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By M. Dupuis

It has been previously demonstrated [l] that there is no obvious thermal balance related issue limiting the size of a Hall-Héroult cell. Yet, it is well known that a forced-air sidewall cooling system is part of the AP50 cell design [2], In the present study, the authors analyze the impact of thermal loading on the mechanical deformation of high amperage cell potshells. The effect of adding cooling fins or a forced-air sidewall cooling system is then assessed.

Jan 1, 2005

By H. R. Shakeri, R. Mayer, M. J. Worswick, A. Rahem

The current focus of research and development in transportation industry is to use lightweight materials such as aluminium alloys for more structural components. In this regard, maintaining safety of the passenger and vehicle is the most important; therefore crashworthiness of components made of lightweight materials must be evaluated prior to sizable application of these materials. The focus of the present study is to understand failure and damage mechanisms during the axial crushing of aluminium tubes made of A1Mg3.5Mn alloy of 2 and 3.5 mm thickness. Due mainly to complexity of the crushed tubes, a microstructural approach is considered. In this study optical, stereo as well as scanning electron microscopy techniques have been used to study damage and failure mechanisms in these types of tubes, which are essential energy absorbing components in passenger vehicles.

Jan 1, 2006

By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012

By Samuel B. Rombeger

The behavior of gold in hydrothermal systems is evaluated as a function of pH and oxygen and sulphur activities at temperatures to 250°C. Under conditions of stability of pyrite and argillic alteration as emblages, gold will be transported as bisulphide complexes. In systems containing significant amounts of arsenic, thioarsenide complexes may be important. Oxidation, dilution and reduction in sulphur activity would cause gold deposition from saturated solutions under these conditions. Gold chloride complexes will predominate under oxidized conditions where hematite or other oxides are stable and depo ition would result from increase in pH and/or reduction . Absorption and coprecipitation are po sible mechanisms of deposition for gold in certain low grade depo it . Low concentrations of gold in the transporting solution combined with the ignificant solubility of gold as bisulphide complexes, sugge t hydrothermal solutions rarely may be saturated with gold and coprecipitation with sulphides may be an important initial depositional process. Recrystallization of the sulphides in the presence of the hydrothermal solution would be re ponsible for release of gold to more table ite . Thi mechani m i supported by the close association of gold with pyrite in many hydrothermal gold deposits.

Jan 1, 1986

By V. A. Leão, A. M. Silva, S. M. Bertolino, B. C. S. Ferreira, D. Guimarães

Although not considered a high risk pollutant as compared to toxic metals and acidity, environmental agencies worldwide are proposing regulations to control sulphate in effluents and drainages by setting a threshold value varying between 250 mg/L and 500 mg/L. The aim of this study was thus to compare four different techniques for removing sulphate ions from mining/metallurgy effluents. The first alternative studied was sulphate removal by precipitation as ettringite. Treating a synthetic solution containing 1650 mg/L sulphate at 22±1 ºC resulted in removals close to 85% during continuous precipitation. Sulphate sorption was also investigated using three different ion exchange resins as well as limestone. Fixed bed experiments produced sulphate loadings of up to 70 mg SO4 2-/L resin, at pH 2.0. In neutral wastewaters, limestone is also a potential adsorbent producing a maximum particle loading of 19 mg/g. Sulphate sorption on limestone seems to be an alternative to treating mine waters with sulphate concentrations below the 1200-2000 mg/L range, where lime precipitation is not effective. Subsequently, sulphate removal by sulphate reducing bacteria was also investigated and it was observed that reactor’s hydrodynamic conditions and the choice of substrate are important factors for the process. The different technical aspects of each technology are addressed.

Jan 1, 2014

By Pura Alfonso, Teresa Escobet, Hernan Anticoi, Eduard Guasch, Josep Oliva, Sarbast A. Hamid

"The liberation modelling of mineral particles using mineral liberation analysis have been used in the past to model comminution and concentration processes. In this work this concept has been taken a little further, using comminution and concentration for applying the mineralogical characteristics of particles. This approach is shown using the image analysis, mineral liberation analysis and the distribution density functions for liberation modelling. The work focused on the effect of comminution on mineral liberation for liberation modelling. To model this, effect the mineral liberation of the particles using distribution density and the cumulative distribution was linked to the image analysis of the ore particles. These properties have been estimated by statistical measures such as the distribution density and liberation grade, which were extracted from MLA data and images analysis, using proper image analysis and techniques based on MATLAB software. A comparison of different tungsten ores of liberated particles, has been introduced and evaluated by estimated results and image analysis.INTRODUCTION The chief economic minerals of tungsten are wolframite [(Fe,Mn) WO4] and scheelite(CaWO4), and approximately two-thirds of the world tungsten reserves consist of scheelite deposits (Lassner and Schubert, 1999). Tungsten has unique properties and is widely used in various industrial high strength and high temperature applications. It occurs coarsely aggregated in low grade ores. Most of tungsten ores, particularly scheelite, wolframite and ferberite, occur in deposits with very low content of WO3 (0.1–2.5%) that is not economically viable to apply directly metallurgical methods to extract tungsten (Martins, 2014). Tungsten is considered as a critical metal by the European Union by the economic importance and also the high supply risk (European Commission, 2014; Chakhmouradian et al., 2015).Currently, scheelite is playing an increasingly important role in tungsten industry because the mineral reserve of wolframite is getting depleted after gradual exploitation and utilization (Min et al., 2016). In mineral processing, the liberation of valuable mineral from the gangue determines the efficiency of subsequent separation processes. The liberation characteristics of an ore are primarily dependent on its texture, the association of mineral in the host matrix of gangue minerals, and to some extent on the grinding process (Zhang and Subasinghe; 2013)."

Jan 1, 2017

By H. M. Lima, L. A. Gomiero, C. A. de Morais

ABSTRACT The Caetité-Brazil uranium facility produces approximately 400 tonnes U3O8 per year from an ore averaging 0.29% U3O8. The process steps are ore crushing, heap leaching with sulphuric acid, uranium separation and purification by solvent extraction (SX) with a tertiary amine, followed by stripping with a sodium chloride solution, precipitation as ammonium diuranate (ADU), and product drying. A change in the milling process is being evaluated to increase production and uranium recovery. Heap leaching will be replaced by conventional agitated tank leaching of the –590 µm ground ore slurry in a sulphuric acid medium. Replacement of the stripping reagent is also being considered.

Jan 1, 2012

By Atsushi Sainoki

Blast vibration induced by mining activities, such as stope production blasts, could lead to the initiation of seismic events that inflict damage to mine openings. In this paper, the effect of stope production blasts on nearby fault is examined. First, validation of blast vibration attenuation is performed with a numerical model representing a single blast hole through comparison with that calculated from charge-weight scaling law derived from in-situ data. Subsequently, a mine-wide scale model with a fault parallel to a steeply dipping, tabular ore deposit that is mined out with sublevel stoping method is generated, and the stopes are extracted and backfilled with static analysis to simulate burst-prone conditions on the fault. Based on the stress states, dynamic analysis is performed, in which blast vibration is applied to grid points on a stope wall on the hanging wall side. This assumes 9 blast holes located close to the wall, and blast-induced particle velocities that consider the positional relationships between the assumed blast holes and the stope wall are applied. During the dynamic analysis, blast sequence is considered, and stress states and shear displacement on the faults are examined. It is found from results that, after a rise in normal stress on the fault due to compressive waves induced by the blasts, the normal stress decreases because of the reflection of the compressive waves on the fault. The reduction in the normal stress due to the reflected waves is found to be large enough to cause the fault to slip. The results also show that the level of normal stress eventually keeps decreasing with time as the blast sequence proceeds and that an increase in shear displacement on the fault is accompanied by a decrease in normal stress. This study clarifies the mechanism by which blast vibration causes the fault to slip. In addition, the simulation technique to apply blast vibration that takes into account blast sequence and the locations of blast holes to a stope wall is developed.

Aug 1, 2013

By M. G. Manzone

Approximately two-thirds of the annual 210,000 tons at copper refined by AMAX Inc. at the United States Metals Refining Company in Carteret, New Jersey, comes from a wide variety of copper scrap ranging from low-grade smelter scrap to wirebar-grade material. The equipment and methods used to effect such large-scale metal recycling in an urban area and the measures taken to collect and recover metal values from smelter and refinery byproducts while protecting the environment from pollution are described and discussed.

Jan 1, 1977

By Nicholas J. Welham

"The effect of extended ball milling has been studied for two industrial processes: (1) the processing of metal sulphide concentrates; and (2) the carbothermic reduction of ilmenite to synthetic rutile. The plant concentrates were a gold ore with 128 g/t Au of which 8% was non-refractory and a zinc concentrate with copper impurities.The gold concentrate showed complete dissolution of the gold bearing minerals after milling giving almost complete gold liberation. The zinc concentrate showed almost all of the sulphides had solubilized leaving the gangue and elemental sulphur. A study of pure pyrite and arsenopyrite shows that selective dissolution should be possible by a simple leaching process directly after milling.The milling of ilmenite and coal together results in a temperature decrease of 150°C in the subsequent carbothermic reduction of ilmenite, in addition to improving both the rate of reaction and the selectivity of reduction to rutile. IntroductionAlmost all mineral processing plants use mills for the size reduction of particles prior to physical and chemical processing. When continuing beyond size reduction the energy transferred causes deformation, breakage and realloying of particles giving a steady-state particle size. The breaking also causes increasing damage to the crystal structure by formation of smaller grains giving an increasing number of grain boundaries and increasing crystalline defects due to deformation. The increasing number of grain boundaries and defects leads to increased reactivity, which can be seen directly by a reaction within the mill, or indirectly, via a decrease in the subsequent annealing temperature required for reaction."

Jan 1, 1997

"The Australasian Joint Ore Reserves Committee (JORC), which is sponsored by the Australian mining industry and its professional organisations, developed the JORC Code to provide minimum standards for public reporting. JORC was first published in 1989 and later incorporated into the Listing Rules of the Australian and New Zealand Stock Exchanges making compliance mandatory for listing public companies in Australia and New Zealand."

Jan 1, 2003

By Norman Orr, J. W. Gregg, Jack Wahl

The Pembina Cardium pool is a low permeability, stratified, solution-gas drive reservoir. Water-flooding has proven to be an effective means of pressure maintenance for all areas of the pool in which an economic rate of water injection can be maintained. The majority of water injection wells in the pool are converted oil well~ with capacities greater than 100 millidarcy-feet. If the average injection rate per unit of capacity can be in-creased the lower capacity areas of the pool can be economically flooded. Theory, laboratory work, and two . early miscible-flooding projects with-in the pool suggested that average water injection rates for converted wells could be increased two to three-fold by the initial injection of natural gas liquids and natural gas. How-ever, these two early projects received volumes of natural gas liquid!:' and high-pressure natural gas which would be economically prohibitive for routine stimulation. Area D, one of the Five-

Jan 1, 1962

By N. Campbell

"The fault under consideration follows a northerly trend past the west; side of the original settlement of Yell ow knife; which is situated 600 miles; north of Edmonton and 400 miles from the Northern Alberta Railway; terminus at Waterways; Alberta. The mining properties chiefly concerned; include the southern part of the Giant claims; on the east side of the fault; and the Con-Rycon-Demelt claims; on the west side 3 1/2 miles to the south.; Geological data were also obtained from the eastern part of the A.Y.E.; property; which lies south of the Giant claims; and from the Negus; Meg; Yellorex; and Kam properties; which are south and southeast of the ConRycon-; Demelt claims (see Frontispiece; also Fig. 5).Recognition of the major faults in the Yellowknife Bay area, including the West Bay fault, which appears to be the greatest, resulted from the work of A. W. Jolliffe (formerly of the Geological Survey of Canada) in 1935 and subsequent years. It has been stated with little exaggeration that these faults rank with the largest known steeply dipping dislocations of the earth's crust.In the winter of 1939, a mineralized shear zone named the 'Creek vein' was found on the Giant property. It was noted that the space relationship between this shear zone and a body of quartz-feldspar porphyry is roughly the same as that between the Con C-4 shear zone and a body of acid flows lying north of the Con property. Coupling this relationship with the assumption that the movement along the fault is dominantly horizontal, it was postulated that the Giant shear zone represented the faulted extension of the Con C-4 shear zone.As geological information became more extensive, certain weaknesses in this concept became apparent, and when spectacular orebodies were discovered on the Giant property in 1944 the question of possible faulted extensions became an important consideration. Consequently, in the spring of 1944, an extended investigation was undertaken, the results of which are embodied in this paper."

Jan 1, 1954

By Alan Bauer, Melvin A. Cook

Measured detonation pressures of "prills and oil" (94/6 ammonium nitrate/fuel oil) and three of the new "slurry" blasting agents are presented and compared with computed, ideal detonation pressures and with detonation pressures expected from the measured detonation velocities. Results seem to show that the peak pressure in the detonation wave in these cases is the Chapman-Jouguet pressure and that no "spike" exists in these detonation waves. The absence of the Zeldovich-von Neumann "spike" is noteworthy in view of the very long reaction zone lengths of these mixtures. The measured detonation pressure of one of the slurry blasting agents (DBA-3") under steel confinement ( 172 kilobars) is shown to be considerably greater than the ideal detonation pressure of 75 per cent gelatin dynamite (p. = 135 kilobars) despite the fact that the detonation was still somewhat non-ideal in "DBA-3," its computed ideal detonation pressure being 180 kb. The popular 94/b AN /FO blasting agent exhibited a detonation pressure of only 13.5 kb in 5" paper tubes, but 37.5 kb in 5"• steel pipe compared with a computed ideal pressure of 40 kb.

Jan 1, 1961

By Edouard Asselin, Tasawar Javed

The precipitation of hematite from ferric sulphate - cupric sulphate - lithium chloride acidic solutions was studied in a batch reactor. The effect of several variables on the extent of hematite precipitation as well as on its crystallinity and purity was investigated. The variables studied include: initial ferric concentration (1.5 - 30 g/L), retention time (0 - 12 h), initial sulphuric acid concentration (0 - 30 g/L), temperature (150 - 220 °C) and chloride concentration (0 - 25 g/L). The results show that hematite is preferentially precipitated at lower initial iron concentrations. Longer retention times increased the fraction of hematite in the precipitates but did not affect its crystallinity to a significant extent. On the other hand, higher temperatures increased the purity and crystallinity of the hematite. At lower acid concentrations hematite and goethite were precipitated. However, only hematite was precipitated when the initial acid concentration was > 12.5 g/L. Better crystalline hematite was formed at lower acidities. Increasing chloride concentration increased the amount of hematite and decreased the amount of iron sulphate hydroxide phases, but did not affect the crystallinity of the hematite.

Jan 1, 2015

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

"For the Kazchrome DC Ferrochrome plant, SMS-group specifically designed an electrode column that would minimize downtime. Special features include the possibility for on load electrode jointing, on load slipping, and back-slipping. Electrode consumption is strongly related to furnace load and impedance, and is very low at high loads, which makes the graphite electrode an alternative to consider even in AC applications. The electrode could also be applied in other DC applications, as for example TiO2 slag, the novel Conroast process, or (twin) DC FeNi furnaces, and could possibly be installed during bigger shut downs. This paper will describe some of the design considerations and operational performance data on this novel column in the FeCr industry that could also be of interest for the FeNi or PGM industry if these would continue to develop towards DC technology.INTRODUCTION Every DC furnace has a cathode and an anode. The anode applied is commonly known as the Concast design, though the original design was by ABB who handed it over to Concast, subsidiary of the SMS-group. Some well-known DC furnaces outside the steel industry where the Concast bottom has been installed are listed in Table 1 as well as a few other key design features.Sidewall cooling and some other data have been left out for reasons of space, and being a lesser relevant design feature to this paper. HES stands for Hollow Electrode System, in which feed is charged through an electrode. Table 1 is built up chronologically according to first start-up date. Below comments are given to briefly explain some of the columns in Table 1: •,“Arm” in the “Cathode” column means that the design of the cathode holding and regulating mechanism consists of an electrode arm as depicted in Figure 1. •,Charging is relevant as some operations started with HES charging, whereas recently most new operations have started without HES but only charging chutes, of which at least some are close to the electrode and possibly others installed closer to the sidewall. •,“Dome” in the “Roof” column means that the design of the roof involves a center piece that can be exchanged if worn. •,The optimal roof design still seems to be a topic of debate, where no design is without problems."

Jan 1, 2017

By S. Joshi, E. Asselin

An electrochemical quartz crystal microbalance (EQCM) was used to study the leaching of pure gold in deaerated 1 M Na2S solution. Multiple cyclic voltammograms were measured between -0.76 and 1.242 V (SHE) at 20 mV/sec and 2 mV/sec and the frequency shift of the quartz crystal was simultaneously measured. Both the forward and reverse scans showed oxidation occurred between -0.40 to 0.20V. The frequency shift increased during both the forward and reverse scans in the potential range of -0.40 to -0.06 V indicating electrode mass decreased. Since at -0.40 to 0.20 V oxidation peaks were also observed, part of the oxidation was due to oxidation of gold. Eh-pH diagrams were constructed and showed soluble Au(I)-S(IV) species formed between -0.30 and 0.10 V (SHE). Atomic absorption spectroscopy of the test solutions and the mass change recorded by EQCM both showed about 0.015 mg of gold leached. Since the majority of the frequency shift increase corresponding to gold oxidation occurred at -0.40 to -0.06 V during multiple cyclic voltammogram measurement, the total leaching of gold could be approximated to occur at this potential interval to give a leaching rate of ca. 6.4x10-5 mg/s-cm2.

Jan 1, 2011

By Desmond Y. M. Lee

This paper presents a procedure to prepare input for the computerized pit design system at Iron Ore Company of Canada. The procedure is simple and requires very little training. Also, it is general enough to accept both bench (horizontal cross section) maps and section (vertical cross section) maps. The output of this procedure is data which represent blocks of ore and waste with dollar values based on mineral content. The ultimate pit design is presented in printer-generated graphs, with numbers indicating the depths of pit bottom walls. Roads are added manually by the engineer with the aid of other computer programs. Section maps and bench maps are also printed as part of the output of the ultimate pit design.

Jan 1, 1978

By R. A. King, B. G. Hunt, C. E. T. White

"This paper reviews the history, occurrence, properties, and uses of indium, and describes the commercial production and fabrication of that metal by The Consolidated Mining and Smelting Company of Canada, Limited (Cominco), at Trail, B.C'. Indium is produced commercially at Trail from dross retreatment furnace D.R.F.) slag, a complex by-product of the lead smelting operations. Furnace feed prepared from this slag is smelted with coke and limerock in an electric furnace. The e1ectric furnace bullion is parted electrolytically, producing a market-able lead-tin alloy containing about 8 per cent tin, and leaving the indium in the anode slime. Recovery of indium from the anode slime involves roasting the slime with sulphuric acid, followed by leaching with water, purifying the leach solution, recovering the indium by sponging with zinc or aluminum, and re-fining electrolytically. This process yields standard grade (99.97+ per cent) indium which is either sold or refined •to high purity ( 99.999 per cent) indium for special uses requiring higher purity metal."

Jan 1, 1959

By M. A. Vos

"Cretaceous sands and clays underlie an area of approximately 5,000 km2 in Northern Ontario, southwest of James Bay. The deltaic deposits occur as a wedge of continental sediments to the north of an east-trending fault scarp referred to as the Precambrian Escarpment. They rest on older sedimentary formations of the Moose River Basin (Jurassic, Devonian) and are covered by glacial tills and marine sediments of the Quaternary period. Outcrops are restricted to occasional exposure in the deeply incised riverbeds.In 1975 and 1978, drill programs sponsored by the Ontario Government provided new information on the extent and quality of the deposits. Fourteen holes at approximately 12-km intervals were drilled to a maximum depth of 189 m by reversed- circulation chip drill methods. Some core was obtained as well. Analytical results show that the thickness of Cretaceous deposits exceeds 100m in several instances. Abundant kaolinitic clay and quartz sand of glass-grade quality, both unique materials in Ontario, are available in an area where hydroelectricity and lignite resources combine to enhance the energy outlook.IntroductionThe presence of refractory clay in deeply incised riverbeds in Northern Ontario was known to geologists travelling the rivers as early as 1875. Robert Bell (1877) reports outcrops of clay and lignite on Coal Brook, a tributary of the Missinaibi River. E.B. Borron in 1880 collected a sample of clay from the bed of the Missinaibi River which H.H. Croft of the University of Toronto considered to be ""nearly if not quite, equal to the Cornish clay used in the manufacture of English porcelain"" (Keele, 1920, p. 42). The Cretaceous age of the clay, sand and lignite deposits was determined with the help of plant remains collected by Keele. He referred to the deposits as the Mattagami series, which later became the Mattagami Formation."

Jan 1, 1982