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By Martin Kesting

The world wide growth dynamics and the continuously growing demand for energy, results in increasing energy prices. Looking from this point, the efficient exploitation of fossil fuel deposits has become a more important factor to the production of energy raw materials than ever before. This shall be reached by an increase of the automation degree of the bucket wheel excavator in the open pit mining as well as a quality increase of the entire mining process chain. A further optimization of this operation can only be achieved by gathering additional information about the input parameters. The earlier and more exact the description of the input parameter, the greater the effectiveness of the entire process chain. To address this major issue, the RWE Power AG assigned the Institute for Transportation and Automation Technology with the research project "SIMT, Sensory Identification of Material Type and Detection of the Interfaces" [Kes07]. Presently, the control of the bucket wheel excavator is carried out manually by the operator, as well as the visual identification of the different geological layers and the energy raw materials. In this paper, a sensor-system is introduced, which was developed in order to transfer the manual material identification and detection of interfaces into an automatic online procedure. A special challenge and the main focus of this contribution is the integration of this sensor system into a bucket of the bucket wheel excavator. For measuring procedures where direct contact with the in situ material is necessary, the sensor has to be integrated into the bucket. Since direct contact with the material is not necessary, it can be integrated next to the bucket wheel. The results of a preliminary study show that although there is a broad spectrum of sensor technologies for material and interface identification, only a few are suitable for an application in on-line measuring at the bucket wheel excavator. Taking into consideration the demands on the sensor technology, the studies carried out and comparable applications of individual sensor technologies which have already taken place in practice, the integration of the following measuring systems have been realized: ground penetrating radar / reflection measurements, geo electric, resistance geo electric technology. The solution developed in the research project offers for the first time the direct integration of sensor systems into the bucket of a bucket wheel excavator. It will now be possible to test other measurement methods and sensors, not only for the ones already mentioned. As an example the integration of a triaxial accelerometer to measure the solid borne sound and vibrations concerning the cutting of different materials will be shown.

Oct 1, 2009

By P. Wells, P. Quinn

"A moveable flotation miniplant was designed and constructed at the research laboratory of Inco Technical Services Ltd. to address the need for flowsheet development with a limited amount of ore (such as drill cores). It consists of one rod mill, two regrind ball mills, one vibratory screen, 24 flotation cells of various sizes and two Venturi aerated flotation columns. The setup has continuous monitoring capability for pH, dissolved oxygen, oxidation-reduction potential, conductivity and temperature in conditioning tanks and flotation cells. Various options regarding flotation reagents, circuit configurations, and fineness of primary grind and regrind can be readily evaluated. The throughput of the miniplant is 20 – 30 kg/hour ore.Unit operations such as flash flotation, magnetic separation and gravity concentration can also be evaluated as an integral part of an entire flowsheet development.This communication describes the basic design features of the miniplant and some examples of applications are given.INTRODUCTIONInco operates numerous mines in Sudbury and Thompson and will shortly bring the Voisey’s Bay mine into production. It has long been recognized that the ores from different mines or from different depths of the same mine can give different responses in flotation. There is a growing need to properly evaluate the ores before feeding the mill to maximize the return of the mine/mill operation. Inco Technical Services Limited at Sheridan Park, Mississauga, Ontario has developed a batch laboratory procedure to address this issue. The results are considered in the overall economical assessment of new mine operations.For ores that cannot be processed by the existing mill operations or that will be processed by a new mill, it is necessary to develop a flowsheet that can maximize the economical return of the mine/mill operation. While recognizing the importance and contribution of the laboratory batch flotation procedure, it does not generate reliable data for flowsheet simulation and design. A full-scale pilot plant campaign is normally required to obtain the design data but often this is not possible due to a limited amount of ore obtainable from the drill core. A small-scale pilot plant (mini pilot plant or miniplant) capable of processing 20-30 kg/h ore can provide this data prior to a full-scale pilot plant campaign. A miniplant can also be used to optimize the circuit configurations, reagent additions and recycle options of process water before pilot plant work and can be used to test a different flowsheet configuration for an existing mill before re-piping a plant circuit."

Jan 1, 2003

By Jim Truskoski, Alain Bouchard, Andy Kerr, Germain Labonté, Jim Barrett

"Improving mill grade recovery relationships is always good business. INCO’s Clarabelle Mill has just undergone a $16 million process upgrade that was designed to improve nickel recovery by 2%. The “Mill Redesign Project” was completed on time, under budget and delivered the promised improvement in recoveries.This paper describes the methodology of the Mill Redesign Team, details of the process improvements and the critical success factors that helped the team deliver on its promises.With a payback of under one year, the Mill Redesign Project will play a key role in ensuring a competitive edge as INCO embarks on its second century of operation.INTRODUCTIONIt is not uncommon in milling operations to encounter a crisis. That is the point when the process does not behave as expected and fails to respond to the increasingly desperate efforts of the metallurgists and operators. Flowsheet and process changes are attempted and abandoned. With luck, one or more of the changes achieves some mitigation of the original problem or more usually, the original cause of the problem disappears. Regardless, the metallurgist can sit back and bask in the apparent success of his or her endeavours.Less common is when a problem is carefully diagnosed, a team put together to explore all avenues and recommend a path of action that is implemented on time, on budget and immediately delivers on the promises which are sustained over time. This is one such story. It is the story of the Mill Redesign Project at INCO’s Clarabelle Mill in Copper Cliff, Ontario.BACKGROUNDThe Clarabelle Mill was built in 1971 on the southern rim of the Sudbury basin. At that time it was one of four mills operated by INCO in the Sudbury area. During the 1970’s, 80’s and 90’s, the need for increased process efficiency, higher levels of sulphur rejection to tails and the concurrent development of high capacity mills and flotation cells, resulted in the consolidation of INCO’s Sudbury area milling operations into a single, expanded facility at Clarabelle."

Jan 1, 2003

By R. E. Whitehead

"Alkali/alumina and MgO/alumina molar ratio plots graphically portray both chemical and mineralogical changes accompanying potassic, phyllic, argillic, chloritic, and alunitic alteration of quartz monzonites and granodiorites hosting porphyry (as well as lode and greisen) ore deposits. The molar ratio plots can be used to identify different types of alteration. In most cases, the identification based on molar ratios coincides with petrographic data. In those instances where the molar ratio and petrographic identifications do not agree, the mineralogy might need to be re-examined. Hydrothermal alteration studies using trace elements could benefit from the application of complementary alkali/alumina molar ratio plots.Le diagramme des rapports molaires alkali/alumine et MgO/alumine illustre clairement les changements chimiques et minéralogiques qui accompagnent les altérations potassique, phyllique, argillique, chloritique, and alunitique des monzonites à quartz et des granodiorites encaissant les gîtes de type porphyrique, ainsi que des veines et des greisens qui leur sont associés. Les diagrammes de rapports molaires peuvent être utilisés pour identifier divers types d’altération. Dans la plupart des cas, l’identification basée sur les rapports molaires est en accord avec celle basée sur les données pétrographiques. Là ou il y a désaccord entre les rapports molaires et les données pétro-graphiques, il peut être nécessaire de réexaminer la minéralogie. Les études de l’altération hydro-thermale accompagnées d’une étude des éléments traces auraient avantage à utiliser un diagramme des rapports molaires alkali/alumine."

Jan 1, 2009

By R. J. McLeod

"CONTROL STRATEGYThe Lake Dufault Division of Falconbridge Copper Limited has been concentrating a complex copper zinc ore since late 1964. An ARL X-ray on stream analyzer was installed in 1966 for process control. A Digital Equip-ment Corporation PDP8 was added in 1968 for more complete control. To improve the system the computer was exchanged for a Moded PDP-81 in 1971.The new computer is time sharing with 8K core memory and 32K disc storage. A new interface was installed to accommodate 14 X-ray streams and additional analog signals for process control. The system gave us additional capacity and flexibility to make changes in operating programs and control strategy while on line. As the computer is used for process control a modified focal language was chosen as the operating language for ease of operation. This language is more suitable for process control than for statistical work.The main components of the control system are(a) Computer(b) Interface(c) Production Control X-ray Quantometer(d) Teletype terminals(e)Reagent feeders(f) Sample SystemThe operation of the system consists in the computer selecting the various streams to be analyzed by a PCXQ Quantometer. When the flowing sample is presented to the X-ray the intensities of the various elements are read by the computer from analog to digital converter, the assays are then computed. From the tonnage and assays the computer is programmed to determine the amount of reagent added to various parts of the circuit. The computer drives the feeders via the interface for the required amount of reagent. After following a certain sequence the computer prints out the performance and control data on an ASR35 Teletype. The data is printed out approximately every seven minutes. Any des¬ired changes in the program or strategy can be made during operation via an ASR33 Teletype connected to the computer."

Jan 1, 1973

By Jiwen Zhang

Abstract Due to the blocking nature at the crusher station, straightforward application of queuing theory cannot give realistic results on the performance of a shovel-truck-crusher system. A new queuing network-based model has been developed in which, the crusher station is formulated into an open queuing network and the whole shovel-truck-crusher system into a closed queuing network with the crusher station as a special server. To fully account for the influence of blocking, Monte Carlo simulation is first used to obtain the performance parameters of the open queuing network for the crusher station. The closed queuing network for the entire system is solved by applying the Extended Summation Method (ESUM), in which the crusher server is described by the simulation results. The model has been applied to the Yuanbaoshan open-pit coal mine to analyze its shovel-truck-crusher system and to improve its efficiency. Results indicate that the blocking at the crusher is an important factor affecting the crusher output and in turn the efficiency of the whole system, and prove that the model can realistically describe the behavior of such systems.

Oct 1, 2009

By Jiwen Zhang

Due to the blocking nature at the crusher station, straightforward application of queuing theory cannot give realistic results on the performance of a shovel-truck-crusher system. A new queuing network-based model has been developed in which, the crusher station is formulated into an open queuing network and the whole shovel-truck-crusher system into a closed queuing network with the crusher station as a special server. To fully account for the influence of blocking, Monte Carlo simulation is first used to obtain the performance parameters of the open queuing network for the crusher station. The closed queuing network for the entire system is solved by applying the Extended Summation Method (ESUM), in which the crusher server is described by the simulation results. The model has been applied to the Yuanbaoshan open-pit coal mine to analyze its shovel-truck-crusher system and to improve its efficiency. Results indicate that the blocking at the crusher is an important factor affecting the crusher output and in turn the efficiency of the whole system, and prove that the model can realistically describe the behavior of such systems.

Oct 1, 2009

By J. A. Finch, A. R. Laplante, R. Espinosa-Gomez

"The Niobec concentrator rejects up to /5% of the Nb as slimes (-10u.m). The recovery of Nb from these slimes by column flotation is being studied. An essential condition for selective flotation is slimes dispersion. A particle size analyzer, the Sedigraph 5000D, was used to monitor dispersion in plant waters with combinations of organic and inorganic dispersants and flotation reagents. Flotation reagents were particularly detrimental to dispersion with sodium silicate. The best dispersion conditions were selected for column flotation tests. These tests revealed that reagent combination had a pronounced effect on froth stability. Careful frother selection achieved good froth stability under conditions of good dispersion. Plant water increased the required dispersant concentration causing mineral depression.IntroductionSlimes (-10 u.m) rejected at Niobec contain up to 15070 of the over-all Nb content . Recovery of Nb from these slimes would significantly increase over-all recovery. A suggested recovery route involves two phases: (1) carbonate flotation (to remove most of the carbonates) depressing silicates and pyrochlore (as currently done at Niobec); and (2) selective (direct) pyrochlore flotation from the silicates. Phase 2 has been addressed and several routes to achieve selective flotation are available. Phase I was attempted with the selective reagent scheme used at Niobec but a considerable amount of pyrochlore floated with the carbonates due to poor slimes dispersion."

Jan 1, 1987

By Martin Murenbeeld

Outlook: Nine Bullish Arguments 1. Global fiscal and monetary reflation: PIIGS, US, etc. 2. Global imbalances: the dollar must decline 3. Global FX reserves are ?excessive?: diversification 4. Central bank attitudes to gold: now positive 5. Gold is not in a bubble: room to rise 6. Mine supply is flat: ?peak? gold? 7. Investment demand: long-run uptrend 8. Commodity price cycle: many years to run 9. Geopolitical environment: positive

May 1, 2010

By S. Belair, V. Weigel

As a growing mining company, ERAMET is looking for new positions on the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earth elements (REE), and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by already known practices, from both technical and economic points of view. In this context, ERAMET has developed since 2008 an innovative hydrometallurgical process which has been successfully operated at a pilot plant scale. While the upstream part of the process aims to dissolve the valuable elements in sulphuric acid, the downstream part of the process aims to recover them separately in a marketable form. The focus here will be on the recovery of the REE. The ore deposit contains approximately 1.4% of REE including 87% of light REE and 13% of medium-heavy REE. The challenge in this process lies in the fact that the major elements in the matrix are iron and aluminum. An innovative process has been developed in order to recover all of the REE in these unfavourable conditions, described in this paper.

Jan 1, 2014

By Dave Bulled, Chris Bennett, Glenn Kosick, Glenn Dobby

"Mining companies around the world are embracing geometallurgical modeling at a rapid rate, as senior executives realize that inputs must be properly measured if the output is to be managed effectively. Geometallurgical modeling is used to scientifically manage risk in project evaluation, for plant design and production forecasting, and optimization of production planning and mineral processing/metallurgical unit operations. The technology also provides a solid foundation for implementing broad corporate strategies with respect to intelligent asset utilization and metal sales. Over the past five years, MinnovEX Technologies Inc. has been actively engaged in developing, promoting and applying geometallurgical modeling technology for major mining companies around the world. This paper describes the methodology for successfully applying the technology for the unit operations of comminution and flotation in the mining industry.INTRODUCTIONGeometallurgical modeling (referred hereon as geomet modeling), in theory, can be applied to its full potential on all unit operations in mineral processing; however, this paper will concentrate on two of the largest unit operations, namely comminution and flotation, where the technology is actually being practiced by many large mining companies. For concept studies and prefeasibility studies, aspects of geometallurgical technology are regularly applied but in a less rigorous manner than for final feasibility studies where justification for funds is sought. This paper will focus on the final feasibility stage of a project and on existing operations or planned expansions, where the full power of geometallurgical technology is brought to bear in a cost effective manner.One of the unique aspects of geomet modeling, when used to its potential, is the ability to design plants, and forecast and plan production with a quantifiable degree of precision, something that was unattainable in the past. This means that when new comminution and flotation plants are designed, the mining companies and financial institutions involved in the project can measure the precision of the design and therefore better understand and manage project risk. It means that for existing and new operations, metal sales personnel can carry out their sales strategies with a much better understanding of the degree of error associated with production forecasts of concentrate/metal and quality of concentrates. For mine and mill managers, geomet modeling allows the effect of the mine plan on the downstream processes to be quantified; thereby allowing the mine plan to be recast in a more optimized manner. Finally, existing concentrator personnel can optimize their unit operations based on a more definitive understanding"

Jan 1, 2004

By Euler De Souza

The authors conducted a study of backfill practices in underground mines across Canada to assess the current state of backfill usage and to overview potential hazards associated with backfill practice, from preparation to transportation to placement. The primary aim of this study was to cover each component of a typical mine backfill system, and to identify potential incidents leading to the disruption of backfilling operations and any associated corrective actions. This paper, Part I of the study, deals with surface operations consisting of backfill material supply and backfill plant preparation. Part II of the study, which deals with underground operations consisting of backfill transportation and backfill placement, is also presented in these proceedings. A review of safety measures associated with current backfill operations and recommendations for procedures of best practice that should be implemented to reduce fill-related hazards in all mine backfill workplace environments are presented. In general it has been found that system failures normally lead only to minor losses to the operations.

May 1, 2009

By S. Schwartz, T. Bilney

"Over recent years a number of techniques have been developed as part of the AMIRA1 P9 project to represent mathematically or measure directly sub-processes occurring in flotation cells. These include the determination of:•,?a machine parameter (bubble surface area flux, Sb);•,?a froth parameter (froth recovery, Rf );•,?entrainment and drainage parameters (???and d); and•,?an ore floatability parameter (Pi).These flotation parameters allow the plant engineer to develop a model of the flotation circuit that can be used as a powerful tool to diagnose the performance of that circuit. The recently developed JKSimFloat V6 flotation simulator uses these parameters to predict the flotation circuit performance that would arise from changes in operating conditions and circuit configuration.This new flotation technology was applied to the Placer Kanowna Belle Gold Mine in Western Australia. A series of plant surveys, cell characterisation measurements and laboratory batch tests were conducted to determine the flotation circuit model parameters to be used within the JKSimFloat V6 simulatorA thorough flotation circuit analysis was then performed at Kanowna Belle using JKSimFloat V6. The recommendations that were provided by this circuit analysis have resulted in large improvements in the flotation performance at Kanowna Belle. These include a 1.3% increase in flotation gold recovery and a substantial decrease in operating costs. The analysis is still ongoing, however, the benefits already obtained from applying this technology have resulted in a US$1.3 million a year improvement to the mine."

Jan 1, 2005

By Lee Nichols

Convergent Bitumen Recovery Context of discussion It should be noted that the CBR process is a conceptual bitumen recovery feed methodology, designed to provide supplemental bitumen to the oil sand operations of Northern Alberta. To date the following have beencompleted. ?Bench Scale testing. ?Peer group brainstorming. ?Energy Balance ?Confidentiality agreements have been signed with several companies Discussions are ongoing with industry and although conceptual atthis stage the process holds significant promise.

May 1, 2007

By James A. Finch

"I offer a personal view of what the next 30 years holds for mineral processing. Re-stating that mineral processing will remain a vibrant industry in raw material production, growth opportunities in waste management are identified. The processing sequence familiar now (mining -mineral processing -extraction) will become more interwoven. In situ processing (i.e., milling underground) will evolve from concept to demonstration. Opportunities to exploit physical properties altered in chemical (pyro-and hydro-) processing will present themselves. In primary grinding, the path to AG/SAG milling will progress with little deviation but opportunities in regrinding are wide open. Flotation will see the trend to designing bubble/particle reactors accelerate simultaneously with a vigorous response from mechanical cell suppliers. Gravity separation remains a bastion of the lone inventor but I anticipate that the new lines will come from the waste management business. I finish by examining the ""research cycle"", identifying growth in small ""high tech"" companies and university research centres.IntroductionI have been asked to offer a personal view of""where we are going in mineral processing?"". Gazing into crystal balls is quite a cottage industry as we approach the end of the millennium. Academics are often asked to assume the role of visionary, I presume because it is considered in their mandate, to reflect and philosophize (or, less charitably, because they are considered to have the time). Since this is the 30th Annual Canadian Mineral Processors Operators Conference, I am tempted to suggest the next 30 years as my frame of reference. This is about equivalent to one engineer's career or, given it takes typically 15 years to go from concept to realization in mineral process engineering (Napier-Munn, l 997a), about 2 ""invention cycles"". With this length of cycle, much that is familiar now will remain so over the 30 years.Research and development (R&D) is in response to need. The overarching need in mining is to find new ore bodies. Process developments cannot compensate for a depleting deposit or a declining commodity price. Mineral processing R&D is characterized by incremental gains, aimed at pushing the mine down the cost per tonne league table. Breakthroughs are the exception (flotation at the turn of the century was one). This must be kept in mind when trying to predict the future in our business."

Jan 1, 1998

By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011

By V. D. del Valle, T. G. Joseph, J. J. Berezan

Aggressive driving patterns, rough and poorly maintained roads and pit floors, along with the occasional bump and poorly placed load from a shovel can create intense and sometimes serious vibration levels on a heavy hauler. The effects of high vibration have been shown to be of concern for the health of the operator as well as the reliability of the equipment. It is proposed that an onboard vibration warning system based on the ISO 2631-1 standard could be used to help operators reduce the vibration levels experienced in a heavy hauler. The onboard system would consist of a screen that displays the instantaneous vibration in the form of three lights: green (safe zone), yellow (cautious zone), and red (danger zone), as well as an overall vibration exposure or dose for the entire shift. With the utilization of the warning system, it is anticipated that the overall vibration levels will be decreased resulting in improved operator health, a reduction of vibration-induced maintenance, and improved haul roads through reduced impact loading and repair for localized trouble areas.

Jan 1, 2004

By W. L. Thayer, K. A. Jonasson, R. D. Coleman, J. D. Hazlett, C. E. Capes

"Loss of coal fines in reject slurries limits the yield of coal cleaning operations. Difficulties in handling fines also limit the extent of physical cleaning in treating coals with finely-disseminated impurities. Selective oil agglomeration allows even extreme fines to be processed and offers some novel approaches for coal cleaning and utilization.The oil agglomeration process for the recovery and beneficiation of fine and ultrafine coal has now been commercialized by the Chemical Engineering Section/Chemistry Division of the National Research Council (NRC). This paper describes these activities to apply oil agglomeration and related fine coal technologies on an industrial scale. Pilot plant and large scale results are described, as well as aspects of agglomerate utilization in both wet and dry form."

Jan 1, 1988

By R. S. Simkus, J. R. Egan

"Changes have recently been applied to the Sullivan Concentrator lead and zinc circuits to treat fine-grained ores which make-up the majority of ore reserves in the mine. Pilot plant test work conducted in 1990-91 indicated that concentrate grades would be substantially improved by reducing the particle size (P,0) of the lead from 38 to 15 µm and the zinc from 45 to 24 µm.Circuit revisions involved installation of major new equipment including: two GUO kilowatt Vertimills for regrinding, a 4 metre diameter column flotation cell and a 4 metre diameter hyperbaric pressure filter for dewatering. Duties of the existing regrind mills were reassigned.IntroductionThe Sullivan ore body is a massive sulphide deposit consisting of fine grained mixtures of sulphides, sometimes inter-banded with country rock and varying widely in their content of lead, zinc, iron and silicates. Principal economic minerals are marmatite and galena. Iron is mainly present as pyrrhotite (85%), and to a lesser extent as pyrite (15%) .The orebody has been actively mined since 1923, with 1992 ore reserves estimated at 15,800,000 tonnes with an average grade of 4. 7% lead and 7. 9% zinc. Current plans call for treatment of 1,600,000 tonnes/year, (7,000 tonnes per operating day), with flotation feed grades of 5.9% lead, 10.1% zinc, and 22.0% iron."

Jan 1, 1994

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016