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By E. P. Gush

Diamonds, an enigma in a mineral resource sense. Chemically, diamonds are no more than carbon crystals in a cubic system-formed one might add under conditions of great pressure and temperature. They have certain physical properties which are fairly unique. They are very hard, they have a high refractive index, they luminesce, some of them fluoresce, they have a high specific gravity, they don't wet and they are a good conductor of heat. In a way, a rather clinical set of qualities. Of course, these qualities are what give diamonds their use and their beauty. It is on the emotional side that they get complex and stir memories of legends, of beauty, of wealth and romance, of war, happiness, bad luck and curses. It is on the emotional side that the value of a diamond is established, if such a thing is possible. Diamonds are extremely varied, there are more than 5000 categories into which they are sorted, so there is room at each point across the spectrum for their individualities to emerge, and accordingly their attractiveness to each buyer is unique.

Jan 1, 1994

By H. M. Friede

Notes on the composition of pre- European copper and copper-alloy artefacts from the Transvaal by H. M. Friede. Ph.D. (Visitor) Seven copper artefacts (five ingots and two ornaments) found at prehistoric sites in the Transvaal were submitted to analysis. All the artefacts showed a high copper content and a relatively Iow level of impurities. A little-known ingot type from the Limpopo Valley ('nail' ingot) is described, and its analysis is given. The analysis of two copper ornaments that come from sites dated to the 5th Century AD. and the 11th Century AD. showed the constancy of the composition of copper articles over long periods. The well-known 'Blaauwberg Ingot' was re-analysed, and the results showed that this ingot cannot be regarded as a true bronze. Analytical values for the composition of three brass artefacts from Bambandyanalo (Mapungubwe), Northern Transvaal, are given. Some aspects of pre-European bronze manufacture and brass smelting, and of early metal trade from the East Coast into the interior of South Africa, are discussed.

Jan 2, 1975

By A. Koursaris, J. B. See

The influence of Iscor coke and Delmas coal on the reduction of Mamatwan manganese ore to ferromanganese was examined by use of a variation of the 'stationary charge in controlled environment' (SCICE) technique. The charges of Mamatwan ore and the appropriate reducing agent were heated to temperatures between 1300 and I600 °C and either allowed to cool immediately the required temperature had been reached or held at that particular temperature for periods of up to ... hours. The heating rate was 350°C per hour, the particle size of the ore was between 2,83 and 12,7 mm, and the particle size of the reducing agent was between 2,83 and 6,35 mm. After being allowed to cool in air, the reacted charges were examined by optical microscopy, X-ray-diffraction analysis, scanning electron microscopy, and electron-microprobe analysis. No significant difference was found between the changes observed during the reduction of Mamatwan manganese ore by Iscor coke and by Delmas coal. A hypothesis is advanced to explain the mechanism of formation of the Fe-Mn-C alloy.

Jan 1, 1979

By P. J. D. Lloyd, Jill Urban, M. R. Urban

The adsorption of gold from cyanide solutions onto constituents of the reef, and its role in reducing the efficiency of the gold-recovery process by M. R. URBAN. M.Sc. (Chem. Eng.) Rand (Visitor). JILL URBAN. B.Sc. (Chem. Eng.) Rand (Visitor) and P. J. D. LLOYD. Ph.D. (Cape Town) (Fellow) Evidence for the adsorption or re-precipitation of gold from cyanide solutions onto gangue minerals of the Witwatersrand reefs has been gathered over a number of years by various investigators. The evidence from tests using radioactive tracers is conclusive and indicates thlt adsorption contributes about 0,1 g/t to the total gold loss from conventional reduction works. The loss is a function of the alkalinity and cyanide concentration of the solution, and it appears to be affected by the extent of time between milling and cyanidation. The heavy minerals appear to be the strongest adsorbers, and the clay minerals somewhat less strong adsorbers. A sensitive qualitative test based on thin-layer chromatography permits the extent of adsorption and desorption to be readily determined.

By J. Martinovic

The large proportion of gangue minerals present in platinum bearing ores in South Africa provides challenges to the flotation and down stream processes. In order to take effective measures to reduce their recovery in flotation an understanding of the mechanisms and factors influencing their behaviour is needed. Typical gangue minerals are pyroxene, feldspar, quartz, chromite and talc. Of these, talc is a naturally hydrophobic mineral and although it is present in relatively small quantities, it has a disproportionate effect as it has a strong froth stabilizing effect, increasing the recovery of other gangue minerals by entrainment. Talc recovery is effectively reduced with the addition of polymeric depressants. Although the other gangue minerals are assumed to be hydrophilic and their recovery by entrainment is expected to follow the water recovery, there is some evidence that they may be activated by the typical reagent suites used. Reagents such as copper sulphate, added as an activator, and collectors are used to selectively induce hydrophobicity on the sulphides. It has been shown that some of these gangue minerals can be activated. This research work investigates whether inadvertent copper activation is mineral specific and evaluates the mechanisms and factors affecting the reversal of activation with the addition of the depressants using electrokinetic measurements, adsorption and microflotation tests. Results are presented that show that the selected minerals do respond differently and that the reversal of activation is dependent on mineral type, depressant type, dosage and ionic strength of the electrolyte.

Jan 1, 2004

To determine the characteristics of a mineral deposit, the usual practice is to take samples, analyse the properties of those samples and infer the characteristics of the deposit from these properties. This analysis can be done using statistical methods. In the present work we are concerned with two types of statistical approaches, classical statistics and spatial statistics. If one uses classical statistics to represent the properties of the sample values, the assumption is made that the values are realizations of a random variable. The relative positions of the samples are ignored, and it is assumed that all sample values in the mineral deposit have an equal probability of being selected. The likely presence of trends, zones of enrichment, or pay shoots in the mineralization, is ignored. The fact that two samples taken close to each other are more likely to have similar values than if taken far apart is also not taken into consideration. In contrast, spatial statistics will be used if one chooses to consider that the sample values are realizations of random functions. On this hypothesis, the value of a sample is a function of its position in the mineralization of the deposit, and the relative position of the samples is taken into consideration. The similarity between sample values is quantified as a function of the distance between samples and this relationship represents the foundation of spatial statistics. There are few situations where classical statistics can be used. The assumption that all sample values in the mineral deposit have an equal likelihood of being represented will be satisfied only if the sample values are randomly distributed, or if the sample positions are random. Sample values are in fact never randomly distributed within a mineral deposit. Further- more, geologists usually avoid taking samples at random (random sampling), as it is correctly accepted that samples located on a regular grid, or approximately on a regular grid, give more information than randomly located samples. In practice, classical statistics should be used only in the early stages of exploration, when the number of samples available is relatively small and the distances between samples are large. In these circumstances, and whenever the information available is not sufficient to permit the use of spatial statistics, application of the methods described in this chapter is justified.

Jan 1, 1978

In the investigation described here, it was found that the main effect of temperature is on the rate of flotation, and that adsorption of the reagent is not rate controlling. Above 10°C, the flotation rate of pyrite and gangue increases almost exponentially with a rise in temperature. Below that temperature, the flotation rate of pyrite shows a sudden marked decrease, that of gangue increases, and the sulphur grades are significantly poorer. In the flotation of pyrite, the mass transfer of the pyrite from the pulp to the troth is thought to be the ratecontrolling step, whereas the flotation of gangue is controlled by the combined effect of the stability and velocity of the froth and the viscosity of the elutriating medium. The latter is probably the controlling effect at temperatures below 10°C. Little difference was noted in the recoveries (provided no time limit was set) with changes in temperature; hence adequate recoveries can be obtained at Iow temperatures by the introduction of longer residence times for the pulp. The adverse effects of Iow temperatures on grades can be overcome only by additional cleaning or by heating of the pulp.

Jan 1, 1984

By J. T. Collins, C. J. Cloete

Secunda Collieries forms part of Sasol Coal, the coal division of the Sasol Group of companies, and already produces 29 Mt of coal per annum from its four collieries: Twistdraai, Brandspruit, Bosjesspruit, and Middelbult. The successful establishment of this mining complex was achieved only through a unique team spirit in which the central services and the decentralized teams under the leadership of the mine management of each of the four mines played an important role. The Secunda mining complex has now reached the optimization phase, during which the mining cost, productivity, safety, and quality of work become as important as production. The setting of priorities and problem solving over the long, medium, and short term are essential for improving the performance of the four collieries. Management had to adapt to the fast-changing environment during the enormously fast build-up of production. The major challenges in the environment were posed by the frequent dolerite intrusions, the extremely hard cutting conditions caused by carbonated nodules and thin sandstone intrusions in the coal seam, and excessive roof and face pressure in some areas due to semi-massive sandstone formations in the rock strata.

Jan 1, 1986

By M. Cortie, L. Iorio

The amount of nitrogen contained in an austenitic stainless steel affects its properties significantly. The maximum content of nitrogen feasible in a range of experimental low-nickel austenitic stainless steels containing significant additions of copper is evaluated The nitrogen content is calculated based on published interaction coefficients, and by use of the FACT thermodynamic computer program and database. The differences between the two methods of prediction can be attributed to inaccuracies in the published interaction coefficients. The calculated nitrogen contents of some experimental alloys are compared with the actual nitrogen contents obtained when the alloys were produced in an induction furnace. The actual nitrogen contents obtained were higher than those predicted by either method, and this is believed to be due to a super saturation of nitrogen occurring in the melt, which was not relieved during the short period in which the charge was molten. It was evident that the experimental alloys can contain between 0,25 and 0,40 per cent nitrogen (depending on temperature, composition, and nitrogen pressure) when melted in a sealed induction furnace, and this is more than adequate for the purpose of forming and stabilizing the austenite phase.

Jan 1, 1994

By E. Shavartz, N. B. Strydom

The incorporation of individual cooling in a compressed-oxygen closed-circuit breathing apparatus by E. SHVARTZ, M.Sc. (U.C.L.A.), Ph.D. (U.S.C.) (Visitor) and N. B. STRYDOM, M.Sc., Ph.D. (Illinois) (Fellow) A conventional compressed-oxygen breathing apparatus, which did not include provisions for dehumidification of the inspired air at high environmental temperatures, was tested at these temperatures with and without conductive cooling in the form of 2 kg of pre-frozen ice placed inside the breathing bag of the apparatus. The pre-frozen ice provided conductive cooling of the soda lime and of the chest and abdomen of the subject, who performed moderate work at 50,1 "c. Without cooling, the subject was exhausted after 35 minutes because of a wet-bulb temperature of the inspired air of 46"c. With cooling, the subject finished 2 hours of work. This was possible by keeping the soda lime at a relatively Iow temperature, which resulted in a wet-bulb temperature of the inspired air of only 42 °C after 2 hours, and by conductive cooling of the chest, which resulted in the maintenance of a relatively Iow heart rate and rectal temperature.

Jan 7, 1975

By A. J. Lynch, N. W. Johnson, D. J. McKee, G. C. Thorne

The behaviour of minerals in sulphide flotation processes, with reference to simulation and control. by A. J. LYNCH, Ph.D., N. W. JOHNSON, Ph.D., D. J. McKEE, Ph.D., and G. C. THORNE, B.Sc. (Hons.) (Visitors) In sulphide flotation processes, there are two mechanisms by which particles are transferred from the flotation pulp to the concentrate: adhesion to air bubbles and natural flotation, and entrainment in the froth. The entrainment mechanism is particularly important for particles of non-sulphide gangue, which do not absorb collector. The importance of controlling the recovery rate of water was illustrated in plant testwork in which selectivity between valuable sulphides and sulphide gangue, and between valuable sulphides and non-sulphide gangue, was altered by manipulation of variables affecting the water recovery rate. The two mechanisms should be recognized in the development of a control system. Most of the control schemes in operating plants have concentrated on reagent additions, which affect the natural flotation mechanism. Although control of the chemical environment is clearly of paramount importance in flotation, plant tests have shown that control of the variables affecting the entrainment mechanism is also important.

Jan 4, 1974

By D. Harbottle, D. Rhodes, T. F. Jones, S. R. Biggs

Multiphase process design and optimization often depends upon the rheological properties of sludges and slurries. In practice the task of determining these important properties is usually carried out by removing small samples from a process line or process unit and performing tests with proprietary bench-top analysers near to site or at a remote laboratory. Sampling will remain an important procedure in industrial processes, but there is also a strong case for augmenting the routine information obtained using an in situ sensor, as suggested below. ?Sampling protocols can result in extensive turnaround periods from sample collection to the generation of results. The delay can have an effect on a variety of factors such as product quality, process operability and efficiency. ?Sampling of toxic or radioactive material can prove an even greater challenge to minimize human involvement. ?Removal often changes the rheology of a specimen, and might lead to incorrect conclusions being drawn about the condition of a sludge. ?Sludge and slurry in a containment suffers a gravitational gradient, so that a removed sample should be paired with its location, particularly in the vertical dimension.

Jan 1, 2007

Solvent loading: It is agreed that it is advantageous, as far as reagent cost is concerned, to operate at maximum solvent loading. However, owing to the fact that no reliable automatic solvent flow controller is yet available, control tends to be erratic with the result that there is risk of losing uranium. As can be seen from Mr Tunley's plot, the graph representing total ammonia cost is fairly flat between loadings of 3.5 and 4.0 gpl, while the graph representing uranium loss in the raffinate is steep. It is, therefore, safer to operate slightly below optimum loading in the absence of absolute control. Should the purity of the final product gain importance, operation at optimum loading or even slightly above, may be advantageous. Solvent losses and clarification of pregnant solution: The cost of replacing solvent, as indicated by Mr Carman, represents a high percentage of the overall Purlex costs. It is, therefore, agreed that, amongst other factors, efficient clarification of the pregnant solution and mixer-settler design have an important bearing on the cost. However, as at Blyvooruitzicht, the Buffelsfontein plant can tolerate a suspended solids content of 50 ppm without serious deterioration in efficiency. An increase in the suspended solids content from 15 to 50 ppm normally accounts for an increase of approximately 1 ppm in amine loss. Clarification of acidic pregnant solutions is much more difficult than that of alkaline solutions. Sand clarifiers are being used at Buffelsfontein with moderate success. Clarified solutions containing less than 20 ppm of solids in suspension can be produced, depending on the quantity and type of flocculant used in the filtration process, the thickness and the grading analysis of the sand beds and the quality of supervision. An on-stream duty of approximately 0.15 gallon per sq ft of surface area is obtained. Hydraulic handling of clarifier sand, while cleaning, may effect the efficiency of a clarifier, as size segregation of sand particles may lead to inefficient "pockets" in a sand bed. Control of the solution level in the sand clarifier also affects the quality of the effluent. Exposure of the sand bed invariably causes a cloudy effluent. Recycling of the final and initial solution discharged before and after skimming the clarifier sand improves the clarification efficiency significantly. Post-precipitation of silica and possibly sulphate salts, after clarification, may give a false impression of inefficient clarification. This phenomenon is more pronounced when treating hot supersaturated solutions. Ageing and cooling of the solution before clarification assist in stabilising the solution and reduce precipitation after clarification. The maintenance cost of sand clarifiers at Buffelsfontein is in the order of 0.35 cent per metric ton of solution treated. A redundant ion-exchange column has been tested successfully, either as a primary or a secondary clarifier, depending on the quality of the filtrate treated. The conventional pebble and sand beds in the column have been retained. Operation was enhanced by the addition of a two-foot deep resin bed as a filtering medium. The suspended solids content was reduced to less than 5 ppm. Mixer-settlers: Mixer-settler design is a controversial subject but, in view of the high costs of solvent compared to relatively low pumping costs, it is believed that mixing and pumping functions should be separated. Separate facilities for pumping and mixing not only give greater operational flexibility but also permit eventual changes in the flow circuit as technology develops. Scrub technique: Unlike the pilot plant, where the crud was carried away in the aqueous phase, crud is carried over with the organic phase in the full-scale plant. This carry-over of crud into the strip bank aggravates crud formation in the first strip stage. This phenomenon may result from a slight difference in settler design and/or a variation in the relative phase depths in the two plants. Bypassing of the scrub aqueous solution from the fourth to the second stage was introduced in order to avoid dilution and partial neutralisation of the acid added to the third stage, as it is known that a low pH value enhances the transfer of iron into the aqueous phase. The low aqueous flowrate in the third scrubbing stage was overcome by introducing an aqueous phase recycle. Gleaning: Mr MacDonald's contribution on "gleaning" was most informative. This process for recovering solvent from raffinate seems to show at least as much promise as coalescers and other methods employed to date. Similar tests conducted at Buffelsfontein pilot plant gave 60 per cent amine recovery from raffinate containing 10 ppm amine. However, the circuit was not operated at equilibrium and recovery may be expected to drop as the amine concentration of the "Gleaner" circuit increases.

By W. A. Hustrulid

CONTENTS PART I The theory of percussive rockdrill operation. Blow frequency Piston impact velocity and blow energy Thrust requirements Prediction of penetration rate Drillsteel life Bit wear PART II Measurements of percussive rockdrill performance Thrust-penetration rate measurements Blow frequency Piston impact velocity and blow energy Prediction of penetration rates The effects of hole diameter Thrusts applied by men Bit wear Appendix I Experimental procedure and rockdrill and drill steel specifications Appendix II Piston impact velocities and energies PART III Practical implications. Provisions of adequate thrust Conclusions INTRODUCTION In South African gold mines some 100 million tons of rock are broken each year by drilling and blasting. Only minor improvements to this method of rockbreaking have been made since the general introduction of pneumatic rockdrills for stoping 50 years ago and, more recently, of drillsteels tipped with tungsten carbide. The combined total cost of drilling and blasting amounts to almost R0,50 per ton of rock broken, which is just short of one quarter of the direct cost of stoping or development. Rockdrilling accounts for about R0,25 of the total cost of rockbreaking, of which RO,12 represents labour costs and R0,13 the cost of drillsteels, rockdrill spares and power. Mine air compressors use over 7 X 108 kWh of electric energy a year, amounting to 7 percent of the total electric power used by the gold mining industry. The efficiency of percussive rockdrilling is, therefore, of considerable significance to mining costs. Over the past four years the Mining Research Laboratory of the Chamber of Mines of S.A. has been engaged in experimental studies of percussive drilling. These experiments were conducted at test sites on Robinson Deep Gold Mine and Vlakfontein Gold Mine, made available by Gold Fields of South Africa, Limited. Three rockdrills, designated types A, Band C, of different manufacture, were used in the experiments which involved the measurement of the following operating characteristics: 1. Throttle air pressure 2. Applied thrust 3. Penetration rate 4. Air consumption 5. Blows per minute 6. Drill steel revolutions per minute. The results of these investigations are presented in three parts. Part I, "The theory of percussive rockdrill operation" which provides a concise, mathematical description of the performance of a percussive rockdrill in terms of its principal mechanical dimensions and operating conditions, and an analysis of the bit and gauge wear of drillsteels. Part II, "Measurements of percussive rockdrill performance" in which the experimental results are presented in terms of thrust-penetration rate curves at different throttle air pressures and throttle pressure-air consumption curves, which are shown to agree well with the predictions of theory. In addition, data relating gauge wear on the drillsteel and penetration rate to the distance drilled are discussed. Part III, "Practical implications" in which an analysis of the status of thrusting devices is made and the benefits that would derive from using uptimum thrusts are discussed.

By B. Strohmeier

An account is given of the use of a computer to control the performance of three ultra-high-powered electric-arc furnaces in Iscor 5 steelmaking plant at Vanderbijlpark, South Africa. Several of the reports and graphs printed by the computer are reproduced.

Jan 1, 1985

By D. H. C. Griffiths, D. R. Davis, D. B. Paterson

Consolidated Murchison Limited is the only primary producer of antimony in South Africa, producing approximately 18 per cent of the total world production. This paper gives a technical review of the history, occurrence, mining, and metallurgy of antimony at Consolidated Murchison. World antimony markets are also discussed, together with the end-uses.

Jan 1, 1986

An investigation into the stability of large open stopes at Premier diamond mine, Culinan, South Africa, is described. The open stopes are located in a weak kimberlite orebody, directly underneath a 75 m-thick sill of gabbro. Two and three-dimensional stress analyses were carried out in a back-analysis of the stresses and failure around the first open stope created under the sill. The results were used in the prediction of the future stability of the planned open stopes, intervening pillars, and sill.

Jan 1, 1987

The increasing transportation of solids by pipeline, in South Africa and internationally, replacing the conventional transportation methods of rail, road, and conveyors, has resulted in much research into this area of solids transportation. Pipeline wear continues to be an area of specific concern, since it constitutes a major cost during the life of a pipeline installation. Wear data from an accelerated wear test and actual pipeline tests are presented. Trends in the performance of the pipeline materials tested are discussed, and possible solutions to the problem of pipeline wear are presented.

Jan 1, 1992

By J. H. Bulloch

A short review is given of the effects of corrosion fatigue on the materials used in pressurized water-reactor vessels. Selected topics such as testing procedures, test data, and mechanisms in simulated environments are discussed. The main fact that emerges is that most of the data on the growth of fatigue cracks reside below the ASME X1 1980 High-R 'Wet' design-code lines, Le. they fall within that specification. Finally, some recent advances in the understanding of the corrosion-fatigue behaviour of such materials in pressurized water reactors are highlighted.

Jan 1, 1987

By D. E. Scheck

A computer-aided blast design consultant system has been developed. The software consists of two modules: one uses theoretical and empirical formulae and procedures to design a blast based on user supplied geological and mechanical data, while the other is an expert system that analyzes blast vibration problems and recommends remedial action using knowledge based rules. The system is currently undergoing field evaluation.

Jan 1, 1987