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By F. M. Carlson

Comparisons are made between the results of the Buckley-Leverett and Kern solutions, which describe immiscible displacement of oil by gas in a linear system and the results obtained from a less restrictive numerical model. This model takes into account the effect of compressibility of the oil and gas and the effect of allowing changes in the amount of gas in solution in the oil. These effects are best exemplified by imposing large pressure drops across the system. With these large pressure drops, comparison of the model solution with the Buckley-Leverett solution reveals that the Buckley-Leverett solution provides estimates of recoveries at breakthrough of the gas that are too low. In contrast to the model, the Kern solution predicts breakthrough recoveries that are too high. A modification to the Kern solution is presented to facilitate more accurate predictions of recovery at gas breakthrough for gas injection at pressures higher than the saturation pressure of the oil.

Jan 1, 1974

By E. E. Remmenga

Often a collection of analytical data, which should reasonably be expected to follow the normal distribution, contains too many extreme values, which the experimenter is inclined to eliminate according to some arbitrary procedure. The stepwise computer procedure described for this purpose is similar to many other truncation procedures; however, because truncation of a basically normal distribution causes a downward bias in the estimated variance, this procedure provides a graphical method to compensate for the bias.

Jan 1, 1971

By C. H. Elder, M. C. Irani

Two degasification test boreholes were drilled to depths of 1,238 and 1,212 feet on Bureau of Mines property at Bruceton, Pa., as part of the Bureau's long-range coal degasification program. The holes provided detailed geologic information and geologic sections, which were correlated with regional stratigraphic cross sections prepared by the Pennsylvania Geological Survey. Gas content determinations and coal analyses were made on the Upper Freeport, Middle Kittanning, Clarion, Brookville, and Mercer coalbeds; gas content of the coalbeds ranged from 53 to 165 cubic feet per ton. Formation pressure and gas flow tests were conducted on selected coalbed intervals in borehole 1; formation pressures ranged from 292 to 473 psig. The middle Kittanning coalbed was hydraulically stimulated using very heavy gelled water, but gas production remained low because gel residue and formation water inhibited the flow of gas. Gas contents in the Clarion, Upper Brookville, and Mercer coalbeds were anomalously low owing to the proximity of porous sand- stones which act as reservoirs for gas migrating from coalbeds.

Jan 1, 1977

By Robert L. Chufo, H. Kenneth Sacks

Medium-frequency (MF) waves can propagate in a coal seam, bounded above and below by conducting rock, in an approximate transverse electro-magnetic (TEM) transmission-line mode with the electric field vertical and the magnetic field horizontal. The theory of this coal seam mode is applied to recent MF data for a number of mines in order to classify the propagation characteristic of the mines in a simple way. When conductors such as rails, trolleylines, or power cables are present in the vicinity of the measurement path, it is found that the magnetic field versus range plots have two distinct regions with very different slopes. This effect is attributed to coupling of the cylindrically spreading coal seam mode to a low-attenuation conductor guided mode. As a result, voice communications range between mobile transmitters can extend several thousand meters. The use of MF for mine communications is discussed.

Control dust generated during undercutting in salt mines without causing ore-solubility problems that result from excessive water use. Approach A foam generator was developed to provide a reliable foam to control dust on cutting machines used in mining water-soluble ores. The system was designed to keep total foaming agent/water mixture flowrates below the flow-rates characteristic of water-only systems. The foam generator consists of a reservoir to hold the premixed agent and water, a metering pump, and a small compressor to aerate the mixture. The system is compatible with all cutting machines. How It Works One of the current wet-bar techniques, the through-the-bar trickle system, pumps water through a pipe in the cut-ting bar to its tip placing the water behind the kerf. If the pipe conducted foam effectively the foam would be released in the kerf where it would mix with the cuttings and the dust produced by the chain. For improved foam delivery, however, it is recommended that the pipe be replaced with an external channel welded along the top of the bar. This provides excellent dust control while avoiding the accumulation of copious quantities of foam in the heading. The system is very simple. The foam generator is a 50-gallon tank filled with a mixture of water and foaming agent. The mixture is pumped through a wye fitting to a second line where it is mixed with compressed air, (300

Jan 1, 1984

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By J. A. Eisele

As part of its goal of maintaining an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines has studied the removal of iron from simulated aluminum nitrate leach liquors by solvent extraction. Iron must be removed from aluminum nitrate liquor produced by leaching calcined kaolinitic clay with HN03 to reduce the iron level in alumina to less than 0.02 wt-pct Fe203 for use in reduction cells. The parameters reported are for (1) extracting iron from a feed containing 1.5 g/l Fe with di(2-ethylhexyl) phosphoric acid (EHPA), (2) stripping loaded organic phase with 20-pct HCI, and (3) water washing of loaded and stripped organic phase. Recommended operating conditions are two extraction stages using 15 vol-pct EHPA in kerosene and three stripping stages using 20-pct HCI. Results are also given for tests using other extractants and stripping agents.

Jan 1, 1982

By Ann G. Kim

Samples of gas were obtained directly from the coalbed during drilling of horizontal and vertical boreholes in six different formations. The samples were analyzed by gas chromatography for C1 to C5 hydrocarbons and for 02, H2, H2, He, and C02. Methane in the gas varied from 63 to 99 percent; carbon dioxide from 0.1 to 15 percent. The CH4 /CO2 ratio varied and showed no apparent correlation with age, rank, or bed. The majority of samples contained ethane, propane, and butane; hydrogen and helium were found in some samples. Oxygen and nitrogen were usually present, possibly as a result of air contamination. A more extensive sampling program would be necessary to establish relationship between the amount and composition of the gas in the coalbed and other factors.

Jan 1, 1973

By Yael Miron

ANFO blasting agents may undergo an exothermic reaction when they contact warm ore bodies that contain pyrite and its weathering products. The reaction is very fast at temperatures above 80° C. Urea, when present in sufficient amounts, inhibits this reaction at temperatures below 180° C. But urea-ammonium nitrate mixtures are very hygroscopic and, in certain climates, may be difficult to handle in the field. Reaction-inhibiting characteristics of three compounds were reported by the Bureau of Mines in 1979. Recently, the Bureau investigated the reaction-inhibiting qualities of five additional compounds. Mixtures of ANFO, pyrite, weathering product, and prospective inhibitors were slowly heated, under conditions simulating a hot borehole, to determine prospective inhibitor capability at temperatures up to ~175° C. Small-scale thermal tests of the same mixtures were used for verification and clarification of results. Two organic compounds, phthalimide and xanthine, similar in structure to urea, failed to inhibit the reaction. Zinc oxide and calcium carbonate were found inferior to urea, though zinc oxide raised the onset of reaction from 80° C to about 140° C. Only magnesium oxide was found to be similar to urea in its inhibitory ability at temperatures below 175° C. Based on results from analysis of quenched residues, the use of more than 5 wt-pct magnesium oxide is recommended.

Jan 1, 1982

By Vijia K. Karra

The goal of aggregates producing companies across the United States is to ensure their workers go home safely each day. At the National Institute for Occupational Safety and Health (NIOSH), researchers are pursuing this vision of safety and health through a fact-finding approach for reducing injury illness in various mineral sectors. Surveillance data from Mine Safety and Health Administration (MSHA) has been the source for such analyses. It helps to focus research efforts on key machinery, workers, and their tasks. The second installment of this two-part series follows last month's focus on crushed stone.

By Seth C. Schaefer

The Bureau of Mines studied thermodynamic properties of Al-Ni alloys con¬taining 0.54 to 30.04 atomic percent nickel with the aid of the high-temperature galvanic cell Al(1) // Al+3 (AlCl3 in NaCI.KC1) // Al-Ni alloy (1 or s). Activities of aluminum and nickel (compared with pure liquid metals as the standard state) show pronounced negative deviation from Raoult's law at 1,273 K. The properties [?G, ?Gxs, ?G ideal, ?GA1, AGxs1, ?Gni , and ?GNixs] have been derived from the experimental data and are summarized in tables and illustrations. At 1,127 K, the thermodynamic stability for the invariant three-phase equilibrium consisting of a saturated liquid, A13Ni, and A13Ni2 has been uniquely defined by an activity for aluminum of 0.751. A free energy of formation at 1,127 K of -7,940 cal/g-atom was derived for the compound A13Ni.

Jan 1, 1975

Reduce the number of conveyor-related accidents in the mining industry by providing recommendations for effective operation of conveyor belt cleaning systems. The Problem Troughed belt conveyors provide effective, and efficient materials transport and their use has increased throughout the mining industry. Carryback, the spillage that accumulates under the belt, is a problem even with belt cleaning systems installed. Mining personnel are exposed to safety and health hazard; as they attempt to clean up this spillage. Approach To investigate the influence of metal-segmented-blade belt cleaners on the amount of carryback spillage, the. Bureau identified and tested the following parameters: (1) amount of pressure applied to the cleaner blades, (2) friction between the blades and conveyor belt, and (3) wear rates of different metal blades. The test parameters were quantified by recording the amount of carryback material passing the metal cleaner blade, and the weight loss of the blades. The data collected were used to identify the following critic d operational parameters of a segmented-blade conveyor cleaner system: (1) the existence of an optimal operating pressure for the conveyor and cleaning systems and (2) elimination of recessed patterns on the working side of the conveyor belt.

Jan 1, 1989

By W. Blake, J. K. Whyatt, T. J. Williams

Researchers at the U.S. Bureau of Mines collected and analyzed over core measurements and other indicators of in situ stress characteristics at the Lucky Friday Mine, Mullan, ID. An analysis of these data revealed that significant local variations in in situ stress are present in this mine and that these variations existed prior to mining. High stresses were found to be associated with the most competent strata and a locked section of a fault. An estimate of the predominant stress field was developed for mine-wide modeling. The estimate shows that the greatest principal stress was oriented north of northwest. This information should provide a basis for mine-wide structural modeling of the Lucky Friday Mine and should generate important insights into localized stress conditions, which may significantly affect both local and mine-to-mine variations in seismicity induced by excavation.

Jan 1, 1995

By W. F. Marshall

The effect of engine parameters on exhaust emissions from two diesel engines was studied experimentally. Fuel-injection characteristics and intake air conditions were considered as parameters influencing the emissions. Emphasis was placed on the effect of parameter variations on nitrogen oxide (NOx) emissions, because diesels generally emit very low levels of carbon monoxide (CO) and unburned hydrocarbons. Emissions other than NOx were at lowest levels when the engines were adjusted for best performance. NOx emissions can be diminished somewhat through variation in fuel-injection characteristics, but there generally are penalties in emissions of CO, smoke, and unburned hydrocarbons or in engine performance. Temperature and composition of intake air have a significant effect on NOx emissions. Levels of NOx are reduced by recirculating the exhaust gas or by adding water to the intake air stream. However, the rate of water added or exhaust gas recirculated must be limited to prevent the degradation of engine performance and increased emissions of CO and smoke. At high exhaust recirculation rates, levels of CO and smoke were increased such that it was necessary to derate the engine and also to use a catalytic system for oxidation of CO.

Jan 1, 1971

By Laurance L. Oden

The Bureau of Mines studied three processes for preparing NaAl(OH)2C03) the intermediate compound which is calcined to produce alkalized alumina: (1) Mixing of Na2 C03 and of A12 (S04)3 solutions, (2) digestion of aluminum hydroxide in solutions of Na2C03 and NaHC03 at 90° C, and (3) addition of CO2 at 25° C to caustic solutions of aluminum to precipitate aluminum hydroxide followed by digestion at 90° C. The first process had the highest raw material consumption and washing requirements, and successful application of process 2 depended upon the availability of active aluminum hydroxide. Process 3 was the most effective, considering both process technology and raw material requirements. Procedures were also investigated for washing, filtering, drying, and calcining precipitates. Analytical methods included X-ray diffraction, atomic absorption spectroscopy, differential thermal analysis, and thermogravimetric analysis.

Jan 1, 1969

By Joseph C. Zelanko, Anthony T. Iannacchione

One of the most difficult and longstanding engineering problems associated with coal mining is the catastrophic failure phenomenon known as coal mine bursts (known in the United States as bumps). For more than 70 years, researchers and practitioners have attempted to determine whether this destruction observed underground is caused by stress conditions within the coal pillar or from distant seismic sources in the mine roof and floor strata. The role of confinement and the extent of failure in solid pillars and panels have also proven difficult to define. These are important issues, since control solutions need to be based on a fundamental understanding of the problem. Obsenations by U.S. Bureau of Mines researchers over the last decade have helped to clarify certain aspects of these issues. Microseismic sensors and geomechanic field measurements have located areas of excess energy release, identified stress conditions in coalbeds close to failure, and recorded the response of mine structures prone to bursts. In the present study, data available for a range of U.S. bursts were considered in an effort to evaluate both common and distinctive features. Although the attempt revealed little commonality, encouraging results were produced by categorizing coal bursts by source mechanisms. When a coal burst is thus categorized, differences in environmental factors-such as geology, stress fields, and mining methods-are highlighted, and viable control strategies are readily recognized.

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX A - PNEUMATIC TRANSPORT OF FLY ASH 1. Introduction Two types of pneumatic transport of fly ash are critical to the success of (1) Transport of fly ash from the fly ash truck to the entrance to the borehole. Depending on the surface topography, this may be horizontal, decential and ascential. (2) Vertical downflow of fly ash through the borehole. All fly ash trucks have limited pressure with which they can pump the fly ash. Thus, the pressure drop in the fly ash hose will define the maximum length for pumping and consequently the maximum distance that the fly ash truck can be parked from the auxiliary blower. The same relationships describe the flow of the dilute fly ash-air mixture produced by mixing with the auxiliary air from the blower and thus define the selection of the pipe diameter. These are im¬portant considerations in the proper selection of the location of the passages to be sealed and the type of surface preparation required. The flow characteristics of fly ash down the borehole determine the selection of the minimum borehole diameter and the blower pressure. This appendix presents theoretical analyses of these flow regimes and summarizes the limited experimental data obtained during the field tests at Grant Town, described in Section 8.4. The analysis for the borehole flow is presented first as it is of greater interest to the program. This is followed by a discussion of the horizontal flow.

Jan 1, 1973

By Jon K. Ahlness

The Bureau of Mines, in cooperation with the Institute of Mineral Research of Michigan Technological University, and the Upper Great Lakes Regional Commission, conducted an investigation of electronic sorting of native copper ore from Upper Michigan. This report is based on research by the Institute of Mineral Research under contract to the Bureau. The test program evaluated the use of belt and rotary sorters on various size and grade fractions of ore. Both plant-scale sorting and lab sorting tests were run. The plant sorting objectives were to determine the sortability of different ores and the efficiency of the electronic ore sorters. High-and low-grade ores from both conglomerate and amygdaloid types were separated into four size fractions. The two larger sizes were sorted on belt sorters and the two smaller ones on rotary sorters. Copper recoveries ranged from 20.0 pct from a feed grade of 0.40 pct to 80.3 pct from a feed grade of 1.08 pct. Lab sorting tests of conglomerate ore were run to determine the efficiency of a belt sorter equipped with a second sensing coil located above the belt and to determine the sorting characteristics of larger ore size fractions than those used in the plant sorting. Copper recoveries from the combined feed sizes ranged from 47.0 pct from a feed grade of 0.13 pct to 96.8 pct from a feed grade of 4.87 pct. For all the ore types except one, it was found that the copper recovery increased with the feed size.

Jan 1, 1980

By Ruth A. Holmes

A Bureau of Mines method for recovering nickel, cobalt, and copper from low-grade domestic laterites is described, which includes the unit operations of solvent extraction and electrowinning. Previous Bureau work indicated that addition of Na2S04 (sodium sulfate) to the nickel electrolyte improved current efficiency in nickel electrowinning. The present study determines the compatibility of Na2S04 with nickel strip-ping in the solvent extraction operation of the Bureau method. The effect of adding 100 g/l Na2S04 on nickel stripping, phase disengagement, and pH was determined in comparative laboratory-scale tests. In continuous-circuit testing, Na2S04 reduced stripping efficiency to the extent that five, instead of four, strip stages were required for complete stripping of nickel from the loaded solvent. In tests made in a phase-disengagement cell that had a variable settler area, the addition of Na2S04 did not significantly affect phase separation characteristics. The pH of the nickel electrolyte in the temperature range of 20° to 65° C was also unaffected by the addition of Na2S04. An economic evaluation showed that the energy saved by adding Na2S04 to the electrolyte would more than offset the cost of adding another stripping stage.

Jan 1, 1983

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of selected ingredients employed in the formulation and manufacture of conveyor belts. This work was done to supplement similar studies of samples from finished conveyor belts and thus provide basic data for correlation of the potential toxic behavior of a finished belt with that of the individual ingredients. This report covers the study of (1) basic polymers (styrene-butadiene, neoprene), (2) reinforcing fibers (Nylon 6,6, Dacron, viscose rayon), (3) flame-retardant plasticizers (tritolyl phosphate-isomeric mixture, tri-p-tolyl phosphate, tributyl phosphate, tris (dichloropropyl) phosphate), (4) plasticizers (diphenylphtha1ate, di-(2-ethylhexyl) sebacate), and (5) a vulcanization accelerator (2-mercaptobenzothiazole).

Jan 1, 1977