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By Alla D. Mah

The work described in this report is part of a Bureau of Mines research program for obtaining heats of formation of inorganic oxides, carbides, and nitrides by combustion calorimetry. The heats of combustion of molybdenum subnitride (Mo2N) and chromium subnitride (Cr2N) were measured. The data were combined with previous determinations of the heats of formation of molybdenum trioxide and chromium sesquioxide to obtain the heats of formation of the two subnitrides from the elements at 298.15° K. The corresponding free energies of formation were estimated. The heat data were compared with those of nine previously studied nitrides.

Jan 1, 1960

By K. O. Bennington

Enthalpies of formation of three sodium titanates were determined by hydrofluoric acid solution calorimetry, The values obtained for formation from the elements at 298.15° K are -370.9±0.5 kcal/mole for Na2TiO3, -832.1±0.9 kcal/mole for Na2Ti307, and -1,510.9±1.7 kcal/mole for Na2Ti6013. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature both from the elements and from the component oxides for Na2Ti03 and Na2Ti307.

Jan 1, 1973

By M. Kanda, J. W. Adams

A system for measuring amplitude probability distributions (APD’s) of electromagnetic noise in coal mines is described and typical APD’s from an underground coal mine are presented. The APD is a basic statistic required for the design and analysis of communication systems, especially those intended for use in noisy environments, and where neither overdesign nor underdesign is acceptable. The rms and average field strengths are obtained by integration of the APD, and examples are shown at several frequencies. All field strength levels are given in absolute units. Selected frequencies cover the range from 10 kHz to 32 MHz.

Jan 1, 1973

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Le Système International d'Unités (SI) Equivalents of Common United States Units Length 1 ft (foot) = 0.30480 m Mass 1 lbm (pound mass) = 0.45359 kg Force 1 lb (pound) = 4.4482 N Volume Flow Rate 1 cfm = 0.00047195 m3/s Mass Flow Rate 1 lbm/min = 0.00756 kg/s Pressure (wg at 20° C) 1 inch wg (water gage) = 248.36 N/m2 1 inch wg = 248.36 Pa Power 1 hp (horsepower) = 0.74570 kW Energy 1 ft-lb = 1.3558 J Torque 1 lb-inch = 0.11298 N-m

Jan 1, 1977

By H. R. Babitzke

The purpose of this investigation was to develop an alloy of columbium for use at high temperatures and for nuclear applications. The properties of possible alloys were determined, and the more promising ones were selected for further improvement. Criteria for selection were machinability, hardness, workability, tensile strength, and oxidation resistance. Thirteen 100-gram ingots, ranging from 100 percent columbium to 100 percent vanadium, were prepared and subjected to various tests. Also included for comparison were zirconium and the zirconium alloy, zircaloy-2. Test results showed that a columbium alloy, containing 10 atomic percent vanadium merits further development. Besides being workable at room temperature, the columbium-10 atomic percent vanadium alloy has oxidation resistance superior to the other alloys of the series and is also superior to zirconium or zircaloy-2. The latter two materials have comparable neutron-absorption cross sections. The strength and hardness values of the alloys tested were found to increase with increasing vanadium content, reaching a maximum at 50 atomic percent vanadium and decreasing with further increase in vanadium. This behavior is typical of binary alloys wherein each element will retain any proportion of the other in solid solution. INTRODUCTION There is an increasing need for alloys for service at high temperatures. Since current world reserves of columbium metal approximate 1,500,000 tons (1),4 this metal is now readily available. Columbium can ties; be considered a practical base material for high-temperature alloys required in nuclear reactors and in aircraft and space vehicles. General requirements chosen are: (1) Workability, (2) satisfactory mechanical properties at temperatures approaching 1,000° C., and (3) resistance to oxidation at such temperatures.

Jan 1, 1962

By J. J. Drost

The feasibility of basic oxygen furnace (BOF) offgas heat recuperation by preheating scrap was investigated on a pilot plant scale by the Bureau of Mines. In this study, offgases generated during the oxygen blowing of a molten pig iron and scrap charge were passed through a static bed of shredded auto scrap. Scrap quantities varying from 100 to 180 pounds and representing from 22 to 40 percent of the 450-pound BOF metallic charge were preheated in this manner. Average scrap bed temperatures of 1,650° F for 100 pounds of scrap and 1,150° F for 180 pounds of scrap have been achieved during the blows. As compared to cold scrap used in the normal BOF practice, it was found that by preheating scrap, usage could be increased by 43 percent. The thermal energy recovered by this preheating method can account for up to 44 percent of the energy necessary to melt the scrap.

Jan 1, 1974

By Robert C. Johnson

Domestic byproduct fluorine (in fluosilicic acid) availability at various price levels of aluminum fluoride were determined and a contingency availability curve developed. The supply of byproduct fluosilicic acid is restricted in amount to certain geographic regions, where plants processing phosphate rock are located, and the byproduct can be collected. The maximum possible U.S. annual supply, based on potential plant capacities, is 373,400 tons of fluosilicic acid containing 295,400 tons of fluorine. Based on inputs of 5, la, 25, 50, and 100 thousand tons per year, five levels of producing aluminum fluoride from fluosilicic acid (100 percent) were costed. Based on a 12-percent discounted cash flow rate, including the cost of salvaging the fluosilicic acid, the calculated selling price of aluminum fluoride ranged from $233 per ton to $448 per ton. At the higher price, 98 percent of the potential supply of byproduct fluosilicic acid could be used profitably; at the lower price only 46 percent could be used profitably.

Jan 1, 1973

By R. J. Hundhausen

The Shamrock copper-nickel mine in Jackson County, Oreg., was formerly a part of the Chisholm mercury property. In 1948 new owners advanced the old workings 40 feet to reveal encouraging widths of copper-nickel sulfide, ore on the Shamrock claim. When the owner's funds became exhausted, the Bureau of Mines carried on the development in 1949-50, completing 1,650 feet of bulldozing trenching, 396 feet of drifting, and 3,419 feet of diamond drilling. The Bureau's trenching disclosed a separate surface deposit 600 feet south of the mine deposit. This and the previously known deposit subsequently were diamond-drilled. The underground deposit has a known length of 100 feet, a dip length of. 100 feet and a width varying from 1 to 25 feet. The surface deposit is 200 feet long, 200 feet deep, and 5 to 38 feet wide. Neither deposit has been entirely delimited by development to date.

Jan 1, 1952

By Mark I. Copeland

The Bureau of Mines discovered that silicon and nickel additions can prevent the formation of copper alloys of Sn, Sb, and As on the surface of steel during reheating to hot-working temperatures. When molten, these copper alloys cause surface hot shortness during hot working. Wrought steels were reheated isothermally and by simulated industrial practice; the resulting surfaces were metallographically evaluated. The steels contained, In weight-percent, 0.20 C, 0.45 Mn, and up to 1.00 Si, 1.00 Cu, and 0.15 Ni, and up to 0.30 Sn, Sb, or As. The larger the Cu, Sn, Sb and As content of the steels, the greater the amount of silicon necessary to prevent copper alloy formation. A content of 0.10 Ni considerably decreased the amount of silicon necessary for copper steels containing tin and antimony, but not for those containing arsenic. Theories for the beneficial effect of silicon and nickel additions are presented.

Jan 1, 1975

By Lowell Stroud

This report is the third in a series presenting equilibrium vapor-liquid data for helium-bearing natural gases. The first two reports contained phase data for the gases processed for helium at the Bureau of Mines Amarillo and Exell, Tex., helium plants. The present report offers similar information for a lower-helium-content (0.75 mole-percent) natural gas to be processed in the Department of the Interior's long-range helium-conservation program. A windowed-cell apparatus was used to obtain 218 samples of equilibrium vapor and liquid phases at 73 experimental conditions ranging in temperature from -100° F to -275° F and in pressure from 100 to 500 psi. From the phase data, the condensation characteristics, helium solubility, and equilibrium-vaporization-coefficient data for helium, nitrogen, and methane were evaluated. The effect of using a. preliminary hydrocarbon trap upon the subsequent vapor-liquid compositions is reported. A brief comment regarding the composition effect of passing the gas through a gasoline-removal unit is also included.

Jan 1, 1963

By D. Harrington, R. R. Sayers

For several years the writers have been studying various phases of the effect of air conditions in metal mines upon underground workers ; in 1918 a short study was made in certain hot and deep mines and brief reports were issued in the Engineering and Mining Journal ( August , 1920) and in the U. S. Public Health Reports (Vol . 36 , No. 4 , January 28 , 1921 ) . In 1921 a more extended study was made (also in hot and deep metel mines ) with intent to determine the limiting conditions imposed upon underground workers by the physiological effect of various air movements , temperatures , and humidities , with and without work . It is the purpose to publish a series of short papers on this later investigation , each paper to consider one particular phase of the work . The present paper deals with the effect on body temperature and pulse rate in still air as compared with moving air of temperatures from 90 to 100° F . and 100 per cent relative humidity, the subjects at rest .

Apr 1, 1923

By Maria I. De Rosa

High temperatures encountered by mine rescue teams during emergency situations may cause severe physiological strain, hindering the men from carrying out rescue and recovery missions. A prototype ice-cooling garment (ICG) was developed by the Bureau of Mines to alleviate physiological strain due to heat stress. The effectiveness of the garment was tested with acclimatized and unacclimatized subjects at a typical work rate (1,200 Btu/hr) expected during rescue operations and at various hot environments (97° to 113° F dry bulb and 80° to 89° F wet bulb). During exposures with the ice cooling garment, the subjects were able to maintain a safe deep body temperature of 100.4° F or below Without the garment, the deep body temperature rose beyond values of 100.4° F, a condition considered unsafe for continuous work in hot conditions. Both heart rate and skin temperature values were lower while wearing the ICG. Subjective observation also indicated a marked benefit by wearing the ICG.

Jan 1, 1976

By D. R. Tesarik, M. K. Larson, D. K. Denton, J. B. Seymour, R. L. Rains, T. J. Williams

Because backfill has occasionally collapsed into an active working area, posing a hazard to miners, engineers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health and Hecla Mining Co. installed instruments in a cemented, backfilled, stope-ramp intersection at Hecla’s Lucky Friday Mine, Mullan, ID. The purpose was to measure stress and strain changes in the backfill and reinforcing members during undercut mining. The instruments were monitored for 6 months while three successive cuts were mined below the intersection. Readings showed induced loads up to 3450 kPa (500 psi) in the backfill as stope walls converged 2.5 to 12 cm (1 to 5 in). The backfill then deformed against the top and bottom plates of the 2-m- (6-ft-) long vertical rock bolts installed as reinforcement, producing loads to 177 kN (40,000 lb)on the rock bolts. We hypothesize that a compressive zone was created in the backfill that allowed the backfill to remain stable as long as the compressive zones from adjacent rock bolts overlapped. This hypothesis is presented in graphical form. Of particular interest was the effect of loading on trusses installed to augment the vertical rock bolts and wire mesh typically installed in backfill. Data from the instruments indicate that wall closure perpendicular to the vein induced loads in truss legs parallel to the vein and in the rock bolt driven through the center of the truss, but, because they are designed to function under tension, truss legs perpendicular to the vein supplied in significant support as a result of compressional forces from wall closure. Based on this study, use of trusses was discontinued, and an alternative support system of wood beams and posts was installed as needed to ensure the safety of miners working beneath the backfill in stope-ramp intersections.

Jan 7, 2001

By Seth C. Schaefer

The Bureau of Mines has determined the standard Gibbs energies (AGf°) of CoS1.035 (cobalt sulfide) and Ni2.515S2 (nickel sulfide) with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, CoS1.035, CoO, S02(g, 1 atm)//Zr02//02(g, 0.0114 atm), Pt, with the overall cell reaction C0S1.035(c) + 1.535 02(g, 0.0114 atm) = CoO(c) + 1.035 S02(g)¬ These results, combined with the best available data for ?Gf° of CoO and S02 from the literature, give the standard Gibbs energy of formation of CoS1.035 for the reaction Co(c) + 0 5175 S2(g) = CoS1.035(c) ?Gf° = -38.890 + 18.87 x 10-3T ± 0.185 kcal/mole (866.0 - 1,104.9 K), where temperature (T) is expressed in kelvins. Similar measurements were obtained for the cell Pt, N12.515S2, NiO, S02(g, 1 atm)//Zr02//02(g, 0.0122 atm), Pt, with the overall cell reaction Ni2.515S2(c) + 3.2575 02(g, 0.0122 atm) = 2.515 NiO(c) + 2 S02(g). Combination of these results with data for ?Gfo of NiO and S02 from the literature yields the standard Gibbs energy of formation of Ni2.515S2 for the reaction 2.515 Ni(c) + S2(g) = Ni2.S1SS2(c) ?Gf° -65.377 + 24.67 x 10-3T ± 0.541 kcal/mole (968.6 -1,053.7 K).

Jan 1, 1981

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

Ahmed, M.,• "Development of an Integrated Control System for Mine Ventila¬tion and Firedamp Drainage," Mining Engineer, Vol. 127, No. 91, April, 1968, pp. 382-392. Andrews, J. W., "U. S. Mine Ventilation Standards," Paper presented at the International Mine Ventilation Congress, Sept., 1975. Boyle, J. A., and Conn, 0. S., "The Control of Mine Ventilation Utilizing Multiple Main Fans," Paper presented at the Seventy-second Annual CMIA Meeting, Pittsburgh, December 1958. Collinson, P. L., and Vance, W. E., "Mine Ventilation Planning," The Mining Engineer, Volume 121, No. 14, 1961, pp. 141-156. Committee on Industrial Ventilation, Industrial Ventilation, 12th Edition, 1972. Grever, R. E., "Automatic Monitoring of Ventilation Conditions in European Coal Mines," Symposium on Engineering Systems Design for Mine Safety, Michigan Technological University, August 1973. Hall, C. J., Airflow in Mines - Thermodynamic and Motive Column Analyses, The Book Concern, Printers, Inc., Hancock, Mich., 1967, 263 pages. Hargraves, A. J., "Planning and Operation of Gaseous Mines," Canadian Mining and Metallurgical Bulletin, Vol. 66, No. 731, March 1973, pp. 119-128. Harris, E. J., "The Fluid Network Analyzer as an Aid in Solving Mine Ventilation Distribution Problems," SME-AIME Transactions, Vol. 228, 1963, pp. 391-395 Higgins, J., and Shuttleworth, S. E. H., "A Tracer Gas Technique for the Measurement of Airflow in Headings," Colliery Engineering, November 1958, Vol. 35, pp. 483-487. Kaiser, K. M., and Bhowmick, B. C., "Recent Developments in Mine Ventila¬tion Instrumentation," Journal of Mines, Metals & Fuels (INDIA), June 1974, pp. 155-162. Kalasky, J. D., and Krickovic, S., "Ventilation of Pillared Areas by Bleeder Entries, Bleeder Systems, or Equivalent Means," Trans¬actions AIME, Volume 254, December 1973, pp. 284-291. Mahajan, J. K., "Ventilation Planning for a Deep Metal Mine," Min. Geol. Met. Inst. India, Volume 69, 1972, pp. 31-38.

Jan 1, 1977

By H. G. Iverson

Solid state reactions of manganese with silica were investigated in high-temperature tests. Reactions of 0.5 to 4.0 moles manganese (Mn) with 1 mole silica (SiO2) at 1,100° C and of 2.0 Mn:SiO2 mole-ratio mixtures at 1,000° to 1,150° C yielded products consisting of a slag phase and a metallic phase. At 1,100° C, the slag phase from reactions of the low Mn:SiO2 mole-ratio mixtures was composed of SiO2 and rhodonite (MnSiO3), and the slag phase from the high Mn:SiO2 mixtures was composed of MnSiOs and tephroite (Mn2SiO4). The metallic phase from the corresponding low Mn:SiO2 mole-ratio reactants consisted of two manganese silicides, Mn5Si3 and Mn3Si; from the high Mn:SiOg mixtures, it was Mn and the manganese silicide (Mn5Si). For the higher mole ratios of MnSiO2 the manganese content in the metallic phase increased, while the manganese and silica contents of the slag phase remained nearly constant. The slags did not contain free or uncombined manganese oxide (MuO). For the 2.5 to 4.0 Mn:SiO2 mole-ratio mixtures reacted at 1,100° C, the maximum quantities of silica reduced and of the manganese in the slag appeared to become asymptotical at about 41 and 48 percent, respectively. A brominating procedure was developed that was highly selective in removing the metallic constituents from the reaction product, leaving the slag phase as residue. X-ray diffraction patterns were obtained on prepared silicides Mn5Si, Mn3Si, and MnSi.

Jan 1, 1967

By G. L. Oldright, Virgil Miller, F. K. Shelton, Keck. W. E., Horst Sieg

Potash is one of the principal foods and is necessary for the growth of most vegetables, grains, and fruits. For many years, this country depended entirely upon foreign sources for its supply of potassium compounds. However, during the last 15 years the domestic production of potash has gradually increased, as shown in table 1. 7/ Imports now supply only half of the American market. In 1936, the equivalent of 207,000 tons of K20 was imported, and 210,000 tons was produced domestically. In 1935, domestic consumption was approximately 420,000 tons of potash, a 57 percent increase over that for 1934 and surpassing previous peaks of 1928 and 1930.

Jun 1, 1937

By Mary F. Koehler

Interoxidic compounds, such as vanadates, have not been studied extensively in the field of thermodynamics. This is a report of three vanadates of sodium--metavanadate, pyrovanadate, and orthovanadate. Vanadates of other metals will be considered in future reports. The heats of formation at 298.15° K. of the three sodium vanadates (both from the oxides and from the elements) were derived from the results of sodium hydroxide solution calorimetry. Free energies of formation were obtained by combining heat and entropy values. The results support the conclusion that the three sodium vanadates were stable with respect to all possible decompositions in which vanadium retains its pentavalency.

Jan 1, 1960

By Edwin B. Cook

This report presents the results of calculations of the equilibrium composition of the products of combustion with air of six different mixtures of octane CgH18, plus PbEt4 and halogen-bearing scavengers at three air-fuel ratios, at pressures of 5 and 30 atm., and at temperatures of 350°, 1,000°, 1,800°, and 2,000° K. The air-fuel weight ratio has the values 12, 15:12, and 18. The concentration of PbEt4, M, in milliliters per gallon of iso-octane, has the value 1 or 3. The word "case" is used to designate the halogen concentration. Three cases have been considered [ ]

Jan 1, 1953

By David C. Oyler, Hakan Gurgenli, Gregory M. Molinda

Historically, miners have known that roof rocks originally composed largely of mud were prone to slaking and deterioration when exposed to water and humidity. Mine Safety and Health Administration (MSHA) records show that roof falls are more prevalent in summer and late fall. Field data shows higher bolt loads and increased room convergence in summer months. Laboratory data shows that very high internal pressures can be generated by significant strain in clay-rich rocks. In summer months humidities ranging from 70-100% can cause rock strains up to 7%, and rock pressures of 14,000 psi, more than enough to break apart weak shales and fireclays. The National Institute for Occupational Safety and Health (NIOSH) conducted wet/dry immersion cycling of clay-rich rocks. Results show that the rocks most prone to moisture deterioration are fireclays, claystones, and sandy shales, all of which have disrupted bedding. Of the 7 mudrocks with a weatherability index above 40%, none showed consistent fissile bedding. Black shales were surprisingly resistant to wet/dry water immersion cycling. Generally, mixed rocks (stackrock), typically susceptible to horizontal stress, are more resistant to moisture-deterioration. Mine roof rocks tested with moisture sensitivity ratings above 50% (moisture sensitivity index ranges from 0-100 with 100 being the most sensitive) all came from mines which had roof skin problems and used supplemental support to prevent rock fall injuries. Some roof rocks showed lateral variability of moisture sensitivity values, suggesting the need for more samples in highly varying roof rocks. Swelling strains of mudrocks showed that almost all of the swelling occurred in the first 24 hours after immersion. The wet/dry immersion cycling test used provides an accurate, quick and inexpensive method for estimating the moisture sensitivity of mudrocks. With this information mine operators can begin to anticipate hazardous ground and prepare appropriate roof support.