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"Pilot plants for pressure hydrometallurgy represent special design and project execution challenges. Over the past twenty years, Zeton has designed and fabricated a variety of world-class pressure hydrometallurgical pilot-plant facilities, and this paper discusses design considerations and strategies related to such projects. Project execution methods are also discussed, and guidance is given for the selection of materials of construction and for the selection of appropriate pressure and temperature design points for pressure hydrometallurgical pilot equipment. The paper concludes with a discussion of the need for process similarity with future commercial operations and the realities of pilot-scale equipment.INTRODUCTIONThe process technology developer or owner and the designer/fabricator of a new pilot-plant facility are faced with some difficult technical choices even after the decision to build a dedicated plant has been taken. A pilot-plant project is usually on the critical path of a large commercial project involving investments many multiples greater than the capital cost of the pilot plant. Schedule savings in the design, manufacture, and commissioning of the pilot plant or in a rapid completion of the experimental program can be disproportionately beneficial to the overall development project. However, inappropriate shortcuts resulting in major oversights can be disproportionately problematic.A number of considerations and suggestions for both the project execution approach and the process engineering design of pressure hydrometallurgical pilot-plant facilities are presented as a guide for potential owners and operators of new pilot-plant equipment and facilities."

Jan 1, 2012

By Mohammad Reza Khalesi, Ruhollah Rezazadeh, Mohsen Izadi Yazdan Abadi, Mahmoud Abdollahy

"The rotary vacuum drum filter (RVDF) is widely used for dewatering in mining industrial. In general, different parameters have influence in the solid-liquid separation such as: solid percent, level of vacuum, particle size distribution, filter cloth and chemical additives. These parameters can influence on some variables such as cake moisture, throughput and filter cloth life time. The aim of this study is to propose some chemical additives to improve the rate of filtration and decrease cake moisture of Gol-E Gohar iron ore concentrate by using laboratory scale bottom feed vacuum filter and suggest a filter cloth with long life time (more than 400 hours). Effect of particle size distribution on filtration investigated in large scale by measuring the thickness of cake and cake moisture.Increasing molecular weight of anionic flocculant lead to increases throughput but cake moisture increases too; While the filter aid increases throughput and decreases cake moisture simultaneously; the combination of them show different behavior. TSS and filter cloth life time have directly relation with material and type of filter cloth weave. Depending to type of feed, two polyester and polypropylene filter cloth are suggested. More over twill and satin weave have the best results. To prove the laboratory results some industrial tests performed in Gol-E Gohar hematite iron ore concentrate plant.INTRODUCTION“The process of grinding and classification involves the use of large quantities of water. The separation of solids from liquids is usually achieved by gravity sedimentation in thickeners. For fine particles this is a slow process. In general, 75–80% of the water can be separated and removed by thickeners. For further water removal, filters are used where in excess of 90% of the water can be removed” (Gupta, 2006).“Many types of filters are available, which are broadly classified here as vacuum, pressure, precoat and depth filters. Each classification contains a number of sub-processes. A category of filter that uses vacuum induced driving forces and semipermeable media to facilitate the separation of solids from suspension. While pressure differences across the filter are limited to less than 85 KPa (usually 75 KPa), most units are capable of processing a wide range of feed materials in a continuous manner” (Rushton, 2008)."

Jan 1, 2016

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

By L. Voisin, K. Yamaguchi, D. G. Mendoza, K. Ltagaki

The behavior of arsenic and antimony in the Cu-0 system was thermodynamically investigated to understand their elimination during a blister-making stage in copper smelting. Firstly, the phase relations in a miscibility gap composed of the liquid slag and copper phases in the Cu-0-As and Cu-0-Sb systems at 1523 K were established by a quenching technique. It was found that arsenic and antimony distributed preferentially into the slag phase in the miscibility gap. Secondly, the activities of arsenic and antimony in the miscibility gap of these systems were determined at 1523 K by using a double Knudsen cell - mass spectrometer method. It was clarified that the activity of arsenic in the copper and slag phases showed the negative deviation from ideality while that of antimony in the copper phase a slightly positive deviation. These data obtained in this study suggest a possibility to eliminate arsenic and antimony by means of over-blowing in a converter after discharging the slag.

Jan 1, 2007

By W. Beres, M. Bielawski

Recent research on the development of erosion resistant coatings has been directed to the finite element modelling of the behavior of coating and substrate, and their interface under the impact of eroding particles. The approach presented in this paper is based on advanced computer simulation techniques using ABAQUS/Explicit to investigate stress and strain at the surface and at the coating/substrate interface of multilayer coatings under single particle impact. It was found previously that solid particle erosion mechanisms are predominantly governed by the kinetic energy of the impacting particles. However, recent modelling efforts revealed that effects of various material models could be also significant. Therefore, different material models representing relevant coating and substrate properties were investigated and the effects of these models on the coating/substrate response were studied. Particularly, differences between elastic, elastic-plastic and brittle cracking model responses were assessed.

Jan 1, 2006

By W. L. Falconer

"IntroductionThe very recent emphasis on the importance of the northern portions of the Alberta basin as a prospective oil province has led the oil companies northward into new and undeveloped territory. Northern Alberta is a land of continuous forest, covering a plains-type topography. The plains are only occasionally broken by sharp, broad river valleys. Tributary streams head up quickly and very soon lose themselves in large undrained areas. It is these pseudo-swamps that cause most of the troubles and headaches of the oil explorer.The rivers have served as the main transportation arteries since people first ventured into this area. The bush is being pushed back, but the advance is slow and there is very little more than trappers' trails beyond a few miles from the Northern Alberta Railway lines and the recently built Grimshaw or McKenzie Highway. Indeed, bush and muskeg flank many miles of the railways and roads within as close a distance as fifty miles of Edmonton. Northern Alberta is pioneer country in the truest sense of the word, and our greatest problems derive from this fact. In all pioneer areas, the first requirement is the development of access roads, and before active oil exploraton can get down to the job at hand these roads and trails must be an accomplished fact. There are two factors in Northern Alberta which offer discouragement to the oil explorer: the first and greatest stumbling block is presented by the numerous muskegs, large and small; the second is the fact that road building uses up so much of reservation time. Of course, the second is aggravated by, and a direct result of, the first. So we come back to the main problem facing the development of the north - the muskegs."

Jan 1, 1950

By R. D. Westervelt

IN JULY 1954, the first iron ore from the deposits in the Knob Lake vicinity was mined and shipped to Seven Islands. The beginning of the production may well be the greatest advance in Canadian economy in the past fifty years. In 1955, the Canadian iron ore output was more than twice that of 1954, an in-crease due principally to the iron ore shipments from the Knob Lake area. Previous to this, Canada's iron production was 1.85 per cent of the world's output. Now, this percentage has risen to approximately 5.5 per cent and shows every indication of increasing further as the production rate from the area is increased. In 1955 the Iron Ore Company of Canada shipped over 7 million tons of iron ore and expects to ship over 10 million tons in 1956. Present facilities may be enlarged to handle up to 20 million tons per year. If the expected I 0 million tons per year are exported, Canada's iron exports will be second only to her wheat and newsprint exports. Before production began from the Knob Lake deposits, years of development were necessary in the area. Geologists spent several summers mapping the general area in order to unravel the complicated stratigraphy and petrology. Particular attention was paid to the mapping of the iron formation and all stages of alteration from fresh iron formation to ore were observed.

Jan 1, 1957

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By Doug Milne

Linking Classification Systems with each other Similar Parameters between systems Different Rock Mass Properties Rock Mass Classification parameters and geology Different sources of data Commonly Used Rock Mass Classification Systems Q? = Q with SRF = 1.0 RMR? = RMR with no joint orientation correction RMR76 = 9lnQ + 44 RMR?76 = 9lnQ? + 44 RMR76 = RMR89-5 RMR?76 = GSI = RMR89-5 MRMR = ??MRMR

May 1, 2013

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By D. B. Stewart

This paper reports on an investigation undertaken to determine the exhaust gas temperatures of operating underground mining equipment. The effectiveness of platinum catalytic purifiers is discussed. From exhaust temperatures, it is concluded that LHD engines are highly loaded, haulage truck engines are moderately loaded and utility vehicle engines are lightly loaded.

Jan 1, 1979

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By J B. Magee

Sheep Creek Mines Limited has developed several operating techniques that have greatly assisted in keeping unit costs at reasonable levels. Some of the techniques, as described in this paper, include organization, accounting, warehousing, bonus and contracts. INTRODUCTION THIS paper is a non-technical report on operating techniques developed by Sheep Creek Mines Limited at their Mineral King mine, located near lnvermere, B.C. Depressed metal prices and continually rising labour and materials costs have necessitated a continuous search for method to keep operating costs down. The newly developed techniques and practices have greatly assisted in maintaining unit costs. Sheep Creek Mines Limited is a mining company incorporated under the laws of the Province of British Columbia. The Company's share capital is 3,500,000 common shares, witl1 a par value of 50 cents each, of which there are 1,875 000 shares is-sued. The Company has eight di-rectors. The administration, exploration and accounting offices are located in Nelson, B.C. The Company's working capital is approximately $1,500,000.

Jan 1, 1963

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By M. Dadvand, G. Kipuros, A. Dadvand

"The ability to codeposit fillers within a nickel matrix has led to the production of a new generation of cermet coatings with properties useful for various applications. Hexagonal boron nitride (hBN) is a ceramic-type particulate matter with thermal conductivity, thermal stability, inertness, and lubricity properties that allow it to be codeposited. In this paper, a method was developed for modifying hBN surfaces to allow them to be uniformly dispersed in water-based solutions such as an electroless nickel plating bath. hBN surface modification improved wear performance of the electroless plated cermet due to enhanced interaction between the particulate and nickel matrix. RÉSUMÉ La capacité à effectuer un dépôt simultané de charges dans une matrice nickel a abouti à la production d’une nouvelle génération de revêtements cermet (une combinaison de céramique et de métal) dotés de propriétés très utiles pour diverses applications. Le nitrure de bore hexagonal (h-BN) est une matière particulaire de type céramique utilisée pour ses excellentes conductivité et stabilité thermiques, son inertie ainsi que son caractère lubrifiant, qui permettent son dépôt simultané. Cet article explore une méthode mise au point pour modifier les surfaces du h-BN de manière à ce qu’elles se répandent uniformément dans des solutions aqueuses telles qu’un bain de dépôt autocatalytique de nickel. La modification des surfaces du h-BN a amélioré la résistance à l’usure du placage autocatalytique du cermet en raison d’une interaction accrue entre la matière particulaire et la matrice nickel.INTRODUCTION Electroless nickel alloy coatings can be used for many applications; however, the need for improved tribological properties such as higher wear resistance and better lubricity has increased interest in incorporating particulates (fillers) into the nickel matrix by codepositing the particulates with nickel during the plating process. The selection of the particulate type depends on the desired properties (Sahoo & Das, 2011; Sudagar, Lian, & Sha, 2013). In terms of tribological applications, electroless nickel-based composites are categorized mainly into lubricating and wear-resistant composite coatings depending on the type of particles incorporated. The electroless nickel-phosphorus (Ni-P) composite coatings are composed of codeposited solid lubricants such as polytetrafluoroethylene (PTFE), graphite, WS2, MoS2, and hexagonal boron nitride (hBN) and, compared to nanocomposite electroless Ni-P coatings, they demonstrate a lower coefficient of friction. On the other hand, the nickel-phosphorus wear-resistant composite coatings are composed of hard particles such as silicon carbide (SiC), aluminum oxide (Al2O3), boron carbide (B4C), silicon nitride (Si3N4), diamond, tungsten carbide (WC), and zirconium oxide (ZrO2) and, compared to nanocomposite electroless Ni-P coatings, they have higher hardness and better wear resistance (Sahoo & Das, 2011; Sudagar et al., 2013; Parucker, Klein, Binder, Ristow, & Binder, 2014; Chakarova, Georgieva, Petrova, Dobreva, & Stoychev, 2016)."

Jan 1, 2018

By L. López

Argentina reported about 40,000 tonnes of uranium (tU) as reasonably assured resources and inferred resources for the production cost category <130 US$/kgU in the OECD-NEA/IAEA classification scheme. These resources belong to the following projects: Sierra Pintada, Cerro Solo, Don Otto, Laguna Colorada, Laguna Salada, Meseta Central and Amarillo Grande. With three heavy water reactors in operation and an approximate installed capacity of 1.7 GWe, the current natural uranium requirements are about 220–250 tU per year. Based on various nuclear growth scenarios, it is estimated that by 2030 there will be a generation capacity of some 3,092 GWe for the reference case, with raw material needs of some 486 tU per year. Currently, there are no perspectives for local uranium production in the short term, and it is thought that uranium projects with identified resources must complete resource delineation and advance in technical pre-feasibility studies for the recovery of uranium. It is expected that Argentina continue meeting the uranium demand with imports in the next following years. In the Latin America region, both Brazil and Paraguay could be considered as potential uranium suppliers. In conclusion, despite the apparent growth prospects for the use of nuclear energy to generate electricity in Argentina, there are no immediate prospects for the provision of uranium oxide concentrates from domestic deposits for fuel fabrication. This has implications for supply and energy security.

Jan 1, 2020

By W. J. D. Stone

"INTRODUCTION Over the past decade, a number of publications have described the advances in High Intensity Wet Magnetic Separation. A number of significant, but small capacity installations were made and are successfully operating. These were followed some three years ago by larger installations treating ilmenite gravity concentrates; at least one machine treating 25 tons per hour of new feed was installed and is successfully operating.However, this still did not result in general acceptance that High Intensity Wet Magnetic Separation could be applied on a large scale. Neither did it dispel the feeling that High Intensity Wet Magnetic Separation was ""expensive"" and hence, confined to small scale – high value applications suchas the cleaning of tin concentrates. In addition, there is the usual reluctance of being the ""guinea pig"" which has resulted in waiting to see ""someone else"" make the first large installation decision. Such a decision and installation has now been made.Therefore, the purpose of this paper is to show that High Intensity Wet Magnetic Separation has been commercially accepted on a large scale and to show its general application to the base metal mineral industry.Examples are confined to a few specifics due to the large volume of preliminary test data that is available. The art has now reached the stage where much of the preliminary work should be taken through to serious evaluation."

Jan 1, 1971

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By P. Sauriol

This work addresses the design challenges and demonstrates the capabilities of a novel water transfer factor measurement apparatus. Several measurement concepts were screened on the basis of their water transfer factor accuracy using Monte-Carlo generated virtual experiments. The most promising measurement concept was assembled and tested to assess its actual measurement accuracy. For these concept validation experiments, the polymer electrolyte membrane fuel cell was simulated by adjusting the water injection rate to corresponding levels. Combining the anode and cathode measurements, the water transfer factor accuracy was typically better than 0.01. Real-time measurements of the water transfer factor on both anode and cathode sides of a polymer electrolyte membrane fuel cell were achieved. The anode and cathode side measurements were in good agreement with each other; however the anode side measurements were generally more reproducible. A parametric study showed that stream humidification plays an important part in the water transfer across the membrane electrode assembly. Finally the water transfer factor along the channel of a 300cm2 co-current fuel cell was obtained by using a series of six 50cm2 sub cells. The results were in good agreement with predictions from a recently proposed model.

Jan 1, 2005

By F. P. Hassani, Jacque Ouellet, M. Hossein

A laboratory investigation was undertaken to evaluate the effectiveness of different binding agents in a paste backfilling operation suitable to be used in a sulphide-rich environment. Different combinations of Portland cement and fly ash type C as well as ferrous slag were used as the binding agents. The unconfined compressive strength of the samples was measured for extended curing periods. The results indicate that the addition of 3% slag in the binding agent mix could produce strengths up to 0.5 MPa in the samples under investigation. For higher binding contents, the addition of Portland cement will lead to higher availability of calcium hydroxide and calcium aluminate, which are susceptible to deterioration from the phenomenon known as sulphate attack. Using slag, on the other hand, will reduce the permeability, availability of calcium hydroxide, and dilute the calcium aluminate ions reducing the susceptibility of the samples to sulphate attack. However, gypsum will form which could have the same detrimental effect on the strength of the treated matrix. Therefore, special attention must be given to the content and properties of agents used to activate the pozzolanic properties of the slag.

Jan 1, 2001