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By R. Batterham

"The history of mineral processing is indeed long and has always been tied to mining methods of the day. While many new processes and devices have been developed, the most significant trend in recent times has been the ever increasing scale of operations. There is serious doubt this ongoing trend is enough to match the global trend of falling grades and rising energy demands needed for mineral processing. As well we see that globally, the social licence to operate for mining (and hence mineral processing) is far from secure. Indeed, some argue that mining as we know it is dying and in the future, mining will be much more environmentally secure, even to the extent of insisting upon “in place” recovery and only bringing to the surface the valued product. In this paper we comment on the ramifications of broader uptake of more sustainable mining for mineral processing methods and address the specific question of whether recent progress in in place recovery will lead to a timely breakthrough. The answer proposed is that this is possible in the next 10 - 20 years but in the meantime, the focus is just as likely to be on removal of waste much earlier in circuits. Either way, mineral processing as we know it will change significantly. INTRODUCTION Mineral processing has a long history well covered in a recent publication (Habashi, 2006) who points out “the ancient Egyptians knew already that it would be easier to melt an earth rich in gold particles than another which is poor. As a result, all efforts were made to enrich the gold by washing away the light gangue minerals. Similarly, another ancient method for enriching gold particles from a river stream was by means of fleece, hence the Greek myth of the “golden fleece”. Since the middle ages, striving for improved economics has driven a string of innovative developments in milling and separation. The reader is again referred to the informative and illustrative text by Habashi."

Jan 1, 2018

By R. S. Wang, S. Z. Zhou, L. Wan, K. W. Zeng, Z. J. Sun, W. G. Wu, Z. B. Qian, X. R. Zhang, Z. K. Hu, Y. Yu

"In view of the present situation that the traditional environment friendly depressants for galena aren’t very effective in the separation of mixed concentrate including copper sulfide and lead sulfide, this research describes a new environment friendly depressant PD-1 and investigates its effects and mechanism in the separation of chalcopyrite and galena. This study is carried out through flotation tests, analysis of infrared spectra and absorption measurements. It is shown that when O-isopropyl-N-ethyl thionocarbamate (Z200) is used as collector, chalcopyrite and galena can be separated in the presence of PD-1 under appropriate conditions. Therefore, it can be concluded that PD-1 has an excellent depression ability and great selectivity for galena. Meanwhile, analysis of infrared spectra demonstrates that PD-1 can strongly absorb on the galena surface by chemical interaction with Pb2+, while it hardly absorbs on the chalcopyrite surface. In addition, the results of absorption measurements reveal that competitive adsorption occurs on the galena surface between PD-1 and Z200, PD-1 can block the absorption of Z200 on the galena surface. However, PD-1 has a little effect on the absorption of Z200 on the chalcopyrite surface under above conditions. What’s more, the hydrophilic groups of PD-1 molecules can make galena effectively depressed. The results of mechanism analysis are in accordance with those of flotation tests.INTRODUCTION In the processing of copper-lead sulfide ores, the process, copper increase and lead reduction (Zhang et al., 2017) after reagents removal of rough concentrate produced by mixed flotation of chalcopyrite and galena, is usually adopted. However, as a result of tight symbiosis and the similar flotability of chalcopyrite and galena, the separation is difficult (Hu and Feng, 2006). There are 3 kinds of depressants for galena in the separation of chalcopyrite and galena concentrate,including dichromate, sulfite and combined depressants of organic or inorganic reagents (Wei, 2012). As dichromate would cause serious environmental pollution, it is gradually banned to be used in industry (Xu et al., 2017; Lin et al., 2017). what’s more, due to the need of acidic slurry, using sulfite is not conductive to the maintenance of equipment and stable production(Wang, 1999). As for the combined depressants, they also have disadvantages of complex pharmaceutical system and no ideal separation effect (Wei and Sun, 2008). Therefore, the development of new safe and effective depressants for galena is a research focus for researchers in the minerals processing (Chen, 2000). In this paper, a new type of organic depressant PD-1 is applied to the copper-lead separation process of ""copper increase and lead reduction"" using Z200 as the collector. In addition, the performances and mechanism of its depression to galena are studied emphatically."

Jan 1, 2018

By Chanki Jeong, Heechan Cho

In this study, batch flotation experiments were conducted to recover rare earth elements (REE) from an REE ore deposit in the Mushgai Khudag area, Mongolia. Apatite was found to be the major REE mineral while monazite and xenomite were observed as minor minerals. The main purpose was to float apatite to increase the REE content. Oleic acid was used as collector and MIBC was used as frother. Sodium silicate was used as a depressant for iron compounds. NaOH was used to adjust the pH of the flotation to about 9.5~10.0. The particle size was 90% less than 152 ?m (- 100 mesh). The content of REE elements was analysed by ICP - OES to determine the contents of REE such as Ce, La, Nd, Pr and Y. When sodium silicate was used, the best result was obtained using 0.2 mL of sodium silicate, 2 mL of oleic acid and 2 mL of MIBC. Under these conditions, the recovery of REE was about 78% and the grade of the first froth product was 42,995 ppm Ce, 24,088 ppm La, 14,236 ppm Nd, 4,388 ppm Pr and 1,570 ppm Y. When conducting flotation after iron minerals were removed by magnetic separation, a better result was obtained; with 2 mL of oleic acid, 2 mL of MIBC and no sodium silicate, the recovery was increased to 90% and the grade was also increased to 58,600 ppm Ce, 28,624 ppm La, 17,160 ppm Nd, 5,348 ppm Pr and 1,971 ppm Y.

Jan 1, 2014

By S. J. Ma

With the very effective depressant and collector developed by China Bluestar Lehigh Engineering Corp (hereinafter referred to as LEHIGH), satisfied results are obtained from laboratorial beneficiation tests on phosphate samples from Karatau, Republic of Kazakhstan by the direct flotation process. In this paper the effect of single factors on performance of flotation is studied and their applicable ranges are proposed. The final test results are described as follows: As the feed contains 23.20 % P2O5, and 3.96% MgO, a phosphate concentrate assaying 29.77%P2O5 and 1.54% MgO is produced, and the P2O5 recovery in concentrate is 88.28%. The beneficiation tests make it possible to simplify existing technology with fine grinding-desliming, followed by reverse & direct flotation system and consequently improve the concentrate grade and recovery for the future beneficiation plant

Jan 1, 2014

By Stephen Simukanga, Jewette Masinja

"Mining has been going on commercially in Zambia for over 100 years. The backbone of the mining industry has been copper production and its by-products of cobalt and gold. Over these years, the mining industry ownership structure has swung from private ownership to state ownership in 1972, and back to private ownership in 1995. Environmental management was first introduced into the body of Zambian legislation in 1991 through the promulgation of the Environmental Protection and Pollution Control Act (EPPCA). The Act’s main functions included the protection of the environment and control of pollution, and in particular to provide for the health and welfare of the people, animals, plants and the environment in general. This Act, was replaced in 2011 by the Environmental Management Act (EMA). The new Act has a number of new elements including: mainstreaming environment in national planning, it provides for the domestication of multilateral environmental agreements, enhances public participation issue, creates a central environmental information depositary, elaborates access to information principles, establishes an environment fund, creates enforcement orders, provides for both Zambia Environmental Management Authority and members of the public to sue for damages following environmental pollution, and provides for the appointment of honorary Inspectors. In addition to this, the Mines and Minerals Act of 1995 provided, for the first time, a section on environmental management in the mining sector. This section also created the Environmental Protection Fund (for mining), and made it obligatory to undertake environmental impact assessment before mining permits could be issued. The Environmental Protection Fund has now been established, as provided for by the law, and currently has more than USD9.0 million in the account. Secondly, environmental auditing is now being carried out annually on mines around the country, the effect of this has been a significant improvement in the environmental management of mining in Zambia. This paper looks at the response of the Zambian mining sector to these pieces of environmental management legislation, and the direction that the mining sector is expected to take on environmental management going forward."

Jan 1, 2014

By Chen Zhiqiang, Luo Chuansheng, Chen Ziqiang, Liu Jianguo, Rao Jinshan

To comprehensively utilize the valuable resource in tailings, increase the economic benefit of mine, reduce the amount of tailings, prolong the service life of tailing dam, the comprehensive utilization of tailing resource is arousing the attention of more and more mines. Research of comprehensive recovery of feldspar and silica from Cu-Mo floatation tailings has been furthered. Technology of "De-sliming-Magnetic Separation-Reverse Flotation-Feldspar and Silica Separation" has been developed to utilize the resource. Slime is removed and reagents cost is reduced by de-sliming. The specific effective collector ZL is used in gangues reverse flotation, and GZ-818 is the collector in feldspar and silica separation. The grinding operation is vital to ensure the liberation degree of feldspar and to eliminate the reagents pollution on minerals surface. To a Cu-Mo flotation tailing assaying K2O 5.22%, Na2O 2.22%, Fe2O3 1.95%, Al2O3 12.05%, SiO270.66%, superfine K-feldspar and silica concentrates can be produced. The feldspar concentrate productivity is 29.67% assaying K2O 8.99%, Na2O 2.86%, Fe2O3 0.16%, Al2O3 16.99% and SiO2 68.92%. The silica concentrate productivity is 14.20% assaying 0.17% K2O, 0.04% Na2O, 0.01% Fe2O3, 0.55% Al2O3 and 98.17% SiO2. The technology provides technological reference model for the similar mines.

Jan 1, 2014

By N. S. Phala

Declining gold grades, mineralogical complexity of ore bodies, increasing input costs, more stringent conditions in the licenses to operate, and uncertain gold price dynamics combine to exert significant ongoing pressure on margins of gold producers. Innovative approaches of extracting the metal from its ores are required to realize value from existing and future assets. In a conventional gold processing plant, size reduction of mined ore to produce floatable or leachable product is a significant cost contributor. A step change in cost reduction will be attained if radically energy efficient grinding approaches can be developed, replacing tumbling mills. In the path towards that goal, some quick wins are possible through waste rejection before grinding, and pre-treatment of mill feed to reduce grinding energy demands. Gold locked in complex mineralizations puts pressure on margins by increasing cost per oz (typically high $/t and low metal recoveries) in the hydrometallurgical steps. Gold miners are primarily price takers. The current narrow range of gold uses (predominantly investment and jewellery) is not an entirely desirable state. Some diversification into commercial uses would potentially be a price stabilizer. In this paper, promising research directions, some not always fully explored in the gold metallurgy research space, are highlighted to stimulate radical innovation for substantial value enhancements. The author strongly believes a shift from a traditionally conservative and incremental innovation approach to a more aggressive one, across all aspects of the gold metallurgy value stream (processes to products), is what the industry needs. Keywords: gold metallurgy value stream, thiobaccilus ferroxidants, HPGR

Sep 1, 2012

By Ye Junjian

The feed ore is the concentrate of low intensity magnetic separation of pyrite tailings, containing TFe47.47%, S19.41% and SiOpyrrhotite. The exploratory tests showed that using a process of flotation followed by magnetic separation could respectively obtain a sulphur concentrate of S 31.08% with a recovery of 82.89%, and an iron concentrate of TFe 59.97% and S 9.52%with a recovery of 30.93%. The reason of iron concentrates with high sulphur grade was that the sulphur grade of flotation tailings was 7.03%. So enhanced flotation for pyrrhotite was investigated in this research. Results show that when the natural pH of ore pulp varied from 5.5 to 6.0, a reagent combination of FS, LH, and BJ displayed the optimum flotation performance for pyrrhotite. After comparisons made on different flotation processing, the previous flotation flow of ?one roughing, one cleaning, one scavenging system and middling reprocessing?, was found, among others, to have the best flotation effect, as the grade and recovery of sulphur concentrate were 31.08% and 82.89%, respectively, and sulphur content of the flotation tailings was 7.03%. The above results indicated it was difficult to raise further the effect of flotation desulphurization. The authors therefore suggested that oxidizing roast should be adopted following the magnetic process for the purpose of further desulphurization. Besides, flue gas containing SO2 8.25%. And the valuable minerals are magnetite and 2 generated from roasting could be reused for sulphuric acid production. Keywords: pyrrhotite, enhanced flotation, desulphurization

Sep 1, 2012

By Andrei Yevdokimov, Ivan Sidorov, Olga Lanchakova, Olga Khmelnitskaya, Tatiana Chikina

"The paper focuses on the results of the research on development of hydrometallurgical process of gold recovery from refractory sulfide flotation concentrates based on fine and ultrafine grinding. Refractory concentrates (the degree of refractoriness is 16.9%-82.6%) were chosen for testing. The efficiency of the process based on fine and ultrafine grinding to treat flotation concentrates with gold intergrown with sulfides and rock-forming minerals was shown. Based on the test work conducted, the process option was chosen. In included grinding of flotation concentrate to the size of 98% minus 20µm in a bead mill, lime treatment with air blow, CIL, filtration and detoxification of liquid phase of the slurry. This process (compared to the basic option) provides the recovery of gold from 82.6%, up to 94.0% and decreases the residual grade in the tailings from 3.3g/t to 1.1g/t at the consumption of 12.6NaCNkg/t. Based on the results of the test work and pilot plant testing, project design criteria of flotation circuit at a Russian plant was developed."

Jan 1, 2014

By G. Aguilera

The mineral suspensions do not present a newtonian behavior as their continuous phase; they can be pseudoplastic, dilatant, or both. The viscosity becomes as the most important rheological variable because the different industrial processes involve a wide variety of rheological scenes, with a specific rheological behavior for each one. Some authors have tried to model the viscosity of suspensions considering the volumetric fraction of solids and others have also kept in mind the size of the particles (Einstein, 1906; Batchelor, 1977; Jinescu, 1974; Krieger and Dougherty, 1959; Tangsathitkulchai and Austin, 1988). Others consider the shear rate (Cross, 1965; Hershel-Bulckley, 1926; Bingham, 1916, etc). However, none of the models is able to simulate the viscosity involving the physical, chemical and mechanic factors at the same time for crowded suspensions. A new model based on Neural Networks is presented, taking into account all the variables of ceramic clay suspensions and chemical additives. Keywords: viscosity, clay minerals, neural networks, simulation, mathematical function

Sep 1, 2012

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By M. Etelapaa

A new approach to controlling the process of selective flotation of sulphide minerals from pyrite in a lime environment is covered in the presentation. Advantages of process control based on the electrochemical potential of slurry controlled by ?? ? electrode are proved and compared to conventional methods of ?? ? metering and conductometry. Keywords: flotation, electrochemical potential, automation dosing system, neural network

Sep 1, 2012

By A. D. Bas

Copper minerals present difficulties during the cyanide leaching of gold ores leading to excessively high consumption of cyanide (and oxygen) coupled with low extraction of gold. Copper cyanide species, if present at high levels, adversely affects the downstream processes such as the activated carbon adsorption and the effluent treatment. In this study, the extraction of gold from a copper-bearing gold ore by ammoniacal cyanide leaching was studied. Furthermore, ammonia leaching as a pretreatment process ahead of cyanide leaching was also examined. Only ~12% of gold was extracted by direct cyanide leaching of the ore. The addition of lead nitrate did not affect the leaching of gold. When ammoniacal cyanide leaching system was used, the extraction of gold was significantly improved to >90%. Similarly, the pretreatment of the ore by ammonia leaching was shown to lead to high gold extractions (98%), in subsequent cyanide leaching with significant reductions in the consumption of cyanide. This appeared to be linked with the ready dissolution/removal of copper during ammonia leaching.

Sep 1, 2012

By P. Gao, J. W. Yu

"Magnetizing roasting-magnetic separation is an important route for the beneficiation of refractory iron ores. In this investigation, a pilot-scale fluidized magnetizing roasting reactor was introduced and used to study the effects of roasting temperature and the flow rates of reducing gas CO and fluidizing gas N2, on the magnetizing roasting performance of an Anshan-type carbonate-bearing fine iron ore. The results showed that the hematite was almost reduced to magnetite by a gas mixture of 4 m3/h CO and 1 m3/h N2 at a roasting temperature of 540 °C. Under the optimized conditions, a high-grade magnetic concentrate assaying 66.1 wt.% Fe with a recovery rate of 91.2% was achieved from an Anshan-type carbonate-bearing fine iron ore assaying 42.0 wt.% Fe. The XRD, VSM, and optical microscopy analyses revealed that the siderite was successfully converted to magnetite by roasting. Some coarse hematite particles were difficult to reduce to magnetite completely; however, these generated magnetite particles with a fine hematite core could also be effectively recovered by magnetic separation after liberation from gangue minerals due to their strong magnetism. INTRODUCTION Magnetizing roasting followed by low-intensity magnetic separation has been considered as an effective solution, both technologically and economically, when upgrading refractory iron ores (Zhang et al., 2012; Peng et al., 2012; Li and Zhu, 2012). According to the type of roasting reactor, the magnetization roasting can be divided into shaft furnace roasting, rotary kiln roasting, and fluidized bed roasting (Zhu and Li, 2014).Shaft furnace magnetization roasting system is mainly composed of heating and reduction processes. The hematite ore is first heated to 700~800 °C in the heating zone, then falls into reduction zone where the weakly magnetic hematite is reduced to magnetite by coke oven gas at 550~600 °C (Yan et al., 2012). However, several years of engineering practices indicate that the shaft furnace can only process the hematite ores with a granularity of 15 ~75 mm, and the shaft furnace roasting is also characterized by heterogeneity of roasted product. Hence, the shaft furnace magnetization roasting technology is gradually replaced by high-gradient magnetic separation with the development of high-gradient magnetic separator. The rotary kiln generally handles the hematite ores with a grain size of less than 30 mm (Zhu and Li, 2014), however the formation of clinker ring in the rotary kiln will affect the yield of iron resource. In the fluidized bed furnace, the hematite ore is shaken up by an upward current of gas which maintains the individual particles in suspension (Yu et al., 2018). The precise adjustment of the gas velocity to the particle size and the specific weight of the hematite ore, make it possible to generate a floating mixture of gas and solids which behaves almost like a liquid (Yu et al., 2017a). The process is reported to have the following advantages over the other roasting techniques: ease of control due to absence of moving parts within the reactor, homogeneity of roasted products, ability to handle fine particles, and high efficiency of heat transfer and mass transfer (Li et al., 2015; Yu et al., 2017b). However, the simultaneous heating and reductive magnetization of hematite ore occur at the same place in the conventional fluidized bed reactor. Therefore, the reductive atmosphere, as well as the safety and stability of anti-explosion are hard to be controlled. Besides, the roasting temperature for conventional fluidized bed furnace is usually up to 950~1150 °C (Liu et al., 2017). Thus, the formation of clinker ring caused by high temperature will affect the operating efficiency."

Jan 1, 2018

By Q. Shi

An investigation into the hydrophobic aggregation of ultrafine smithsonite in surfactant solution has been undertaken through a combination of hydrophobic flocculation experiments, zeta potential measurements, surface tension measurements, and contact angle measurements. The experimental results have revealed that the behaviors of hydrophobic aggregation were closely correlated with the particle hydrophobicity, but they were not lowered byte change of the particle surface charges due to surfactants adsorption. On the other hand, the liquid (solution) surface tension (?LV) plays an important role in hydrophobic aggregation, and the hydrophobic aggregation could not occur below the critical liquid (solution) surface tension (?c). Meanwhile, this flocculation has been observed to require sufficient stirring strength and magnitudes of kinetic energy input to achieve the maximum aggregation degree. From the microflotation results, it has been found that the flotation kinetics response of smithsonite fines is markedly improved due to sufficient stirring strength, and the stirring strength influenced the floc flotation in a manner quite similar to their influence on the hydrophobic aggregation, suggesting that the formation of hydrophobic flocs is a promising means to recover smithsonite in the fine size range.

Sep 1, 2012

By A. Üçyildiz

Magnesium borates of varying compositions and properties are synthesized using different reagents and methods for the possible potential uses as termoluminescent material, anti-wear and anti-friction additive, fire retardant, catalyst for the conversion of hydrocarbons, whisker material and ferroelastic material. In the current work, the conditions for synthesizing MgB4O7 compound by high-temperature solid-state reactions were investigated using boric acid and magnesium oxide as the starting materials. The MgO:B2O3 mole ratios applied in the experiments were 1:1, 1:2, 1:3 and the thermal behaviours of each mixture were studied between 25~1200°C by TG/DTA analyses under static air atmosphere to find out the probable formation temperature of MgB4O7 phase. Considering TG/DTA results, freshly prepared boric acid and magnesium oxide solid mixtures were heated at predeter-mined temperatures and the phases were identified by XRD analyses. Accordingly, MgO:B2O3 mole ratio of 1:2, heating temperature of 950°C and a reaction time of 2 hours were selected as the optimum conditions for the formation of maximum amounts of MgB4O7. After obtaining solids prepared at the pre-determined optimum conditions, their chemical composition, IR spectrum, TG/DTA pattern, B.E.T. surface area value, particle size distribution and SEM images were deter-mined to point out the possible use areas. Experimental results showed that it was not possible to obtain pure product at the optimum conditions due to formation of minor amounts of t-Mg2B2O5 and the presence of some unreacted B2O3. The product synthesized has the potential for use as a corrosion inhibitor on some metal surfaces.

Jan 1, 2014

By O. A. Bascur

It is difficult to analyse the economics without an integrated view of mine transactions, stockpile inventories, process flows and assays. The lack of integration of mining and metallurgical information with sufficient detail to analyse and act is a problem. However, to take action requires real time information from manufacturing assets, corrected for gross errors from trucks, shovels, conveyors, faulty sensors, bad instrument calibration. Validation methods use process models to identify inconsistent information in the case of corrupt actionable information. This paper presents new strategies that transform the data into business information for continuous improvement and optimization. This technical presentation will review recent implementations enabling large metallurgical complexes to improve their data quality for overall production and energy management. A competence center emerges as an enabler for implementing operational intelligence. The evolution of Web services to troubleshoot plant information and to collaborate at the enterprise level is presented.

Jan 1, 2014

By V. V. Morozov, Ganbaatar Zorigt, Delgerbat Lodoy, Y. P. Morozov

"At the processing plant Erdenet, a new facility for advanced ore diagnostics in-stream (at the conveyor), based on optical analyser of mineral composition, was tested. Such systems provide highly accurate in-stream measurements of ore properties. The system provided information on the ore mineralogical composition, the particle size distribution and the impregnation of minerals. A special flatbed facility for optical spectrum-based estimation of fine-crushed ore has been developed, being incorporated into the existing system of ore sampling and analysis. Application of the flatbed facility renders possible a high accuracy of determining ore mineralogical composition. High precision of the optical spectrum-based estimation is achieved using special devices, installed in the sampling and the sample analysis flow sheet, applied by the technical control department. Modern systems for optical spectrum-based estimation of ore grade provide a basis for effective automated control of ore benefication processes, based on the principle of advanced ore grade control. Process management task of grinding and flotation was to choose options that take into account the composition and grade of the ore coming. The calculation data array comprises consumption of reagents, ore processing, grind size etc. The systems implemented at the processing plant contributed to increasing copper and molybdenum recovery. INTRODUCTION In-stream ore grade analysis is a new trend in effective control of ore benefication processes. This is realised based on radiometric measurements in the X-ray and visible spectrum regions, in which mineral components of the initial ore (Sbárbaro and Villar, 2010) or the benefication products become apparent (Hyotyniemi and Ylinen, 1998; Haavisto and Hyötyniemi, 2010). An important advantage of such methods is in-stream measuring ore parameters, including mass fractions of individual minerals, which makes it possible to use the information obtained in the processes of automated control."

Jan 1, 2018

By Zhen Hu, Chenghang Wang, Jianjian Zou, Xiujuan Li, Hanwen Li, Tai Wang, Baoxu Song

A rare earth deposit in Sichuan, China is rich in wulfenite in addition to bastnaesite and barite, and the deposit has already adopted high intensity magnetic separation technique to pre-enrich the rare earth minerals, during which the wulfenite and barite have been left in the non-magnetic product. Because the chemical composition of wulfenite is only 24.17% Mo and 42.15% Pb, it is very hard to obtain qualified lead or molybdenum concentrates by physical separation process. To pre-concentrate the wulfenite, flotation has been first introduced, and by using 100g/t GY-7 as dispersant, 1500g/t CP-1 as depressant and 160g/t GY-4 as collector, a floatation concentrate assaying 15.52% Mo with a recovery of 86.12% was obtained. Then a leaching process was conducted by using 1.2mol/L Na2S as leaching agent, and molybdenum can be translated into sodium molybdate in the solution with a leaching recovery of 99%. To recover rare earth oxides (REO) and lead from the leaching residue, a magnetic separation process has been conducted. Above all, by the whole process, the molybdenum recovery reaches 86.16% in the sodium molybdate solution, and a lead concentrate assaying 54.59% Pb with recovery of 27.99% could be obtained.

Jan 1, 2014

By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014