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Surface Plasmon Resonance (SPR) spectroscopy, combined with cyclovoltammetry, has been successfully used to study the interactions between ethyl xanthate, heptyl xanthate, dithio-phosphate and propyl trithiocarbonate flotation collectors and a gold surface. Large, easily measurable responses have been obtained in the potential areas where the thiol collectors are known to interact with gold. The four collector types lead to differing SPR maximum values, with longer alkyl chains resulting in higher SPR responses, and the trithiocarbonate leading to the highest response values. The SPR responses differ considerably from the current density response at very anodic and cathodic potentials. There are indications that thiols might still be adsorbed at potentials as low as-300 mV (vs SHE). Keywords: flotation collectors; thiol collectors; cyclovoltammetry; surface plasmon resonance spectroscopy.

Jan 1, 2005

By Glenn Kosick, John Starkey, Glenn Dobby

"A practical new test has been developed for SAG hardness determination. Using two kilogram samples of minus one inch diamond drill core or crushed muck samples, the Starkey SAG Test has been shown to give accurate predictive information which directly relates to on-stream SAG mill performance. Typical results and test criteria are discussed in the paperAchievements to date include:• Identification of hardness profiles and the location of hard and soft zones in a large ore body.• Accurate prediction of the hardness of a bulk sample by using an adjacent diamond drill hole.• Derivation of a plotted curve relating pilot plant power to laboratory relative hardness.• Demonstration that for every test done to date, the Starkey SAG Test produced a product size distribution identical to that produced in a pilot plant or full scale plant SAG operation.This test can now be used for blast hardness monitoring and short term control of mine production in existing plants and for identifying the proper locations for bulk samples in new projects. In addition, new SAG mill design can now be rationalized in a low cost way to eliminate unforeseen production shortfalls.IntroductionThis paper is presented to introduce the Starkey SAG Test, a practical new laboratory tool for measuring the relative hardness of small ore samples in a semi-autogenous grinding (SAG) environment. The test was first designed for use on diamond drill core samples during the prefeasibility stage of new mining projects, to provide new information about the ore body at reasonable cost. It is a new tool and does not replace existing pilot plant test requirements.The test will also be useful for throughput prediction in existing SAG plants by assisting in short and long term mine planning, where forecasting of metal grades and milled tonnage is used to control mine profitability. Because in-plant hardness testing has previously been unavailable on small samples, this test offers exciting possibilities for SAG mill operations where hardness variation is or could be a problem.The Starkey SAG Test provides the following benefits to the mining industry"

Jan 1, 1994

The theme of this conference is æRediscover OtagoÆ and the conference occurs during a resurgence of economic activity in New Zealand, and in particular at a time when the Macraes Gold Project has had a significant effect on mining and business activity in Otago. The Macraes Gold Mine has implemented a Zero Accident Programme and this paper reviews some of the factors responsible for the implementation.

Jan 1, 1992

By John Wilson

"The Rietveld numerical method was used to calculate the relative abundances of phases in both synthetic binary mixtures and synthetic and natural ores, using X-ray diffraction data. The results were compared with those of image analysis and a chemical method. The ranges of the relative errors were estimated. The Rietveld method is found to be acceptable for determining the abundances of major and minor phases and the amorphous component of partially crystalline samples. In complex mixtures, where there are several trace phases (~<2 wt%) present, the technique becomes less accurate. It is most useful as an alternative technique to image analysis when sample preparation is problematic or sample particle sizes are sub-micron. It is a manual method which requires user input during the fitting process, but is both simpler and faster than image analysis due to the reduced set up time and sample preparation required. It is now implemented at CANMET as a technique for quantitative analysis.INTRODUCTIONUntil recently, the Applied Mineralogy group at CANMET used only image analysis and chemical techniques to determine phase quantities. An effort to develop quantitative X-ray diffraction (XRD) has been on-going for several years. Initially, the reference intensity ratio (RIR) method with external standards was tried with some success (Szymanski and Petruk, 1989). The main difficulty with this technique was finding adequate standard material for each phase present in the sample. This shortcoming made the method ultimately impractical, given the wide variety of materials which come to the laboratory for analysis.The Rietveld refinement method of quantitative XRD (Hill et al 1993, Mumme et al 1996), in contrast, requires no standards and requires minimal sample preparation and therefore a more rapid turnaround compared to image analysis. The Rietveld method also has advantages over image analysis in that it can identify and quantify polymorphs, ultra fine materials and many types of hydroxide products. As well, it is useful for analyzing materials such as bauxite or talc, which do not polish well enough for making mounts of the quality required for image analysis. To quantify amorphous material and phases which are present in amounts below the detection limit of XRD, the addition of a standard material is still required. However, in such cases only one standard is needed, which is alumina."

Jan 1, 2003

By G. Bee, Z. Gavelan, R. Espinel, Y. Roditis, X. Ochoa

In August 1996 Barrick Gold Corporation acquired the Pierina property, an advanced stage exploration project, high in the Andean Cordillera of Peru and in November 1998, in a record time of just over two years, poured the first gold. After more than three years of a very successful operation at some of the lowest operating costs in the world, this presentation serves to briefly describe the project through design, construction and start-up and in particular to spotlight some of the challenges that have been overcome in valley heap leaching in a high rainfall, alpine setting.

Jan 1, 2002

By Calvin Konya, Anthony Konya

State and Federal construction specifications require the Blasting Contractor to prepare a Master Blasting Plan which is reviewed by the Owner’s Representative. The Master Blasting Plan requires the Contractor to submit the design of a typical blast. Most blasting specifications also require the Blasting Contractor to submit Daily Blasting Plans. The Master Blasting Plan and the Daily Blasting Plan require that the Blasting Contractor also submit the types and quantities of explosives and initiators used. The specifications also request that the Blasting Contractor submit the pounds of explosive used per delay for both production and presplit blasts. The Blasting Contractor may also be required to predict the anticipated ground vibration and air overpressure levels for the proposed blasts. There are equations that can be used to predict the ground vibration. There are also equations that can be used to predict the air overpressure levels. The data for these equations were primarily derived from quarry and surface coal mine and some construction blasts. Data from major construction projects were analyzed in this study to determine new air overpressure propagation equations for construction blasting. These new prediction equations compare calculated results analyzed from field data with other existing air overpressure prediction equations. Production blasting air overpressure values are also compared to air overpressure from presplitting

Jan 1, 2015

By Sutham Niyomwas

Keywords: Al2O3-SiCW, Ceramic Matrix Composite, Carbothermal Reduction, Kaolin The formations of Al2O3-SiCw composite have been obtained in situ by carbothermal reduction of a mixture of kaolin and activated carbon. The reaction temperature was controlled at between 1400°C to 1600°C. The synthesized products were mixtures of alumina and silicon carbide in the form of whiskers. The effects of milling time of precursors and reaction temperature are presented. XRD and SEM analyses indicate complete reaction of precursors to yield Al2O3-SiC as product powders, with the SiC having porous and whisker morphology.

Jan 1, 2005

Adverse ground behavior events, such as convergence and falls of ground, are some of the most significant challenges and hazards in underground mines. Our goal is to work toward mine-wide, digital, and real-time three-dimensional geotechnical situational awareness and predictive capabilities in complex underground mining operations. This will benefit operators, engineers, and management by enabling them to develop a more proactive approach to ground control. To this end, and inspired by research in the field of remote sensing and autonomous robotics, this paper assesses the potential of mobile light detection and ranging (LiDAR) data acquisition for high-frequency, high-accuracy monitoring tasks in Global Navigation Satellite Systems (GNSS) deprived underground mines. Limitations of current monitoring practices are reviewed. Relevant academic and commercial developments in the fields of indoor mobile mapping systems (MMSs) and simultaneous localization and mapping (SLAM), robust autonomous robotic platforms, and automated remote sensing data processing are highlighted, and their current shortfalls are evaluated. To conclude, the ramifications of this work for the development of future autonomous underground mine monitoring solutions are discussed.

Jul 28, 2020

By D. B. Lovett

The work described in this report was directed toward identifying and devising methods to minimize the previously observed variability between working level hour exposures and the alpha particle track densities resulting on Track Etch films exposed to mine atmospheres containing radon and radon daughters. The disequilibrium between radon and its daughters was shown to directly affect this Track Etch film calibration factor. The wide range of disequilibrium states possible in mine situations amply explains the variability in the previous tests. A file of published mine atmosphere composition data was compiled and was used, along with atmospheric compositions derived from several theoretical models ref the atmospheric behavior, to evaluate the variability of several dosimeter configurations and concepts. A nonlinear, iterative regression analyse; was formulated that successfully predicted working levels to within 8 to 10% from only the alpha particle activities (Rn, RA, and RaC&apos;) data such as are obtainable from Track Etch films over a wide range of disequrlibrium conditions. A model expressing atmospheric concentrations as a function of radon source strength, plate out rate factor, ventilation rate and the fractional re-entry by recoil of previously platted-out daughters was derived and used in the regression program in addition to preparing a set of reference tables and graphs showing the disequilibrium behavior of the atmosphere. Other factors that can affect the Track Etch Film response writ considered and shown to he less crutial than the disequilibrium state. The results of a series of exposures of a dosimeter concept fixture in the Denver Mining Research Center radon chamber air presented and discussed.

Jan 1, 1976

Lignite deposits of Central Otago Miocene Dunstan Formation accumulated on a broad alluvial plain and on deltas that flanked a large freshwater lake. The regional subsurface distribution and configuration of the lignite-bearing strata are identified within the context of depositional systems and placed into a genetically defined stratigraphic framework. The stratigraphic and depositional models constructed, should form an integral part of the geological assessment process to guide future regional or mine based lignite drilling programmes. Further testing and evaluation of the commercialy important lignite deposits in the Blackstone and Roxburgh Coalfields are required to adequately characterise the lignites and their geological setting, particularly to select methods of mining and wise uses of the lignite.

Jan 1, 1992

By Richard H. Singleton

Greensand, which is widely distributed in the Eastern United States, was produced in 1976 only by the Inversand Co., a subsidiary of Hungerford & Terry Inc., near Clayton, N. J. Production and sales information is withheld by the Bureau of Mines. Raw greensand produced by the company was sold for agricultural use as a soil conditioner. Processed greensand was sold for use as a filter medium for the removal of manganese, iron, sulfide, and other elements from water.

Jan 1, 1978

By I. L. Bell

The ironmasters of America had asked the Iron and Steel Institute to visit the USA. The Council decided it was not possible to accept, but Mr. Bell visited; this is an account of his trip. Topics covered include transport, charcoal, coal measures, coal, anthracite, bituminous coal, flux, magnetic iron ore, specular iron ore, limonite, red hematite, clay ironstone, black band ironstone, smelting works, blast furnaces of Pennsylvania, Lake Champlain furnaces, Lake Superior furnaces, Cleveland furnaces, Pittsburg furnaces, Missouri furnaces, and those of the southern states. He goes on to describe Catalan hearths, malleable iron works, Bessemer works, the Blair steel process, and labour.

Jan 12, 1875

By A Rorke, B Cubitt, R Beeslaar

The recent drop in the value of the South African Rand has resulted in an increased export value for South African coal and has lead to new coal reserves becoming available for mining. Very often these reserves are in close proximity to existing structures and utilities thus calling for stringent blast control measures to keep the risk of vibration, air blast and fly rock damage to a minimum.

Jan 1, 1997

By Germán Mallén

Como parte de los estudios línea base realizados por MWH Perú S.A. para el proyecto aurífero Chucapaca de las Canteras del Hallazgo en el distrito de Ichuña de la región Moquegua, Perú, se investigó el origen de boro, alta salinidad y otros componentes que perjudican la aptitud de los ríos Ichuña y Tambo para irrigación y otros usos. En este sentido, se encontró que la calidad de agua es perjudicada principalmente por altas concentraciones de sodio, entre otros, precipitándose como hidróxidos de estos metales debido al pH neutro en el río. En ese sentido, el presente texto describe la relación de este impacto químico con los manantiales entre el Cerro Chucapaca y el cañón del Río Ichuña/ Alto Tambo, ubicados al Norte de Moquegua, donde presentan la característica distribución de diferentes tipos de aguas volcanogénicas sobre un sistema de convección hidrotermal de agua meteórica profunda reciclada, calentada y movida por una cámara magmática andesítica que aporta calor y gases.

Sep 21, 2013

By Gruenewaldt von

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The principles of shear-driven aggregation of particulate matter suspended in fluids, a common industrial method of concentration and separation, were applied to a convecting magma to estimate the time required to sparge or strip the PGE and Cr content and concentrate it into the boundary layers. It was calculated that an ore-grade (e.g. 6 ppm PGE) boundary layer about 1 m thick would require 100 000 years at most to form from a body of magma 500 m deep with a PGE content of 20 ppb. Since concentration would be most vigorous when the magma was warmest, at least half of this concentration would take place in the first 10 000 years. The effect of dispersive pressure in the boundary layer would generate a concentration high of refractories just below the top of each boundary layer and another just above the bottom. If the magma was a double-diffusive system, it might evolve by the downward cascade of enriched boundary-layer material into the hotter, lower magma layers, where depending on saturation levels chromites would equilibrate and sulphides undergo partial or total resorption, enriching PGE levels in any remaining sulphides. This cascade process would in time greatly enrich the lower regions in PGE-bearing sulphides and chromites

Apr 1, 1994

By L. Holappa

Ferroalloy production is an energy-intensive industrial sector with significant CO2 emissions. In this paper the current situation in ferroalloy processes is discussed from the standpoint of global environmental issues, trends and development. Progress and data of ferroalloys production are frequently compared with the steel industry, which is a closely related sector and the main user of ferroalloys. Emission factors of processes and electricity production are examined as well as possibilities and future scenarios of how to diminish CO2 emissions. As a part of this study a questionnaire was submitted to experts in the field of ferroalloys worldwide to survey opinions on the ferroalloy industry today and in the near future (2020). Eighteen questions concerning raw materials, energy, environmental aspects, by-products and economic aspects were responded to by seventeen experts, the answers were analysed and conclusions were drawn. Keywords Ferroalloys, energy, CO2 emissions, electricity, sustainability, questionnaire.

Jan 1, 2010

By M Blanch

Gas management practices across the Australian underground coal industry have evolved significantly since the early nineties with the introduction of hazard management plans, directional drilling techniques, surface gas predrainage methods, and the widespread use of ventilation and gas reservoir simulation software.The improvements are evidenced by a substantial reduction in the occurrence of outbursts and gas related delays during a period where coal production rates have increased three to four fold. The development of effective gas predrainage strategies have been afforded by the use of reservoir simulators and a significant increase in the availability of measured gas reservoir data, in particular gas content and composition, adsorption isotherms and permeability. That said significant opportunities remain to optimise gas drainage designs and increase certainty in the gas predrainage design process through an enhanced understanding of coal seam permeability and how it is applied in the gas drainage design process.This paper describes the discrepancies between measured and actual seam permeability found during the recent assessment of two pilot predrainage programs executed in the coal measures of Queensland’s Bowen Basin. The results of those programs illustrate the need to better understand the validity of measured permeability data. The history match method employed in the pilot well assessments is proposed as an integral step in the routine gas drainage design processes that will ultimately lead to increased certainty and flexibility in gas predrainage practices.CITATION:Blanch, M, 2017. Coal seam gas predrainage optimisation through an enhanced knowledge of coal seam permeability, in Proceedings Australian Mine Vent Conference 2017, pp 73–78 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

At Appin colliery, geological structural analyses and investigations of roof conditions suggest roof failure may be attributed to vectorial stresses acting on underground openings, and inducing movement along inherent discontinuities in the surrounding rocks. Certain complex joint and fracture patterns tend to exhibit the effect of this movement resulting often in local deterioration in natural support.The following conclusions are drawn.1. Roof failure is related to the inherent nature of the roof rocks, the presence of mechanical discontinuities, and the vectorial stresses imposed upon it.2. Roof failure is not necessarily related to the statistically most prominent jointing.3. Colliery development approximately parallel to the direction of the statistically most prominent jointing sometimes results in favourable roof conditions.4. The maximum principal stress is the resultant of those vectorial stresses acting upon a mine opening and may be inferred from roof adjustments to those stresses after mining.5. Statistical analyses of jointing in the mine workings can provide clues to the tectonic force or forces which have been regionally or locally influential.6. There is a probable relationship between mining induced fracturing, jointing, and micro-fractures in quartz grains, within the sediments of the mine roof.

Jan 1, 1970

By Bernard Hertlein

¦ Drilled shafts resist scour seismic loads better than groups of driven piles ¦ Drilled shaft construction creates less noise and vibration than driving piles ¦ Drilled shafts permit direct observation of bearing stratum, and confirmation of location ¦ Drilled shafts are cost effective

Jan 1, 2001

Experimentally determined and theoretically explained phenomenon of zonal disintegration of rock around the development working brings about the radical changes in existing ideas about the mechanism of interaction rock massive with engineering constructions.The essence of the phenomenon consists in the fact, that forming of non-elastic deformations zone goes on by way of more intensive deformation and destruction of rock simultaneously in several zones, covering partially or fully output circuit and divided by zones of destructed rock. Under the influence of change of massive strained-deformational condition of depositional rock an accidental deviation of zones of supplementary expansion and compression of rock from the previous positions take place. One can observe multiplicational change of the outline, size and form of all disintegration zones in the time within the area of the working influence at massive. This phenomenon was named "fluctuation of zonal disintegration of sedimentary rock around development working".

Jan 1, 1991