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By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip corrosion (method 530.22),5 color (method 10.11),6 sulphur content (method 520.11) copper-dish evaporation residue (method 520.11),7 and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and try will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation.

Jan 1, 1930

By J. M. Seward, W. D. Dietzman, M. E. Hawkins

Analytical studies of formation waters are widely used by the petroleum industry as an aid in solving problems such as identifying intrusive waters , corrosion studies , treating injection water , and choosing open or closed water- injection systems . The solution of a problem is often simplified when reliable analyses of the waters under consideration have been made previously . Chemical analyses and electrical resistivity measurements are presented on 267 samples from 74 fields in south Arkansas , and 199 samples from 80 fields in north Louisiana .

Jul 1, 1960

By J. E. Hamak

This publication contains analyses and related source data for 162 natural gas samples from 15 states and 4 foreign countries. Of the total samples, 154 were collected during calendar year 1992. The remainder were collected earlier, but releases granting permission to publish were not received until 1992. None of the analyses have been previously published in annual reports. All samples were obtained and analyzed as part of U.S. Department of the Interior, U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free-market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1993

By P. G. Barnard

The Bureau of Mines investigated the effects of various additions of rare-earth metals or rare-earth oxides on the mechanical properties of cast and wrought plain-carbon steels. Rare-earth metals, as misch metal, were added to medium-carbon steel in amounts to 0.70 weight-percent; rare-earth oxides, as a commercial mixture, were added in amounts to 1.50 weight-percent. The melting and casting of conditioned steels were done in a vacuum-induction furnace, to avoid formation of oxides from the melting atmosphere and to pro-vide better control over chemical composition. At room temperature, data for tensile strength, yield strength, elongation, and hardness of cast and wrought steels were obtained by standard testing equipment and procedures. Impact tests were conducted on as-cast steel specimens. The greatest amount of tensile ductility and impact strength was obtained in as-cast steel with 0.50 to 0.70 weight-percent misch metal additions. No significant improvement on mechanical properties was indicated in wrought steels containing rare-earth metal additions in the range from 0.10 to 0.70 weight-percent. In general, the rare-earth oxide additions up to 1.50 weight-percent had little effect on the tensile properties of steel in the cast, wrought and annealed, or wrought and normalized condition.

Jan 1, 1967

By L. G. Marshall

Gypsum mining and processing has been one of the principal industries in Iowa for more than 75 years. For most of that period, Iowa has ranked among the five leading States in the production of crude gypsum and of calcined-gypsum products. The Fort Dodge area accounted for 11 percent of the gypsum products produced in the United States in 1956. Before 1927 the output by the major companies came from underground operations, using a room-and-pillar stoping method. At present, all production comes from quarries. The quarry methods at the various properties are similar. This paper describes the quarrying, methods employed in the district and the type of equipment used by each company. The sections on history and geology are, in part abstracts from State annual reports and an Iowa Geological Survey publication.3/

Jan 1, 1959

By L. B. Pankratz

Heat contents were measured for Na2CaSi04 and Na2Ca2S02 between 298° and 1,300° K, for Na2Ca2Si309 between 298° and 1,500° K, and for Na4CaSi3O9 between 298° and 1,350° K. Copper-block drop calorimetry was employed. Reversible, first-order transitions were found for Na2CaSi04 and Na2Ca2Si309. The transition for Na2CaSi04 is at 830° K with a heat absorption of 160 cal/mole; that for Na2CagSi309 occurs at 750° K with a heat absorption of 1,550 cal/mole. Results for the other two silicates showed no irregularities. A table of heat content and entropy increments above 298.15° K and heat con-tent equations are included for use in thermodynamic calculations.

Jan 1, 1968

By Franklin D. Slagle

Porosity and bulk-and sand-grain-density values were determined for 2,040 core samples of 30 formations from 47 wells in New York, Ohio, Pennsylvania, and West Virginia, and are compiled for petroleum industry use in well-log evaluation and geologic studies.

Jan 1, 1967

By L. C. George, J. W. Jensen

A new system for precisely counterbalancing and measuring vapor pressure operates by servomechanical principles . It was developed with the objective of determining the vapor - pressure equations of metal halides . The system is isolated from the vapor - pressure bulb by a diaphragm transducer that signals a pressure regulator to null any pressure difference that is detected . Pressure measurement and readout are continuously performed by a servomanometer , accurate to ±0.003 cm Hg for the range of 0.1 to 200 cm Hg . High response rate and sensitivity are obtained . Methods of use are described , and results for CdC1 and PbC1 , in agreement with data of other investigators , are given as examples .

Jan 1, 1964

By Carlton E. Brown

Impinger dust-counting methods are used by industrial hygienists for determining the number concentration of unhygienic siliceous dusts in industrial atmospheres. Various statements have been made regarding the size of the smallest particles revealed by the microscopic employed in such determinations. Published data on the subject are quite limited. This report presents information on the size of the smallest particles revealed by light-field and dark-field techniques applied to impinger and electric precipitator samples collected from experimentally established aerosols of silica dust and bituminous-coal dust. Size distribution and number concentration of particles of the various sizes in the aerosols were determined from samples collected by thermal precipitation simultaneously with the impinger and electric precipitator samples. The size of the smallest silica and bituminous-coal dust particles determined in the light-field counting method used was about 1./1, . There was relatively little variation in the values from 8 impinger and 33 A.-C. precipitator samples of silica dust and 13 impinger and 13 A.-C. precipitator samples of coal dust. The coefficients of variation of the values from the four sets of determinations were low, ranging from ± 7.7 to t 10 percent. This size of 1,14 is close to the limit of resolution of the microscopic method used and to various previously suggested values. The size of the particles determined in the dark-field counting method used was smaller than the size (about 0.28A ) of the smallest particles determined in the light-field, oil-immersion method used for the thermal precipitator samples.

Jan 1, 1951

By Robert A. Speirer, Richard G. Burdick

Methods of detecting geologic faults and other linear features by means of processed LANDSAT satellite images have gained prominence during the past several years . There have been numerous programs written to pick these " lineaments , " but they have been almost universally tailored to large computers . This Bureau of Mines report describes a detection method developed for use with a minicomputer . The method comprises a suite of programs that scans an image for all " potential " lineaments . From this partially analyzed data , the final lineaments are picked by another routine . The method was field tested in an area of south- central Wyoming , and results indicated good agreement between computer- picked lineaments and ground features . Most of the known geologic faults in the area were picked by the method . Such features as roads and trails were also picked but were easily distinguished from faults during field inspection . The method is relatively new but promises to be a viable reconnaissance technique for the mining industry in geologic structural analysis .

Jan 1, 1965

By E. C. Lane

This paper is a preliminary report of the results of the Bureau of Mines' twenty-second semiannual survey of motor gasoline marketed in the United States. A more detailed discussion of the whole survey is in preparation and will be published as a companion, report. The second paper, in addition to giving a more complete summary of the data included in this report, will present results of the determination of copper-strip core lion (method 530.22), color (method 10.11), sulphur content (method 520.11) evaporation residue (method 530.1), and gum content as given by the Bureau of Mines steam oven method.9 The retail price at the time the sample was taken and tax will also be stated for each sample. The present paper deals specifically with data relating to gravity, vapor pressure, and distillation. It has been the feeling of some investigators that the practice, followed in previous semiannual surveys, of grouping all types of motor fuel together without discriminating between "competitive price gasoline," benzol blends, Ethyl gasoline, "high-test" fuels, etc., has detracted from their usefulness because the data did not permit drawing conclusions in regard to any one type of fuel, and tended to obscure differences between fuels of the various types. Therefore, in order to remedy this condition, the samples of the present survey have been divided into two groups; one called "competitive-price gasoline" and a second group called "premium-price motor fuels."

Jan 1, 1930

A study was conducted by the Bureau of Mines to evaluate natural gas as an automotive fuel and to provide guidelines for optimum engine adjustments for low exhaust emissions. The study was conducted using a single-cylinder engine, a multicylinder engine, and a total of eight vehicles. Results from single-cylinder engine tests showed that the light-load, lean-limit misfire region for natural gas begins at an air-fuel ratio between 150 and 160 pct of stoichiometric. Changes in ignition timing significantly influenced emissions of nitrogen oxides and hydrocarbons, but had little effect on carbon monoxide emission. Low emissions can be achieved with current-design engines by adjustment of engine parameters, but only with heavy penalty to engine performance. Emissions from vehicles fueled with natural gas are virtually unaffected by ambient temperature change within the range 20° to 100° F. The organic emissions from engines fueled with natural gas were estimated to be 22 to 25 pct as reactive as the emissions produced using gasoline. Levels of exhaust emissions from vehicles fueled with natural gas were unchanged over 10,000 miles of normal driving.

Jan 1, 1973

By M. S. Seehra, R. S. Pandurangi

"A comparative study of the intensities of the IR modes in the pjlotoacoustic and. FrIR spectroscopy of amorphous and crystalline SiO2 particles is presented. It is observed that in photoacoustic spectroscopy of amorphous SiO2, IR modes of surface species are enhanced by over an order of magnitude compared to the bulk IR modes of SiO2. This effect, though not yet understood, may find applications in surface science.Since the publication of the Rosencwaig-Gersho theory of the photoacoustic effect in solids in 1976 [1], a great deal of attention has been paid to the development .of photoacoustic spectroscopy (PAS) into an analytical technique for condensed matter studies, especially when combined with the modern Fourier transform infrared (FTIR) spectrometer [2-8]. PAS has now been applied to a variety of experimental situations [2, 3] and it is particularly suitable for opaque powders and for cases where ~ample preparation (e.g. mixing with KBr as is usually done in FTIR spectroscopy) is not desirable. Another area of interest is the depth profiling feature of PAS, which is studied by varying the modulation frequency of the incident radiation [2-8]. The one-dimensional Rosencwaig-Gersho theory for non-porous samples has been extended to other cases [9-12]. Recently it has become known [11, 12] that for porous samples with porosity the IR modes are enhanced by a factor proportional toe. This enhancement is due to the pressure wave set up in the interstitial gas in the porous sample and this enhancement has been reported by a number of groups [12-14].In this Letter we report the observation of anomalously large enhancement of the PAS signal for certain surface IR modes on the surface of amorphous silica particles. This observation differs from the previous reports in that certain surface modes are enhanced by over an order of magnitude compared to the bulk IR modes. Although the reasons for this enhancement of the surface IR modes in PAS are not understood at present, this observation may open up new approaches to the study of surfaces. Results of these initial observations are given in this Letter. ·Experimental studies reported here were carried out on an FTIR spectrometer (Mattson Instruments, Model Cygnus 100) equipped with an MCT detector. The same instrument was used for PAS studies in conjunction with an MTEC (Model 100) PA cell. The sample cell and the spectrometer are continuously flushed with dry, CO2 free air obtained by the use of Balston Instruments Air Dryer Filter System (Model 75-60). Usually data were collected for 32 scans at 4 cm-I resolution, although both scan and resolution can be varied. For FTIR studies, samples were mixed with IR-grade KBr and pelletised. For PAS, no sample preparation is necessary and data are ratioed against dry carbon black [4, 5]."

Jan 1, 1989

By M. B. Royer

Sulfur is present in many ores and other raw materials that are used in the production of metals and alloys of industrial importance. Its presence, especially in ferrous-metal products, generally is undesirable because of its detrimental effect during processing and upon various physical properties of the finished metal. Therefore, various methods are resorted to for elimination of the element to some specified maximum final content. Such removal or elimination of sulfur is designated as desulfurization.

Jan 1, 1948

By W. H. Frederic, F. H. Gibson, R. F. Abernethy

This publication contains the quantitative values for phosphorus , chlorine , sodium , and potassium in United States coals . The samples tested were taken from commercial shipments and have been selected to represent the principal coal producing areas of the country . Due to combining the analytical results from two separate surveys , values for the four elements are not available for all samples .

Jan 1, 1965

By Ralph Husack, J. W. Eckerd, G. A. Brady

The effect of gamma radiation on Pennsylvania anthracite and on reactions between anthracite and other materials was studied using a shielded , selfcontained 23,000 - curie cobalt 60 source . When anthracite was exposed to air at 65° C the reaction with oxygen was greater in the presence of radiation. than in its absence . Although drop- shatter tests indicated that exposure to radiation decreased the resistance to breakage of anthracite , this evidence of structural weakening was not supported by the results of grindability or particle- size studies . Irradiation caused definite changes in the gases evolved from evacuated samples of anthracite ; the percentages of hydrogen and carbon dioxide were increased, and the methane concentration remained unchanged . Carbon monoxide was evolved only from the unirradiated samples . Electron paramagnetic resonance (EPR ) measurements indicated large differences between evacuated samples and those exposed to air . There was little or no difference between irradiated and unirradiated samples , except that the free- radical content of unirradiated samples of anthracite increased progressively with higher temperatures of evacuation , but in the case of irradiated samples , no such behavior was found . Attempts to produce carbon disulfide and calcium carbide by reacting anthracite with sulfur up to 120 ° C , and with calcium oxide up to 400 ° C , were unsuccessful .

Jan 1, 1964

By Paul W. Johnson, Ralph C. Kirby, Frank A. Peters

An evaluation is presented for a process designed , on the basis of published work , to extract alumina as potassium alum from clay using sulfuric acid and potassium sulfate . The silica residue is separated by filtration . Ferric iron is reduced to ferrous iron , and the alum is crystallized from the solution , leaving the ferrous iron in solution . The alum crystals are separated from the solution and redissolved for feed to autoclave decomposition . In an autoclave the alum is partly decomposed to a basic alum , recovering five - ninths of the sulfuric acid and two - thirds of the potassium sulfate without using an acid plant . The basic alum is decomposed by calcining , and the potassium sulfate is then removed by washing with water . Operating costs for a plant producing 1,000 tons of alumina a day are estimated at $ 96.15 per ton of alumina . The fixed capital cost is estimated at $ 155 million . This process is not competitive under current economic conditions with the production of alumina from bauxite by the Bayer process . Improvement in leaching , basic alum decomposition , and washing could reduce the costs and improve the product which contains some potassium .

Jan 1, 1963

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered equipment and subassemblies approved and certified by the Bureau of Mines for use in noncoal mines. Testing of diesel-powered equipment is one phase of the Bureau's program of health and safety that concerns approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, or toxic hazards in underground mines, when such equipment is used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study of their design, safety features, and use. Equipment must pass exacting tests and must meet strict requirements established through research and experience and listed in the Bureau's permissible schedules before the Bureau approves it as permissible for safe use in mines.

Jan 1, 1963

By Radford Schantz

In 1990, the Bureau of Mines (BOM) conducted a mineral investigation of the mines and prospects in the East Mojave National Scenic Area (EMNSA). San Bernardino County. California During field work. BOM identified 701 mines and prospects in EMNSA for which the geology, mineral resources, and mining history were compiled and summarized. Analytical results for 1.188 rock samples collected are tabulated. Total value of identified resources in EMNSA is $5.0 billion. Twenty-four mines and prospects were deemed profitable under current economic conditions. Development could generate considerable economic benefits to San Bernardino County. Potential economic benefits from mining the deposits were evaluated under the following access restrictions for EMNSA: 1) fun access, 2) HR 3460, and 3) S 11/HR 780. Under the full access scenario, cumulative mine revenues are $3.0 billion, cumulative personal earnings at mines and supporting industries are $0.94 billion, and annual jobs at mines and supporting industries are 2,379. Under HR 3460, mine revenues, personal earnings, and annual jobs are $2.9 billion. $0.88 billion, and 2,165, respectively. Under S 11/HR 780, mine revenues, personal earnings, and annual jobs are $1.0 billion, $0.32 billion, and 936, respectively.

Jan 1, 1990

By George H. Schnakenberg

This Bureau of Mines publication describes a passive personal sampling device for N02 in air, developed by the New York University Medical Center under Bureau Grant G0133066. The sampler has been successfully demonstrated in the field and in the laboratory. In corroborative laboratory trials the agreement with reference method is excellent. The overall accuracy is approximately ±5 pct of reading to a precision of about ±l pct. All evidence indicates that these samplers should indicate the time-weighted-average N02 concentration to the above accuracy and precision equally well in the field since effects of wind velocity and relative humidity are negligible and the effects of temperature are about 0.1 pct per °F. The duration of exposure and the approximate temperature are the only data that need to be collected in the field. A two-step analysis procedure in field or service laboratory is then used to obtain the total cumulated exposure to N02 in parts per million-hours (ppm times hours), which can be converted to the time-weighted-average concentration of N02 in ppm by dividing cumulated exposure by the duration of the exposure.

Jan 1, 1976