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By W. E. Lamont

Flotation studies of phosphate-bearing waste pond materials, low-grade washer products, and raw ores, all from the Tennessee brown phosphate district, showed that these types of materials could be treated without des liming to recover high-grade phosphate concentrates. The investigation showed that fine grinding before flotation was a requisite for increased recovery of the phosphate values and that the optimum pH conditions were in the range of 10.0 to 10.5 when using anionic collectors. Multiple-cleaning of the rougher phosphate concentrate was required to produce high-grade concentrates. Phosphate recoveries ranged from 60 to 82 percent and were inversely related to the grade of concentrate produced.

Jan 1, 1972

By L. G. Austin

"This paper is based on the development of the Maza-Austin technique for characterizing thousands of coal particles by approximate analysis of the major inorganic constituents Ca, Al, Si, K, Na, Fe and S in each particle. The technique has sufficient sensitivity to work on small volumes, is fast enough to handle large number of particles within a reasonable period of time, and consists of scanning electron microscopy combined with energy dispersive x-ray spectrometry (SEK-EDS). A computerized SEK-EDS system that allows the automated analysis of hundreds of coal particles per hour' is described. The analysis is based on the location and tracing of coal particles embedded in a polished specimen, the selection of sampling points on the traced particles, the collection of an x-ray spectrum from each sampled point for a defined period of time, and the processing of the x-ray intensity to calculate point composition using ZAF corrections. Procedures for correcting for dead time, background, detector efficiency and spectrum overlap are described. These corrections are essential if reasonably accurate analyses are to be obtained from unknown complex mixtures of the elements in a coal or fly ash particle. Examples are given. INTRODUCTION Coal is a complex mixture of organic and inorganic materials. The inorganic fraction is referred to as mineral matter (Gluskoter, 1978) but can occur in three modes: (i) an observable mineral species; (ii) as cations held by ion exchange to carboxylic groups; and (iii) in chelate complexes. The mineral matter content normally represents a significant proportion of a coal, with an average value of about 15% for US coals (Gluskoter, 1975). The standard methods of analysis of the mineral matter in coals are performed on a sample selected to represent the whole coal as closely as possible, and give the overall inorganic composition in the coal. Such analyses are of limited use for solving problems originating from the behavior of individual coal particles, whose compositions vary widely from the average value. This is particularly true in pulverized coal combustion, where the current methods of predicting the slagging and ·fouling potential of a coal are based on the bulk ash composition, but the fly ash particles which create the deposits originate from coal particles with large differences in mineral compo1ition. Some examples can be found where, in a comparison between two coals, the one with the smaller slagging potential according to the mean ash composition was the one that behaved worst in the furnace (Moza et al., 1980; Koza and Austin, 1983). The u1e of gravity fractionation to assess the slagging potential of pulverized coals has shown that conventional ASTM analysis is not sensitive to differences in the distribution of mineral matter when comparing coals (Borio and Narciso, 1979). Bryer (1979) concluded that coals should be examined for fouling and slagging potential by analyzing gravimetric and size-fractionated coal, preferably pulverized· and ground to the size expected at the mill outlet."

Jan 1, 1989

By Michael A. Trevits

During the time period from 1990-2007, there were 1601 reportable fires that occurred in the U.S. mining industry (an average of 89 fires per year). The leading causes of U.S. mine fires include flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion. The National Institute for Occupational Safety and Health (NIOSH) is conducting a program of research addressing metal/nonmetal and coal mine fire prevention, detection, management and suppression. In the metal/nonmetal area, work was focused on technology transfer and training, and research to reduce the number of mobile equipment fires and their hazards. In the coal arena, research is underway to determine the root cause of cutting and welding-related fires and to evaluate the effects of ventilation schemes relative to the spontaneous combustion risk in longwall mines. Relative to fire management, research is ongoing on remote mine seal installation and remote mine fire suppression technologies. Finally, research is continuing to develop comprehensive and usable smoke management techniques and to develop mine fire growth models, propagation, and suppression. This paper presents a summary of some of the mine fire research and provides an overview of the next phase of the NIOSH mine fire research program.

Jan 1, 2010

1. Data from the Mine Safety and Health Administration (MSHA) indicate that a total of 241,502 employees worked in surface mining locations in 2003, corresponding to 212,113 full-time equivalent (FTE) workers. • Surface employees accounted for 84.6% of all mining employees. • The majority of surface employees (73.7%; n = 177,927) were mine operator employees as opposed to contractor employees. • Stone operator employees comprised the greatest percentage (27.2%; n = 65,743) of surface employees.

Feb 1, 2005

By X. Shi, V. Vallyathan, N. S. Dalai

"Using. ESR spin trapping methodology, evidence was obtained that fresh quartz dust in a cell-free aqueous medium generated hydroxyl - and possibly superoxide radicals. The hydroxyl radical generation potential decreases on storing of fresh quartz dust in ambient air and on the addition of either catalase, superoxide dismutase, desferoxamine, or DMSO. The role of quartz related radicals in the biochemical mechanism of acute silicosis is suggested from these findings.IntroductionThis report summarizes our electron spin resonance (ESR) detection of oxygenated radical formation by freshly crushed quartz particles in a cell-free aqueous medium, and its inihibition by radical scavengers. This study was undertaken with to elucidate the primary biochemical mechanism involved in the development of silicosis (Farber, 1983; Reiser and Last, 1979; Silicosis and Silicate Disease Committee, 1988). In particular the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still not well understood (Farber. 1983; Reiser and Last, 1979;). It is generally believed that the action of quartz particles on the cell membrane is the starting point of the silicotic process (Farber, 1983; Parazzi et al., 1968). Thus the surface characteristics of the quartz particles have been the subject of several recent studies (Bolls et al.. 1983; Dalai et al., 1986; Fubini et al., 1987). Recently, We reported that mechanical crushing of quartz under normal atmosphere generates free radicals which decay with time, and that these free radicals are associated with a higher cytotoxicity of fresh quartz dust as compared to aged dust from the same stock (Dalai et al., 1986; Vallyathan et al.. 1988). The formation of Si• and. SiO--type of radicals from quartz particles crushed under atmospheric conditions has also been reported by Fubini et al. (1987). In addition, Gulumian and van Wyk (1987) have reported that quartz particles react with hydrogen peroxide (H202) to generates hydroxyl radicals (•OH) and suggested that this process might contribute to quartz's pathogenicity. However, these authors did not report the effects of metal chelators, so it was not clear as to whether the detected -OH radicals simply resulted from the Fenton reaction involving exogenous metal ion contaminants. Earlier, Marasas and Harington (1960) reported that quartz particles could function as an oxidant in a number of in vitro oxidations, including the hydroxylation of proline and lysine. They postulated that silica dusts, on reacting with water, could release H2O2 which might have the potential to react with various biological constituents and thus cause tissue damage. In fact, Gabor and coworkers (Gabor and Anca, 1974; Gabor et al., 1975) suggested that the cytotoxicity of quartz particles might be associated with the generation of some 'factor or factors possessing the properties of a free radicals capable of promoting the peroxidative chain cleavage of polyunsaturated fatty acid moieties of the phospholipids in the cell membrane. More recently Weitzman and Graceffa (1984) reported that asbestos is able to catalyze the generation of • OH radicals from H2O2. Their later work indicated that lipid peroxidation may be one of the mechanism by which asbestos produces tissue injury (Weitzman and Weitberg, 1985). This is significant because • OH radicals are capable of causing peroxidation by abstracting hydrogen atoms from cell-membrane lipids and initiating lipid peroxidation in lysosomal membrane (Fong et al., 1973). In fact, the formation of oxygenated species in reactions involving quartz was suspected since Kolbanev et al. (1980) reported the detection of H2O2 in the reaction of fresh quartz particle with aqueous medium. The present work was thus undertaken to detect the anticipated formation of some oxygenated, radical species by reactions of quartz in a cell-free media and its inhibition by radical"

Jan 1, 1988

By E. L. Burwell

Application of the in situ recovery process to oil shale was tested during two field experiments near Rock Springs, Wyo. The results of these tests demonstrate that a self-sustaining combustion zone can be created in an oil shale body, that this zone can be moved through the oil shale, and that the process will produce shale oil. Evaluation of the combustion process by monitoring produced fluids for physical and chemical properties and volumes is described. The material and energy balance obtained is compared with a second evaluation based on extensive coring of the test area after the test was terminated. Several side results of the research are noted such as ground surface heating by underground burning and production of low-to medium-Btu gas during retorting.

Jan 1, 1973

By Joanne L. Johnston

Researchers at the U.S. Bureau of Mines have developed a new technique for bonding strain gauges to rock bolts. These instrumented bolts are used to determine load at intervals along the length of the bolt so that reliable, consistent measurements for the design of support systems can be obtained. In this Information Circular, this technique is described in detail and should result in improved miner safety in underground mines.

Jan 1, 1993

By M. Howard Berliner

In August 1943 the Bureau of Mines completed seven churn-drill holes in an area of old mine workings near Linden, Wis., formerly known as the Argall mine. The work was undertaken as part of a general investigation by the Bureau of the zinc and lead producing area of southwestern Wisconsin at a time when special effort was being made to increase the production of metals necessary for war. The area was selected for investigation on the basis of its favorable geologic structure, past history, and apparent mineralization.

Jan 1, 1948

By H. E. Perlee

The concentration limits of flammability and autoignition temperatures of trichloroethylene in atmospheres of air, oxygen, and nitrogen tetroxide have been determined in a spherical vessel. The autoignition temperatures of TCE in atmospheres of air, oxygen, and nitrogen tetroxide were found to be 419°, 396°, and 221° C, respectively. The flammability zones of TCE-air, TCE-oxygen and TCE-nitrogen tetroxide mixtures at 100° C were found to be 10.5 to 41, 7.5 to 91, and 13.5 to 69 volume percent TCE, respectively. In addition, maxi-mum combustion pressures of 50 ps and 140 were recorded for constant volume combustion of the lower limit mixtures of trichloroethylene in air and oxygen, respectively.

Jan 1, 1966

By D. J. Parker

This report is based on data collected in and about the Liberty mine of the Liberty Fuel Co. by D. J. Parker and W. W. Kessler on December 13 and 14, 1933. An important phase of an examination to determine the general condition of a mine with respect to safety is the collection of dust samples from rock- dusted areas. Definite conclusions, based on intelligent interpretation of the analyses of such samples, can be reached only when the general condition of the mine is known. A similar examination and report were made on this property in January 1930 by D. J. Parker and R. I. C. Manning. Since that time much has been done by the management to improve safety conditions in this mine. The changes made will be noted in the course of this report. The mine is in Spring Canyon at Latuda, Carbon County, Utah, and is served by a branch line of the Denver & Rio Grande Western Railroad about 7 miles long and connecting to the main line near Helper, Utah. The writer desires to express his sincere appreciation for the many courtesies and helpful cooperation extended by Superintendent George Schultz and Mine Foreman F. W. Koelling.

Nov 1, 1934

By D. W. Frommer

The investigation reported in this paper is one of several included in a broad program of developing new or improved concentration processes for the oxidized and partly oxidized deposits of lead and zinc, A sample from the Playter lease, Newton County, Mo., containing pyromorphite was successfully concentrated by fatty acid flotation to a grade of over 62 percent lead. Owing to the presence of a high content of slime-size values, the overall recovery of lead at that grade was limited to 44 percent. DESCRIPTION AND HISTORY OF PROPERTY The mineral pyromorphite is a chlorophosphate of lead containing 76.4 percent lead, and, although it occurs frequently in association with other lead minerals, it is considered a minor ore mineral of lead. The manner of occurrence of oxidized lead minerals, including pyromorphite, which frequently are no larger in grain size than the clay with which they are found, militates both against development of a simple beneficiation process and high recovery. The profitable exploitation of such deposits depends not only on a successful treatment procedure but a highly favorable metal market as well. For these, and perhaps other reasons, very little research has been done on the recovery of pyromorphite from its deposits.

Jan 1, 1956

By E. G. Valdez

Laboratory research demonstrated that ceramic wall and floor tile can be produced from electric furnace phosphorus slags composed of calcium silicates. Grinding the slag in a pebble mill, followed by magnetic removal of deleterious magnetite, produced a raw material that could be compounded and formed into wall tile by dry pressing, sintering, and glazing. The effects of process variables such as forming pressure and sintering temperature were investigated. Wall tile bodies produced by this method were comparable to commercial tile. The tiles were readily glazed to a smooth shiny finish and met ASTM Specifications C34-62 for structural clay load-bearing tile. The estimated cost of producing wall tile by this method compared favorably with the retail market value for similar wall tile. Addition of borax or other additives to the ground slag followed by dry pressing and firing likewise produced a commercial grade of floor tile.

Jan 1, 1974

By W. A. Haley

This is the second of a series of publications that describes the progress of mechanical longwall coal mining in the United States in which a German coal planer was employed.3/ Details of the equipment, a description of its operation, and the results obtained in mining the experimental panel were published in the preceding report. Experimental mining with the planer in the first panel showed an improvement in performance over conventional mining methods at the coal company's Stotesbury 11 mine. The work, which was begun on an experimental basis, soon proved successful, and the coal company purchased the equipment for continued use. Two panels, adjacent to the first, were developed and mined with the planer. Each of these panels was shorter than the preceding one because water seepage from a surface creek limited development. On completion of mining in the third panel, the planer equipment was moved by the cooperating company to a nearby mine operated in the same coal bed where a large area of coal suitable for planer mining is available.

Jan 1, 1954

By G. St John Perrott

"The United States Bureau of Mines is cooperating with the State of Utah and the City of Salt Lake in an investigation of methods of abating the smoke nuisance in Salt Lake City. In the course of this work samples of the atmosphere have been collected and analyzed in an attempt to determine the part played by sulphur dioxide or smelter gases in polluting the air at Salt Lake City.A fairly wide-spread opinion exists in Salt Lake City that the smelters contribute appreciably to the smoke nuisance. The gases discharged from the smelter stacks are believed (1) to float over the city in a heavy blanket which prevents the smoke from rising, and (2) to unite with the water vapor in the air to form corrosive fogs injurious to health and property.The first of these theories seems untenable. If the gas did not mix with air it would sink, owing to its heavier specific gravity, and form a blanket an the earth. Actually, the gas diffuses rapidly in air and any part reaching Salt Take must he thoroughly diluted. Perhaps sulphur dioxide in sufficient concentration might aid in fog formation. The more obvious nuisance, however, would be the injury to health and vegetation.The Garfield smelter is 16 miles west of the city, The Murray smelter 8 miles south, and the Midvale smelter 12 miles south. Under normal operating conditions, a relatively small amount of solid matter is discharged from these stacks. The toxic gaseous constituent of the discharge is sulphur dioxide, it is being discharged from the smelters the year round. If they are a factor in the city's smoke problem, the concentration of this gas in the air of the city should be appreciable and should increase toward the smelters, the con centration being highest with a south or a west wind."

May 1, 1920

By Jacqueline A. McClaskey

The U.S. Bureau of Mines Information and Analysis Directorate collects world-wide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The Bureau's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the U.S. Bureau of Mines survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1992

By L. C. Headley

A series of exploratory tests was conducted to determine the effects of steady electric fields on fluid flow and streaming potential in narrow passages and porous media, the effects of steady electric fields on fluid interfaces, and the influence of internal voltages on fluid flow in a porous porcelain sample. Voltages greater than about 5 kilovolts were found to influence liquid droplets emanating from a capillary tube. Solutions of polyethylene oxide and polyacrylamide in water exhibited widely different behavior than that of other liquids tested. Liquid-liquid displacement tests in porous samples to determine the influence of high voltage applied to the displacing liquid on flow rates and recovery gave no significant differences. No consistently measurable effects were noted, either on flow rate or streaming potential, when an electric field was applied transverse to the direction of flow in porous media and in narrow rectangular or cylindrical channels. Experimental values of formation factor and streaming potential for a porous porcelain sample agreed qualitatively with those calculated from electrokinetic theory for ultrafine capillaries. However, the agreement for the electroviscous effect was not good.

Jan 1, 1970

By L. J. Kane

Several processes being developed by the Federal Bureau of Mines to provide new and more efficient uses for coal require practical methods for removing dust from hot gases. Filters provide such means. The efficiency of filters made of aluminum silicate fibers and porous stainless steel was determined. The results obtained with the fibers were previously reported.5 In this investigation tests were made with three porosities of stainless steel filter material (grades C, D, and E) at a gas flow of 1,000 std. c.f.h./sq. ft. of filter, temperatures of 75° and 1,000° F., and dust loadings (as represented by cumulative dust fed) of 100, 1,000, and 10,000 gr./sq. ft. of filter. Pressure drop during the runs ranged from 0.1 to 21 in. of mercury, and dust removal from 25 to 99.93 pct. Filters having the finest pores gave the greatest pressure drop and percentage of dust removal; however, their dust-holding capacity was slightly lower. Usually, their ability to remove a higher percentage of dust at the same pressure drop more than compensated for the slightly lower dust-holding capacity. With increase in temperature, for the same weight rate of flow of gas, the pressure drop increased and the percentage of dust removal decreased. The effect of temperature was probably due to the accompanying change in the linear velocity and viscosity of the gas.

Jan 1, 1961

By L. B. Berger

In this investigation, the ampoule type of carbon-monoxide (CO) detector which is manufactured under license of U. S. Patent 1,644,014 (October 4, 1927) was tested for sensitivity and reliability. This detector was devised primarily for examining the air of manholes and sewers for possible dangerous contamination with CO before workmen enter these places, but due to the simplicity of the device it may have a more general usage for examination of atmospheres which are known or suspected, to be contaminated with CO. Some of the suggested uses are the examination of the air in garages, tunnels, mines, around blast furnaces, gas plants, and in the home.

Jan 1, 1930

By Edward L. McHugh, Charles Sabine, Louis J. Denes, Jami M. Girard, Peter Metes

The Spokane Research Laboratory, National Institute for Occupational Safety and Health, is investigating various remote sensing technologies as possible tools to detect, monitor, and mitigate hazardous situations in surface mines that could lead to catastrophic slope failure. Promising technologies include a field-portable spectro-polarimetric imager and a stationary interferometric radar device. Field tests were conducted of a prototype visible and near-infrared spectro-polarimetric imager (SPI) built at the Carnegie Mellon Research Institute. The SPI employs anacousto-optical tunable filter (AOTF) to control wavelength, a phase retarder to measure polarization signatures, and a digital camera and computer to capture data. Images obtained at the Mountain Pass and Castle Mountain mines in southeastern California showed that the instrument is capable of obtaining hyperspectral images of highwalls, outcrops, hand samples and drill core in the field. We have retrieved spectra from Mountain Pass images that closely match those of bastnaesite and have had some success in classifying images. Although radio frequency noise in the data limited spectral classification of imagery, we project that careful alignment of the AOTF should minimize the noise and greatly improve classification.

By Manuel Gomez

A general prediction model for the Hardgrove grindability index was constructed from 735 coal samples using the proximate analysis, heating value, and sulfur content. The coals used to develop the general model ranged in volatile matter from 12.8 to 49.2 percent, dry basis, and had grindability indexes ranging from 35 to 121. A restricted model applicable to bituminous coals having grindabilities in the 40 to 110 range was developed from the proximate analysis and the petrographic composition of the coal. The prediction of coal grindability within a single seam was also investigated. The results reported support the belief that mechanical properties of the coal are related to both chemical and petrographic factors of the coal. The mechanical properties of coal may be forecast in advance of mining because the variables used as input to the prediction models can be measured from drill core samples collected during exploration.

Jan 1, 1970