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By B Arthur, K Sexsmith, D Hockley, S D

At the proposed Crandon Project, mill tailings would be depyritised for upland disposal. The resulting pyrite concentrate would be disposed of in the underground workings as a cement-amended paste backfill. In the long term, the underground workings would be flooded and the potential for the paste backfill to generate acid would be limited. However, while the mine is operational, there is potential for oxygen ingress to the backfill that may lead to sulfide mineral oxidation and acid generation. A series of humidity cell tests were completed to assess the potential for groundwater contamination. To assess effects of surface area on oxidation, the humidity cell tests were conducted on moulded cubes of paste backfill. The tests were terminated at different intervals, and the cubes were dissected and examined mineralogically. Various leach extraction procedures were also used to assess the progress of oxidation and secondary mineralisation within the paste backfill. The test results showed that: the cement amendment significantly contributes to acid neutralisation and results in a lag in excess of one year before the onset of acidic conditions (in comparison to less than three weeks for the pyrite concentrate); the depth of oxidation in the paste backfill is restricted to about 1 mm after 107 weeks of testing; and secondary minerals form a distinct ærindÆ at the surface of the paste backfill. The results indicate that acid generation in the backfilled stopes would be minimal. The importance of including the surface area effect in the testing (ie using moulded cubes) is clearly demonstrated.

Jan 1, 2003

By D Pienaar, B McFadzean, C T. O’Connor

Collector and frother molecules in sulfide mineral flotation are thought to have separate roles in the flotation process, where the collector selectively hydrophobizes the mineral surface and the frother adsorbs onto the bubble surface, inhibiting bubble coalescence. Molecular interactions have been observed between these molecules which allow them to co-adsorb at each of the respective interfaces, improving pulp phase recovery. This study investigated the molecular interactions between sodium diethyl dithiophosphate (SDEDTP) and hexanol, and the mechanism by which these interactions improve the recovery of galena. In this study each of the respective interfaces were investigated for the adsorption of SDEDTP. The adsorption of SDEDTP on galena was measured by UV-Vis spectrophotometry and isothermal titration calorimetry. At the air-water interface foam stability and pulp bubble coalescence was used to quantitatively discern if there are interactions between SDEDTP and hexanol. Microflotation and induction time experiments were performed to determine the effect of SDEDTP, hexanol and their mixtures on mineral recovery and bubble-particle attachment. The results of all these tests were collated to determine if SDEDTP-hexanol mixtures synergistically improve sulfide mineral recovery. It was found that SDEDTP reduced bubble coalescence in the pulp demonstrating activity at the airwater interface. Together SDEDTP and hexanol synergistically enhanced foam stability. This indicated that there are attractive molecular interactions between these reagents. Even though DTP did not adsorb onto galena, DTP-frother mixtures synergistically improved the recovery and attachment probability of this mineral. Adsorption studies with aeration showed that DTP in the presence of a frother transfers from the air-water interface to the galena mineral-water interface during bubble-particle collision. It was proposed that the transfer of hexanol through the thin film enhanced the kinetics of film thinning between the bubble and the particle by destabilising the thin film thus improving pulp phase mineral recovery.

Aug 24, 2022

By D Goel

India, the second-largest steel manufacturer globally, achieved crude steel production of around 126 million tonnes (Mt) in the last financial year of April 2022 to March 2023 (FY23), against an installed capacity of 162 Mt. In its National Steel Policy, 2017, India has undertaken targets to take the crude steel production capacity to 300 Mt by 2030–2031 and production and demand to around 255 Mtpa, also by this deadline. The blast furnace-basic oxygen furnace (BF-BoF):electric arc furnace-induction furnace (EAF-IF) ratio in 2022 was at 44:56.

Sep 18, 2023

By B Manda, K L. Sandvik, K Musiwa

Mining and processing of pyrite ore at Iron Duke Mine, north east of Zimbabwe, generates large quantities of acidic mine water as a result of the oxidation of iron sulfides on exposure to air and water used in the drilling and blasting operations. The acid mine drainage (AMD) contains elevated levels of dissolved Fe, Al, Mn and sulfate and has characteristic pH values ranging from about 0.50 to 3.00. Handling and disposal of such a drainage places significant impacts on the economics of the mining operation due to the corrosive nature of the drainage on infrastructure, the limitations placed on water reuse and discharge to the environment under a new law governing effluent discharge. Treated sludge at Iron Duke is chemically unstable, changing pH from ~7 to ~3 within four days after deposition in the evaporation ponds. The effluent does not meet the permitted level of neutral pH, 500 mg/l sulfate and less than 2000 mg/l total dissolved solids. Excessive acid seepage from the evaporation ponds has resulted in contamination of the ground water below the ponds area, which shows high mean annual levels of iron (368.67 mg/l), sulfate (1702.89 mg/l) and low pH (2.86) in addition to other pollutants. This poor quality seepage infiltrates into the nearby Yellow Jacket River, contaminating the public water source. Furthermore, a deterioration of the land area and vegetation adjacent to the tailings dump is also observed. Understanding the controls on the neutralisation of acidic drainage and long-term sludge stability after placement in evaporation ponds is essential to minimise costs of closure requirements and for the protection of environment and human health. This study examined the effects of the master variables pH, redox potential, acidity and alkalinity on acid neutralisation. The results indicate that ferrous hydroxides are not as stable as ferric hydroxides and that proper oxidation of iron also leads to better sludge stability, higher treatment efficiency and a manageable sludge viscosity. Metal hydrolysis and secondary mineral formation at the evaporation ponds under a wide range of pH and redox conditions is responsible for equilibrium shifts in metal reactions, resulting in high potential for metal leaching and mobility. Mechanisms of metal attenuation are also discussed.

Jan 1, 2006

DURING the four years, 1922, 1923, 1924, and 1925, China produced the following quantities of non-ferrous metals and ores: Antimony Products - 67,869 (long) tons. The production for 1925 was 20,869 tons, of which 80% was regulus, 14% crude,and 6% oxide.Arsenic (White) - 4200 tons. The production for 1925 was 1200 tons, but only 90 tons were exported, some 25% of which to Hong-Kong, France, and U.S.A. each, and the rest in small lots to other countries. Domestic consumption was 1110 tons, and thelocal price for "cake" was around £47 per ton on 1925 exchange.Arsenic Ore (Realgar) - 1400 tons.Lead Ore (Galena) - 44,853 tons. The production for 1925 was 10,853 tons, of which 16%, produced in Korea, went to Japan, and 84% produced in Hunan, went to Europe.Manganese Ore (Pyrolusite) - 142,567 tons. The production for 1925 was 42,567 tons, of which 94.3% went to Japan.Tin Ingot - 33,480 tons. In 1925 the exports to Hong-Kong were 8880 tons of usual rough tin of 94% to 96%. Most of this was refined to No. I Chinese quality of 99.3% and exported to U.S.A. and Europe, owing to the good price ruling.Sulphur - 12,000 tons. Sulphur is included in this list in order to explain how its production led to the discovery of some other ores.Wolfram - 19,668 tons. The production in 1925 was 5868 tons, most of which came from the Quee Mee mountain district in South Kiangsi, from the detrital deposits. Civil disturbances prevented the usual output from Hunan border.Zinc Ore (Blende) - 134,190 tons. Exports for 1925 were 34,190 tons of low-grade ore, averaging 30% zinc, 14% lead, and 7% silver...

Jan 1, 1927

The influence of strongly chemisorbed solutes such as oxygen and sulphur on the rates of reactions at the gas-liquid iron interface is briefly reviewed. Deductions from recent studies of the rates of decarbur- ization of carbon-saturated liquid iron indicate ideal adsorption behaviour for sulphur over a wide temperature and composition range. This is in fair accord with available infor- mation on surface tensions in the Fe-C-S system. Previously unpublished results for the kinetics of the 14C02-CO exchange reaction are in accord with ideal absorption of oxygen on liquid iron. The derived value for the ideal adsorption coefficient of oxygen at 1550¦C is in quantitative agreement with measurements of the depression of surface tension in the Fe-0 system. Consideration is given to the applicability of such results to the violently agitated systems of steelmaking.

Jan 1, 1980

The Vera Nancy orebodies, although simple in overall geometry, are in detail generally narrow, multi-veined and fluctuating in width, strike and dip. Tight geological control is required to optimise gold and silver production from this bench stoping operation. The processes used to model the resource and to control ore drive development have evolved since mining commenced in 1997. Grade control is a combination of orebody sampling, geological data collection, understanding orebody geometry and the optimisation of ore driving and stoping activities. Global resource modelling utilises mainly drill hole data which is largely superceded by drive development data as stope development progresses. The orebody has a relatively low nugget effect that assists in grade estimation. Rather than rely on sophisticated grade interpolation methods, resource estimation to-date has focussed on developing the geological understanding of the orebody to ensure the framework for estimation is correct. Drill data alone is not adequate to define deposit geometry for stoping . Drive data is used as the dominant data set for stope geology modelling once development for a stope is complete.

Jan 1, 2000

By A G. Grice

Surface disposal of mining processing wastes is usually perceived as an undesirable consequence of meeting societyÆs needs for metals and minerals. Environmental disasters associated with the discharge or storage of such wastes, though infrequent, can have very damaging consequences for the environment and the industry. Reducing or eliminating the potential for such events may be achieved by placing some or all of these processing wastes back into the voids created by the mining operations. Processing operations may limit or enhance the opportunities for using tailings and other waste products as a backfill material. Backfilling is a truly multi-disciplinary process and requires the informed involvement of mining, metallurgical, engineering and environmental specialists. This paper describes the range of fill types currently being used in Australian mines, particularly those utilising processing wastes as constituents. It focuses on how processing operations can affect the suitability of these materials for the various types of fill, the resulting fill properties, fill performance and costs.

Jan 1, 2002

By C Li

Removal of gangue minerals from ilmenite concentrates can be accomplished by relatively low temperature roasting in controlled gas atmospheres to selectively enhance the magnetic separation characteristics of the ilmenite. At roasting temperatures below 800¦C the magnetising reactions are often not consistent with phase equilibria considerations. Metastable phases can nucleate and control the roasting products. In weathered ilmenites the phase assemblages and microstructures in the altered ilmenite grains can influence the roasting reactions. In this paper we give an overview of the phase chemistry of chemically weathered ilmenites and of metastable phases formed by low temperature roasting. We also report the results of roast experiments conducted in a neutral gas atmosphere. Major increases in magnetic properties after short roasting times at low temperatures were obtained for a range of ilmenite concentrates. For example heating a secondary ilmenite concentrate from Western Australia for 15 minutes in nitrogen at 600¦C gave an increase in the three kilogauss magnetic fraction from three to 92 wt per cent. The solid state phase changes accompanying the inert atmosphere roasts were characterised by combining elemental analyses with quantitative phase analyses of the ilmenite concentrates and their roast products. It was found that the phase reaction that is principally responsible for the increase in the magnetic properties of weathered ilmenites involves a transformation of disordered ferrous-containing pseudorutile to an ordered ilmenite-hematite solid solution containing typically ten to 35 mole per cent of the hematite component. Examples are given of the application of the inert atmosphere roast to effect separations of ilmenite from gangue minerals.

Jan 1, 2001

By J Krawcz, S Wasilewski, W Mironowicz

Barometric pressure and its variation in deep underground workings have a considerable effect on ventilation conditions. Pressure changes which create transient states of air flow and air parameters in workings are especially significant. Experiments have shown that pressure changes have a remarkable effect on air parameters at mine workings and hence, attempts to evaluate the scale of this phenomenon are of value. Continuous monitoring of the barometric pressure on the surface of mines allows for the detection of changes in pressure which undoubtedly influence alternations of pressure in the underground areas of mines. Very important factors are the internal disturbances of pressure within a mine ventilation system due to variable conditions of fan operation and the operation of a winding machine where a mine cage moving in a shaft causes piston like disturbances. Local transient disturbances caused by temporary opening/closing of air stoppings due to personnel or underground transport traffic are of importance. The results of over two years of observations of barometric pressure and its influence on pressure variation in underground mine workings are presented in this paper. The observations were possible through the installation of pressure sensors at selected points of the downcast shaft in a mine. Of interest are the observations of the transient states of pressure and other air parameters caused by emergency fan stoppage, movement of a mine cage and changes due to the opening of air stoppings. Data acquired during experiments of opening and closing air stoppings were used for the validation of a flow model in a long working.

Jan 1, 2005

By Sarracino R. S

A number of ideal detonation codes are used internationally for estimating the strength of explosives compositions. Important and far reaching decisions by explosives users are ofen based on the predictions of these codes, but since different codes can deliver very different answers for the same composition, there is a strong possibility of decision makers being misled. In order to both provide a sensible basis for comparing the theoretical energy from explosives from different manufacturers and to prevent the entire rating system from slipping into disrepute, it is in the interests of all to reach agreement on fundamental criteria used by detonation codes for detemtining strength. The problem is illustrated by a case history and basic conventions are proposed, specifically the adoption of energy of reaction as a fundamental and code independent indicator of explosive energy, and agreement on disclosure by suppliers of key non-proprietary information. These measures would assist explosives customers in assessing the true strengths of explosives from the strengths calculated by the different ideal Codes.

Jan 1, 1990

By Warren L. J

The recovery of phosphate minerals from the Mt Weld deposit by froth flotation has been studied by many researchers. Most of the flotation experiments were carried out with a tall oil fatty acid as collector and sodium silicate as dispersant and gangue depressant at pH about 10. Several rougher stages and cleaner stages and, sometimes, a desliming stage were included. The major difficulty was to reduce the Fe2O3 impurities in the concentrate to the required level. We used QEM*SEM (Quantitative Evaluation of Materials by Scanning Electron Microscopy) to provide a comprehensive and accurate mineralogical analysis of the flotation products. The analysis indicated that the Fe2O3 impurities were mainly recovered in the second concentrate, owing partly to the incomplete depression of the liberated iron oxides by the sodium silicate and partly to composite particles containing iron oxides. The selective depressing action of sodium silicate was improved by adjusting the variables such as the modulus (SiO2/Na2O), pH and time of standing of the stock sodium silicate solutions or by adding some polyvalent metal salts into sodium silicate solution. The flotation process was optimised to produce a phosphate concentrate with the required grade and recovery (38.6 per cent P2O5, 2.67 per cent Fe2O3, 13.7 for P2O5/(Fe2O3 + A1203), at P2O5 recovery of 81.5 per cent). The possibility of recovering the rare-earth phosphate, monazite, from the Mt Weld deposit by flotation was also studied.

Jan 1, 1991

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

By S A. Ravishankar, W Perez

Flotation is one of the main concentration processes to purify kaolin clay via the removal of naturally occurring impurity minerals containing Ti and Fe. Currently, there are two types of collector chemistries used in the industry to float coloured impurity minerals. These are traditional tall oil fatty acids (TOFA) and specialty hydroxamate (AHX) based collectors. AHX based collectors have long been known to be the most selective collectors to float Ti and Fe based coloured impurity minerals (CIMs) as compared to TOFA based systems. AHX based collectors provide, not only improved selectivity and simplified process, but also more importantly, make it possible to treat certain kaolin resources that do not respond to standard TOFA systems. However, the relatively higher cost of straight AHX collectors has restricted broader application of these collectors in kaolin clay and other oxide flotation applications for a long time. Recent technological advancements, in both making and formulating AHX products more economically, increased the usage of these collectors in kaolin applications. Modified AHX products offer more economical alternatives and process options to provide high purity kaolin clay products for specialty applications based on cost-performance criteria. In this paper, the flotation performance of a series of newly developed AHX formulations is provided along with the characteristics of AHX flotation in general. In addition, flotation performance of earlier AHX collectors is provided based on published literature as background data.

Jan 1, 2005

By Watt JS

The ash content of coal can be determined using radioisotope X-ray techniques. A number of overseas applications of X-ray techniques are described; however these suffer from the disadvantage of either not compensating for iron variations or, if compensation is used, using X-rays of low penetration with consequent sampling difficulties. Current Australian Atomic Energy Commiss- ion (AAEC) research on X-ray techniques is aimed at overcoming the limitations of these methods. The AAEC method involves making measurements proportional to mass absorption coefficients of X-rays in coal at two energies. Calculations and experiments with X-rays up to 35 keV have shown that ash content can be determined to about 1 wt.%. This work is being extended to higher X-ray energies to enable the technique to be used directly on a conveyor belt or in a hopper. Neutron techniques can be used to measure the concentration of specific elements such as carbon, hydrogen and silicon in coal. Their con- centration is correlated to the coal parameters of interest. Methods of moisture determination based on hydrogen measurement and ash determina- tion based on silicon and aluminium measurement are described. Energy content can be determined accurate- ly by analysing the carbon content of coal

Jan 1, 1978

By Weimin F

In the last decade, great strides have been made in the raise boring technique in China. Extensively, the drilling and blasting method has been replaced by the mechanized raising method since 1980. There are now over 3C raise drills operating in more than 20 mines. The diameters for shaft boring varies from 500mm to 2000mm, and to depths up to 90m. Tlis paper mainly describes the performance, mtLin technical achievments and applications of all four kinds of raise drills, and auxiliary equipment. Finally, some recommend- ations for future improvement in the raise boring technique are presented also.

Jan 1, 1987

In 1997, the Australian coal industry through Standards Australia committee MN-001 Coal and Coke recognised the need to produce a Standard giving some instruction on how to inspect and audit mechanical sampling systems. A Guide was developed by sampling subcommittee MN-001-04 and in 1999 the Standard was released as AS4264.5 æGuide to the Inspection of mechanical sampling systemsÆ Coal and Coke. Since that time the author has assisted with other committees in developing the Guide for other commodities such as concentrates and a generic standard for particulate materials. (AS4433.6 released 2000). The Coal and Coke guide is also currently a work item for ISO Standards. This paper is focused primarily on auditing and inspection procedures for coal mechanical sampling systems. It highlights the need for at least a three level inspection protocol where the operators manning the system maintain operational checks, the operators are regularly supervised by the company managing the system and once per year an independent auditor inspects the whole system to ensure compliance with design and standards. It does not cover short- and long-term maintenance of individual systems. With companies already certified to the ISO9000 series, this guide forms the framework to bring the operation and inspection of their mechanical sampling systems into line with these principles.

Jan 1, 2005

By Omnes G

Sixty Schlumberger electrical soundings were carried out in the Depot Springs area, near Agnew, Western Australia as part of an investigation into the availability of groundwater for the Agnew nickel project. The object of the survey was to locate calcrete aquifers related to Tertiary drainage channels on the Pre- Cambrian surface. The electrical soundings were initially interpreted using sets of master curves and auxiliary point methods. Electrical sections were produced and contour maps prepared of apparent resistivity for AB=80m, total conductance of the overburden and transverse resistance.

Jan 1, 1975

Three key areas of C.I.P. plant design, viz. leach- ing time, adsorption and the gold loading on the carbon, are discussed and illustrated with examples. The need for accurate pilot plant data for use in assessing and optimising design is emphasized. This approach should minimize capital and maximise return on capital. It is demonstrated that, as regards adsorption, economics favours short retention time, high gold loadings and mechanically agitated, draft tube reactors. INTRODUCTION Little attempt appears to have been made in Australia to design the present generation of C.I.P. plants to achieve an economic optimum. Most would, seem to have been based on pre- liminary leaching data, gold extraction and value and rule of thumb which, in general, has led to over design and over capitalisation. An essential step to effective economic design is a comprehensive pilot plant study to establish definitive operating parameters, yields and reagent costs. In most cases the cost of developing this data will be more than offset against capital savings in plant; the operating profit should be increased substantially, and profit is maximised for known

Jan 1, 1982

By Singh RN

Monolithic packing systems have gained in popularity as a gate side packing method. However, there has been no detailed investigation to assess their underground strength behaviour. This work includes the laboratory and in situ investigation for strength behaviour determined on various monolithic packing materials namely Tekpak-XX, Hydropak-20, Hydropak-30, Astrapak-3R, Flashpak, Thyssen pack and Aquablends. A simple technique for assessing the pack strength was developed at the laboratory by using a penetrometer, of which penetration resistance can be directly correlated with the uniaxial strength of the pack. The in situ strength investigations were made on core samples obtained from three pipes inserted inside the pack, while the penetration test were made on the pack surface. The in situ results indicated that the packing material develops an inconsistent strength on various part of the pack which was mainly related to an inadequate mixing of grouts inside the pack.

Jan 1, 1992