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By Martin A. Elliott

"INTRODUCTION During the recent war the Bureau of Mines was requested to obtain in¬formation on the temperature at which ammonium nitrate mixed with certa: contaminants would react rapidly. This information was desired in connection with an investigation of an explosion that had occurred during the evaporation, by air agitation, of volutions containing ammonium nitrate in which compressor oil that might have passed the filters was suspected of being a contaminant.During the course of this work it was found that mixtures of ammonium nitrate and zinc reacted rapidly at comparatively low temperatures: and since zinc could not positively be eliminated as a contaminant in the explosion in question, a series of tests was carried out, not only with mixtures of ammonium nitrate and compressor oil but also ammonium nitrate and zinc with and without oil. A few experiments were made with metals other than zinc.The investigation was not as extensive as might have been desired, owing to limitations -in time. The results are presented at this time in view of their current interest in connection with the Texas City disaster, in which a large quantity of ammonium nitrate detonated in the holds of two ships."

Mar 1, 1948

By Alla D. Mah

The energies of combustion of zirconium carbide and hafnium carbide were measured by combustion calorimetry and the heats of combustion and formation. of zirconium carbide and hafnium carbide were derived . The results are-- ZrC AH298.15 ( combustion) = -308.60 ± 0.55 kcal /mole , AH298.15 ( formation) -47.0 ± 0.6 kcal /mole , AH298.15 = HfC (combustion ) = -306.08 ± 0.20 kcal/mole , AH298.15 ( formation) -52.3 ± 0.4 kcal /mole . = INTRODUCTION This report contains the results of calorimetric measurements to obtain the heats of formation of zirconium carbide ( ZrC) and hafnium carbide ( HfC) . The work was conducted as part of a Bureau of Mines program for determining the heats of formation of oxides , carbides , and nitrides by combustion calorimetry . Combustion calorimetry is one of the most precise calorimetric techniques . The chief obstacle to obtaining accurate heat of formation values for carbides , and the chief reason for the variation in the results of different investigators , is the lack of purity of the carbide samples . Corrections for impurities always involve assumptions which lead to uncertainties . In general , a large impurity correction is accompanied by a large uncertainty in the final result .

Jan 1, 1964

By Fred D. Wright

A compressor and utility station, which is believed to be one of the largest mobile units of this type ever constructed, was placed in operation at the Bureau of Mines experimental oil-shale mine near Rifle, Colo., during. 1949. This mobile unit mounts two 770-cubic-feet-per-minute air compressors, a 2,500-gallon water tank, and a 200-cubic-foot air receiver. The mobile base of the unit is a 30-ton trailer 30-feet long and 12-feet wide. Prior to the construction of this unit, compressed air was supplied to underground workings through pipe lines connecting with a stationary compressor plant on the surface. The power consumed in supplying compressed air to underground drilling crews was 0.531 kw.-hr. per ton of shale broken. Use of the mobile unit has cut this figure to 0.421 kw.-hr. per ton of shale broken and, more important, has eliminated the cost of installing and maintaining underground air and water lines.

Jan 1, 1950

By C. L. Brown

Among the more recent developments for breaking coal in mines is the Airdox system, in which high-pressure compressed air is conducted to the points of application by means of heavy-duty steel and copper tubing. Stray electric currents can be detected on y of the compressed-air lines, and evidence of such currents is rev led, by arcs and sparks when contact is made between the tubing and mine track or other equipment forming a current path with the track. Explosive gas is liberated in many coal mines; therefore, from the standpoint of safety, it is desirable to eliminate all possible sources of gas ignition, including stray electric currents. The purpose of this report is to reveal the source, magnitude, and possible methods of controlling stray currents in compressed-air lines that are used in connection with Airdox systems. Stray electric currents have been studied in most coal-mining localities in the United. States where Airdox equipment is used. The information given in this report is based on the find of these studies.

Jan 1, 1949

By L. C. IlsLey

The last previous Bureau of Mines publication relative to details of permissible methane detectors (Bulletin 331, published in 1930) describes detectors of four different types, namely flame, combustion, catalytic, and a combination Weatstone-bridge and catalytic type in which catalytic action at the surface of a platinum filament when in methane causes a change in the temperature and resistance of the filament, thus unbalancing the bridge circuit and giving a reading proportional to the methane concentration. Three detractors of the latter type have been approved since 1930. A brief description of each follows: U. C. C. Detector Approval No. 902, covering the U. C. C. indicating detector, as described in Bulletin 331, was extended. January 27, 1930, to cover important changes in design that permit checking the calibration of the detector at any time whether in gas or fresh air. Essential features of the detector are shown in figure 1.

Jan 1, 1937

By T. M. Barczak

This report describes Bureau of Mines research to develop methods to evaluate loading on longwall roof supports to permit better design and more efficient utilization of these structures in compliance with the geological conditions in which they are employed. The resultant vertical and horizontal force acting on the canopy of a shield can be determined, either from a statically determinate solution assuming rigid-body mechanics and elimination of certain unknowns, or from an elastic solu-tion by analysis of the load-displacement relationship of the shield structure. A two-dimensional rigid-body model is presented that determines resultant shield forces by measurement of leg, canopy capsule, and lemniscate link forces. An elastic solution is presented, in the form of an elastic stiffness model with two degrees of freedom, which describes the load-displacement relationship from the stiffness of the shield structure as determined in the Bureau's Mine Roof Simulator (MRS). The ability of both models to determine resultant forces acting on the shield canopy are evaluated from full-scale tests in the MRS. More advanced numerical models are also discussed as part of the Bureau's continuing effort in the evaluation of roof support structures.

Jan 1, 1987

By Irving Hartmann

Modern mechanized mining with high-speed machines, multiple-entry systems, multiple blasting, high-velocity air currents, and rapid haulage has brought many economic benefits and has on the whole enhanced safety in the coal-mining industry. It has, however, also introduced some added hazards, the control of which requires concerted effort and ingenuity. Mechanized mining has greatly increased the production and dissemination of fine coal seam or in mine entries. Use of high-speed machines has increased the probability of formation of incendive sparks, which are produced by frictional contact between moving metals and certain mineral substances in the coal seam or in the adjoining rock strata. In gassy seams rapid extraction of coal has increased the rate of gas evolution. These facts have made more urgent the need of preventing the ignition of coal dust and the development of widespread mine explosions. The ignition hazard can be controlled best by eliminating all potential igniting sources and by careful attention to ventilation designed to prevent accumulation of gas capable of triggering a coal-dust explosion. Frictional spark ignition by mining machines and suggested safeguards are discussed in a recent publication. Extensive research and long experience have shown conclusively that the propagation of coal-dust flames can be arrested and the development of widespread explosions prevented by properly applied, generalized rock dusting.

Jan 1, 1956

By Mary H. Brown

The heats of formation of oxalic acid and sodium, potassium oxalates, and lithium oxalates were related by solution calorimetry to the heat of formation of (COOH)2.2H20, a value believed to be reliable as reported in the literature. The following heats of formation were determined: (COOH)2(a), -198.1±0.1; (COOH)2(ß), -197.8±0.1; UAW,, -328.7±0.4; Na2C204 -316.2±0.1; K2C204, -321.9±0.2; and K2C204-H20, -393.5±0.2 kcal/mole. The heat of the crystalline transformation (COOH)2(a) ? (COOH)2(ß) was determined to be 0.30±0.02 kcal/mole at 298.15° K.

Jan 1, 1970

By Kenneth E. Hjelmstad

The U.S. Bureau of Mines (USBM) has developed an electromagnetic (EM) fire warning alarm sys-tem for underground mines. The system generates a magnetic field for through-the-earth signal trans-mission to microreceivers carried by individual miners. EM fields can induce electric currents in metallic conductors; if an EM transmitting antenna and an electric blasting cap array are too close, the field could induce a current in the blasting array and cause an unintentional initiation of the electric detonators. The USBM conducted tests that define the safe and unsafe regions for using electric detonators near the transmitting antenna of the warning alarm system. The minimum safe distance between a transmitting antenna and a blasting array is the distance where the induced electrical current in the blasting array is 50 mA, which is the safe current level specified in Federal mine safety regulations. Tests indicate that at transmitting power levels of 100-and 1,000-W, separation distances of 9 and 21 m, respectively, were required. These distances are small compared with the dimensions of a mine. Thus, the tests indicate that, with proper placement of the transmitting antenna, the warning system can be used safely in the proximity of blasting arrays.

Jan 1, 2010

By J. H. Perry, D. W. Houseknecth, C. A. Kertis, A. T. Iannacchione

Major problems facing the development of coal and gas resources of the Hartshorne Coalbeds include the complex distribution of minable and unminable coal, high methane content and bed pressure, faulting, variations in degree of dip, presence of natural gas fields in associated sandstones, and legal problems, caused by local geologic characteris- tics, in identifying gas origin. This Bureau of Mines study provides pertinent geologic information for long-range planning of subsurface coal and gas production from the Hartshorne Coalbeds. Pittsburg, Coal, Hughes, and Atoka Counties, OK, have approximately 1 billion metric tons (1.1 billion short tons) of Hartshorne coal in place. The methane resource of Hartshorne Coalbeds is estimated at 9.2 billion m3 (325 billion ft3) and varies with overburden and rank, These estimates were compiled from gas well density logs, coal-core data, out- crop measurements, abandoned mine maps, and the literature. The Hartshorne Coalbeds represent a valuable coal and gas resource which at present is contributing nothing to coal and gas production. This report discusses potential problems and serves as a reference for future exploration and development work. Recognition of these potential geologically related problems prior to development of this basin will reduce hazards and allow for an economic recovery of these resources.

Jan 1, 1983

By C. Sunderman, J. Johnson, S. Signer

Researchers at the National Institute for Occupational Safety and Health have developed a miniature data acquisition system (MIDAS) that can measure resistance changes and temperature, store data for later retrieval, and illuminate LED lights. This instrument can be used with strain-gaged bolts, cable bolts, CSIRO stress-measuring gages, string pots, and any other instrument that uses single-ended, resistance-type gages. MIDAS has the capability to measure up to 16 gages at preset time intervals and store more than 2000 scans, yet is small enough to fit in a 35-mm hole. Because the MIDAS consumes little power, a 9-V alkaline battery will operate the system for 6 months. Data from the MIDAS can be sent to a PC via an RS232/RS485/IRdA port. A software program was written to set operation parameters, graph data, and store all information directly to a spreadsheet. Three LED lights change from green to yellow then red based on reading levels and/or rates of change. This feature can be used with different types of gages to warn miners of possible rock instabilities. The MIDAS has received MSHA experimental permissibility approval and is currently being tested at several mines.

By Leslie H. Sharp, Martin J. Gavin

Those of the oil-shale operators in this country who are sincerely attempting to make a real industry out of oil-shale developments, are anxious to obtain fundamental data on the retorting of oil-shale; particularly as regards the effect of certain variable factors in the process of retorting on the quantity and quality of products yielded from oil shales when they are subjected to destructive distillation. From careful examination of a con siderable number of suggested processes for treating oil shales and the con flicting ideas on which they are designed, it seems probable that accurate information of a fundamental nature is highly essential to the successful establishment of an oil-shale industry in this country. . Accordingly, the United States Bureau of Mines, in cooperation with the State of Colorado, is undertaking to furnish some definite and impartial information of this type through investigations now under way at the University of Colorado, Boulder, Colo. A retort for the distillation of oil from oil shale has been designed and installed, together with the necessary auxiliary equipment for controlling and determining variable factors of distillation, and for recovering and de termining the quantity and quality of the products yielded from the shales. The retort is of such a nature that conditions of retorting can be accurately . and completely controlled, and varied at will. It is not designed as a com mercial retort, but only for research purposes. A testing laboratory with equipment necessary for the examination of the shales, physically and chemic ally, and the products yielded by them, has also been fitted up . The material used in the investigations is oil shale obtained from the DeBeque, Colorado, shale field. It yields on distillation in the Bureau of Mines testing apparatus, about 42 gallons of oil to the ton, and is there fore a fairly representative sample of the shales that probably will be first worked in Colorado. The shale used will be as uniform as possible in character and oil yield and will all be obtained from the same seam at the same point, in order to avoid the introduction of unnecessary variable factors in the tests and to render results strictly comparable •

Jul 1, 1920

By T. Whitrnoyer, J. Sneckenberger

"The acOustic impedances of seven rat lungs were measured at frequencies between 100 and 6400 Hz. Rats were divided into two groups: a silica exposed group (N=3) and a control group (N=4). The silica exposed group was injected intratracheally with silica solution. Three of the control group were intratracheallyinjected with saline. Between four and six weeks after theinjections, all lungs were excised and degassed. Lungs were,suspended in a pressure Chamber, with the trachea canula attached to the end Of a tapered impedance tube. The lungs were subjected to transpulmonary pressures between -30 cm H2O and 6 cm H2O to simulate deflation and inflation. With transpulmonary pressure being held constant, the impedance tube was excited with random noise. A dual channel analyzer calculated H12(f), the transfer function between the two microphones. This function was used to calculate the lung's impedance at that pressure. The impedance magnitude spectra of both groups typically had peaks at 2000,3500, and 5500 Hz. Statistically significant differences. (90%confidence level or greater) between the two groups occur at the 3500 Hz peak at transpulmonary pressures of 20, 8, 6, 4, and 2 cm of H2O. This fact seems to confirm that this method can detect. lung disease. Further research will indicate whether this method will be able to detect the onset Of coal worker's pneumoconiosis.INTRODUCTIONOne of the first studies of impedance Of the human lung were conducted by DuBois et al.[2] using the forced OscillatiOn technique. This technique, however, was limited to frequencies below 30 Hz. Further studies by Van Den Berg [6] revealed thatthe lung reflected higher frequency sounds (100-10,000 Hz), instead Of behaving as an anechoic termination. This discovery has lead to several studies of the acoustical properties of both human and animal lungs at high frequencies [3,4,5]."

Jan 1, 1988

This report was prepared by Jacob Tolsma and Arnold N. Johnson of the Uniroya 1 Research Center, Wayne, New Jersey. The valuable assistance and suggestions of the project officers, Mr. Ronald D. Hill, Dr. David R. Maneval and Mr. John J. Buscavage is gratefully acknowledged. The authors are grateful to the following Uniroyal personnel: Mr. Daniel Shichman, manager of Engineering Research, and Dr. Emmanuel G. Kontos, manager of the Polymer Physics Research for their direction, encouragement and suggestions regarding the experimental work, and Mr. Mark Olson for the design of the hollow auger soil sampler. We also wish to gratefully acknowledge the efforts and contributions of ideas proposed by our consultants, Dr. Frank T. Caruccio, assistant professor of geology at State University College, New Paltz, New York, and Dr. Pa Ho Hsu, associate professor of soil chemistry, Rutgers University , New Brunswick, New Jersey.

Jan 1, 1972

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

C 2 Complete Hoisting Systems A Above Ground Installations A total of seven companies were identified who supply complete emergency escape hoist units for above ground installations The units have been designed predominately to meet the needs of coal mine operators to satisfy the requirements of the Coal Mine Health and Safety Act of 1969. The seven companies are as follows 1 Dover Conveyor and Equipment Co. 2. Coeur d' Alenes Co. 3. Connellsville Corp. 4. Scott Midland 5. W W Williams Co. 6. Equipment Corporation of America 7. Timberland Ellicott Table VIII contains detailed specifications and price information on each of these units. The units have a number of similarities

Jan 1, 1976

By Marie Farnsworth

"The Anhydrite ProblemThe Nonmetallic Minerals Experiment station of the Bureau of Mines at Rutgers University, New Brunswick, N. J. has recently undertaken a study of the chemical and physical properties of anhydrite having in view its wider utilization anhydrite (CaSO4) in contact with water at ordinary temperature and pressure rehydrates, slowly forming gypsum (CaSO4.2H42O). In nature this is an extremely slow process, and laboratory experiments are being conducted to determine methods of accelerating the rehydration. The tests recorded herein cover one this study, and while they are negative in character in so far as the major problem is concerned, certain facts established by the tests, bearing on the stability relations of gypsum and anhydrite seem sufficiently important to be placed on record.Early Researches on Gypsum and Anhydrite.It is to Lavoisiar that we are the first scientific study of the calculation and hardening of plaster of Paris. He sums up his experiments in the following passage: ""If gypsum, which has been deprived of its water of by means of heat, is again treated with water (to make what is commonly called mortar) it takes it up with avidity, rapid and irregular crystallization occurs, and the small crystals which are formed are so entangled in each other that a very hard mass results."" Later, he observed that the dehydration of gypsum occurs in two stages: three-fourths of the combined water is much more easily driven out than the last fourth. LeChatalier first determined the temperature decomposition accurately, his method was as follows: Pulverized gypsum was placed in a glass tube in the middle of a paraffin bath, the temperature of which was raised in a progressive and regular manner. A thermometer gave at each instant the temperature the salt, and the passage of the mercury column past each division of —co. was cared by a registering chronograph. The rise in temperature was except at 128°C. and 168°C. where breaks occurred."

Nov 1, 1924

By A. B. Hooker, L. C. IlsLey

"Field inspections and data relative to the use of rubber-sheathed trailing cables in mines show that much cable is ruined or its probable life shortened by being overheated in service.The length of cable required to make connection from a source of supply to a machine at the face workings may be 100 to 500 feet. As a rule, the cable is carried on a reel and unreeled as required; and thus in most cases soma of the cable is not removed from the reel. The overheating generally occurs in that part of the cable which is left on the reel.Factors that determine the heating of trailing cables are:1. The size of the conductors in the cable.2. The maximum energy to be supplied through the cable, based upon the horsepower of the motor and the degree to which the motor is loaded.3. The voltage of the supply and the variation of the voltage at the receiving end.4. The time length of current flow and whether continuous or intermittent.5. The kind of current (direct or alternating).6. The amount of ca· le left or the reel.7. The type of cable used.8. The kind of reel used.In connecti0n with an investigation of the general performance of rubber-sheathed trailing callas, the Bureau of Mines has made a limited study of some of these factors, including the following points:"

Jul 1, 1931

By C. H. Gorski

Evaluation of raw materials for mineral wool is one phase of the Bureau of Mines broad program for the more effective utilization: of our mineral resources. The experimental work and test-evaluation results on several raw materials as useful components for the production of mineral wool are presented in this report. Samples from all sections of the United States, including copper slag from Tacoma, Wash., pebble phosphate slime from Florida, and granites from Massachusetts and Minnesota, have been blown into mineral wool successfully in the laboratory tests. Maximum conservation of the Nation's mineral and manpower resources requires maximum utility of those resources. Al though the domestic reserves of oil, gas, and coal are tremendous, judicious use of these fuels through the use of proper insulation will insure the highest thermal efficiency. The effectiveness of mineral wool as a heat-insulating material has assumed an increasingly important role in the national economy, and it has become a fuel saver in countless applications. The most immediate concern to many is the use of mineral wool in the home, which promotes uniform temperature and minimizes drafts by reducing heat transfer through the walls, ceiling, and floors. There are, however, many industrial and commercial uses that require large volumes of mineral wool each year.

Jan 1, 1951

By R. H. King

A very simple cold-bend test was devised and tested for evaluating thermoplastic jackets used on mine-power-feeder cables. A test sample is bent into a semi-circle whose radius is equal to the minimum bend radius recommended by IPCEA and then cooled to the, desired test temperature (-35°C). While at temperature, the sample is straightened by pulling the cable ends with a winch arrangement. The results show that of the jackets tested, those which cannot withstand the test literally burst when the sample is straightened.

Jan 1, 1978

By Robert M. Doerr

In a process being investigated by the Bureau of Mines for recovering alumina from domestic nonbauxitic resources, calcined kaolinitic clay is leached with hydrochloric acid. Iron impurity in the clay is coleached and is removed in a solvent extraction step prior to crystallization of aluminum chloride hexahydrate, which is subsequently thermally decomposed to alumina. The FeCI3-HCl stripping liquor from the solvent extraction step is unsuitable for discharging to the environment; furthermore, economics requires recovery of the contained chloride values. In the present research, it was shown that the stripping liquor can be reacted with calcined clay to yield AlC13 in solution, plus precipitated iron oxides, residual silica, and unreacted excess clay as mixed solids. For the recovery of the AICl3 solution, the slurry could be separated or returned to the clay-HCI process stream at the solids washing step that follows primary HCI leaching of the clay. For the range 20° to 99° C, the time (t) (103 sec) required to react the waste liquor with excess clay, for essentially complete iron precipitation, depends on the absolute temperature (T) chosen, according to the expression t = e[(9.000/T) -23.5J. (1) Alumina was tried as a reagent alternative to clay but was not very effective, even under pressure and at high temperatures.

Jan 1, 1982