Search Documents

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By Y. Hayashi, A. Fuwa

To analyze zinc vaporization kinetics of zinc smelting slag in the ISP furnace, reduction reaction rate of zinc oxide from ZnO-FeOx-CaO-SiO2 slag system with CO-CO2-Ar gas mixtures has been measured by a therm o-gravim etric apparatus at various ZnO content, Pco, and temperature. The reduction rate was measured under a chemical reaction control in the initial three minutes where surface zinc content can be assumed constant. Through the reaction rate dependency analysis on ZnO contents, Pco and temperature, discussion has been made on its reaction mechanistic information in terms of rate coefficient, adsorption/desorption mechanism and activation energy.

Jan 1, 2008

By A. Atrafi, L. Barroilhet

The top size of particles in the flotation of potash ores, which can be as large as 4 mm, exceeds by far the top size in other flotation plants. It is then understandable that while long chain amines are used in the flotation of fine fractions (below 0.8 mm) of potash ores the coarse particle flotation also requires an extender oil. While new and very promising fluidized-bed flotation machines (e.g. HydroFloat) constitute a significant development in the flotation of coarse particles, in the area of extender oils, as reviewed in 2007 by Strathdee, Gotts and McEachern, there have been no new developments to replace the industry standard asphaltene-based carcinogenic extenders. This situation first of all results from the experimental problems that arise when water-soluble minerals like sylvite are to be tested in saturated brine. Both oils and longchain amines are water/brine insoluble. The oil with the amine dissolved in it can however be emulsified and then used as an extender oil. Such oil droplets must wet KCl particles and the emulsion must be stable to avoid handling problems. In this paper we test the use of the phase inversion technique as a method of studying wettability of KCl particles by the oil in saturated brine, and the effect of amine dissolved in this oil on the wettability. The results show that this relatively simple technique can be used to characterize the wettability of fine KCl particles by the tested oil and to determine the effect of added amine on it, and so it can be useful in selecting proper extender oils.

Jan 1, 2016

By Gerhard W. Heinrich, Gerald V. Schroeder, Daniel A. Murphy, Daniel F. Suarez, Jamie B. Beauchamp

"Washwater 'Finger' sprays were installed and tested in the copper/nickel separation circuit at Strathcona Mill to improve flotation capacities and related metallurgical performances. The new spray design features submerged sideways introduction of wash water into the flotation froth through nozzles at the end of vertical pipes which are suspended from a header above the froth. This maximizes the effective cross sectional area of flotation vessels while maintaining effective froth cleaning and a desirably high density of the concentrate slurry. The plant tests gave increases of copper concentrate production rates of 17% to 20% for conventional cells and 16% to 20% in column flotation at target grades of 29% to 30% copper and of less than 0.5% nickel. Basic considerations and concepts of tests and evaluation procedures are described.IntroductionMeeting flotation concentrate grade targets at maximum production rates and recoveries is a challenge all too familiar to operators of base metal ore concentrators. Frothwashing is an option to improve grade/recovery performance by minimizing entrainment of impurities into the concentrate, which is commonly known since the sixties (Kaya & Laplante, 1989). It has been recommended for the flotation of sulphides and industrial minerals alike (Kaya & Laplante, 1989; Miller, 1969; Heinrich, 1989) and has found its ultimate application in flotation columns (Finch & Dobby, 1990). The washwater addition in a flotation column is most evenly distributed over the column's cross-sectional area thus ensuring almost complete displacement of feed water from the froth by a countercurrent washwater flow -provided, a positive bias is maintained. Therefore, flotation columns are ideal for cleaning flotation. However, there is usually less room for boosting the concentrate production capacity by increasing airflow or slurry level then with conventional cells because of the smaller cross-sectional area available."

Jan 1, 1994

By X. -G. Chen, J. Qin, K. Liu, D. Racine

"Understanding the thermo-mechanical fatigue (TMF) behavior of materials plays a significant role in the safety design of critical components used in aerospace and automotive industries, such as engine blocks and cylinder heads, which undergo the cyclic change of temperature and stress. However, the cyclic changes of temperature, stress and strain make it difficult using the traditional testing methods to accurately simulate the TMF process. In the present work, the Gleeble® 3800 system was successfully applied to develop a reliable procedure to measure the TMF behavior of aluminum alloys. The modified setup together with the new designed program allows the Gleeble system to precisely simulate the cyclic profiles of temperature and mechanical strain. The novel procedure includes the calibration and verification of the TMF setup to ensure the test validity with Young’s modulus measurement, multi-cycle measurement of the thermal strain and zero stress adjustment followed by online monitoring the TMF cycles. The results of the TMF testing of an AA6061 alloy under cyclic temperatures (60–300°C) and various strain amplitudes (0.2–0.6%) were demonstrated. Its TMF behavior was characterized by the typical hysteresis loops and cyclic stress-strain response.INTRODUCTION The thermo-mechanical fatigue (TMF) behaviour becomes increasing important to evaluate the elevated-temperature properties of materials used as the critical components in automotive and aerospace industries, such as the gas turbines (Hu, Shi & Yang, 2016; Moverare, 2007; Segersäll et al., 2015) and engine blocks (Grieb, Christ & Plege, 2010; Javidani & Larouche, 2014). During the cycles of start-up and shutdown of the engines, these components undergo a complex change of loading. Meanwhile, a dramatic temperature gradient exists on the components due to the cooling system. Therefore, the cyclic changes of load and temperature can give rise to the TMF and may limit the use life of such components (Hu, Shi & Yang, 2016; Javidani & Larouche, 2014; Moverare, 2007). Hence, performing the TMF tests to precisely simulate the cyclic changes of load and temperature to understand the TMF behaviours of materials is playing a significant role in the safety design of these components. For TMF tests, two principal types of cycles are generally employed, including the in-phase (IP) cycle where the load and temperature are at the same phase (i.e. maximum load at highest temperature) and out-of-phase (OP) cycle where the maximum load is applied at minimum temperature (Kliemt, 2012; Miller, 2014). The most significant damage mechanisms in engine components are reported to be OP TMF cycles (Javidani & Larouche, 2014; Kliemt, 2012)."

Jan 1, 2018

By Willie van Niekerk

As mining projects get larger and more complex there is a need to examine the use of project management techniques developed for large construction projects in order to ensure completion of the project on time and budget. In recent years the construction/civil industry has sought new methods to ensure that multimillion dollar projects involving multiple contractors, working in an increasingly legislated work environment, are delivered to the clients satisfaction. The paper describes these methods, which range from program management to systems and tools to gather all project information such as schedule and cost, and relates how these can be applied to large international mining projects. The paper also describes the benefits that an independent project manager can bring to a client or owner?s team by setting up the relevant organization and controls together with the appropriate contract and procurement strategy.

May 1, 2009

By R. A. Rabnett, G. Paget, Patrick Walsh

"Tumbler Ridge, Canada's newest resource community, has been developed differently than have been other resource communities.Since its conceptualization, emphasis has been placed on the establishment of a traditional municipal government at early a stage as possible.Planning f or the community goes back to 1977. By then, extensive study by provincial agencies had shown a new resource town would be required to exploit north east coal. The Ministry of Municipal Affairs, in conjunction with a consultant named R.A. Rabnett began the extensive Tumbler Ridge conceptual plan.The results of the conceptual plan are evident in the organizational and planning goals of Tumbler Ridge. In every aspect from the election of officials to some financial matters, the town functions as a normal municipality. With the resource companies of the North East Coal Development within its municipal boundaries. Tumbler Ridge has been able to debenture its capital projects against its municipal tax base.The town's ability to function as a normal municipality is enhanced by its control over Crown land it has purchased from the province. This gives it further control over the development of the community and helps in establishing agreements with the resource companies and the provincial government to ensure that housing and service needs are met. While resource company representatives sit on certain municipal committees, their roles are advisory in nature.The community continues to move toward full municipal status and will have a fully elected Council by 1986.BackgroundPlanning for the development of northeast British Columbia coal resources began in 1976 under the aegis of the provincial Cabinet Committee on Coal Development. A series of subcommittees were established including a Townsite/Community Development subcommittee. The Ministry of Municipal Affairs chaired this subcommittee and continued as the lead agency for the provincial settlement planning effort over the period 1976 to 1981."

Jan 1, 1983

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

By Tomoya Kawasaki, Tatsuya Motomura, Yutaka Yasuda

Saganoseki Smelter, one of the largest copper producers in Japan, currently operates a single flash smelting furnace to produce 450,000 tons of new copper annually. The smelter used to employ two flash furnaces, and integrated the two into one in 1996. Since then, various improvements to its facilities and technologies have been made to increase productivity. To upgrade the operation efficiency, "stability" was considered a key issue, and the measures were taken to increase the operation and facility reliability. Currently, the furnace is running at a feed rate of 215 DMT/h, while the furnace utilization has been maintained at 97%. This paper outlines recent improvements that have made to increase furnace productivity and efficiency.

Jan 1, 2014

By E. G. Baltuch

Natural Ventilation in mining and metallurgical processing applications is key to proper operation function. There are number of ventilator designs available to a project team or design engineers, the selection of which will affect both the type of building structure required, project costs and design performance which is difficult to rectify or re-engineer once implemented. Research and applied results, such as that performed by Air-Therm Inc., demonstrates that computational fluid dynamic simulation allows for 5 dimensional observation, analysis and optimization at significantly lowered cost than previously possible. These results have been fully implemented on a number of mining and metallurgical applications and the company continues to study, optimize and innovate as new tools become available to provide the best possible engineered solutions for particular applications.

Aug 1, 2013

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994

By K. Negishi, H. Izui, Y. Komiya

"Aluminum has the disadvantage of low strength. In order to obtain the high strength composites, crystals were refined in the composites. Grain refinement was approached at two process points, generating new grains and grain growth. It is important for refinement how to control the grain growth. Spark plasma sintering (SPS) technique and TiB2powder addition prevent grain growth. To investigate effects of strain and additives to the alloy, aluminum powder was sintered at 70 MPa and 80 MPa, changing the content of TiB2additive powder by SPS method. As the results, the crystal grain size was finer in the composite sintered at higher sintering pressure and with larger amount of additive, though over 1.0mass% TiB2addition dissuades grain refining. These grain refinements improve hardness and tensile strength of sintered aluminum alloys.INTRODUCTIONAluminum matrix composites have low density, high specific strength, and low cost. Their applications are growing continuously in the field of automotive and aerospace industries. Recent studies to improve their good mechanical and tribological properties use different ceramic materials such as Al2O3(Das, Munroe, & Bandyopadhyay, 1996; Ashwatha & Anthony Xaviorb, 2014),SiC(Hassani, Bagherpour, & Qods, 2014), B4C(Ehsan, Masoud, Touradj, Amir Hossein, & Ali, 2015),TiC(Ehsan, Ali, Masoud, Kamyar, & Touradj, 2017), and TiB2(Fei & Zhong-Hua, 2013).On the other hand, grain refinement is also an important techniques for improving the properties of aluminum alloys. Finer grains improve the mechanical properties of the alloy. For cast and wrought alloys, addition of grain refiners in molten alloys accelerates generation of nucleus and suppresses grain growth. Al-Ti-B alloy is generally added as grain refiners in the molten aluminum alloys(Easton & Stjohn, 2001). Especially, TiB2has very high melting point, low density, and excellent hardness. Therefore, TiB2was selected as additions into aluminum alloys. Liquids reaction leads to high cost, oxidation, discoloration of molten alloy, and clustering of additive powder as compared with solid reaction such as sintering. However, sintering of aluminum alloy powder with ceramic powders is difficult for oxide layer surface. Recently, we take attention to spark plasma sintering (SPS) as advanced sintering process. SPS process can easily sinter a high quality specimen at a lower sintering temperature and in a shorter time than conventional sintering processes. By SPS process, we have sintered titanium powders that are as difficult to be sintered by any other processes as aluminum powders, and improved mechanical properties by adding hard ceramic powders TiC and TiB(Kamegawa, Izui, Komiya, Kobayashi, & Arimoto, 2015; Sampei, Izui, Komiya, Shigimura, & Suzuki, 2015). Furthermore, it is important to consider not only pure aluminum but alloys for solid-solution or precipitation strengthening. Actually, pure Al does not have enough strength compared with the alloys. Al-Cu alloy and Al-Mg alloy demonstrate adequate strength for industrial and commercial sectors. Al-Mg alloy retains good formability, and has high resistance to corrosion. It is therefore used for many applications. We must consider alloying processes. The most cost effective process is blended elemental technology where alloying elements are added to base powder as elemental or master alloy powder (Smugeresky & Dawson, 1981; Yasue, Radjai, Miwa, & Sakaguchi, 2003; Bolzoni, Esteban, Ruiz-Navas, & Gordo, 2012)."

Jan 1, 2018

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By K. Aziz

The solutions to unsteady-state gas flow in a radial system have been reviewed in order to aid in the interpretation of drawdown data. It has been the practice to evaluate the time and rate conversion constants, directly or indirectly, by using reservoir data. This paper presents a method of determining these constants from drawdown data. A simplified approach to the de-termination for the various boundary conditions is presented. An example of a problem which illustrates the use of this theory appears in the appendix. UNSTEADY-STATE FLOW EQUATION The solution of any unsteady-state flow problem involves (1) the continuity equation, (2) the equation of state of the fluid, (3) the equation of fluid motion and (4) the boundary conditions. For the Darcy flow of a gas in the horizontal radial plane, the equation is when the viscosity, compressibility and permeability to gas flow may be assumed constant and the medium

Jan 1, 1963

By Jian Deng

Rockbursts are sudden and violent failure of rocks in deep and/or high stress mines, which may destroy the excavation space and cause an accident or even the death of mining workers. This study is motivated by the pervasiveness of rockbursts all round the world. It has been found that rockbursts are often stimulated by dynamic fluctuation which is generated by mining operations or other sources of vibrations, such as blasting in adjacent stopes. This paper attempts to investigate the dynamically stimulating mechanism of pillar rockbursts in hard rock mines from an innovative point of view. Rockbursts are classified into triggered rockbursts and induced rockbursts in accordance with the magnitude of the stimulation force. Triggered rockbursts occur only when a small fraction of stress changes associated with rockbursts is accounted for by the causative excavation, whereas induced rockbursts happen where the causative factor is responsible for most of the stress changes required to produce the rockburst. By considering rockbursts as a dynamic instability problem of structures, rigorous mathematical models are set up for triggered rockbursts and induced rockbursts, respectively. By using the method of averaging and the method of eigenvalue problems, the boundaries of rockburst occurrence of a pillar are obtained for these two rockbursts. A new explanation of the failure mode of fretting or necking of pillars is given, the perturbation effect for pillar rockbursts is found, and the parametric resonance mechanism of pillar rockbursts is revealed. The quantitative relation between blasting parameters and pillar rockbursts obtained can be directly used to control the rockbursts. Contrary to conventional methods where only rock materials or rock specimen were used to study rockbursts, this investigation attaches more attention on the structural effect on rockbursts, which have strong potential applications in deep mining.

Jan 1, 2015

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By Robert E. Wood

Engineers have known for some time that the efficiency of filtering iron ore concentrate slurry can be significantly improved by pre-heating the slurry ahead of the filters. However, heating such large quantities of dense slurry by conventional means has proven to be inefficient and high-maintenance. Recently though, submerged combustion was considered by Altos Hornos de Mexico SA (AHMSA), an integrated steel producer in the state of Coahuila, Mexico, as a means of pre-heating their iron ore concentrate. The company toured many iron ore facilities in Brasil and Labrador, reviewing their heating processes, and concluded that submerged combustion could provide a competitive advantage through operational efficiency and lower capital cost than steam boilers. Inproheat was retained by the company to design and manufacture a SubCom slurry heating system to heat 403 m3/h of iron ore concentrate slurry from 25°C to 60°C. The 60GJ/h SubCom system consists of five natural gas combustion chambers mounted in an iron ore concentrate storage tank. The system features a heat recovery unit whereby the exhaust gases are used to preheat the incoming slurry stream, giving the system an overall thermal efficiency of 95%. As a result, the steel company expects to realise significant improvements in filtering efficiency which will enable them to increase the capacity of their pelletising plant without installing additional filters.

May 1, 2010

By T. H. Patching, M. W. Mikhail

"Data from a standardized procedure for measuring methane desorption rates from samples of Western Canadian coals gave a good correlation (0.994) with the percentage of fines (-0.6 mm) found in the corresponding run-of-mine coal. The correlation was independent of the mining method and the top size of the samples. It is suggested that both methane desorption rate and the production of fine coal sizes are functions of the fissuration of the coal being mined.This relationship, in conjunction with established data of degradation by unit process equipment, may be useful in predicting the amount of fines that will be produced from new seams of coal and by planned new washeries. It also could be a valuable guide in modifying existing washery processes to minimize production of fines."

Jan 1, 1980

By John Smith

"The RTZ Corporation PLCFrom a company's point-of-view, a good investment decision is one which results in the purchase of an asset that is worth more than it costs. Thus, in order to judge the merit of an investment opportunity, it is necessary to estimate the value of the assets to be acquired.Discounted cash flow (DCF) analysis has become widely adopted by companies in assessing potential new investments. The principle is a simple one: invest in projects which have a positive net present value, and reject those which do not. However, perhaps because of its apparent simplicity, DCF analysis is frequently misused. Good practice in the use of the technique is discussed, together with several common misconceptions.Sound analysis requires sound data; thus, the valuation process relies heavily upon a wide range of specialists to provide the basic input from which cash flow forecasts can be built up. The analyst must maintain close liaison with these specialists from the outset in order to ensure that the data provided is indeed relevant and complete.IntroductionBefore turning to the main subject of this paper ""How Companies Value Properties"", it is of interest to consider first a slightly different question ""Why do Companies value Properties""? In other words, for what purposes are such valuations prepared? Certainly the commonest, and probably the most important circumstance in which a valuation is required is when the company is considering an investment opportunity. This may be the direct purchase of a property or group of properties from a third party, but could also be the opportunity to develop a new operation or expand an existing one.A very simple objective in making any kind of investment is to make our shareholders richer than they would otherwise have been. That is, to make investments whose value to shareholders exceeds the consideration required to acquire them. Thus the investment decision focusses on the difference between an asset's value and its cost.This distinction between ""value"" and ""cost"" is an important one. Study of a company's balance sheet may tell a lot about the cost of this company's assets, but very little about their value. Then again, it is sometimes argued that a business should be bought because this will result in assets being acquired for less than their replacement cost. This merely compares one cost with another, it says nothing about value."

Jan 1, 1991

By Robert B. Parsons

"The Province of Manitoba tabled a Budget on March 11, 1992, which contains some important new initiatives designed to improve the fiscal environment for mining in the province. In addition, the Minister of Energy and Mines has released details of the Mineral Exploration Incentive Program which was originally announced in the 1991 Budget.Introduction""We recognize the important contribution o f mining to the economic activity of our province, including direct and service jobs and export earnings. We are determined to secure its future."" - The Honourable Clayton Manness, Minister of Finance, Province of Manitoba, March 11, 1992.With these words of introduction, Manitoba Finance Minister Clayton Manness announced a number of significant measures aimed at improving the fiscal regime for exploration and mining in Manitoba. At the same time, details of the Manitoba Mineral Exploration Incentive Program (MEIP) were released."

Jan 1, 1992