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By Robert S. Warfield

The Federal Bureau of mines and U.S. Geological Survey conducted exploratory investigations and geologic mapping in the Wishbone Hill district of the Matanuska coalfield almost continuously from 1942 through 1958. These investigations delineated reserves of high-volatile bituminous coal necessary to supply the rapidly expanding military and civilian requirements in the Anchorage area. This report describes the program conducted by the Bureau of Mines from 1949 through 1958, and briefly summarizes previous investigations, the results of which have already been published. The coal-bearing structure on both the north and south limbs of the prominent Wishbone Hill syncline was explored by 8,719 feet of churn drilling and 25,460 feet of diamond-core drilling. A total of 33 holes were drilled ranging in depth from 60 to 2,114 feet. To supplement the drilling operations, bulldozer and dragline trenching were undertaken at key locations; about 25,000 cubic yards of dragline trench were excavated in the vicinity of the old Premier mine.

Jan 1, 1962

By David C. Grant

In situ uranium mining offers the advantages of minimal environmental disturbance, low capital and operating costs, and reduced mining development time. It is becoming an increasingly attractive mining method for the recovery of uranium from secondary ore deposits. In order to better understand the process, a laboratory technique was developed and used to study and simulate both the chemical and physical phenomena occurring in ore bodies during in situ leaching. The laboratory simulation technique has been used to determine effects of leaching variables on permeability uranium recovery, and post-leach aquifer restoration. This report describes the simulation system and testing procedure in sufficient detail to allow the construction of the system, and to perform the desired leaching tests. With construction of such a system, in situ leaching of a given ore using various leach conditions can be evaluated relatively rapidly in the laboratory. Not only could optimum leach conditions be selected for existing ore bodies, but also exploitation of new ore bodies could be accelerated.

Jan 1, 1985

By V. R. Miller

The Bureau of Mines conducted research on substitute brazing filler alloys with properties similar to those of silver filler alloys in an effort to conserve silver and reduce hazards from cadmium emissions. Experimental work was conducted first on the commercial silver brazing alloys BAg-I, BAg-la, BAg-2, and BAg-3 to establish criteria for evalu-ating the substitute alloys. Properties investigated included the wettability of copper, brass, and steel substrates, and the strength of joints made with the filler alloys. A series of experimental alloys containing 50 to 60 pct Cu, 20 to 28 pct Mn, and 17 to 30 pct Zn was prepared and evaluated, together with Cu-Mn-Zn alloys with 5 pct Pb or 2 pct Ni. Wetting properties and joint strengths were not as good as those for silver filler alloys, and the high application temperatures reduced the copper and brass base metal strengths. However, experimental alloys containing 70 pct Cu, 15 to 20 pct Mn, and 10 to 16 pct Sn had wetting and strength properties approaching those of the silver filler alloys. The application temperatures for these alloys were high-er than those for silver fillers, but not as high as those for the Cu-Mn-Zn alloys. With the Cu-Mn-Sn alloy fillers, copper alloy joint members are less deteriorated by recrystallization than when applying Cu-Mn-Zn alloys. The Cu-Mn-Sn system has potential for further devel-opment as a substitute brazing alloy system, particularly if the melting temperature can be reduced by the addition of other elements without decreasing the ductility and wetting.

Jan 1, 1983

By W. F. Watts

The U.S. Bureau of Mines has conducted research on methods to reduce and to measure diesel particulate matter (DPM) aerosols in underground coal mines. One objective of this report is to present findings from an investigation of the DPM reductions obtained by an engine-mounted integrated control system consisting of a dry system (DS) and a diesel particulate filter (DPF). Another objective is to present results from the usc of a size selective personal sampler to measure DPM concentrations in an underground coal mine. Bureau laboratory tests of the integrated dry system and diesel particulate filter (DS-DPF) have shown that DPM emissions can be reduced up to 97 pet with little change in gaseous emission concentrations. The DS-DPF is undergoing certification tests conducted by the Mine Safety and Health Administration (MSHA). Subsequent to passing all safety requirements, it will be tested in an underground coal mine. A baseline survey of DPM concentrations and aerosol size distributions in a cooperating mine was completed in August 1988. A prototype DPM personal sampler was tested during this survey. Based on results from this test, an improved unit has been developed. This unit is scheduled for extensive field testing by MSHA in 1989.

Jan 1, 1989

By Jack G. Croeni

The Bureau of Mines developed a method to extrude low-density tungsten powder billets into rods and sheet bar with high-energy-rate forming equipment. Billets were compacted and sintered in an atmosphere of hydrogen to obtain a density of approximately 60 percent. Extrusion was conducted at reduction ratios of 6.25 to 1 and 9 to 1 at 1,800° C to prod e high-density, sound material. Yield strengths obtained were higher than those of material produced by conventional powder-metallurgy techniques, but ductility was lower at high temperatures.

Jan 1, 1966

By Craig C. Hustwit

A pilot-scale treatment study was conducted on a copper-zinc bearing metal mine drainage using a pipeline treatment system called the In-Line System (ILS). The objective of this U.S. Bureau of Mines study was to determine whether the ILS could be extended from the treatment of coal mine drainages to the treatment of metal mine drainages. Hydrated lime (Ca(OH)2), quick lime (CaO), and caustic soda (NaOH) were used to neutralize the drainage. A novel reagent slurry of Ca(OH)2 and type C fly ash was also evaluated. Except for Ca(OH)2-fly ash slurry, treatment performance was evaluated for all reagents at pH values of 7,8,9, and 10. The Ca(OH)2-fly ash slurry was evaluated at a pH of 10. All reagents tested neutralized the metal mine drainage and substantially reduced the dissolved metal concentrations. It was concluded that the ILS could be useful in the treatment of metal mine drainages.

Jan 1, 2010

By J. B. Salsman

As part of the research effort on investigating the effects of microwave energy on the chemical and physical properties of minerals and ores, the U.S. Bureau of Mines (USBM) Tuscaloosa Research Center has conducted research to measure the dielectric properties of these materials. The objective was to establish a reliable database for use in predicting the effects of microwave heating on a wide range of minerals. The dielectric constants and loss factors of minerals, commonly referred to as the dielectric properties, were determined utilizing the theory of microwave propagation through an open-ended, air-filled coaxial line that was terminated at its open end with the particular mineral under investigation. In this phase of microwave research, the USBM measured the dielectric properties of powdered minerals with medium to high electrical conductivities in the frequency range of 300 MHz to 3 GHz and as a function of temperature from 25 to 325 °C. Since the minerals were prepared as powders, techniques were used to relate the measured dielectric properties of the powdered minerals to the dielectric properties of the mineral at its theoretical or natural density.

Jan 1, 2010

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By S. C. Termes

The Bureau of Mines has used Fourier transform infrared spectroscopy (FT-1R) to study in situ reactions of aqueous solutions of potassium ethylxanthate with CU(II)-and Pb(II)-activated sphalerite plates, in which the plates were both the infrared-transparent windows and the reacting surfaces. A copper (I) ethylxanthate formed predominantly with Cu(II)-activated sphalerite, regardless of the activation time. The products formed on Pb(II)-activated sphalerite depended on the activation times; a short activation time (30 min) yielded a lead ethylxanthate-like product, but a long activation time (90 min) yielded a considerable amount of dixanthogen.

Jan 1, 1986

By J. M. Mutmansky, C. Lee

"Measurement of the size and elemental characteristics was performed on airborne coal mine dust samples collected by multi-stage cascade impactors as well as channel samples of the geologic materials. Size distributions were obtained using precise weighing techniques on the impactor substrates. Elemental analysis on the samples was performed by the proton-induced x-ray emission (PIXE) method, a rapid and non-destructive method of multi-element analysis.The various analyses were performed on 9 major and 21 trace elements. The results indicate the importance of intake air and shuttle car movements as sources of dust. The association of coal dust characteristics with channel samples was investigated using the coefficient of proportional similarity as a statistical measure. Results show a strong relationship between major elements and the geologic material being cut but a similar relationship between trace elements and geologic materials is not consistent.1. INTRODUCTIONThe most significant occupational disease in the coal industry is known ·as coal workers' pneumoconiosis (CW'P). While CW'P has existed for centuries, its mechanism of occurrence and association with coal dust has been well understood for only a few decades. In the 1930s, the significance of this disease led state and government officials in the USA to perform extensive epidemiological and environmental studies in the major coalfields. Study of these results plus later studies in the coal producing countries of Europe eventually led to the dust regulations that appear in the Federal Coal Mine Health and Safety Act of 1969.The impacts of the 1969 act were a productivity decline and increased production cost. Many analysts attributed this in large part to difficulties in complying with the new dust standards (Brezovic 1981). However, compliance was met in most continuous miner sections rather quickly. The remaining problem area is that of longwall mining where the procedures and layout of the minin~ system make it difficult to meet the standards."

Jan 1, 1989

By Robert L. Lagace

The purpose of the work reported herein was to investigate whether available telephone multiplexing equipment offered a means to rapidly upgrade the traffic-handling capacity of present mine telephone systems and provide for selective calling for safer and more efficient mine operation. Common sense was used to decide whether or not an item could be termed "available." Since conventional telephone gear is not designed to interface pager phones for example, existing shelf items would require adapters to compatibly interface these two types of gear for independent operation over the present single twisted pair used in mines. These and similar small items were allowed, but if a system required any extensive design work to adapt it for the mines, we ruled it "not available."

Jan 1, 1975

In 1962 and 1963, two in situ combustion pilot tests were conducted in the shallow Second Venango sand near Reno, Pa. Because of poor oxygen utilization and lack of production response, both tests were considered failures and were terminated. The area was then relatively inactive until late 1966, when a development well drilled near the 1963 test site had surprisingly good production in what was considered to be a pressure-depleted reservoir. Other wells drilled in and around the old thermal pilot areas also came in as good oil producers. This report presents a study of the increased oil production from the Second Venango sand in the Reno area, and the apparent connection of the present production response and the old thermal pilot tests. Apparently combustion occurred in the Second Venango sand after the 1962 and 1963 experiments were terminated and, supported by large volumes of air left in the reservoir after the 1963 test, generated carbon dioxide which helped repressure the formation. This field evidence of combustion warrants another pilot experiment to further explore the use of properly designed in situ combustion techniques in increasing production from the Second Venango sand.

Jan 1, 1971

By John C. Machisak

THE INJURY data and experience at quarries and related plants of the United States are presented in this publication under the following general sections (A) General injury experience: Tables 1-3: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment data. (B) Injury experience at different kinds of quarries: Tables 4-5: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment, data. (C) Injury experience by States: Tables 6-20: Current data on the number of injuries, injury-frequency rates, accident agency, degree of injury, and related employment data. (D) Selected injury data: Tables 21-30: Current data on various selected factors of operating conditions at different kinds of quarries, including employment size-groups, length of shifts, comparative severity of injuries, and injury data and related employment experience at dimension-stone and nondimension-stone quarries and at underground quarries. (E) Historical injury experience: Table 31: Injury and employment data on the quarrying industry for 1911 through 1957. Statistical data on injuries and related employment in the quarrying industries have been collected annually from the operating companies since 1911. Reporting to the Bureau of Mines is voluntary; there is no Federal law compelling operators of quarries and related plants to supply such data. Data presented herein may not be complete for the entire industry. They are however, believed to be representative of the hazards common to all quarry and related workers. Moreover, the figures are comparable as between States-a significant fact in view of the lack of uniformity among the States with regard to the classes of injuries covered by State reports and other factors that tend to make it impracticable or impossible when using State records to

Jan 1, 1960

By R. C. Buehl

A pyrometallurgical process for recovering manganese from open-hearth furnace slags or low-grade manganiferous iron ores is described. The slag or ore is smelted in a blast furnace to produce spiegeleisen; the speigeleisen is then blown with air in a basic converter to give an oxide slag. This slag product contains 60 to 75 percent manganous oxide and may be considered a synthetic manganese ore. In the smelting operations coke rates for five test periods ranged from 3,255 to 4,130 lb per ton of spiegeleisen. The recovery of manganese in the spiegeleisen varied from 60 to 76 percent. Recovery increased to 83 percent when the open-hearth slag feed to the blast furnace was diluted with a high-? grade iron ore sinter to facilitate smelting. In blowing the spiegeleisen a cyclic procedure was developed that gave nearly 90 percent recovery of manganese in the slag product (synthetic ore) yet prevented excessive contamination of the slag by phosphorus and iron. The overall recovery of manganese was about 75 percent when iron ore sinter was used with the open-hearth slag in the smelting step. The metal remaining after oxidizing the manganese from the spiegeleisen contained approximately 3.5 percent phosphorus. It was refined in a basic converter by blowing with air in the presence of lime" A high--grade iron and a basic phosphate slag were produced.

Jan 1, 1965

By John J. Henn

As part of the U.S. Department of the Interior programs on rutile, authorized by the Office of Emergency Preparedness in June 1967 under provisions of the Defense Production Act, the Bureau of Mines reviewed available literature on major proposed processes for producing rutile substitutes. The processes are grouped according to the major processing step, and important operating features are described. Sixty-one references are cited.

Jan 1, 1970

By Frank A. Peters

The Bayer process treating Jamaican bauxite was evaluated from an economic standpoint, using standard estimating methods and published data, to present a reference point for cost estimates for nonbauxite alumina processes. The estimated operating cost for a plant producing 1,000 tons of alumina a day is $47.96 per ton of alumina when charging $8 per ton for bauxite and $2.30 per hour for direct labor. The estimated fixed capital cost is $46 million.

Jan 1, 1966

By Michael G. Zabetakis

Investigation of gas explosions usually reveals that the combustible gases have come from transmission and storage facilities or from natural gas or oil wells. However, combustible gases such as methane and hydrogen can derive from biological processes. Hazardous situations have been created in the past by the use of abandoned mines for the disposal of sewage and rainwater, by the interconnection of storm and sanitary sewers, by sealing the openings in manhole covers when repaving the roadway over a sanitary sewer, and by the construction of buildings over or near garbage fill areas without adequately providing for the release of combustible gases.

Jan 1, 1962

By Arnold B. Hubbard

This report presents a hydrogenolysis study undertaken to obtain information on the constitution of the kerogen or organic material in Colorado oil shale and to determine some of the properties of the hydrogenolysis products. The high yield of hydrogenolysis products was separated, so far as possible, into type compounds; a number were identified. The results thus obtained were used as a basis for proposing the possible existence of certain structures in kerogen. To the authors' knowledge, few or no hydrogenolysis studies have been made of Colorado oil-shale kerogen by others. However, this method has been used in studying the constitution of coal. In general, the coal studies involved treating pulverized coal at different temperatures and hydrogen pressures with different catalysts. In some instances different solvents were used during the treatments.

Jan 1, 1959

By L. K. Weaver

The purposes of this Bureau of Mines report are to review the history of the domestic offshore hydrocarbon production; to project offshore oil and lease condensate production from 1971 through 1985; and to show the impact of offshore development on the onshore segment of the petroleum industry. Since 1954, offshore production has provided an increasingly larger portion of the domestic oil production. Domestic offshore oil and lease condensate production has increased from about 2.0 pct of the U.S. total in 1954 to 16.7 pct in 1970. Likewise, marketed gas production has increased from 1.0 pct of the U.S. total in 1954 to 15.0 pct in 1970. The past performance of exploration, leasing, development, and production of the offshore petroleum industry was used to make projections of offshore oil production. A comparison between onshore and offshore operations was also made. Assuming a tentative Department of the Interior offshore leasing schedule is completed by 1980, the authors estimate that by 1985, about 30 pct of domestic crude oil and lease condensate production from the lower 48 States will come from offshore areas. Currently, leasing of Federal offshore areas has been delayed due to environmental considerations. The rate at which off-shore hydrocarbons will enter the energy market will depend, to a large extent, on how soon environmental considerations are resolved. Assuming that offshore leasing will resume in the near future, U.S. offshore production of crude oil and lease condensate should be about 934 million barrels in 1985.

Jan 1, 1973

By Robert K. Koch

The Bureau of Mines investigated separating HF from HF-SiF4-H2O mixtures by passing the mixed gases through a sodium fluoride slurry in an airlift scrubber and forming a mixed precipitate of NaHF2 and Na2SiF6. The oven-dried precipitate was thermally dissociated in two stages. The first stage was carried out at 400° C and dissociated NaHF2 to NaF and HF. Condensation and analysis of the evolved HF proved it to be 97 to 99 weight-percent HF containing 0.79 to 0.99 weight-percent H2O and 10 to 93 ppm silicon. The second stage was carried out at 700° C and dissociated Na2SiF6 to NaF (for recycle) and SiF4. The quantity of HF recovered from gaseous HF-H2O-air mixtures decreased with increasing relative H2O concentrations. Air was beneficial when scrubbing extremely dilute wet HF gases. At HF partial pressures of 0.24 and 0.013 mm Hg in the scrubber entrance gases, HF partial pressures of 6.2 x 10-4 and 9 x 10-6 mm Hg were obtained, respectively, in the scrubber exit gases. Scrubber efficiencies were 99.7 and 99.3 percent.

Jan 1, 1966