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By F. Concha

A robust theory of sedimentation-consolidation evolved and was accepted by researchers world-wide in the last two decades of the 20th century. This theory provides a reliable method of thickener design and simulation. However, a process model, simple or sophisticated, empirical or phenomenological, is useful only if it is possible to determine, in an objective way, its experimental parameters. Research workers at the University of Concepción, together with Cettem Mineral Technology Center, created an integrated system of thickener design, simulation and control, including instrumentation, algorithm and software, which can be used by personnel in industry without specialized knowledge of thickening theory. In the paper, the development of three instruments for the measurement of pulp concentration, solid flux density and sediment compressibility is described. Each instrument uses software for data input, parameter calculation and results display. The paper also describes software for the optimization of the experimental parameter and for the design and simulation of industrial thickeners. Finally, mathematical algorithm and control strategies based on the phenomenological model are presented and compared with classical feedback control.

Jan 1, 2014

By Anuttam Patra, Romain Bordes, Andreas Fredriksson, Tommy Karlkvist, Krister Holmberg, Kota Hanumantha Rao

The present investigation aims to develop and distinguish mineral specific reagents with two functional groups for use in flotation of calcium containing minerals. For this purpose, a series of dicarboxylate-based surfactants with varying length between the carboxylate groups (one, two or three methylene groups) were synthesized. As reference, a surfactant with the same alkyl chain length but with only one carboxylate group in the polar part was synthesized. The adsorption behavior of these new reagents on pure apatite and calcite mineral surfaces was studied using Hallimond tube flotation, FTIR and ? potential measurements. The relation between the adsorption behavior of a given surfactant on a specific mineral surface and its molecular structure over a range of concentration and pH values, as well as the region of maximum recovery were established. It was found that one of the reagents, with a specific distance between the carboxylate groups, was much more selective for a particular mineral surface than the other homologues synthesized. This selective adsorption of a given surfactant to a particular mineral surface relative to other mineral surfaces as evidenced in flotation studies is substantiated by ? potential and infra-red spectroscopy data.

Jan 1, 2014

By X. G. Liu

Bentonite is an excellent sealant mineral material because of its desirable swelling and self-healing characteristics, low permeability, sorptive qualities, and longevity in nature. A new type of water-swelling building sealant made from bentonite was studied in this paper. The building sealant is prepared by Na-base bentonite, vaseline and paraffin wax under different mass fraction of bentonite (which is 60%,65%,70% respectively). Under unrestricted state, some properties of samples were investigated. The volume expansion ratio at 24 h is 211%, 222%, 256% , and permeability coefficient is 2.86×10-8 cm/s, 4.15×10-8 cm/s and 4.78×10-8 cm/s respectively; low temperature flexibility of the sample (bentonite quality is 65%, 70% respectively) is good, and it does not flow heated for 2 h under 80?. The results of XRD and SEM indicate that bentonite is coated preferably by vaseline, and the spacing of layers of bentonite do not changed. The sample can keep full water swelling ability, and has good molding process. The test results prove that the properties of samples may reach the standard of building sealant.

Jan 1, 2014

By Y. Posedko Eugene, S. S. Gudkov, Yu. E. Emelyanov, A. V. Bogorodsky, A. V. Boldyrev, S. V. Balikov

"The article presents the results of precious metals leaching using halogen solvents and their precipitation on a sorbent in the process of pressure oxidation. A technology of pressure oxidation – carbon-in-leach treatment (POX-CIL) of refractory sulphide gold-bearing flotation concentrates with the addition of a halogen solvent and a sorbent was developed based on the laboratory studies and pilot plant tests. The technology involves the following steps: oxidation of a flotation concentrate; precious metals dissolution and recovery on a sorbent; precious metals elution; electrolysis of eluates; smelting of cathode precipitates with producing Dore beads. This approach ensures oxidation at least 98% of sulphides and gold of more than 95%. The POX-CIL process have the following patents: a patent of the Eurasian Patent Organization No.017438 “A method of processing materials containing precious metals and sulphides” and a patent of the Russian Federation No.2625146 “A method of precious metals recovery from refractory sulphide gold-bearing materials”.INTRODUCTION Gold-bearing ores are classified as readily amenable to cyanidation, or non-refractory, and not readily amenable to cyanidation, or refractory [1]. Special attention should be given to the three most common technological types of gold-bearing ore materials, according to the Irgiredmet’s classification: pyrite-arsenopyrite ores with finely disseminated gold locked in sulphides (physical depression of gold in cyanidation process); cupriferous gold-bearing ores, when cyanidation comes along with chemical depression of gold by mineral compounds (cyanisides); carbonaceous ores showing higher sorption activity to precious metals dissolved in cyanide. Direct cyanidation of refractory sulphide gold-bearing materials does not provide high recovery of precious metals. There are the following methods of refractory gold-bearing ores and concentrates preparation to subsequent gold recovery: roasting, fine grinding, bacterial and pressure oxidation (POX) [2]. Existing POX-cyanidation flowsheets involve high costs due to a large amount of process operations and using expensive and environmentally hazardous sodium cyanide."

Jan 1, 2018

By Q. Huo

The alumina production might not continue when the sulfur content of bauxite was too high. In order to bring down the sulfur content in bauxite, we studied on the bauxite desulfurization by bacteria screened from the acid mine drainage at mines of high sulfur content. The screened bacteria were domesticated by the high sulfur content bauxite. The experiments of bauxite desulfurization were carried out under the conditions of 5% pulp density, temperature of 30?, rotate speed of 120rpm. Bacterial desulfurization for 30 days, the sulfur content of the bauxite was reduced from 5.73% to 1.55% and the desulfurization percent was 72.9%. The recovery percent of alumina was 94.3%. The study showed that it was feasible to bring down the sulfur content of bauxite by bioleaching and this technique might make full use of the low grade bauxite.

Jan 1, 2014

Sedimentary deposits such as sandstone are formed by the aggregation of cemented sand grains. Phosphates and laterite present similar aggregation of mineral grains. Grains and cement have different mineralogy and chemical characteristics. During size reduction through crushing or coarse grinding, the rocks are crumbled. Mineral grains and cement are then liberated, and the produced size distribution reflects their ?natural size distribution?. Mathematical modelling of these concomitant effects of crumbling and mineral liberation necessitates a specific material description and the adaptation of the commonly used theories of breakage kinetics and population balance. The coarse particles are mainly agglomerates made of mineral grains and cement particles whereas the fine particles are grains and cement with a natural grain size distribution. The population balance between the different particle size and particle types during size reduction takes into account the breakage rate and the progeny size distribution. The breakage rate can be described by a simple probability function or by a first order kinetics whereas the progeny size distribution is described by a breakage matrix. The model proposed here considers that the agglomerates will produce other agglomerated particles, liberated grains and cement particles; the two latter having their natural size distribution. The liberated grains and cement particles are subject to size reduction and follow the most commonly used theory of breakage. The present paper describes the theoretical approach of the concomitant crumbling and liberation effects. The application to a mathematical model for the cone crusher is presented. The advantage of such approach is then demonstrated through a simulation study for the optimisation of a crushing plant. Keywords: mineral liberation, modelling, crushing, sedimentary ore

Sep 1, 2012

By P. K. Sen, Mrinal K. Ghose

Tailing slurry is usually abrasive and possesses high viscosity. This paper examines the existing iron ore beneficiation process and focuses on some of the key environmental issues related to the disposal of tailings. It identifies that almost 32% of the iron ore extracted ends up as tailings and they are usually disposed in slurry form in tailing ponds. By the year 2000, 27 Mt of iron ore tailings were generated in India, which has become one of the biggest waste handling problems to the industry. Characteristics of the tailings vary widely. So the physical nature of tailings cannot be considered separately in isolation without considering the mill effluent from the beneficiation plant. In the present investigation, studies were carried out in three iron ore mines in India to evaluate the characteristics of tailings from the beneficiation plant. The tailing samples were collected from different locations during a time period of one year and analyzed. The results will be discussed and the characteristics of the tailings have been evaluated. The disposal system of tailings at the three mines was evaluated. The research on the settling characteristics of tailings indicates that the area provided in the existing tailing ponds in India is much more than that of the experimental results. This paper concludes that sedimentation tests are essential to design appropriate tailings pond with respect to size. In the proposed scheme it is suggested that an additional unit process, i.e. sedimentation tank be added to the process before the disposal of tailings to the tailing pond.

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. The starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions round the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions.

Jan 1, 2003

By V. Runkana, N. K. V. Nadimpalli, S. Sahu

"IsaMill™ has been in operation in the recent past for fine grinding of low grade ores to extract non-ferrous minerals. IsaMill™, typically, consists of a series of uniformly spaced identical disks mounted on a rotating shaft which is encased in an outer shell. The mill offers high energy efficiency for fine grinding and an inherent scalability. But, it encounters certain operational challenges such as non-uniform distribution of grinding media coupled with high wear rate of the disks and solid walls of the mill at specific locations—which adversely affect the mill performance. To circumvent these operational challenges, design modification of the disks through heuristics, by introducing a reduced diameter disk (RDD) at specific locations, is a common practice in industry. But there is no systematic scientific study in this regard. In the current work, we developed a discrete element method (DEM) based model and simulated for the IsaMill™ operation to study the effect of RDD on the efficiency of the mill and wear rate of the solid walls and disks. Since the first set of disks experience the high wear rate due to the high loading of the charge, the RDD was introduced at the first two disks. The simulations were performed at different diameters of the RDDs and at different media loadings. The performance of the mill was analyzed based on the power consumption, the wear rate on disks and the distribution of media particles inside the mill. Besides, the performance variables such as mean velocity of media particles and total impact energy provided useful insights into the milling operation. It was observed that the reduction in disk diameter yields lower wear rate of the disks at the cost of decrease in power draw at a constant high media loading. Whereas, when the media loading was decreased, the amount of wear and power drawn was comparable for both the most reduced and least reduced disk diameters. Therefore, there is an optimum choice of RDD for a given mill loading to maximize the mill performance while reducing the wear rate of the disks."

Jan 1, 2018

By S. Banisi, E. Arghavani, Gh. Parsapour, S. Mousavi

Maximization of water recovery in thickeners is an essential step in the mineral processing industries. The Gol-E-Gohar iorn ore processing plant uses a center pier thickener with a diameter of 38 m and depth of 4 m. The feed rate is 50 t/h solids with a concentration of 5% (w/w), and it has been designed to provide an underflow containing 50% solids. The performance of the thickener was not as expected judged by the overflow stream containing 0.6% solids and water loss of 52 m3/h in the underflow. A criterion called the index of flocculation incorporating the perimeter-based fractal dimension of flocs, floc size, and settling velocities was proposed and used to determine the optimum flocculant dosage which was found to be 20 g/t. The fractal dimension of flocs in a pulp containing 5% solids was found to be between 1.16 (no flocculant) and 1.56 (40 g/t flocculant) which indicated highly branched and loosely bound structures for the flocs as flocculant dosage increased. At these conditions, the size of the flocs which was recorded by a digital microscope increased from 93 µm to 403 µm. A new feedwell with a special design with the aim of preventing flocs breakage and maximizing energy dissipation of pulp was constructed and installed. These modifications led to an increase in the thickener drivehead torque from 5% to 18% of the rated torque, indicating a higher bed depth. Finally, installation of a PID controller reduced the drivehead torque relative oscillation from 52.0% to 12.7%. These changes increased the solids concentration of the underflow from 49.0% to 56.9%, decreased the overflow solids concentration from 0.6 % to values smaller than 0.01% and resulted in a reduction of 27% in water loss in the thickener underflow.

Jan 1, 2014

By Kaioeng Wang, Qi Liu, Yahui Xiang

"In the differential metal sulfide ore flotation it is desirable to replace the toxic inorganic depressants with environmentally benign chemicals. Chitosan, as a natural and non-toxic polymer, has been proven to be an efficient depressant for chalcopyrite while allowing galena to be floated by xanthate collectors. However, the poor solubility of chitosan limits its potential applications as the flotation could only be carried out at about pH 4 where chitosan is soluble. A carboxymethyl derivative of chitosan, named N-carboxymethyl chitosan (N-CMC), was synthesized by substituting the amino groups of chitosan with carboxymethyl groups. The substitution significantly improved the solubility of chitosan. The structure of N-CMC was studied and compared with chitosan via Fourier transform infrared spectroscopy (FTIR). Flotation tests were performed on single minerals and mineral mixtures (with weight ratio of 1:1) with the addition of appropriate amount of potassium ethyl xanthate (KEX) and N-CMC. The solution pH was varied from neutral to alkaline. The flotation concentrates and tailings were collected and analysed for the contents of copper and lead. FTIR measurements showed that new peaks of C=O stretching of -COOH and N-H deformation of -NH- appeared in N-CMC, which indicated that the carboxymethyl groups were introduced and the amino groups were the sites for the substitution. Flotation results indicated that N-CMC could depress either chalcopyrite or galena depending on the pH. The results were not affected by the sequence of KEX and N-CMC addition. Therefore, N-CMC is potentially useful in Cu-Pb sulfide separation following a bulk Cu-Pb flotation. The N-CMC was also found to have surface cleaning functions, and was able to remove contaminating copper ions from galena surfaces. Therefore, its application in sulfide ore flotation is expected to be more robust than the original chitosan."

Jan 1, 2014

By J. Yianatos

The regrinding stage is necessary to achieve the particle size (liberation) for the final upgrade in the cleaning flotation process. At present, vertical mills (Vertimill) are employed at industrial scale, using small steel balls as grinding media. The regrinding process characterization requires mixing regime knowledge along with the mean residence time of the liquid and solid phases. The residence time distribution (RTD) and the actual mean residence time estimations from theoretical relationships are complex due to the presence of three components (solid mineral, balls and water), mass transport characteristics and segregation affecting solid holdup. Therefore, the experimental RTD determination is suitable for industrial mills. In this work, RTD measurements were performed in two different industrial flotation plants. Both plants operate with Vertimills of 1000-1500 HP in the regrinding process with different circuit arrangements according to the plant treatment capacity. The RTD was measured using the radioactive tracer technique. This technique allows for non-invasive tracer detection where the procedure consists of selecting a liquid (Br82 in aqueous solution) or solid (irradiated solid) tracer for RTD data acquisition in real time. The RTD was modelled by the Large and Small Tanks in Series (LSTS) model, which allowed the characterization of the different mixing regimes for both liquid and solids in the regrinding mills. Effective mean residence times in the range 2-11 min were obtained with RTD shapes similar to those obtained in tumbling ball mills. It was found that residence times of liquid and fine particles were similar, which is consistent with results observed in other mixing systems, e.g. mechanical flotation cells. Also, the mean residence times estimated from the RTD allowed the mass balance adjustment to be validated from metallurgical sampling data. RTD estimations are useful for better understanding the Vertimill behaviour and to identify the actual breakage rates. Keywords: vertical mill, residence time distribution, particle size, modeling

Sep 1, 2012

By E. Barsky

Physical principles of two-phase flows with a polyfractional solid phase have not received a sufficient theoretical interpretation as yet. Two-phase flows in the separation mode with a counter-flow of particles are even more complicated. Only statistical methods give an insight into general regularities of such processes. These processes can be interpreted best by analogy with the statistical model of an ideal gas developed by L. Boltzmann, although here a number of difficulties arise. The notion of a statistical system for such flows is substantiated. A mathematical estimation of a statistical system is presented. New notions are introduced, namely, potential extraction of a system and lifting factor. A relationship having the physical meaning of entropy is derived for a two-phase flow in the separation modes. The connection of this new entropy with flow parameters, such as the number of particles, separation factor and chaotizing factor, is established. Properties of this entropy are analyzed, as well as the analogy and difference between this entropy and Boltzmann?s entropy. The notion is formulated and the definition of the chaotizing factor of a process is suggested. In the framework of a statistical approach to two-phase flows in the separation mode, the notion of flow mobility has been formulated. Principal regularities of mass transfer in zone/apparatus sys-tem are analyzed. Principal ideas of a cellular model of the process are formulated, and main relationships for its description are derived. Proceeding from the cellular model, a dependence describing the degree of fractional separation of a narrow size grade is found. The analysis of this dependence makes it possible to reveal the crucial role of the Froude criterion for gravitational separation processes. It is found empirically that this parameter is a basis for the affinization of separation curves (Barsky E, Barsky M, 2006; Barsky, 1980).

Jan 1, 2014

By Juan Pablo Segovia, Alonso Pereira, Fernando Concha, Daniel Sbarbaro, Samuel Vergara

A robust theory of sedimentation-consolidation evolved and was accepted by researchers worldwide in the last two decades of the 20th century. This theory provides a reliable method of thickener design, simulation and control. However, a process model, simple or sophisticated, empirical or phenomenological, is useful only if it is possible to determine, in an objective way, its experimental parameters. Although it is important for a mineral processing plant to perform periodical laboratory test to determine thickening parameters, and in this way adjust the operation, not always these tests represent the behavior of the material in the process. It is important to be able to determine these parameters directly in the thickeners. Research workers at the University of Concepción developed new instrumentation, algorithms and software for the determination of thickening parameters. In this paper, two new instruments for the on-line determination of the settling velocity and the compressibility of the sediment are presented and results of tests in a major mineral processing plant in Chile are described.

Jan 1, 2014

By A. K. Mukherjee

In this apparatus closed sized particles are placed in a container and then fluidized by passing water through the load of particles. Water flow is adjusted to deposit particles in one or more layers depending on the specific gravity of each of the particles, after which the deposited particles are separated in portions of different specific gravity. The obtained portions represent different ore content of the closed sized fraction. The process is repeated for all other size fractions to generate washability curve of the feed. Three different types of iron ores and one coal sample are tested in this equipment. The theoretical yield-grade curve generated for iron ore feed is unique in absence of any such practice for ore minerals. Similar curve is generated for coal and it is compared with washability curve, an existing practice followed worldwide. This comparison validates the performance of the process and the equipment.

Sep 1, 2012

By I. Gombköto

To sustain the growth of industrial production necessitates the increasing of the amount of processed mined raw and secondary materials. As a side effect of raw material production, the amount of tailings material, - coming from mineral processing operations ? increases as well. Using wet technology, these tailing materials are generally transported and stored with the water used for previous operations. This habit could lead to dangerous situations. Enough to remember the disasters had happened to the last decade, safe tailings operations need to remove as much water from the solid as possible. Environmental, technical and economical needs should meet, therefore using a technology combining these specific needs could be necessary. Paste technology was introduced generally into tailings operations at the last ten years, as an answer to the call of the above mentioned challenges, however there are still many questions to answer within the frame of using it. The Institute of Raw Materials Processing and Environmental Process Engineering of the University of Miskolc has been dealing with mechanical process engineering, especially by the support of the EU project TAILSAFE Contract nº EVG1-CT-2002-0066 and the NKFP 3A/068/2004 Hungarian fund extensive research has been carried out about paste technology. Different test methods and materials were applied. Tested tailings materials were as follows: different fly ashes from coal power plants from Pécs ? Hungary, Gyöngyös ? Hungary, Neyvil ? India, different Croatian ashes, hazardous waste incineration plant ashes from Dorog ? Hungary, different kind of sands from Hungary, fine glass sand from Fehérvárcsúrgó ? Hungary, flotation ore processing tailing from Gyöngyösoroszi ? Hungary. Different additives, as gypsum, bentonite and cement were tested as well. The applied test methods were as follows: physical material testing (laser sizer, piknometer, different microscopes), X-ray diffraction analysis, settling columns, the three measuring pipes tube viscometer (16~27 mm pipe diameter), a hydraulic test loop with different pumps (40~53 mm pipe diameter, 0.2~4 m/s average slurry velocity range, 0%~52 % volumetric concentration range), rotational viscometer, Cassagrande yield locus tester and the slump cone test. This paper summarizes and systematizes the results of the aforementioned research as well as reports about the developed paste pipe transport design method based on the fine suspension ? coarse mixture model. The paper also reports about a systematic experimental series with different materials to establish criteria when high concentration suspensions behave like paste.

Jan 1, 2014

By Nilmara Dias, Maria Margarida Martins, Maria Teresa Carvalho

"The heavy residual fraction of the mechanical and biological treatment (MBT) plants treating undifferentiated municipal solid waste is mostly composed by inert materials, such as glass, stones, ceramics and brick. Glass, appearing in significant grade and amount, is not recycled today due to the high content in the other materials, mainly stones. All these materials have approximately the same density but stones have significantly different shape from other materials particles. In this paper it is presented the research developed to eliminate stones appearing in the fine fraction (2.8-8 mm) of the MBT plants heavy residual fraction (MBTr) using a shaking table operated in dry conditions. Two different samples from two different MBT plants were used. Firstly, the samples were characterized (materials content and particle size analysis). Then, laboratory work was carried out to optimize the operation of the shaking table, by changing the machine parameters, deck slope and movement frequency. The study showed that it is possible to upgrade the product in glass. The best results, obtained with one single stage of processing, were 82% content in glass with 84% in recovery, in the glass concentrate, when the coarser fraction (-8+5.6 mm) of one of the MBT plants was used. With the intermediate particle size fraction (-5.6 + 4mm), the glass concentrate attained 74% content in glass with 91% recovery."

Jan 1, 2014

By J. Kolacz

A new optical sorting system based on a complex image analysis and high definition imaging has been developed by Comex. The image analysis is based on high definition cameras of different types and advanced filtration tools for verification of waste particles. Different mineral properties are used to identify the processed material. The system is further combined with a high speed rejection mechanism based on FPGA technology and operating in real time conditions. This provides a minimal error when removing waste particles from the sorted material.

Jan 1, 2014

By S. H. Shahcheraghi

The four operational parameters including collector dosage, frother dosage, conditioning time and pH, are the most important parameters effective on the flotation kinetic. The present study has been done at the Miduk Copper Complex in the province of Kerman. The effect of operational parameters on the flotation kinetic of copper minerals were studied and analyzed, so the optimum conditions for flotation kinetic of copper sulfide minerals were obtained. Under the obtained optimum operational conditions, the recovery of copper sulfide flotation at the 95% confidence level was estimated to be between 92.76% and 95.48% and the copper sulfide flotation kinetic constant was estimated to be between 1.40 and 1.45 min-1. Results showed that the consumption of the X231 collector (O-isopropyl-N-ethylthionocarbamate) and the A65 frother (Polypropylene glycol) could decrease up to 35% and 50% respectively while the copper sulfide recovery increases about 1 up to 2% at the laboratory scale. Keywords: flotation kinetics, sulfide copper, optimization, the Miduk Copper Complex, response surface method

Sep 1, 2012

By Boris Albijanic, Hongjuan Chen, Bogale Tadesse

"During mechanical flotation of fine liberation sized complex rare earth ores, a large fraction of ultrafine valuable mineral particles are lost to tailings. Fine gangue mineral particles can be entrapped within the froth phase and be floated together with target mineral particles. Another common challenge in ultrafine rare earth mineral flotation is the formation of a sticky froth (excessively stable froth). Thus, the improvement of the flotation of fine and ultrafine rare earth bearing minerals through appropriate cell design and reagent selection is highly desirable. The aim of this study is to investigate the performance of a pico-bubble cavitation flotation column in improving selective recovery of ultrafine rare-earth elements (REEs) bearing minerals from complex and low-grade ores. In pico-bubble cavitation column, very small bubbles are generated which are capable of attaching to ultrafine particles and consequently modifying their surface properties. The overall effect of these processes should lead to improved flotation selectivity and recovery of ultrafine RE mineral particles. In this paper, the effects of a number of flotation operating variables on recovery and grade of REE minerals was investigated using a continuous pilot scale pico-bubble column flotation. At the flotation conditions used in this study, subtle monazite upgrade was observed while gangue Fe oxide was preferentially floated even in the presence of depressants. INTRODUCTION Rare earth elements (REEs) have unique properties such as superconductivity and catalytic activity, and are in high demand for a large number of cutting-edge technologies in the modern world including the production of mobile phones, fuel cells, displays, permanent magnets for wind power generation, high-capacity batteries, green energy devices, etc (Naumov, 2008). REEs tend to be intimately associated within many minerals, and are rarely found in high concentrations in deposits for economic extraction. Up to now, among over 250 minerals containing REEs, bastnasite (Ce), monazite (Ce, Th and La) and xenotime (Y) are the three main minerals that contain sufficient grade of REEs for commercial exploitation (Zhang and Edwards, 2012). The deposits that contain bastnäsite, monazite and xenotime usually have complicated mineral compositions, with various valuable minerals of fine embedded grain sizes in association with complex gangue minerals. In order to ensure liberation of the REEs minerals, fine grinding to less than 30 µm is necessary. This fine grinding leads to difficulty in recovering a large proportion of fine and ultrafine particles in separation processes such as flotation (Trahar and Warren, 1976). Consequently, highly liberated and ultrafine fine valuable REEs particles are lost into tailings during traditional mechanical flotation. Besides, the formation of extremely sticky and stable froth inhibits the drainage of hydrophobic particles. Thus, improving flotation of rare earth bearing minerals, particularly the ultrafine size range, is highly desirable."

Jan 1, 2018