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By Young-Dae Kim, Dong-Sic Kim, Jong-Jin Pak, Kyung-Hyo Do

"Sulfur is one of the most harmful elements in stainless steel (SIS) products and the specification of sulfur content is getting more severe for high grade SIS. In order to accurately control the desulfurization reaction in high chromium containing SIS melts, it is important to know the thermodynamic interaction between chromium and sulfur in Fe-Cr melts over a wide range of chromium content. In this study, the equilibrium sulfur distribution, Ls, between a Ca0-Alz03 slag and Fe-Cr-C,.,-S melts were measured under CO atmosphere in the temperature range of 1823-1923 K. The specific effect of chromium on the activity coefficient of sulfur in the melts was determined with the consideration of carbon effect on sulfur. A separate experiment was carried to determine. Ls between a slag and FeCr- S melts (Cr: 0-30 mass%) at 1873K to check the validity of the thermodynamic parameter determined in the present study.IntroductionFerritic stainless steels containing chromium (Cr) up to 30 mass% have been developed for a good corrosion resistance and a high formability to replace austenitic SIS. Especially, Sulfur (S) causes a reduction of high-temperature strength and the hydrogen induced cracking (HlC) in stainless steel for line pipes. [l]Many studies on the desulfurization of hot metal and liquid steel have been carried out for several decades and they used HzS-H2 gas equilibrium technique for measuring the effects of many alloying elements on the activity coefficient of S in liquid iron. However, the study on desulfurization of Fe-Cr melts was very scarce.[2] In order to accurately control the desulfurization reaction of high Cr stainless steel, it is essential to know the thermodynamic relation between Cr and S in Fe-Cr melt over a wide range of Cr content and temperature.In the present study, the thermodynamic interaction between Cr and S in liquid iron was determined by measuring the equilibrium distribution ratios of S between Fe-Cr-C,.1-S melts containing a wide range of Cr up to 30 mass% and a 55 mass%Ca0-45 mass%Alz03 slag of which the sulfide capacity was pre-determined using Fe-C,a1-S melts in the temperature range of 1823-1923 K. The validity of thermodynamic parameter determined in the present study was checked by measuring the S distribution between a Ca0-Alz03-Mg0 slag of known sulfide capacity and liquid Fe-Cr-S alloy at 1873 K. Using Wagner's formalism, the results of experiment were thermodynamically considered to determine the effect of a specific concentration of Cr on the activity coefficient of S in liquid iron."

Jan 1, 2014

By Juha Järvi

Outokumpu Zinc Oy has two separate roasting lines with fluidized bed furnaces and waste heat boilers for calcine collection and heat recovery. During the last 30 years, zinc production in Kokkola plant has increased continuously and at the same time the raw materials have changed. Therefore, the waste heat boiler has been under continuous research and development. The waste heat boiler plays a significant role in the process and consequently the reliability and efficiency of the device is important for the effectiveness of the entire process. Many changes have been made to the boiler in the last decades. New radiation tube screens, tube bundles, and baffle-plate constructions have been added to the boiler and also rapping systems for the dust have been developed. The latest improvement to the boilers was a baffle wall, located in the middle of the radiation section roof in the first boiler, and baffle plates in the lower part of the convection section in the second boiler. The new boiler design and optimization were carried out using physical water and air-dust modeling as well as computational fluid dynamics. The modeling work agrees well with experiences in practice. The latest developments have increased the operating hours per year and the effectiveness of the waste heat boiler.

Jan 1, 2002

By Nicholas Zabaras, Deep Samanta

"Solidification of metal aluminum and aluminum alloys is modeled on uneven surfaces characterized by sinusoidal curves. Wavelengths and amplitudes of these sinusoidal surfaces are varied to study their effects on processes like solidification, macro-segregation and inverse segregation. Solidification and macro-segregation are modeled using a slightly modified form of a stabilized finite element method developed recently to model high Rayleigh number solidification and porous media flows. For pure metal solidification, the effect of varying amplitudes and wavelengths is observed in heat transfer, fluid-flow ~nd phase change processes. The relative importance of shrinkage driven flow and solutal convection on the redistribution of solute for an alloy solidifying in a rectangular cavity is compared. The analysis is then extended by modifying one of the surfaces to a sinusoid. In this case the effects of varying amplitudes and wavelengths are studied in heat transfer, fluid flow, phase change, macro-segregation and inverse segregation processes.1 IntroductionTransport phenomenon during solidification of alloys is a major cause ofcasting defects such as segregation, micro-voids, hot tears, porosity, internal and surface cracks. Heat flow across metal and mold surfaces directly affects the phase change process and plays an important role in determining freezing conditions within the metal. In alloys, natural convection and shrinkage play an important role in determining the final solute redistribution, macrosegregation and evolution of solid macromorphology. Surface unevenness plays an important role during the early stages of solidification. It influences the heat transfer rate and fluid flow in the melt, which in turn affect the morphology and shape of the solid-liquid interface. The effect of surface unevenness on solute redistribution is important during solidification of alloys, where solute driven flow in the mushy zone is prominent. Thevik and Mo in [7] and [8] used a one dimensional model for studying surface segregation and macrosegregation in alloys under the influence of exudation and solidification shrinkage. Air-gap formation in their model was expressed through a variable convective heat transfer coefficient at the boundary. Tsai et al. in [3] and [4] have modeled macrosegregation in an aluminum-copper alloy driven by shrinkage and solutal convection. They used a single domain model based on mixture theory and solved the transport equations using finite difference methods. Our aim is to model solidification of aluminum followed by macrosegregation and inverse segregation in aluminum-copper alloys on uneven surfaces by finite element methods. These surfaces are modeled as sinusoids characterized by amplitudes, ?s and wavelengths, As, By varying As and ?s, changes in heat transfer, fluid flow, phase-change and macrosegregation are studied."

Jan 1, 2004

By R. N. Reddy

The Pseudo capacitance of layered type Mn02 electrode material for electrochemical capacitors (EC's) was investigated. MnO2 was synthesized in our laboratory. Mn02 was prepared from heating of KMn04 at 300°C in air. Cyclic Voltammetry (CV) experiments were carried out using three electrode system, Saturated calomel electrode as reference electrode, platinum mesh as a counter electrode, and MnOz composite material mounted in a platinum mesh used as a working electrode. Two kinds of composite working electrode materials were used, one was mixture of MnOz and 25 wt% acetylene black, while the other was MnOz, 25 wt% acetylene black and 25 wt% carbon. All the experiments were carried out at 25OC. A maximum specific capacitance of 130 Fig and 118 Fig were observed at the scan rate of 2 mV/s and 20 mV/s respectively in 1M KC1 for composite electrode made with carbon. Results obtained in this study are compared with that of other electrode materials.

Jan 1, 2002

By David Cocke

Study of surface and subsurface interfacial chemistry of metallic and similar systems has its enormous technological importance. Copper, for example, is a common component of many alloys and bulk amorphous systems. It is being increasingly studied today because of its use for electronic interconnect systems where processing is done below 200 ºC. Since several types of copper oxides exist, and the degree of their formation is dependent on temperature, perhaps characterization by EDS-SEM depth profiling and EIS might delineate one type of oxide from another. In this paper, we described our work on transformation of copper oxides with temperature ranging from 70 to 350 °C and their characterization by SEM, EDS, and XRD. We also showed the use of the phase angle portion of the impedance as a means to identify the predominant structure and the transition through Cu3O2 between the predominant stable CuO and Cu2O.

Jan 1, 2009

By Youn-Bae Kang

Evaporation mechanism of S from liquid Fe–C–S alloys at 1873 K was proposed by analyzing available experimental data. It has been known that increasing C content in liquid alloy increases activity coefficient of S ðfSÞ, and it could raise driving force for the evaporation reaction S = S(g). However, experimental data of the evaporation of S in the Fe–C–S alloys could not be accounted for only by considering the increases of fS. In the present study, formation of carbosulfides, CS(g) and CS2(g), was additionally taken into account in order to explain role of C for the accelerated S evaporation. Surface adsorption of S was also taken into account, which retards the evaporation rate of S. An evaporation model equation was formulated. It can be applied to calculate the evaporation rate of S over wider C content (from zero to its saturation to liquid alloy).

By Takeo Fujino, Nobuaki Sato, Junichi Hasegawa, Masato Nakazawa, Kohta Yamada

"Tantalum oxide thin films were deposited on quartz substrates by laser ablation of Ta2O5 target using Nd:YAG pulse laser. Deposition-was observed when a laser light energy higher than 200 mJ and its repetition rate higher than 3 Hz. A thin film of 0.1 µm thickness was obtained by the ablation using a laser light of 300 mJ and 6 Hz for 2 sec. The thickness of the film increased with increasing energy, repetition rate and irradiation time of laser. By the SEM observation, it was found that many island-like particles were deposited on quartz substrate forming a thin film. The obtained thin film, which was identified as ? Ta-O by X-ray diffraction, was oxidized to Ta2O5 by the heat treatment in air at I273 K for 3 h.IntroductionTransition metal oxides have a potential to show special characteristics in electrical, magnetic and/or optical properties. When such compounds are fabricated in the form of thin film, the special properties would be improved or new characters would appear in comparison with bulk materials. Tantalum penta-oxide is widely used as a capacitor since Ta2O5 shows high dielectric constants up to high temperatures. The tantalum solid capacitor has been fabricated by the electrical oxidation of sintered Ta metal cylinder followed by MnO2 film coating. However, further improvements, reduction and layered structure formation, are required for compacting the devices. The layered structure of thin films would be applicable for the above requirements. The formation ofTa2O5 film by low pressure CVD1), photo CVD2) and magnetron sputtering3l were reported. The laser ablation -method is one of the most convenient techniques for the deposition of thin films from their compounds, such as oxides. Formation of Ta2O5 film by pulse laser deposition (PLD) method using ArF excimer4), Nd:YAG (533nm)5) and TEA CO2 6 lasers was reported. In these PLD studies, ablation was carried out in relatively high oxygen pressures resulting in formation of Ta2O 5 film. In this paper, the deposition of tantalum oxide thin film by the laser ablation of Ta2O 5 using Nd:YAG pulse laser was examined at a viliety oxygen pressures ranging from 10-8 to 10 Torr. The morphology of the films was also investigated in relation with substrate temperature and oxygen pressure."

Jan 1, 2000

By Wenjun Duan, Zongliang Zuo, Qingbo Yu, Qin Qin, Junxiang Liu

Moving bed has been widely used in the field of heat and mass transfer and reaction between solid particles and gas. In order to enhance the heat exchange coefficient, there will be tube banks inserted in the moving bed. In the process of drying ammoniates particles or heat recovery from high-temperature particles with moving bed, the particles flow behavior around the tube banks is significant. In this paper, the particles flow behavior around the tube banks is investigated, and all the results can provide guidance for the design and operation of a moving bed.

Jan 1, 2016

By Huimin Lu, Shi Zhou, Lisha Yang

"The Zeolitic imidazolate frameworks (ZIFs) were successfully synthesized by applying a combination of ionothermal synthesis and microwave energies for rapid synthesis. The synthesis was proceeded under various conditions including different raw materials, reaction temperature as well as microwave irradiation time. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are new type of porous materials formed by inerratic polyhedral in three-dimensional. They are the ideal crystalline substances for gas separation and storage. The assynthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and C02 adsorption test. Results illustrated that the synthesized samples had stable structure, high thermal stability (up to 530 °C) and C02 adsorption capacity (10.2 cm3/g at 0°C under ambient pressure). This novel method also showed great advantage with high energy efficiency, safe synthesis conditions, and rapid crystallization time (60 minutes).IntroductionNowadays, carbon dioxide capture has become imperative due to the global warming caused by the increase of C02 in the atmosphere, especially produced by the concentrated sources such as power plants [1]. Zeolitic imidazolate frameworks (ZIFs), also known as coordination polymers, are ideal crystalline substances for gas separation and storage due to their structure diversity, high thermal and chemical stability [2-5]. They are formed by inerratic polyhedra in threedimensional with large cages and small apertures. Traditionally, ZIFs are synthesized by solvothermal method in a sealed autoclave under autogenous pressure [6-9]. However, in order to generate the products, the solvothermal temperature should not be lower than 100°C according to the sovlothermal mechanism. Moreover, at such a temperature, molecules with a low boiling point (such as water) may generate high pressure in reactor which might cause danger [9]. Thus the synthesis requires the equipment to possess resistance to autogenous pressure and corrosion. Further, conventional solvothermal methods need a long time to prepare products, usually a few days, which is a large energy consumption and inefficiency. So it is interesting to synthesis ZIFs through other ways under mild reaction condition with high energy efficiency."

Jan 1, 2012

By A. González

Arsenic is one of the main contaminants present in Chilean copper concentrates and its abatement represents a challenge for the process metallurgy, particularly under the strong environmental requirements in the global community. The possibility to form ferric arsenate directly from a gas phase by means of a heterogeneous reaction between an arsenic gas bearing and iron oxide was studied at laboratory scale. A thermodynamical analysis for the system Fe-As-O-S has been initially made, in order to obtain the stability conditions for the ferric arsenate or other FexAs2O2 type compounds. Experiments were made using an hematite sample suspended in a thermogravimetric device. AS4O6 gas generated from solid AS203 that was passed through the iron oxide sample and its instantaneous weight change was recorded directly. A kinetic study for the AS4O6 volatilization was made to control the gas composition. A chemical control between 300 and 600°C with an apparent activation energy of around 14 Kcal/mol As2O3 was determined. The samples after the reactions were chemically and XRD analysed. Arsenates detected corresponds to complex compounds. Results shows a dependence on temperature and oxygen content in the gas phase. The kinetics for iron arsenates formation is slow, reaching an arsenic capture of 6% after 80 minutes of reaction when an oxygen content of 50% is fed continuously at 800°C and 3,56% As in the gas. Experiences made at the same temperature but under higher oxygen content in a closed reactor, allowed arsenic capture close to 60%. For higher temperatures the capture is considerably lower.

Jan 1, 2003

By Seyed Mahdi Abbasi, Adel Sheikhhosseini

"This research was conducted to study the changes of microstructure, chemical composition and mechanical properties ofIN718 superalloy after adding aluminum to the ESR process slag. The experiments were performed in VIM and ESR furnaces. The results showed adding 1.5 percent aluminum to the slag increase lave phase in the IN718 samples from 0.34 percent in the base sample to 3.0 percent. It also indicated that the more increase of aluminum in slag cause decrease in the aluminum absorb yield in the superalloy.it is observed that increasing aluminum from 0.7 to 1.1 and then to 1.5 percent caused a decrease of absorb from 91.4 to 76.3 and 74.6 percent respectively due to increasing of aluminum oxidation. According to the results, tensile strength increased and ductility declined in the IN718 samples mainly because of rising the amount of y' volume fraction.IntroductionIN718 superalloy is an iron-nickel base superalloy with constant mechanical properties at medium at high temperatures. For the past seven years a considerable amount of time and effort has been expended by both suppliers and users in the study of Alloy 718 [ 1]. The interest in this material stems not only from the interesting metallurgy associated with the alloy, but with the large usage of the material in numerous applications In fact many people believe that the projected use of this alloy increase significantly over the next several years, The large use of Alloy 718 is the result of its performance in respect to high strength, good ductility, good repair weld ability and from its versatility of being supplied in various product forms. This superalloy is used in wide ranges of industries such as aerospace and gas turbines [2]. In the past more than 20 years many researchers did a lot of work to improve the structure stability of IN718 at high temperatures and intended to develop a new 718 type alloy to be used beyond 650 °C. One of the methods is to control and phase precipitation behavior by means of adjustment of Al, Ti and Nb contents. The other idea is to strengthen the matrix by altering the content of solid solution elements such as W and Co. The adjustment of these alloying elements can change phase precipitation behavior [3]. If detailed information dealing with phase precipitation behavior can be obtained before experimental work for alloy development, a lot of time can be saved and the development cost can also be reduced. In recent years, computer modeling based on experimental data plays an increasing role in alloy design and development. Adding Al to the Iron and Nickel increas the strength of superalloy by formation of y phase and subsequence formation of n phase. Ti in IN718 superalloy also helps the formation of MC carbides and gamma prime phase. Increasing Al/Ti and (Al + Ti)/Nb will lead to form finer particles of y'. More uniform distribution of the precipitates and enhancing stability of y' in IN718 superalloy [ 4]. Adding Al to slag of ESR process can reduce the oxide inclusions because of the strong tendency of Al to oxidation. In addition, tensile properties of IN718 superalloy improve. The most significant inclusions in IN718 superalloy are Alz03 and TiN that were found in agglomerate forms. Thermodynamic calculation results indicate that the effect of increasing Al shows a strong increase in solvus while phase solvus shows mildly decrease when Al level is less than 2%, after that it dramatically decreases [ 5]. Laves phase precipitation and the appearance of phase are occurred when Al content reaches 2%. In fact, when Al content is beyond 1.5%, phase has already precipitated in a considerable scale. Shows the fraction of increases greatly while the fraction of phase decreases remarkably with the increment of Al content. Based on thermodynamic theory, if these particles were not existed in the melt during cooling agglomeration would not accrue and the superalloy will be cleaned By adding Aluminum to the slag, the metal reacts with oxyge"

Jan 1, 2013

By G. Van Weert

Refractory gold ores and auriferous concentrates containing silver tend to form refractory silver jarosites during pressure oxidation. Earlier work with pure Ag2S has shown that the addition of iodine species to the autoclave feed yields cyanide soluble iodargyrite (Agl) instead. Near complete silver extractions from the autoclave product were obtained at a I-/Ag+ ratio of 5 or more. This paper reports on the pressure oxidation and cyanide leaching of two industrial refractory (arseno) pyritic silver-bearing concentrates: 1. from Peru (sulphosalts) and 2. from the USA (pyrite, with acanthite occlusions). While using a I-/Ag+ mol ratio of only 1 in the feed, it has been possible to obtain 98 and 97% Ag extraction from the two autoclave products by cyanide leaching, respectively. This compares to 11 and 54% Ag extraction from the as-received concentrates and 4 and 15% Ag extraction, respectively, after pressure oxidation without KI present. The results of the testwork are discussed in terms of concentrate mineralogy and pressure oxidation conditions.

Jan 1, 1994

By Gennadiy M. Poletayev, Mikhail D. Starostenkov, Alexandra S. Starostenkova

"The process of the combustion synthesis was modeled by computer simulation using the molecular dynamics method. The set of the critical parameters regulating the velocity of the reaction was found from these computer experiments. It was established that the character of structure-energetical transformations at the combustion synthesis in the systems Ni-Al and TiAl depended on the type of boundaries used for the phases delimitation in the bimetal thin films.IntroductionProducing new materials and products, based on the combustion synthesis (CS), is the objective of scientific investigations as one of the most perspective one for industrial applications. But there are several problems connected with theory and experiment. It allows us to forecast the properties of materials. First of all, the main problems are stipulated by structure-energetical transformations taking place at high velocities of the reaction and at high temperatures. It prevents the analyzing of the transformation mechanisms in materials, taking place at microscopic, atomic levels in details.It is evident, that computer simulation allows to decide some problems and to approach to more exact theoretical presentation of structure-energetical reactions taking place at CS. It is known, that the most typical systems, where CS is observed, are bimetals Ni-Al and Ti-Al. The investigation of interphase boundary stability in the systems of Ni-Al and Ni-Fe was made by the method of molecular dynamics in [1]. The bimetal thin film was presented by the packing of atoms in the plane (111) of FCC lattice. It was found that the discrepancy in the sizes of atoms A and B of bimetal was compensated by the formation of 60° top dislocations, set against interphase boundary in the absence of point defects and free volume. The density of top dislocations was proportional to the factor of size discrepancy of atomic components of the bimetal. Diffusional reconstruction of the interphase boundary and areas, situated near it, was observed only at definite concentration of point defects - vacancies, inculcated in the structure of the bimetal at the definite temperature. The atoms of the bimetal component of less size penetrated in the area of the second component with higher velocity. The clusters of intermetallic germs began to form. It led to the growth of the system temperature and acceleration of the process of the diffusional reconstruction of thin film. The following transformations were found: top dislocations splitted into single ones, which climbed from interphase boundary into the zone of more plastic component; the formation of sub grain structures took place."

Jan 1, 2001

By Qinghai Pang

"With the increasing proportion of bituminous coal in blend coal, the safety of blend coal during pulverization and transportation is gradually being paid more and more attention. Therefore, the explosivity of bituminous pulverized coal (PC) with different volatile content from 25 to 38% was studied by measuring the combustion flame length after its injection into a glass pipe with the heat source installed in the center. The results indicated that high volatile content bituminous PC is apt to have higher explosivity. By blending different bituminous PC with 10% anthracite, the explosivity of bituminous PC showed a positive correlation with the proportion –OH radical. However, different bituminous PC seemed to have the same explosivity when the addition of anthracite increased to 20%. With the further increasing proportion of anthracite to 30%, the explosivity of bituminous PC with high –OH proportion became negligible while a weak explosivity of high –CH3 proportion bituminous PC still remained.IntroductionWith the increasing iron ore prices and decreasing steel prices, it has become critical for iron and steel enterprises to control the cost in ironmaking and steelmaking process. Blast furnaces (BF) are the main consumer in ironmaking process, which occupies 70% fuel consumption of total steelmaking process [1]. In this circumstance, any means necessary is taken by BF operators to lower the cost of iron in production. Coke and iron ore are the main expense in this process, who takes up a very high proportion in total cost. Pulverized coal injection (PCI) is the most efficient way to reduce coke ratio, which replace coke with relatively cheaper PC.At present, most of BF is injected with blend coal in the consideration of decent combustion property and quantity of heat. Simultaneously, bituminite and anthracite blending is an effective method to obtain blend coals with required composition and performance, such as volatile and ash content, etc. Nevertheless, a very huge gap was found between the price of bituminous coal and anthracite in some regions of China, in which the price of bituminite can be just 70% of the price of anthracite. Thus, iron enterprises in these regions attempt to possibly amplify the proportion of bituminite in blend coal. Increasing proportion of bituminite results in higher volatile content in blend coal, by which the safety of blend coal during pulverization or transportation was deteriorated.Relatively, coals with higher volatile content usually possess stronger explosivity, which means that volatile and explosivity may related to some extent. However, the relationship between volatile and explosivity is not of certainty for some PC with high volatile content around 40% was found to be inexplosive in comparison to the coals with lower volatile content. With the increasing proportion of bituminous coal in blend coal, investigations on the factors of PC explosivity have become more and more important. Therefore, bituminous coals with different volatile content were selected. The explosivity of blend coal and its relationship between volatile content and functionality was investigated in this research."

Jan 1, 2014

By Kazuya Koyama

We are studying the hydrometallurgical recycling process of indium from an Indium-Tin-Oxide(ITO) target. For this process, it is necessary to remove Sn(IV) ions from the aqueous hydrochloric acid solutions containing In(III). In this study, the removal of Sn(IV) ions by a potentiostatic electrolysis method was examined. The polarization measurements and potentiostatic electrolyses were carried out under a nitrogen atmosphere. In the Sn(IV) solution, current begins to rise at the cathode potential of -0.26 V vs. SHE, and increases with a reduction in the cathode potential. In the In(III) solution, current begins to rise at a cathode potential of -0.43 V vs. SHE. Metallic tin was electrodeposited without indium electrodeposition at the cathode potentials of -0.30 and -0.40V vs. SHE. More than 98% of the Sn(IV) was removed at the cathode potential of -0.40 V after the electrolysis for 3hrs. Both tin and indium were electrodeposited at the cathode potential of -0.50V vs. SHE.

Jan 1, 2006

By A. S. Usrnani

Due to both turbulence and the highly variable geometry of castings, a realistic numerical simulation of the metal flow is prohibitvely expensive with current technology. However, when the chief purpose is to achieve realistic thermal fields a precise How simulation is not necessarily required. In this paper we assume a laminar flow regime and obtain the flow field by solving the incompressible Navier-Stokes Equations using a velocity-pressure segregated semi-implicit finite element method. The free metal surface is predicted by advecting a pseudo-concentration function via the computed How field. This involves an explicit finite element solution of a pure advection equation. The thermal field is calculated by solving the convective-diffusive energy equation by an explicit finite element method using the computed flow field and the location of the free surface. All the advection terms are discretized using a Taylor-Galerkin method. The interface between the metal and mould is modelled using special interface elements. The model is demonstrated by solving practical example problems. The results show that a sharp thermal front is maintained during the course of filling without excessive diffusion. The heat diffusion in the mould can be controlled by varying the metal mould heat transfer coefficient.

Jan 1, 1994

By J. R. Donald

Electric arc furnace (EAF) dust, which can be considered as a by-product of the steel recycling process, contains significant quantities of recoverable zinc and iron, as well as hazardous elements such as cadmium, lead and chromium, which can be leached by ground water. The zinc in the EAF dust is found almost entirely in the form of either zinc oxide or zinc ferrite, the latter accounting for 20 to 50 percent of the total zinc. It is important that an efficient process be developed which renders the dust inert, while reclaiming the valuable metals to off-set processing costs. During the conventional carbothermic reduction processes, iron is formed, and this iron can participate in the reduction of the zinc oxide in zinc ferrite. In the present work, the reduction of the zinc oxide in zinc ferrite by iron according to the following reaction: ZnO-Fe2O3(s,s) + 2 Fe(s) = Zn(g) + 4 FeO(s) was studied in an argon atmosphere using a thennogravimetric technique. First, a thermodynamic analysis was performed using the F*A*C*T computational system. Then, the effects of briquette aspect ratio (lid), temperature, zinc ferrite particle size, amount of iron added, as well as additions such as lime, sodium chloride, and calcium fluoride were investigated. It was found that, initially, the reaction was chemically controlled with an activation energy of 178.1 kJ/mol. Then, after a product layer had formed on the outer surface of the briquette, the reaction was restricted by the diffusion of zinc gas away from the reaction interface. The parabolic rate law was fitted to the experimental data, and the parabolic rate constant was found to be: = -6.2275 + 0.0054 T (K)

Jan 1, 1995

By Simon Lekakh, Von Richards, C. Hank Rawlins, Kent Peaslee

"Batch aqueous leaching and carbonation tests were conducted using industrial steelmaking slags to determine the effect of carbonic anhydrase enzyme as a catalyst. Calcium leaching is a strong function of particle surface area, and the extent can be expressed as a function of time and particle size. Carbonic anhydrase did not affect the calcium-leaching rate, however, it did catalyze calcium carbonate formation to achieve a neutralization time near the theoretical rate. Additionally, carbonic anhydrase modified the precipitate morphology due to accelerated particle nucleation. Time controlled tests in which the pH dropped to ~6 decreased the amount of carbonate produced, and this effect was exaggerated by carbonic anhydrase, while pH controlled tests (>8.5) exhibited the highest rate of carbonation. Because the leaching rate was ~50% faster than the carbonation rate, a further increase in the amount of carbonation may be realized by using carbonic anhydrase however pH must be >10.3.IntroductionSteelmaking slag contains high fractions of alkaline earth oxide based phases (i.e., CaO and MgO) that exothermically form carbonates. Thus, it is being considered as a means of permanent carbon dioxide sequestration. At current U.S. steel production rates, approximately 13-17 million tons/year of slag are generated from basic oxygen furnace (BOF), electric arc furnace (EAF), and ladle metallurgy furnace (LMF) processes [1]. BOF and EAF slag is used as high quality mineral aggregate or cement clinker, while LMF slag, produced at ~15% the rate of BOF and EAF slags, has limited use as blast furnace flux or acid mine neutralization with the majority going to landfill [2]. Based on slag’s chemical nature and immediate availability as a co-product from steel production, the steel industry initiated a project to investigate hydrous carbonate formation in steelmaking slag as a method of sequestering carbon dioxide emitted in steelmaking offgas [3]. The goal of this project is to determine the reactor parameters suitable for the design of an industrial system for treating steelmaking offgas with raw or minimally processed slag."

Jan 1, 2009

By John J. Mahoney, George P. Demopoulos, Matthew T. Bohan

In recent times processing of arsenic-laden complex ores and heightened awareness of the detrimental health effects of arsenic has put an increasing burden on metallurgical operations to remove arsenic from processes for disposal in an environmentally stable form. At present, arsenic is removed and prepared for storage by precipitation of insoluble secondary arsenic-bearing minerals. It has been suggested that Ca(II)-Fe(III)-As(V) phases resembling the natural mineral yukonite, under certain conditions, may have a role in controlling arsenic pore water concentrations in arsenical waste storage facilities. In this study, a previous synthesis method of yukonite (Ca3Fe5(AsO4)4(OH)9⋅4H2O) is revisited and new solubility/stability data is presented based on a modified method.

Jan 1, 2014

By Donald J. Hallbom

Limonitic nickel laterites slurries exhibit complex rheological properties including time dependency that varies from thixotropy to rheopexy. Chronic problems may occur if plant designers and operators fail to take time dependency into account. Stress decay tests indicate that laterite slurry takes roughly two minutes to approach steady state after a step change in the shear rate. As a result, most rheometer measurements are taken at a non-equilibrium state, making evaluation difficult. Two minutes is also long relative to the time that a unit of slurry in a processing plant is at any given shear state, so the slurry may never reach equilibrium. This paper presents a method to describe the rheology of laterite slurry using a Flow Array, which describes the rheology using an array of instantaneous flow curves crossed by an equilibrium flow curve. A rate equation for structural change in non-equilibrium conditions allows time dependence to be efficiently modeled. This flow array allows the flow behavior of time- dependent slurry to be predicted in non-equilibrium conditions using a simple time-step methodology. Keywords: Rheology. nickel laterite, hydraulic transport, pressure acid leach, flow array

Jan 1, 2004