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By William F. Caley, A. MacKinnon, P. W. Kingston

"The purpose of this paper is to identify a number of currently available opportunities for exploration and/or mine development in the industrial minerals field in southeastern Ontario. The paper is not intended as a complete review of the industrial minerals industry in southeastern Ontario, but highlights what are seen by the authors as areas where there are immediate opportunities for investment and growth.Traditional exploration targets in the Grenville Supergroup in southeastern Ontario have been vein-hosted gold deposits, industrial minerals, and base metals. In recent years, emphasis has increasingly shifted to industrial minerals, in response to changing technologies in the minerals-consuming manufacturing industries, and to an increasing awareness of the industrial mineral potential in this area.This paper examines the resurgence of interest in exploring for and developing a wide variety of industrial minerals, and it examines the work the Ontario Ministry of Northern Development and Mines has done under the current Canada-Ontario Mineral Development Agreement. Specific development opportunities are identified in various commodity areas. Use oj the industrial minerals wollastonite and nepheline as substitutes for fluorspar in the formulation of synthetic steelmaking slags is also discussed."

Jan 1, 1990

By P. R. A. Andrews

"A sample of flotation feed from Bakertalc Inc., High water, Quebec was subjected to flotation evaluation to improve the recovery of talc. A number of alternative frother/collectors and depressants as well as flotation parameters including pH, conditioning time, frother/collector concentration and pulp density were assessed. In addition, the possibility of using a size coarser than that currently employed for flotation (95% minus 50 um) was investigated.As far as possible, a laboratory duplication of the present circuit arrangement was folio wed so as to minimize the cost of any changes. The best results obtained were a concentrate analyzing 95.96% acid insol for a recovery of 65.98% after four stages of cleaning. With recirculation of cleaner tailings, the recovery would be higher.The possibility of using an alternative method, based on the natural ability of talc to float unaided by a frother/collector, was briefly explored with encouraging results.IntroductionBakertalc lnc ., located in the eastern townships at Highwater, Quebec, Is approximately 140 km east of Montreal near the Vermont, U.S. border. Originally called Baker Mining and Milling Co. Ltd., it has produced pulverized talc products since 1938(1 ), although records show that talc was mined in the area as early as 1871(2). Feed to the mill originally was obtained from local deposits, but since 1952 the van Reet mine near south Bolton, approximately 25 km from Highwater, has been the source of ore .In 1957 a Raymond high -side roller mill was installed which enabled production of a greater range of talc products and, in 1960, new crushing equipment and a dryer were added. Other additions to the mill were the introduction of wet magnetic separation, although this was later discontinued, and flotation to produce high-grade talc concentrates."

Jan 1, 1985

By J. Jin, J. D. Miller

"Bubble attachment at hydrophobic surfaces is of critical importance in the flotation recovery of mineral resources and fundamental experimental results have been reported in the literature describing the details of film thinning, rupture, and displacement. Now, for the first time, bubble attachment phenomena are examined using Molecular Dynamics Simulations (MDS). The simulation involves a nitrogen bubble containing 906 nitrogen molecules in a water phase with 74,000 water molecules at the hydrophobic molybdenite (001) surface. During the simulation period of 1 ns, film rupture occurs and the nitrogen bubble attaches to the molybdenite (001) surface, resulting in a contact angle of about 90o. In contrast, the film is stable at the hydrophilic quartz (001) surface and the bubble does not attach. Contact angles, determined from MD simulation after stabilization of the three phase line of contact, are reported and these results agree well with experimental and MDS sessile drop results. In this way, film stability and bubble attachment are described with respect to interfacial water structure for surfaces of different polarity. For example, the interfacial water molecules for the hydrophobic molybdenite (001) surface have relatively weak interactions with the surface when compared to the hydrophilic quartz (001) surface, as revealed bythe presence of a 3 A water exclusion zone at the molybdenite/water interface. INTRODUCTIONAttachment of air bubbles to mineral particles is of fundamental importance in understanding flotation separation phenomena. It is well known that attachment of an air bubble at a hydrophobic surface includes film thinning, film rupture, and film displacement (Somasundaran, 2006; Wilson, Adlard, Cooke, & Poole, 2000). Experimental techniques, such as high speed video, can catch the process of bubble attachment at a mineral surface (Drelich & Miller, 2012; Niecikowska, Krasowska, Ralston, & Malysa, 2012). However, molecular scale information to examine the phenomena has not yet been reported."

Jan 1, 2016

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By M. Drozd, M. Somppi, Z. F. Yamak

"Activated carbon is used to recover gold in solution from various gold circuit designs including carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes; however, the characteristics and durability of the activated carbon can vary. Handling this medium poses challenges when fine carbon losses occur in the CIP, CIC, and CIL circuit discharge. Additionally, adsorbed gold on carbon fines can be lost to the discharge. The studies in this paper aim to standardize laboratory methods for testing activated carbon qualities specific to the gold industry. The investigation focused on size distribution, platelet content, wet attrition resistance, gold kinetics, and gold loading. The results demonstrate that a 96 h attrition test and a gold loading test form a basis for ranking carbon samples based on expected economic performance of the plant. ¦ KEYWORDS Activated carbon, Carbon attrition, Carbon ball-pan hardness, Carbon evaluation, Carbon fines loss, Carbon turnover RÉSUMÉ Le charbon actif sert à récupérer l’or en solution dans diverses conceptions de circuits de broyage d’or, notamment les procédés de charbon en pulpe (CIP, de l’anglais carbon-in-pulp), de charbon en colonnes (CIC, de l’anglais carbon-in-column) et de lixiviation au carbone, ou charbon au lixiviat (CIL, de l’anglais carbon-in-leach). Toutefois, les caractéristiques et la durabilité du charbon actif varient. La manipulation de ce milieu pose des problèmes dès lors que se produisent des pertes de carbone à grain fin dans la décharge des circuits CIP, CIC et CIL. Par ailleurs, l’or adsorbé sur les fines de charbon peut se perdre durant la décharge. Les études réalisées dans le cadre de cet article visent à normaliser les méthodes de laboratoire pour tester les qualités du charbon actif spécifiques au secteur de l’exploitation aurifère. L’étude portait sur la composition granulométrique, la teneur des plaquettes, la résistance au frottement humide, la cinétique de l’or et l’adsorption de l’or, à savoir la capacité du charbon actif à adsorber l’or sur une période spécifique. Les résultats ont montré qu’un test de frottement de 96 heures et un test d’adsorption de l’or constituaient le fondement d’un classement des échantillons de carbone du point de vue économique en vue de trouver l’échantillon générant le meilleur rendement des usines. ¦ MOTS CLÉS charbon actif, dureté de la batée des billes de carbone, évaluation du carbone, perte de fines de charbon, renouvellement du carbone, résistance au carbone INTRODUCTION The use of activated carbon for gold extraction is among the most common processes in modern gold-milling plants. Although gold losses are inevitable in the milling process, operators often focus on reducing gold loss to tailings. One focus area that is important in gold recovery is optimizing the use of activated carbon and examining potential changes to realize improved economics for carbon-in-pulp (CIP), carbon-in-column (CIC), and carbon-in-leach (CIL) processes. Granular activated carbon (Figure 1) is widely used for gold extraction from slurries containing gold-cyanide complexes. This activated carbon—produced from charred coconut shells—is well suited because of its adsorption kinetics, gold-loading capacity, attrition resistance, and ability to be reactivated. The extraction process using activated carbon technology involves adsorbing gold from an aqueous leachate; the gold is dissolved using a cyanide salt and consequently a dicyanoaurate(I) ion (Au(CN)2–) is formed, as noted in equation 1."

Jan 1, 2019

By J. G. Kim, B. G. Chae, D. S. Cheon, E. S. Park

The underground structures such as high-level radioactive waste disposal thermal energy storage should be designed and constructed considering thermal-mechanical characterization because of long term and/or cyclic thermal stress. High temperature changes in these structures can extend the existing cracks and generate new cracks in surrounding rock mass. In case of long term and/or cyclic thermal stress conditions, it is possible to lose the function of structures caused by the significant cracks and fracture growth in the rock mass. In this study, the critical thermal crack temperature of the granite, limestone and thermal Kaiser effect were evaluated. Experiments were carried out with the heating speed of 1.5?/min. To avoid thermal shock and target temperatures were set at 150? and 250?. In order to verify the thermal Kaiser effect, the samples were heated by 150 ? after 2-3 repetition to 250?. The generation and growth of cracks were observed through an acoustic emission measuring system. The variation of the physical rock properties was measured before and after thermal experiments. After compared with the thermal experiments using PFC2D, numerical simulations were carried out at higher temperatures (400?). The experiments showed that the initial thermal crack temperature of granite and limestone is about 35?, 32? and the critical thermal crack temperature were about 69? , and 49? , respectively. The experiments confirmed the thermal Kaiser effect of experimented granite and limestone due to thermal cyclic loading. From the numerical analysis, the critical crack temperature showed the same tendency as the thermal experiments. The P and S wave velocity of the sample after the experiment were reduced. Therefore, when heat is applied in long-term and repetitive conditions, these cracks may affect the function and stability of the underground structure. Therefore, further studies of thermal stress effects should be performed.

Jan 1, 2015

By M. W. Gilmore, J. Ndlovu, T. Sepoloane, Anglo American Platinum, L. R. Nelson, R. N. Varty, L. J. Bryson, B. Peyper, J. P. Hagemann

"As part of Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) expansion, a new Nickel Electrowinning Tank House, with a nameplate capacity of 32 400 tons per annum, was constructed. Commissioning of the new electrowinning technology, which involved world first full deposit plating, commenced in 2011.The old nickel electrowinning process at the RBMR used starter sheets which, along with a divided cell configuration, was very labour intensive and exposed operators to high levels of aerosols that contained both nickel and acid. To overcome this problem two key design intents of the new technology are aerosol abatement and minimising labour in the electrowinning cell environment, with a design target to reduce the nickel occupational exposure limit (OEL) to half the legislated limit of 0.1 mg.m-3.Commissioning of the new technologies adopted to achieve mist abatement is described, together with a review of technical and operational challenges relating to the titanium blank edge strips, blank roughness and sandblasting optimisation, blank quality control, electrode spacing, polyconcrete cell dimensional stability and cell top furniture. The impact of these on process performance is presented and the development of fault checking and rectification methods, to maintain high process performance, is explained.INTRODUCTIONThe expansion of Anglo American Platinum’s Rustenburg Base Metals Refinery necessitated the construction of a new Nickel Tank House to achieve two primary objectives, namely increasing the nickel electrowinning capacity from 22 500 tons per annum (tpa) to 32 400 tpa nickel, and a design to reduce the nickel aerosols to 0.05 mg.m-3 as a time weighted average over 8 hours, which is half of the legislated occupational exposure limit (OEL) of 0.1 mg.m-3."

Jan 1, 2016

By A. C. Hawken, L. M. Strah

"The Report outlines the Conversion to Rubber Mill Liners and steel grinding balls from the old style Cobalt pocket liners and flint pebbles which had been used in 5'x22' Fraser-Chalmers tube mills for over fifty years. An outline of the past history and some of the plant modifications are mentioned as well.The details pertaining to considerations, modifications and repairs carried out on the mills are described. Factors influencing the rubber liner design are outlined along with the description of the rubber liner design.The performance and advantages to date are given and concludes with brief summary.HISTORYThe original amalgamation-cyanidation mill of Dome Mines Limited went into operation in 1912. Milling has been continuous since 1912, except for two periods; one of 17 months commencing in December 1917, and the other of about 12 months, when fire destroyed the plant in November 1929. Initially the capacity of the mill was 350 tons a day. In 1916 it was raised to 750 tons a day, following which there was a gradual expansion to 1,500 tons a day."

Jan 1, 1977

By James Kear, Romain Prioul, Robert G. Jeffrey, Andrew P. Bunger, Dimitry Chuprakov

"Unconventional gas and geothermal reservoirs are typically naturally fractured and therefore the challenging problem of hydraulic fracture (HF) growth through naturally fractured rocks is an important issue especially for the development of accurate predictive HF models. This paper presents results from laboratory experiments in which HFs have been created in both sandstone and crystalline (gabbronorite) rock specimens such that they impinge either orthogonally or at an oblique angle on an unbonded, machined frictional interface. Depending on the conditions of each experiment, the fractures either cross or are blunted at the interface. The growth behavior was ascertained for these experiments based on a synthesis of the injection pressure record, active ultrasound monitoring, and direct post-experiment inspection of fractured specimens. From these experiments we observe: 1) A contrast between direct crossing and crossing with an offset for orthogonal and oblique intersection, respectively, 2) Apparent independence of crossing/blunting behavior on the friction coefficient for orthogonal intersection, 3) Dependence of the stresses required to promote crossing on the intersection angle between the HF and NF, 4) Existence of cases in which the hydraulic fracture crosses but then essentially ceases propagation such that all fluid is diverted to the interface. INTRODUCTIONHydraulic fracturing is a vital technology used to increase the productivity of oil, gas, and geothermal wells. Predicting hydraulic fracture (HF) growth is, in turn, critical to design of hydraulic fractures that grow to the desired length, accept the desired amount of proppant, and remain contained in the reservoir without unwanted height growth into surrounding layers (e.g. Economides and Nolte, 2000). The importance of HF modeling has prompted 6 decades of research during which simulators have become more efficient, more accurate, and have addressed a growing range of complexities (see review of e.g. Adachi et al., 2007).One of these complexities is the interaction between HFs and mechanical discontinuities such as natural fractures (NFs). Efforts in this area have been mainly driven by development of unconventional (i.e. low permeability) oil and gas resources because essentially all viable low permeability reservoirs, including shale gas/oil reservoirs, are naturally fractured to some degree (King, 2010). One of the most important questions for developing effective HF stimulation strategies in these reservoirs is whether the hydraulic fracture(s) is/are expected to be single-stranded or whether interaction with the NFs will lead to network-like growth. The basic building block for numerical simulators that can address this question (such as Kresse et al., 2013 and Weng et al., 2014) is whether an HF that intersects an NF will cross the NF or whether its growth will be captured by the NF so that additional fluid injection pressurizes the NF but does not generate ongoing growth of a new HF. These scenarios, including subcategories such as crossing with an offset, have been recognized for several decades (Daneshy, 1974; Warpinski and Teufel, 1987, and as recently reviewed and expanded by Chuprakov et al., 2013)."

Jan 1, 2015

By P. R. A. Andrews, R. K. Collings

"There are more than thirty-five deposits or occurrences of celestite in Canada, chiefly in Newfoundland, Nova Scotia, New Brunswick, Ontario and British Columbia. Deposits of economic interest are the Lake Enon and MacRae deposits in the Loch Lomond district of Cape Breton Island, Nova Scotia. Two Cape Breton deposits were operated from 1969 to 1976 by Kaiser Celestite Mining Limited, which supplied an upgraded celestite concentrate to an associated strontium carbonate plant at Point Edward, near Sydney.The MacRae deposit is of current interest because of its possible development for strontium carbonate production using the ""black ash"" process. This process involves chemical leaching, rotary kiln calcining with petroleum coke, washing and treatment with carbon dioxide.Celestite is the basic material used in the manufacture of strontium chemicals, principally strontium oxide, carbonate, nitrate, chromate, chlorate, chloride, sulphide and phosphate. Strontium chemicals, in turn, are used in the manufacture of glass and ceramics, in pyrotechnic devices, in the production of strontium metal and in other metallurgical applications. Recently, strontium ferrites have been introduced into permanent ceramic magnets."

Jan 1, 1991

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By S. W. Brooksbank, R. A. Benkis

"IntroductionThe Republic of Indonesia is a developing Southeast Asian country that unites the Indian and Pacific oceans, and spreads across nearly 14000 islands with a total land area of about two million km-. The distance across the country approximates the distance across Canada: Indonesia extends for more than 6000 km from the northern tip of Sumatra to the eastern border of Irian Jaya in the middle of New Guinea. With a population of around 180million, Indonesia is one of the world's most populous countries. A mix of 366 ethnic groups populates the country and there are some 250 distinct languages spoken. The topography of Indonesia generally is quite rugged because of its numerous volcanos. For example, the island of Java has 121 volcanos, of which 15 rise above 3000 m and another 44 reach heights between 2000 m and 3000 m.Indonesia has a diversified resource base, with plentiful energy resources (coal, oil, gas and hydroelectric), significant mineral deposits, large timber potential and a developed system of agricultural commodity production and export. A high proportion of the primary resources are on the sparsely populated islands of Sumatra and Kalimantan, whereas 7'3 of Indonesia's people reside on Java, or on 70/0 of the country's land area. Around Jakarta in western Java the population density is around 8000 per krn2. This contrasts with less than nine people per km- on Sulawesi (Fig. I)."

Jan 1, 1992

By O. G. Olvera, D. G. Dixon, E. Asselin, L. S. Quiroz

Dissolution rates of chalcopyrite (CuFeS2) were calculated using electrochemical impedance spectroscopy (EIS). The calculated dissolution rate decreased by a factor of 3.2 after the electrode was passivated. The results presented in this work indicate that the reduction of Fe3+ was the rate-controlling step for fresh CuFeS2 electrodes while the transport of cations within the passive film limited the dissolution rate for the passivated electrode. The transfer of cations at the electrode/electrolyte and passive film/electrolyte interfaces did not affect the dissolution rates of the fresh and passivated CuFeS2 electrodes, respectively. The catalytic effect of pyrite (FeS2) on the dissolution of CuFeS2 continued after the passivating treatment. The contact of fresh and passivated CuFeS2 electrodes with different FeS2 particles resulted in increased dissolution rates, due to an increase in the reduction rate of Fe3+.

Jan 1, 2014

"A growing public awareness of work-related diseases such as pneumoconiosis and the impact of this awareness on legislative bodies and on the skilled labour market are reasons why the Canadian mining industry must consider dust control of top-drawer importance. Measurements and standards related to the hazard are necessary to control a dust situation and to avoid excessive risk. The author discusses some of the methods of measurement, standards proposed and terminology used in this developing technology. The purpose primarily is to give a better understanding of the basic advances achieved by those who have applied current knowledge with a measure of success."

Jan 1, 1972

By Nur Hossain

Analysis of Linear Elastic Fracture Mechanics (LEFM) parameters via the Virtual Crack Closure Technique (VCCT) has been obtained for SENT specimens of AM6OB magnesium alloy. It is found that the ratio of initial crack length to initial monotonic plastic zone size is one of the critical factors in establishing the limit of using LEFM concepts. If this ratio is below a certain limit (i.e. when crack lengths are small in comparison to the plastic zone size), loss of similitude stress intensity factor range would occur. This ratio, therefore describes the limit below which the use of LEFM would no longer be admissible. In this study, the above limit was established for AM6OB magnesium alloy. In addition, fatigue crack propagation tests were conducted to ascertain the fatigue response of the alloy and determination of the coefficients of Paris model.

Jan 1, 2010

By S. R. McCutcheon

"The regional stratigraphy of the Lower Carboniferous Windsor Group in the Moncton Subbasin indicates that evaporites could be present in the Marysville Subbasin, part of what was formerly called the Central New Brunswick Platform. The Windsor Group consists of basement-fringing, algal build-ups (Gays River Formation), in places with intercalated siliciclastics (Parleeville), which are laterally equivalent to deeper-water, very thin to thinly bedded, euxinic limestone (Macumber). The Macumber is overlain by stratiform, nodular to mosaic anhydrite (Upperton) that is hosted by carbonate or calcareous siliciclastics. The sulphate also is equivalent, in part, to the algal buildups. Deep-water salts (Cassidy Lake) which overlie and in places are laterally equivalent to Upperton rocks have a basincentre distribution. The Windsor Group is overlain by shallow water evaporites and mudstones (Clover Hill) or by greenish grey mudstone (""transitional beds""). The paleogeographic distribution of these rocks provide important clues that help predict where deposits of salt and potash can occur.IntroductionCurrently there are three known potash deposits in southern New Brunswick (2, 3 and 4, in Fig. I). All three deposits occur in the Windsor Group of the Moncton Subbasin, but until recently their exact stratigraphic position within the group was not known.The Windsor Group is a cyclic sequence of carbonates, evaporites and red beds that is up to 1.0 km in thickness (Schenk 1969, p. 1038). It is Late Mississippian (Visean) in age and the type area is near Windsor, Nova Scotia. The group was named by Dawson (1873) but the rocks were described earlier by Hartt (1867). Dawson (ibid.) was the first to assign rocks in southern New Brunswick to the Windsor Group."

Jan 1, 1983

By J. C. Ingles

"A new technique is in the process of revolutionizing inorganic chemical analysis. Galled atomic absorption spectrophotometry, it combines the use of a special light source, a flame, and the equipment of conventional spectrophotometry, to provide a quick, reasonably accurate method for the determination of a large number of elements.This paper outlines the principles on which it is based, describes the commercial instrumentation"" available for exploiting it, and. summarizes current applications in process metallurgy."

Jan 1, 1966

By H. W. Smith, R. D. Fournier

This paper presents the results of an investigation of a full-scale rod mill. Appropriate numerical techniques are developed for the experimental determination of the parameters of a dynamic mathematical model from steady state data. The results confirm that this full-scale rod mill behaves similarly to laboratory-scale ball mills for which results have previously been obtained. It is noted, however, that although the model presented is adequate for predicting over-all particle size distributions, the size distributions of individual components of a multicomponent ore cannot be predicted.

Jan 1, 1972

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"This paper briefly summaries the status of a recent program aimed at identifying new chemistry for use as sulfide mineral frothers and collectors. The background motivation and planning behind this work is given along with the general families of chemical structures synthesied and studied in detail followed by typical flotation application results in various laboratory and plant scale tests. Flotation testing to date has been very encouraging with often improved recoveries of certain minerals and improved pyrite selectivity being observed over commercially available reagents. In addition, in some cases, the dosage and lime requirements of these new collectors are significantly less than that associated with standard sulfide mineral collectors. INTRODUCTIONFroth flotation is one of the most widely used and economic means of concentrating metal sulfide ores. There are numerous reference books that have been published on the chemical aspects of flotation [e.g., ref. 1-7] which are based on studying the influence on selected minerals of chemical structures that have been used commercially for many years. In fact, almost 98% of the volume of flotation collector and frother reagents used at the industrial level today were known and manufactured in some form 25 years ago [8]. There are many reasons for this lack of significant new flotation reagent development [9] including the general utility and relative cheapness of existing collectors such as xanthates and existing frothers such as the alcohols and glycol ethers. Another reason is the inherent complexity of the flotation process itself coupled with highly variable and difficult to standardize feed materials. This environment makes reliable reagent comparisons difficult and seriously limits the use of theoretically based chemical structure studies to predict new or optimal reagents. In addition, the higher cost of specialty flotation reagents demands that their performance attributes be significantly greater than that achieved with existing all-purpose commercial reagents - something often difficult to prove in practice."

Jan 1, 1988

By Kim H. Shikaze, John R. Hawley

"Even though acid mine drainage is an old problem, particularly in coal mining areas, its appearance in the form of a major environmental hazard in the hardrock mining districts of Ontario was unexpected. The yellow and amber coloured wastes that characterize an acid mine drainage situation were first noted by the Ontario Water Resources Commission in the uranium mining Elliot Lake district. Problems of a similar nature were also noted in the copper-lead-zinc camp at Manitouwadge, the nickel camp at Sudbury and at numerous isolated base metal properties, both in and out of the Province of Ontario.Without exception, when acid mine drainage type effluents were evident, the specific companies involved worked sulphide or sulphide-associated ores. Without exception, the ore bodies contained quantities of iron sulphide (in various mineralogical forms) and, without exception, the milling circuits serving these operations were such that the iron sulphides were rejected to the tailings areas as waste.Once in a tailings area and after a varying period of time, iron sulphides react to form water soluble salts which, when discharged in the effluents from the tailings area, can affect stream chemistry and stream ecology.It is not unusual that the minerals pyrite, marcasite and pyrrhotite (all iron sulphides) react to form a stable oxide under atmospheric conditions. The law of stability of rocks and minerals, for instance, states that rocks and minerals are stable only in the environment of their formation and, as the environment surrounding them changes, the rocks and minerals tend to change to other species which are relatively more nearly stable under the conditions of the new environment (a). Under atmospheric conditions, iron oxide exhibits a greater stability than iron sulphide."

Jan 1, 1971