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"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

By Robert B. Parsons

"Originally intended to be implemented in 1977, but actually introduced effective May 6, 1974, the earned depletion regulations have been substantially refined and modified since their appearance on the Canadian tax scene, so that this important legislation now consists of a highly complicated set of rules which even the most astute follower of tax law has considerable difficulty sorting out!This month, Tax Notes attempts to cut through this bewildering array oj regulations, in reviewing the main features of the earned depletion allowance applicable to mining operations. Despite the phase-out of earned depletion allowances for most oil and gas operations as part of the federal government's new National Energy Program, earned depletion provisions are still alive and well for the mining sector, although they might well be slowly strangling to death in their own entanglement of complexity!"

Jan 1, 1981

By W. R. Cowan

The availability of mineral aggregates for construction purposes is rapidly declining through inadequate resource planning. restrictive zoning and legislation , and competing land uses. The Geological Branch of the Ontario Ministry of Natural Resources has undertaken to provide aggregate inventory reports for all townships designated under The Pits and Quarries Control Act, 1971, and eventually for all towns hips in heavily populated areas. The reports contain maps and recommendations for extractive zoning by municipalities; of necessity only the largest deposits are given priority recommendations. It is intended that these reports should improve the resource planning in areas underlain by large aggregate deposits. The inventory is only possible because a concentrated effort has been made to map the Quaternary geology of populated areas over the last ten years. Future needs require that we develop methods to determine the extent of poorly defined and buried aggregates and that we look for natural alternatives.

Jan 1, 1978

By Ralph W. Edie

"IntroductionTHE GOLDFIELDS AREA in northern Saskatchewan has be-come important in recent years because of numerous discoveries of pitchblende. The area is underlain by rocks of Precambrian age and, because of metamorphism and hydrothermal alteration, the geology in the vicinity of the pitchblende deposits is exceedingly complex and presents a challenge to all geologists •working in the district. This paper is a contribution to the geological literature of the area and presents a description of rock types, supplemented with petrographic, chemical, and spectrochemical data.Field work in connection with this paper was carried out during the summers of 1948, 1949, and 1950 while the writer was employed as assistant geologist for the Crown Corporation, Eldorado Mining and Refining ( 1944), Limited, Gold-fields area. Laboratory work was undertaken at the Massachusetts Institute of Technology during the winter months of 1949-50 and 1950-51 and extended through the summer of 1951.With the exception of SiO2and FeO, all of the new analyses ( 1) presented were carried out by quantitative spectrographic techniques under the supervision of Dr. L. H. Ahrens at M.I.T. Many of the techniques have only recently been developed at that Institute and detailed laboratory procedures have not yet been published."

Jan 1, 1952

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By R. K. Collings

"This paper summarizes research that was done at the Mines Branch, Ottawa, to evaluate samples of phosphogypsum for gypsum products manufacture. The samples were from phosphate fertilizer facilities at: Port Maitland, Ontario ; Valleyfield, Quebec; and Fort Saskatchewan and Redwater, Alberta. All samples were wet-screened, washed, filtered and calcined in a laboratory kettle at atmospheric pressure. Tests were also made at higher pressures in a small autoclave. The gypsum and resulting hemi-hydrate, being acidic, were treated before, during and after calcining with various bases. The hemi-hydrate products were checked for time of set, compressive strength and bond to gypsum wallboard paper. The results of this study indicate that phosphogypsum from each of the sources investigated has potential as a substitute for mined gypsum in gypsum products manufacture. Pilot-scale testing is recommended to confirm that the product would be satisfactory for the manufacture of plaster products on a commercial basis."

Jan 1, 1972

By Witold J. S. Ostrowski

The shaft structure being part of an underground mine, depends on programned functional duties, and on geological and hydrological conditions. The majority of Canadian metal mine shafts are in hard competent igneous rocks, which are in an elastic state of equilibrium around the excavation. Others penetrate soft sedimentary or very weak water-bearing rock formations in which the equilibrium varies from plastic to hydrostatic. Knowledge of how to interpret the underground conditions, determine acting forces and design proper structures is essential for the production and safety of the future mine.

Jan 1, 1973

By G. M. Carrie

Introduction The subject of basic refractories is daily becoming of increased importance in metallurgical processes, and there is a constantly growing necessity for the development of better materials. This fact, together with the realization that Canada possesses one of the best sources of such refractories in the British Empire, if not in the world, made it appear? advisable that the subject be presented to the Empire Mining and Metallurgical Congress at the 1927 meeting. Having been in close touch with developments in the Canadian product during the past five years, G. M. Carrie was requested to prepare such a paper. The Canadian producers of magnesia refractories have succeeded in developing the product to a place where it has almost entirely displaced imported materials from the Canadian market. These developments were made possible by a close study of the methods of preparation of the material, and by an exceedingly careful control of the manufacturing process so as to obtain a thorough blending of the different constituents with the resultant uniformity of composition. This point is very important to the metallurgist, as un-uniform materials are a potent cause of difficulties in most manufacturing processes and the constant trend is towards their elimination. The temperature at which the Canadian material is burned ensures high specific gravity and thorough shrinkage. The grain size of the product is so controlled that the voids are only just sufficient to allow of proper bonding, thus making possible a dense, hard bottom affording high resistance to erosion and shock. Careful proportioning of the constituent elements absolutely prevents disintegration.

Jan 1, 1927

By K. Buxmann

Climate change is a subject of growing concern. Based on the International Energy Agency, about 19% of man made greenhouse gas emissions globally are generated by the transport sector. This paper will focus on the environmental aspects of the light-weighting in transport and the resulting savings of fuel and electricity. Aluminium is an option for lightweight applications in transport, with very high benefits not only in the use stage, but also in the stage of vehicle recycling. Life cycle assessment is used to quantify the relative benefits of light-weighting specific components of cars, commercial road vehicles, buses, ships and trains. A vehicle consists of many components, which are produced by different processes and undergo different types of end-of-life operations. This document does not intend to compare a generic aluminium vehicle with a generic "heavy materials" vehicle. It rather tries to use a pragmatic approach based on specific examples of components where aluminium is used and can be used in the design of new vehicles, also taking into account future developments. The case studies in this paper are based on real cases where aluminium was used. For each component, sensitivity analyses are applied to see the impact of specific parameters such as the end-of-life recycling rate and the use stage driving distance. Significant greenhouse gas savings by the use of aluminium are demonstrated for cars and even higher ones for trucks, buses, trains and ships. In addition, the total potential benefits of light-weighting with aluminium are shown on the global level.

Jan 1, 2007

By G. A. Vissac

METHODS of coal preparation have been greatly developed and improved during the past few years. Under the pressing competition from substitutes that have been displacing coal as a source of heat or power, the coal industry has been able, in many cases, not only to hold its own but to regain much of the lost ground, by offering better products of a higher value. The purpose of this paper is to present, in a brief and simple form, the principles of the latest methods and machinery used in coal preparation, in order to enable the coal operator t0 select methods and equipment capable of solving his own problems in the most efficient and economical way. The paper will deal, in the main, .with coal cleaning. It must be emphasized, however, that a complete coal preparation study covers many other operations, such as handling, screening, de-dusting, dust-proofing, and ash-conditioning. Handling Coal From the producing face to the railway car, coal must be handled with great care, t0 prevent degradation, because the coarser sizes are not only easier to clean than fines but, for our markets, they are often the more valuable. Generally speaking, such care is less important or is unnecessary in the Old Country, where conditions are different. The best way to minimize breakage is to avoid gravity methods in coal transportation. All chutes in a preparation plant should be shaken mechanically, and cleaning processes requiring large surge bins must be avoided. De-Dusting De-dusting of coal is accomplished by the use of vibrating screens, fans, or classifiers, or by a combination of these. Fines below 1/32-in. (or coarser than this, with some coals) can very seldom be cleaned efficiently. Common practice is to discard them immediately, if the moisture content of the coal allows this to be done. Otherwise, they are liable to give unnecessary trouble, either in the form of dust or sludge, which are difficult to collect or to settle. Flotation is the only process which will effectively clean fines.

Jan 1, 1937

By M. S. Badollet, W. C. Streib

"AbstractA commercial method .has been developed for controlling the texture of chrysotile asbestos fibers so that they may possess properties comparable with natural sem1-harsh fibers for use in wet •processes.The physical properties of the soft, silky and slimy fibers are partially altered by a flash-heating process which removes a portion of the molecular water.The heat-treated fibers show an improvement in filterability, an increase in bulk, absorption, and surface area and better electrical properties, such as volume resistivity.IntroductionCHRYSOTILE ASBESTOS fibers are found in nature having varying degrees of texture, referred to as soft, semi-harsh, and harsh. Fibers of each type of texture have inherent characteristics which directly affect their usefulness to industry. Visual differences are apparent under a microscope where it is seen that the soft-textured fibers have a silky, serpentine or wavy appearance, whereas the harsh-textured fibers are coarser and spicular. Semi-harsh fibers, of course, have properties intermediate between these extremes.Fankuchen and Schneider ( l) have shown by the use of low-angle X-ray scattering that the diameter of the harsh type of chrysotile fiber is somewhat greater than tha of the soft variety. Surface area measurements on various chrysotiles of different textures tend to confirm their findings. By nitrogen adsorption methods, it was found that the surface areas of soft types of chrysotile asbestos are approximately 23M2 / g whereas for the harsh types they are as low as 11M2/g."

Jan 1, 1955

Automation Defined ?Using self-operating equipment to reduce human exposure to the mining environment and routine or repetitive work.?-Atlas Copco Terminology: ?Manual Operation ?A vehicle being operated by a person ?in the cab?. ?Radio Remote Control (RRC) ?A vehicle being physically operated by a person through a Line Of Sight (LOS) or Video-Remote equipment. ?Tele-Remote Control ?A vehicle being physically operated by a person at an operator station which is not necessarily located near the vehicle?s working area. ?Autonomous Operation ?A vehicle under self control with the possibility of human supervision and override.

Oct 1, 2010

By D. Van Tonder, C. Edwards

ABSTRACT Solvent extraction is used in many acid leach uranium circuits to upgrade and purify the uranium-bearing solution prior to final product precipitation. A number of strip options are available to recover the uranium from the loaded organic. This paper compares seven of these options on the basis of typical capital and operating costs for the solvent extraction circuit and downstream uranium processing and also considers other related issues. The aim is to provide an objective comparative assessment of these options that could be used as a qualitative guide in process selection or improvement.

Jan 1, 2013

By S. Noh, T. K. Kim, B. O. Lee

Future nuclear reactor systems such as a sodium-cooled fast reactor are being designed under severe conditions in terms of operating temperature and irradiation fluence compared to current commercial reactors. For realization of such systems, it is necessary to develop an advanced structural material having both high strength and irradiation resistance at high temperatures. Oxide dispersion strengthened (ODS) steel is considered as one of the most promising structural material because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. Several advanced ODS steels were designed and fabricated by a mechanical alloying, hot isostatic pressing and hot extrusion processes. This study focuses on the effects of heat treatment parameters during the fabrication process parameters on the microstructures of ODS steels for future nuclear system applications.

Jan 1, 2015

By Milton Fies

Introduction The first experiment in underground gasification of coal in the United States was conducted at Gorgas, Walker county, Alabama, under a co-operative arrangement between the U.S. Bureau of Mines and the Alabama Power Company, at the suggestion of the Power Company. The test was conducted on property of the Alabama Power Company, that owns some 19,000 acres of coal-bearing lands on which there is developed a highly mechanized mine producing some 2,500 cons of good quality steam coal per day. At the same locality ?there is a 200,000 kilowatt steam plant one of the largest in the southern portion of the United States. The Alabama Power Company owes much of its beginning in 1912 to British vision and courage. The original plans for building hydroelectric plants in Alabama, and for the construction of necessary transmission lines, were submitted to Sperling & Company, bankers of London, who agreed to underwrite certain bond issues, the proceeds of which would be used in launching the new Company on its programme. The set-up by which these funds from England were received was through an intermediary Canadian company, which the English investors desired. The Canadian company - Alabama Traction, Light and Power Company, Ltd. became owner of the securities of the Alabama Power Company and marketed its own securities through the banking house of Sperling & Company. Without assistance at this time the Alabama Power Company could not have gone ahead with its programme of expansion and the bringing together of the properties necessary for laying the foundation for a strong Company, fortified with ample power resources essential for future requirements and for dependable service to the public.

Jan 1, 1948

By Maurice A. Roche

Introduction Most of the Flin Flon ore-body, like many others in northern Canada, was covered by water. The original discovery was made where the ore-body outcropped on a strip of land jutting out into Flin Flon lake. The outcrop could be traced for a distance of 600 feet across the strip of land, but disappeared under the lake on both sides of the peninsula. Following the discovery or location of the property, in 1915, and subsequent to its examination by the H.P. Whitney interests in 1925, an extensive diamond-drilling programme was completed, which proved the existence of an ore-body at least 2,600 feet long and 900 feet deep. In plan, the central part of the ore-body at surface attains an overall width of about 450 feet; including waste horses, and gradually becoming narrower to the south. To the north, it stretches out as a much narrower tongue. The main body is a solid sulphide ore containing gold, silver, copper, and zinc. Adjacent to, and on the footwall side of, the solid sulphide ore-body, there are considerable widths of talcy disseminated copper ore, particularly in the upper 300 feet of the deposit, where the maximum widths occur. The ore-body occurs in a greenstone area, the rock being quite hard on the hanging-wall side, with the footwall schisted, talcy, and much softer. The greater part of the ore-body was overlain by 12 to 15 feet of water and from 15 to 90 feet of mud and clay, this material requiring eventual removal, regardless of the system of mining adopted. The total of mud and clay overburden was estimated at 1,000,000 tons. After considerable study, it was decided to mine the upper 300 feet of the ore-body by open-pit methods; the balance of the ore to be recovered by underground mining . The present paper gives an account of the methods adopted in both operations, and of the problems encountered.

Jan 1, 1935

By R. K. Netolitzky

The Weedy Lake, Tower Lake, and Wedge Lake gold deposits illustrate contrasting styles and different ages of mineralization within the same district. The discovery of these deposits was the result of systematic exploration of gold occurrences noted during research of assessment files. The Weedy Lake and Tower Lake depo its reflect a late-stage gold mineralizing event. The e deposits developed along the same major structural break, and also display simi lar mineralogy and alteration patterns. Mineralization is developed in all the lithologies present. The Wedge Lake property, while having occurrences similar to the Weedy and Tower deposits. has the more important Twin Zone which best fits a volcanogenic exhalative model. The Twin Zone has a complex structural history without a recognizable alteration halo. The setting may be proximal to a hydrothermal vent. Mineralization is hosted within a mixed ulphide/oxide/silicate facies iron formation breccia. and the gold is intimately associated with arsenopyrite. The origin and age of the brecciation is key to understanding the mineralizing event. Traditional prospecting procedures in conjunction with conventional B-horizon soil geochemistry were instrumental in the Twin Zone and Weedy lake disco,•eries. Tower Lake was a prospecting discovery partially defined by previous drill programs. This deposit was also identified by B-horizon oil sampling.

Jan 1, 1986

By A. V. Lyamin, J. P. Wang, A. J. Li, Z. Qian

"For general stability analysis of rock slopes, rock mass strength and rock mass disturbance are definitely should be considered. In addition, the impact of earthquakes must be taken into account. In fact, the rock mass strength is very difficult to be assessed which causes the difficulty of analysing rock slope stability. Therefore, an empirical failure criterion, the Hoek-Brown failure criterion, has been proposed. It is one of the most widely accepted approaches to estimate rock mass strength. The rock mass disturbance is important and was found having significant influence on evaluating rock slope stability, especially for rock slope with poor quality rock mass. In the Hoek-Brown failure criterion, the disturbance factor can represent the level of the rock mass disturbance which would provide a reasonable basis for estimating rock mass strength.This research will not only discuss the slope factor of safety, but also consider the influence of the seismic force on rock slope stability assessment using pseudo-static method. In practice, only horizontal seismic coefficient is used. Various magnitudes of the disturbance factor and recommended blasting damage zone thickness are also taken into account. The blasting damage zone thickness considered ranges from 0.5 to 2.5 times of slope height. The research results have potential to be extended and then sets of comprehensive stability charts can be provided for the rock slope stability evaluations. They will be convenient tools for practising engineers. In this study, finite element upper bound and lower bound limit analysis methods are employed. Their applicability has been investigated in some previous studies. The differences between upper bound and lower bound solutions are less than ±10% which would provide reasonable and acceptable range for rock slope stability safety factor estimation."

Jan 1, 2015

By N. Novikov, M. Jastrzebski, N. Kryzhanovskaya, D. Shevchenko, I. Kapran, N. V. Novikov, T. Koehler, B. Zaporozhets

"The PFK FeNi Smelter was re-commissioned by Solway Resources in 2002, ending a long period of economic decline in the adjacent town. In 2009 Hatch was retained to design, supply and install a custom furnace crucible that would accommodate a capacity increase from 34 MW to 40 MW and increase campaign life through binding and cooling technologies, as part of ongoing improvement efforts. The involvement of PFK personnel was critical to the successful integration of the new furnace technology with the existing process and operational practice. The furnace upgrade project was completed in 18 months during 2010 – 2011. Since start-up, the furnace has exceeded production expectations, operating successfully at 42 MW.INTRODUCTIONAfter ceasing operations in the 1990’s, the Pobuzhsky Ferronickel Combine (PFK), located in central Ukraine, was stripped of useful equipment and deteriorated while dormant. The surrounding town experienced a period of economic decline throughout the 1990’s. Solway Industries purchased the complex in 2002 and began a systematic incremental program to re-commission the smelter using both local expertise and specialists from other parts of the former Soviet Union. This led to the re-birth of PFK as a successful toll-smelting complex, and a renaissance for the surrounding economy.As part of the continuing improvement program, PFK approached Hatch in 2009 to study the possibility of a capacity expansion from 34 MW to 40 MW. It was decided, based on the results of the study, to design and install a custom furnace crucible integrating the unique PFK FeNi process with modern Hatch furnace technology. This novel approach had many benefits, including: maximum re-use of existing furnace components (off-gas, feed equipment and transformers), minimal impact on upstream and downstream equipment and building structure, and the retention of a familiar operating regime. The latter was a key factor in the success of the project, as it allowed the extensive operating expertise of the PFK staff to remain highly relevant to the upgraded furnace. This led to minimized capital investment, a rapid start-up and no significant operational challenges switching over to the new equipment incorporating Hatch furnace technology."

Jan 1, 2012

By S. Castro, L. Gutiérrez, L. Uribe

"Use of lime in seawater as a pyrite depressant decreases Mo recovery in flotation of Cu- Mo sulfide ores. When technology that uses sodium metabisulfite (MBS) to depress pyrite is applied, the process is carried out at pH 6.5–7.5, the range where Mo recovery is higher than the usual pH 11.0–12.0 when lime is applied. Redox conditions and chemical reactions involved in depression mechanisms of pyrite by MBS, or sodium sulfite, in seawater are investigated and discussed based on the acidifying effect of MBS, oxidation of sulfite ions by dissolved oxygen, and the role of catalyst of some metal cations (e.g., copper ions) adsorbed on pyrite’s surface.RÉSUMÉ L’utilisation de chaux dans de l’eau de mer comme agent déprimant de la pyrite réduit la récupération de molybdène (Mo) dans la flottation de minerais sulfurés de Cu-Mo. Lorsque l’on applique la technologie utilisant du métabisulfite (MBS) de sodium comme agent déprimant de la pyrite, le procédé se fait à un pH de 6,5 à 7,5, gamme dans laquelle la récupération de Mo est supérieure au procédé habituel utilisant un pH de 11,0 à 12,0 lorsque l’on applique de la chaux. Les conditions de réduction-oxydation (redox) et les réactions chimiques impliquées dans les mécanismes de dépression de la pyrite par le MBS (ou sulfite de sodium) dans de l’eau de mer sont étudiées et débattues sur la base de l’effet acidifiant du MBS, de l’oxydation des ions sulfites par de l’oxygène dissous et du rôle de catalyseur de certains cations métalliques (par exemple les ions de cuivre) adsorbés à la surface de la pyrite. INTRODUCTIONThe copper industry is aware of the difficulties of floating Cu-Mo sulfide ores in seawater. Molybdenum recovery is partially depressed when lime is used to reject pyrite. In plant practice, sodium metabisulfite (MBS) has been demonstrated to be the most promising option for replacing lime in seawater."

Jan 1, 2017