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By Julie Hunt

Rimfire Minerals Corporation: early stage precious metal exploration specialists with discovery opportunities in partnership with major and mid-tier gold producers or prominent junior exploration firms. Mike Roberts, Senior Geologist

May 1, 2006

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By D. T. White

"Metallurgical extraction processes often call for the heating of aqueous slurries. Indirect heat exchangers are generally not feasible for service with high yield stress slurries because of low heat transfer rates. It is more appropriate to heat the slurry by direct contact, typically with steam as the heating medium. Although having a long and successful history, direct-contact heat transfer to aqueous slurries has been used without the support of pilot plant research. This paper provides results of the needed research, the work being done at a scale large enough to enable direct scale up to commercial operations. A pilot plant heater was constructed and tested to develop an understanding of the slurry heating process and to ensure that commercial scale heaters were appropriately sized.INTRODUCTIONPressure Leaching OperationsPressure leaching operations are often used to oxidise sulphide gold ores, or for extraction of nickel and cobalt from laterite ores with sulphuric acid. Where there is sufficient sulphur available, the exothermic pressure oxidation reactions can be self sustaining at temperatures as high as 225 ºC, without having to preheat the feed slurry. At lower sulphur levels, slurry preheating is required. This is typically achieved by utilising the flash steam released from the slurry letdown stages and contacting this directly with cold incoming slurry ahead of the autoclave. The vessels where this slurry-steam contact is made are known as heaters or condensers, with the number of pre-heat stages varying, depending on how much heat is evolved in the oxidation reaction (Mason, 1990).In nickel laterite pressure acid leaching processes, which operate between 245 and 270 ºC, the only significant exothermic reactions are those associated with dilution of sulphuric acid in the leach. As a consequence, slurry preheating with flash steam is always used commercially. In practice the number of flash steam preheating stages required varies from 1 to 3, driven by a number of factors, including other uses for flash steam and the upper temperature limit at which preheated slurry can be pumped. A diagram of a typical pressure acid leach train is shown in Figure 1.For pressure acid leaching operations and at low sulphur levels in pressure oxidation, boiler generated direct steam addition to the autoclave is required to sustain the reaction temperature. For this reason it is imperative that the flash steam – slurry heat transfer is efficient and the slurry temperature approaches that of the flash steam closely."

Jan 1, 2012

By G. R. Phare

Explosives formulation is dictated by desired field performance, which in turn is dependent on such physical properties as strength, velocity of detonation, sensitivity, and water resistance. The design of explosives to obtain these properties is discussed with some reference to detonation and rock mechanics theory.

Jan 1, 1958

By R. K. Jonas

Many leading copper and other mineral processors have rapidly adopted advanced controls in last 5-10 years. Almost 600 multivariable predictive controls have been installed in mineral processing, and almost 50% of those are in copper concentrator plants. In most cases, mineral processors rely on 3rd party support to implement these advanced technologies. One challenge facing advanced control user is the selection providers and services for these technologies. The trend has been towards the use of multivariable predictive control and use of technology provider’s services. This paper will discuss status of advanced control, and the merging trends in the mining industry. A review will be presented of how advanced control is being applied in the mining industry over the last decade, and how user challenges are being overcome. Next the emerging uses of multivariable predictive control (such as multi/inter-unit optimization), focusing on the latest trends in concentrator plants. Finally, a review will be made of emerging technology advances in the that can be advantageous to mineral processors. INTRODUCTION Review of advanced control in mineral processing Advanced controls are serving an increasing role to improve processing plant operations and profitability. As advanced control is being installed into more mining processing plants such as copper concentrators, many of these plants are concerned about the selection technologies and vendors to support the installation and maintenance of these controls. In a study by Jonas and Craw (2011), they found that most new users have not had prior experience with advanced controls. It is the author’s experience of almost 30 years in advanced controls that most mineral processers considering advanced controls can benefit from better understanding of the technologies and their support requirements.

Jan 1, 2019

By Ralph W. Edie

"IntroductionTHIS PAPER deals with chemical and mineralogical changes in wall-rocks associated with pitchblende mineralization in the Gold-fields area of Saskatchewan. The localities at which the rock specimens studied were collected, and descriptions of the various rock-types referred to, are given in a previous paper by the author (5).The geological field work upon which this paper is based was carried out while the writer was employed by the Eldorado Mining and Refining Company during the summers of 1948, 1949 and 1950. The laboratory work§ consisted largely of quantitative spectrographic analyses for both major and minor elements, supplemented by an examination of 250 thin sections of both altered and unaltered rocks.Character of the AlterationHydrothermal alteration, with associated pitchbende mineralization, is widespread in the Goldfields area of Saskatchewan. The most intense alteration is restricted to the immediate vicinity of fault or breccia zones, but large areas are affected to a minor extent.In detail, the relationship between alteration and pitchblende mineralization is complex, as individual veins do not in general have separate alteration halos. Pitchblende generally occurs in gash-like calcite veins or stringers in wide, fractured zones associated with faulting. Large, lenticular and tabular masses of slightly to intensely altered rock occur in the same wide fracture zones as the mineralized veins. However, vein deposition appears to be-long to a later fracturing period, after hydrothermal alteration was more or: less completed. Generally, the veins transect and are confined to highly altered rock, but on the other hand many highly altered zones intersected in diamond drill-core are barren of mineralized veins."

Jan 1, 1953

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015

By G. Deschênes

Located in North West Tanzania, Buzwagi is an underground narrow-vein gold mine owned by Barrick Gold. The plant was commissioned in 2000. The reserves are estimated to be more than 25 years. The ore, containing gold, silver and copper mineralization in sulphides, is processed at 3,300 tpd. This paper presents the results of an investigation to determine the performance of an ammonia-cyanide leaching approach to recover gold from two samples. Coarse gold was recovered by gravity prior to leaching. The gravity tailings had the following composition; 1.97 g/t Au and 0.31% copper for the medium cyanide soluble copper (MCSC) sample and 2.80 g/t Au and 0.53% Cu for the high cyanide soluble copper (HCSC) sample. Experiments were conducted for 72 hours in stirred tank reactors with monitoring and control of parameters. The straight cyanidation produced gold extractions of 76.1% for the MCSC sample and 84.6% for the HCSC sample. Associated cyanide additions were 6.1 kg/t and 11.5 kg/t respectively. The gold extraction of the MCSC sample was improved to 88.8% using 350 ppm NaCN and 700 ppm ammonia. The associated cyanide and ammonia additions were 2.5 kg/t and 1.7 kg/t respectively. For the HCSC sample, 82.5% gold extraction was obtained using 500 ppm NaCN and 600 ppm ammonia. The cyanide addition and ammonia additions were reduced to 3.8 kg/t and 1.0 kg/t respectively. No significant decrease in gold extraction was noticed when the cyanide and ammonia were reduced to 150 ppm and 500 ppm respectively. In the presence of ammonia, a significant amount of cyanide was oxidized to cyanate by the cupric ion. In the absence of ammonia, the formation of copper cyanide was the predominant reaction responsible for consumption of cyanide.

Jan 1, 2012

By Peter Hood

Data on world-wide geophysical activity in mining exploration programs are collected annually by the Society of Exploration Geophysicists' Geo-physical Activity Committee as part of a continuing service to the industry. The data are obtained by sending out questionnaires to all organizations which are known to be carrying out mining geophysical work; the organizations canvassed include mining companies, contractors, government departments and universities. The questionnaire is divided into three sections; namely, ground methods, airborne methods and research. The data compiled from the questionnaires show that world-wide utilization of mining geophysical methods reached a new high in 1967 with total expenditures of (U .S.) $32,323,240. This was divided as follows: ground methods, $18,106,785; airborne methods, $10,-123,405; and research, $4,093,050. For the ground methods, most money was spent on the induced polarization technique ($5,681,780); electromagne-tic methods were second in reported expenditures ($2,010,900). The total reported geophysical line mileage flown was 1,275,072 line miles, with aeromagnetic surveying being the most popular airborne method. The total amount spent on aeromagnetic surveys was $5,832,564 for 895,420 line miles. This gives an average cost of (U.S.)$6.50 per line mile.

Jan 1, 1968

By M. Turner-Jones, N. Steenekamp

"The Lonmin Base Metal Refinery treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode as well as a concentrate containing the platinum group (PGM) metals. The original process employed a Sherritt design and utilizes atmospheric and pressure leaches for the dissolution of base metals. This paper describes the original flow sheet and the improvements made to enhance PGM recoveries, product quality and to increase capacity. Changes include the introduction of flash recycle cooling on the autoclave, batch leaches to improve the quality of the PGM concentrate and the implementation of solid-liquid separation with centrifuges. INTRODUCTIONThe Lonmin Base Metal Refinery (BMR) is about 100 km north-west of Johannesburg and treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode and a concentrate containing the PGMs. The plant was commissioned in 1985 based on a Sherritt design to treat 12 tonnes converter matte per day. The original flow sheet consists of a milling circuit, an atmospheric leach and a pressure leach to produce a PGM concentrate which is despatched by helicopter to the Lonmin Platinum refinery in Brakpan, about 40 km east of Johannesburg. The liquor from the atmospheric leach is treated by crystallization to produce a nickel sulphate hexa-hydrate crystal. The leach liquor from the pressure leach is treated by a selenium removal step followed by electro-winning to produce copper cathode. The spent solution from the copper electro-winning is recycled to both the atmospheric and pressure leach steps to provide sulphuric acid for the leaching reactions.Modifications were made to the original circuit to increase the plant capacity, to improve the PGM recoveries and to improve the quality of the PGM concentrate. Capacity increases included all the unit operations, new mill, new first stage, additional autoclaves, additional nickel sulphate crystallizers, new copper electro-winning and new batch leach reactors for upgrading the PGM concentrate. The current circuit is described in this paper and not the detailed history of each plant change."

Jan 1, 2012

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By D. Duffy, V. Papangelakis

"MgCl2 brines present a number of potential advantages for the processing of saprolite ores for nickel production. With a chloride system it is economically requisite to recover hydrochloric acid, which can be performed in a more energy efficient manner by precipitation and subsequent decomposition, as compared with conventional pyrohydrolysis. In addition, concentrated MgCl2 solutions enhance the activity of acid used, allow atmospheric leaching at elevated temperature and inhibit magnesium dissolution, which reduces acid consumption and increases metal selectivity. Leaching and iron control experiments have been conducted in concentrated MgCl2 brines, up to 4.5 m, to determine the most amenable process conditions. INTRODUCTIONChloride metallurgy has received an increasing amount of attention in recent years, especially with respect to the treatment of nickel laterites. Although the limonitic fraction can sometimes be economically treated by High Pressure Acid Leaching (HPAL), acid-consumption problems are encountered with the higher magnesium content of the saprolite fraction. As magnesium does not hydrolyze under HPAL conditions, as iron and aluminum do, any sulphuric acid used to leach magnesium is subsequently neutralized and wasted. In addition, this magnesium must later be disposed of in some fashion, further complicating the process. The most common method used to process saprolite is the Rotary Kiln-Electric Furnace (RKEF). This uses a kiln to dry and preferentially reduce nickel, before sending the calcine to an electric furnace. Although nickel recoveries are high, and the problems of acid consumption are avoided, the capital and energy costs associated with this process are high (de Bakker, 2011).The problems outlined above have led to the investigation of an atmospheric chloride process for the treatment of saprolite ores. The use of a chloride system presents a number of advantages, but also a few limitations. Metal chlorides tend to be very soluble, with a few notable exceptions (silver, mercury and lead), allowing for smaller processing equipment through more concentrated solutions. This solubility also serves to reduce the potential for scale formation. In addition, a hydrochloric acid leach is more aggressive than a comparable sulphuric acid system, and the activity of the hydrogen ion can be augmented by further chloride addition (Peek, 2011). This activity augmentation in concentrated chloride systems, first reported by Jansz, has repeatedly been referenced as a motivating factor behind chloride hydrometallurgy (Jansz, 1983; Harris and Magee, 2003; Harris et al., 2004; Demopoulos et al., 2008; McDonald and Whittington, 2008; Demopoulos, 2011; Peek, 2011; Verhulst and Lakshmanan, 2011). This activity increase allows a similar amount of acid to perform more in a concentrated solution than in a dilute solution, decreasing overall acid requirements. As such, much focus has been placed on leaching in concentrated chloride systems, or brines, using calcium, magnesium or sodium as the cation (McDonald and Whittington, 2008)."

Jan 1, 2012

By C. Allen, V. Hensel, J. S. Stachulak

"Vale has been actively evaluating new technologies to curtail diesel emissions. This paper discusses the selection, installation, operation, and evaluation of the MANN+HUMMEL SMF®-AR diesel particulate filter system to reduce diesel particulate matter emissions in underground mines. The system uses a sintered metal filter element, an iron fuel-borne catalyst with an onboard dosing system, an electric heater that uses onboard power, and a sensor-based control unit. More than 6,000 h of testing demonstrated that the system represents a breakthrough in the successful control of soot emission from light-duty vehicles with differing soot emission levels, exhaust temperatures, and duty cycles.RÉSUMÉ La compagnie Vale évalue activement de nouvelles technologies pour réduire les émissions de diesel. Le présent article discute du choix, de l’installation, du fonctionnement et de l’évaluation du système MANN+HUMMEL SMFMD-AR de filtrage des particules de diesel pour réduire les émissions de particules de diesel dans les mines souterraines. Le système utilise un élément filtrant en métal fritté, un catalyseur à base de fer dans le carburant avec un système de dosage intégré, un élément de chauffage électrique qui utilise l’alimentation incorporée et une unité de contrôle avec un capteur. Plus de 6 000 heures d’essais ont démontré que le système représente une avancée pour réussir à contrôler les émissions de suie des véhicules légers avec différents niveaux d’émission de suie, différentes températures d’échappement et différents cycles opératoires."

Jan 1, 2015

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By Eddy Dénommé, Deni Villeneuve

"Niobec mine, a producer of pyrochlore concentrates since 1976, became a producer of ferroniobium in 1994 and achieved accreditation to the ISO 9002 standard in 1995. The goal of ISO 9002 is to ensure that the products supplied to clients regularly meet their specifications, through explicit work standards and procedures throughout the production process, from deposit appraisal to ferroniobium production.A key element of ISO 9002 implementation at Niobec consists of the quality control procedures applied to the raw materials: the ore fed to the mill and the pyrochlore concentrate fed to the reduction plant. These controls extend from exploration, deposit appraisal, mine planning and reserves estimation, mining, mineral processing and, finally, ferroniobium production. The implementation of ISO 9002 has allowed more efficient control of the quality of the final product sold to clients. It requires interactive team work, the role of the geologist being to relate all information pertaining to raw material and product quality to the geological framework of the deposits."

Jan 1, 1997

By E. Ghali

"Corrosion of support system components (e.g., bolts, mesh, plates) is a safety and economic concern in underground mines. This paper reports the results of a five-year study wherein corrosion coupons were installed at select locations in participating mines, recovered at regular intervals, analyzed for signs of corrosion, and tested to quantify loss in capacity. Complementary tests were conducted on recovered mesh and friction bolt specimens. The data provide insights into contributing factors for support systems corrosion, which aid in the selection of appropriate support strategies and reliable assessment of the useful life and need for rehabilitation of a support system.RÉSUMÉ La corrosion des composantes des systèmes de soutien (p. ex. boulons, grillages et plaques) est une préoccupation économique et de sécurité dans les mines souterraines. Cet article présente les résultats d’une étude de cinq ans pendant laquelle des coupons de corrosion ont été installés à des endroits spécifiques dans les mines participantes; ces coupons ont été retirés à des intervalles réguliers, analysés pour des signes de corrosion et mis à l’épreuve pour quantifier la perte de capacité. Des essais complémentaires ont été effectués sur les grillages récupérés et sur les échantillons de boulons d’ancrage. Les données aident à comprendre les facteurs qui contribuent à la corrosion des systèmes de soutien, ce qui est utile dans le choix de stratégies appropriées de soutien et pour une évaluation fiable de la durée de vie utile et du besoin de remise en état d’un système de soutien."

Jan 1, 2015

By F. Grant

"General *The mining experiences of the coal mining industry in Western Canada have been extremely varied, with the mining companies having to adjust their operations or fail due to the harsh economy of the country in the first part of the century. The bituminous or mountain mines had the railways as main consumers with, at times, optimism that potential steel producers would require metallurgical coal. The prairie and foothills mines mainly provided household fuels, with the fine coal sold to local thermal power plants at discounted prices. In practically all cases fuel competition was very keen, and the less successful mines ceased operations in short-time spans. Knowledge of the parameters that governed the success or failures of the past coal operations should be of value to the present and future mining companies. The initial coal mines were small and were started to supply local demand. These mines had little in the way of capital machinery, engineering, or transportation equipment; therefore the mining methods and mine plans were very simple. The first industrial-sized mines imported most of their management and mining methods from other mining areas, mainly Great Britain. It took time to change the bias of management and mining methods to the requirements of strata characteristics, with rapid closure to those mines that were slow to adapt working methods. The main markets for coal were for household fuel, thermal power plants and railways, with very few other industrial markets developed. The economy of the period was harsh and cyclic and the coal mines were affected more than most industries by these boom and bust periods. It led to the survival of the fittest or the most efficient. Due to the economy, mechanization was introduced to the mines very slowly, with the inability to sell coal fines at a profit being another reason for the delay. Manual labour with hand tools was the main means of production. The work was heavy and arduous, and the pay was based on contract coal tonnage; therefore both men and management paid close attention to details so that nonessential work could be eliminated. Mine openings were dimensioned so that coal could be loaded easily by hand and support requirements were kept to the minimum. Transporting and handling the timber supports required heavy labour; thus the most efficient dimensions were chosen to suit the strata. On the other hand, during the main production seasons the mines tried to make the strata stress work for them so that the pressure was kept on the coal face to keep the coal loose while the strata, a short distance back, was induced to cave to minimize the abutment stresses. This caused mining to be an art, using skills developed by experience with the strata. This led to the development of efficient mine layouts with the openings dimensioned to the strength of the strata and the type of support available. The lack of capital and mechanization, and the manual labour, induced the mines to correlate their service and haulage systems with their mining methods. This caused many innovations that proved very practical."

Jan 1, 1985

By R. L. Stanton

"The present contribution examines, in some detail, what appear to be the three outstanding features of the field occurrence of the conformable ""pyritic"" deposits. These are their association with fragmental volcanic rocks (and derivatives), their occurrence in sediments of near-shore formation, and their highly variable structural associations.In a recent paper it has been suggested that two such ""pyritic"" de-posits in New Brunswick may have originated as marine concentrations of volcanic base metal and sulphur compounds, and that many of their present features are the result of diagenesis, folding, and regional metamorphism. This is now put for-ward as a general explanation for the particular class of deposit considered.Such deposits should, on this hypo-thesis, be regarded quite simply as an integral part of the particular geological environment in which they occur -as a normal, though minor, sedimentarry type developed, char-acteristically, in near-shore and shelf facies of intravolcanic units formed along the margins of eugeosynclines. They should not be considered -as, for example, is required by the re-placement theory -as later features simply superimposed on a geological situation to which they are genetically unrelated. Where they are associated with folds and other structures, this may be attributed, from one in-stance to another, to mechanical migration during folding, weaknesses induced by pre-existing sulphides, and, occasionally, to fortuitousness.In the light of this postulated origin, it is suggested that the first stages in regional prospecting for deposits of this particular class should be broadly palaeogeographical. Later phases of the search should then be directed to the delineation of sedimentary facies and, finally, to the investigation of geological structure."

Jan 1, 1960

By K. Mayhew, R. Bruce, A. Heidel, G. P. Demopoulos

"Teck and Aurubis are working together to commercialize a technology for the processing of copper arsenic sulphide concentrates that is economic and sustainable with regards to the environment and community. The pressure hydrometallurgical approach is a desirable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. A test work program was carried out where a range of copper concentrates with varying arsenic grades was processed under CESL leach conditions. This paper discusses the stability character (in terms of arsenic) of the resulting residues and their mineralogy. The basic ferric arsenate sulphate phase (BFAS; otherwise known as type 2) was identified as the main arsenic carrier. All CESL residues demonstrated high stability (<1 mg/L As) through a range of aggressive (pH and ORP) environmental leach conditions.INTRODUCTIONArsenic deportment and control in the copper industry needs an integrated approach involving each stage of the value chain, i.e. exploration, mine operation, refining process and mine closure. Teck Resources Limited (Teck), Canada’s largest diversified mining company and Aurubis, Europe’s largest copper producer, have formed a partnership to advance the application of CESL copper-gold technology for the development of high arsenic bearing copper resources (Bruce et al., 2011).Among the options for arsenic control in the metallurgical treatment of copper concentrates is the precipitation of ferric arsenate, which is widely accepted as the most suitable method for stabilizing arsenic (Ferron and Wang, 2003). The pressure hydrometallurgical approach to processing arsenic bearing copper concentrates is a favorable option as mineral extraction and arsenic fixation can take place in a single autoclave vessel. Under CESL pressure leaching conditions (150 °C, 1380 kPa) high copper extraction and arsenic (V) fixation is possible.Within the pressure leach autoclave, arsenate and ferric iron react to form scorodite type phases. The precipitate formed under CESL conditions is dependent on the Fe (III) /As (V) ratio and the tenor of cations and anions, particularly excess sulphate (Gomez et al., 2011a). Previous studies on CESL residues have found arsenic to be present as crystalline scorodite (FeAsO4.2H2O) (Bruce et al., 2011), basic ferric arsenate sulphate (BFAS: Fe(AsO4)1-x(SO4)x(OH)x·(1-x)H2O, where 0.3<x<0.7), and/or arsenate adsorbed on to hematite (Gomez et al. 2011b). Although not a focus of previous work, scorodite was the predominant precipitate formed when the concentrate Fe/As was <1.5 (Mayhew et al., 2010), and BFAS was the predominant precipitate when the concentrate Fe/As was >10 (Gomez et al. 2011b)."

Jan 1, 2012

By C. R. Larsen, R. G. Bradburn, A. L. Mular, B. C. Flintoff

"Following the acquisition of grinding- circuit data at Brenda Mines Limited for simulation purposes, various methods to mass balance the circuit were evaluated. Unfortunately, different answers were obtained for different balancing methods. A data-adjustment procedure was therefore developed. The procedure assumes that all ""best-fit"" criterion. A search is conducted with the minimum set of water masses and narrow size ranges of solids around the circuit (called search variables), which permit the computation of any of the measured data points. Search variables are used to calculate measured values for an objective function of the form: [ ] where W, is a weighting factor•, M1 is a measured value and M. is a corresponding . value calculated from search vanables. The best values of M, are those which minimize R. The above method is compared with others that have been utilized for mass balancing circuits."

Jan 1, 1976