, coring or cutting prismatic specimens from coal for the standard strength tests is difficult, and sometimes not possible. For this reason, a method for the estimation of coal strength from easy tests would be useful.The needle penetration test is a nondestructive index test that is applicable both in the field and the laboratory and does not require any special sample preparation. The test has been used for the estimation of physical and mechanical properties of weak or soft rocks (Okada et al., 1985; Yamaguchi et al., 1997; Takahashi, Noto, and Yokokawa, 1988; Uchida et al., 2004; Aydan et al., 2006; Aydan, Watanabe, and Tokashiki, 2008; Aydan, 2012; Erguler and Ulusay, 2007; Park, Obara, and Kan, 2011; Ulusay and Erguler, 2012; Aydan and Ulusay, 2013; Aydan. Sato, and Yagi, 2014). This study investigates the predictability of coal strength from the needle penetration test."

Jan 1, 2017

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and the rate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By R. Degel

Submerged arc furnaces and electric smelters are applied in numerous metal and slag production lines. Particularly in ferroalloy and non-ferrous metal production, like silicon metal, platinum group metals, calcium carbide, and copper, the units are an essential part of the production technology. Most of these electric furnaces are considered to be highly energy-intensive units. The high level of required electrical power is defined by the process. SMS developed several measures to reduce the overall electrical energy consumption of these metal production lines. In particular, the following measures contributes to a lower energy consumption: improved electrical efficiency with intelligent design and application of components, minimizing the heat losses from the furnaces with a balanced cooling/refractory systems, minimization of process steps (such as elimination of agglomeration), recovery of energy, process optimization (resulting in higher metal yield) and the achievement of higher recovery rates, enlarging furnace capacity to reduce heat losses, and maximizing the power-on time. This paper gives an overview of the above-mentioned solutions.

Jan 1, 2012

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By V. Yahorava

Efficient recovery of precious metals from process solutions is essential for improving process economics. Traditionally, precious metals are relatively effectively recovered from waste streams via precipitation or cementation. However, these approaches have a number of drawbacks, including poor water balance, creation of environmentally unfriendly waste streams, and losses of precious metals. Ion exchange technology is an alternative for the recovery of precious metals from waste or low-grade streams. This technology allows the recovery of the precious metals to extremely low levels (micrograms per litre) with relatively high upgrade ratios from the solution onto the resin without major water balance concerns, while the impact on the environment could be minimized or avoided. Research was conducted on the recovery of platinum group metals and gold from different low-grade and waste streams from one of the precious metals refineries in South Africa by means of ion exchange. Various functionalities and matrices (granular and fibrous) of ion exchange materials were evaluated. The results from these studies indicated that in some cases ion exchange could be very effective for the recovery of precious metals, and that the PGM concentration could be reduced to < 1 mg/L. The upgrading ratios of the various PGMs onto the specific fibres were relatively high for the specific streams evaluated, which might in some cases justify incineration of the loaded material instead of stripping and recycling the adsorbent. The cost of direct incineration for one of the waste streams tested would be less than 1% of the value of the PGMs recovered. However, the adsorbent has to be carefully selected and the process design optimized for each specific stream.

Jan 1, 2014

By M. Shaw, H. R. Heydenrych, A. E. Lewis, E. Glass, J. Chivavava

The removal of calcium from the retentates of reverse osmosis (RO) treated minewater is desirable since it allows the recovery of both additional potable water (through RO) and higher-purity salts (in downstream processing). This, in turn, reduces the need for costly and unsustainable evaporation ponds and enhances the economics and operability of potential zero-liquid discharge downstream processes, e.g. evaporative-, cooling- and eutectic freeze-crystallisation. For this study, a multi-component retentate high in sodium content was considered, typical of those emanating from minewater reclamation plants in Mpumalanga, South Africa. Four technologies were evaluated to remove calcium: gypsum precipitation by addition of lime; calcium carbonate precipitation by addition of soda-ash; heating crystallisation of calcium sulphate anhydrite; and cooling crystallisation of gypsum. Full processes were developed and simulated using electrolyte thermodynamics. Using the results of these simulations, capital- and operating costs, as well as revenues were calculated and used in economic comparisons of the processes. Sensitivities to key purchasing and selling prices were also investigated to understand the impact of changes in these variables. For the case of a low magnesium-to-sodium ratio in the feed, gypsum precipitation through lime addition was found to have the lowest operating and total annualised costs; but, if revenue could be derived from the sale of sodium sulphate, calcium carbonate precipitation through soda-ash addition was favoured. Keywords: Calcium removal, gypsum precipitation, calcium carbonate precipitation, heating crystallsation, cooling crystallisation, economic comparison

Jan 1, 2020

"Chairman: Professor J. C. Griffiths Rapporteur: Mr J. P. G. PRETORIUSPapers:Mine-mill production scheduling by dynamic programming by R. J. Roman Optimization of a large mining venture by J. C. Paynter, B. K. Loveday and C. G. Robinson Economic surface mining of multiple seams by T. V. Falkie and W. E. PorterIn introducing his paper, Mr Roman said that whereas in manufacturing plants the yearly production levels were usually chosen to produce the largest annual cash flow, in a mining operation, the raw materials (ore) were exhaustible so that the production had to be scheduled to maximize the total net present worth of the operation. This optimum production schedule could be determined by using dynamic programming. The required information was readily available to management at most mines. The &apos;possible operating range&apos; of production rates lay between the rate with the highest profit per ton. and that with the highest profit per year. The optimum production rate started typically at the top of this range and decreased slowly as the deposit was depleted.Dynamic programming was used to determine several production schedules for a hypothetical mine-mill complex. The effects of changes in the ore grade estimates, size of deposit and acceptable rate of interest on the production schedule were taken into account. Apart from the fact that the net present worth of the overall profits was larger than that obtained by conventional methods, it appeared from the cases studied that the amount of metal recovered was also greater.Dr it P. King commented that this was a very interesting application of dynamic programming. He pointed out, however, that the market price of the metal was likely to vary significantly and randomly during the life of the mine, and he suggested that the problem should, therefore, be reformulated as a stochastic dynamic programming problem.If the price of the metal rose to abnormally high levels, a much higher than normal production rate could be expected. The results of analyses given in Table 5 showed that the production rate was a function of market price. In his view the stochastic problem could be solved just as easily as the deterministic problem.In reply to a question by Dr King as to whether the function relating recovery to production rate (Table I) was based on real data, the author replied that it was based on the results of an analysis conducted at the Union Carbide Corporation&apos;s Pine Creek tungsten mine in California.Dr D. M. Hawkins stated that costs were incurred when the production rate was altered, for example, in appointing or laying off staff, and that in practice it may be necessary to take these costs into account in finding the optimum production rate. Mr Roman replied that, while normal administrative costs were accounted for, the additional costs incurred in appointing and laying off staff were not taken into account."

Jan 1, 2014

By A. V. Pavlov, A. V. Dubachev, K. L. Kossyrev

The purpose of the given research was to investigate the possibility of high-carbon ferrochromium refining to remove harmful impurities as a result of metal treatment by slag mixtures on the basis of the CaO-MgO-SiO2system. The final conclusions were drawn from experimental results. It was shown that the treatment of high-carbon ferrochromium by SiO2-MgO-CaO slag mixtures with additions of chromium sinter or iron-ore concentrate removes carbon, sulphur and phosphorus from the metal. A mechanism of phosphorus removal from a melt to a gas phase is proposed.

Jan 1, 2004

By G. Bacon

The past decade has witnessed unprecedented growth in the development and implementation of solvent extraction technology in the extractive metallurgy of nickel and cobalt. Solvent extraction is proving to be a powerful tool, opening new opportunities for simpler, more cost efficient and environmentally sound metal refining processes. These advances, however, could not have been possible without the cooperative efforts between the nickel industry and the people and organizations involved with reagents, materials and equipment development and supply as well as solvent extraction research, aided by the accumulated knowledge and practical experience from the copper and uranium solvent extraction operations. This paper provides an overview of these developments and some of the challenges ahead.

Jan 1, 2002

By A. Mboma

Keywords: Furnace, decommissioning, care and maintenance, re-start, funding, nickel Bindura Nickel Corporation (BNC) operates two nickel mines, and treats concentrates from these mines as well as toll concentrates from the region around its Bindura Smelter and Refinery (BSR) complex. At the smelter, concentrates of at least 5% nickel content are blended and dried to 4% moisture in a coal-fired rotary kiln. Matte smelting of concentrate is carried out in a six-in-line electric arc furnace, where the furnace slag is granulated and discarded. Furnace matte is transferred via ladles into Peirce-Smith converters, where, after granulation, a leach alloy containing 68%Ni, 20%Cu, and 6%S is produced. Converter slag is recycled via the matte-smelting furnace. The onset of the global economic recession towards the end of 2008 resulted in a collapse of metal prices, worsening the local situation that was already marred by unfavourable macro-economic conditions in Zimbabwe. As a result, BNC mines were put on care and maintenance in November 2008, followed by Bindura Smelter and Refinery in February and March 2009 respectively. The business environment has since changed, and BNC is getting ready to re-start the plant. This paper describes the decommissioning of the Bindura furnace, asset preservation during the care and maintenance programme in the past two years, and preparation for starting up of the Bindura smelter in the near future.

Jan 1, 2011

By N. Hadebe, A. Mampuru, F. Jantjies

Mintek conducted test work to study the effect of media wear when using Mintek’s Milling-in-raffinate technology. The grinding media consisted of high-chrome and ceramic balls. The tests were conducted using a laboratory 5L 316 stainless-steel rubber-lined mill. Magotteaux supplied the high-chrome and ceramic balls. The raffinate was synthetically prepared using a typical Cu/Co (2.2 g/L Cu, 3 g/L Co) composition. The milling rate, media wear, mill, leach extraction efficiencies, gangue acid consumption, and residence time were studied. The tests indicated that the high-chrome balls had a higher corrosion rate than the ceramic balls. The ceramic corrosion rate was lower than 0.1 mm/y. The highchrome balls performed better during the leach stages with faster milling time, higher leaching efficiencies for both Cu and Co, lower gangue-acid consumption, and lower residence time

Jan 1, 2023