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By K. Eto, H. Akiyama, T. Iwamoto

The Hikoshima smelter carried out an expansion project in 1997 and increased its production from 59,200 t/y to 71,000 t/y. The leaching process and the casting process had production capacities of 84,000 t/y, but because of the electric power situation in Japan, the production capacity in the electrolysis process was limited to 59,200 t/y to justify the production cost. Electrolysis was the bottle neck of the plant. In order to eliminate a part of this bottle neck, and considering the electric power situation in Japan, a way to increase the production during the time when the electric power rate is low was sought. In practice, we increased the number of cells by 36, and further improved the operation procedures in the cellhouse. For example, we improved the working efficiency of the cells, improved the productivity during the night time, decreased the unit power consumption and improved labor productivity. Accordingly, this paper describes the recent operations at the Hikoshima plant.

Jan 1, 2000

By Peter Stiaszny, Andrej Samoilov, Yuri Titovets, Gottfried Hribernig, Nikolai Zolotorevskii

"The model has been developed to simultaneously predict both transformation product portions and mean ferrite grain size from the same common · principles as a result of the austenite decomposition during any cooling path of dual phase steels. The transformation products considered are polygonal ferrite, pearlite, bainite and martensite. The model is based on the classical equations of nucleation-growth theory and also contains some empirical parameters. The chemical driving forces for nucleation and composition of elements at the phase interfaces are derived by computation thermodynamics. The empirical parameters related to the model were determined on the basis of a series of austenite transformation dilatometric curves and grain size measurements for continuous and interrupted cooling of several steel types. The model is aimed to predict phase transformation in the complex cooling conditions of the run-out table of the hot strip mill at YOEST-ALPINE STAHL LINZ GmbH as a part of the computer aided system for prediction and on-line controlling of the mechanical properties of hot-rolled strip.IntroductionThe term ""dual phase steels"" is used to refer to a steel consisting essentially of a dispersion of martensite in a fine-grained ferrite matrix. These steels are of increasing technological interest since they provide a better combination of strength and ductility than any other conventional steel sheet material. The strength is important because it offers an opportunity to produce lighter components, while good ductility is needed to permit easy forming of components. It is generally recognized that martensite plays an important role in determining the strength level of dual phase steels. A full understanding of the role played by the phases in determining such characteristics requires investigating in more detail how to optimize the martensite level of such steels, while maintaining good ductility remains the subject of continued research in the industry."

Jan 1, 2000

By D H. Laubscher

The in situ rock mass rating system û IRMR - leading to the mining rock mass rating system - MRMR - for jointed rock masses has been used (and abused) in mining operations around the world for the past 27 years. Despite the recent development of elaborate design procedures and computer-aided design packages, MRMR remains one of the most versatile and practical mine design systems available. It is important to realise that the rock mass classification system should not be replaced but rather complemented by more sophisticated and detailed design procedures. The classification system is not only the æcrudeÆ method used for initial assessment (as described in some geotechnical literature) but also in many respects a very effective and practical engineering tool. MRMR could, and should be used during the entire stage of mine life as an integral part of the design process. The objectives of this paper are to illustrate using practical case histories from the past decade, some of the pitfalls of the MRMR classification system, to clarify certain misconceptions in its application and update its mining application.

Jan 1, 2000

By Kazuya Kitatani, Gen Sasaki, Naoto Ohta, Hideharu Fukunaga, Makoto Yoshida, Jin Pan, Kenya Nagahisa, Toshihiro Ishikawa

"A sintered SiC (Tyranno-SA) fiber-reinforced MAS glass matrix composite was fabricated by using a slurry infiltration method and hot-pressing. The microstructure and mechanical properties were investigated: To prepare the preform, the MAS glass slurry including a dispersing agent was infiltrated into a bundle of the fibers. The preform was then hot-pressed under the conditions of 1473 K, 30 MPa, 3.6 ksec. A unidirectionally-reinforced oxide matrix composite with 50% Vf. of the fiber and a density of 2.84 g/cm3 was obtained. As the mechanical properties at room temperature, the three-point flexural strength- and quasi-static adsorbed energy were 500 MPa arid 6,000 J/m2, respectively. Without graphite or an h-BN pre-coating on the surface of the fiber, pull-out and bridging of the fibers from the matrix was found, and this leads to a high value of the adsorbed energy. By TEM observation, nano-scale crystalline products were found between the fibers and the glass matrix. The push-out test reveals that this layer causes the appropriate debonding of the interface during the fracture process of the composite.Introduction It is known that the CFCCs (continuous-fiber-reinforced ceramic matrix composites) are characterized by their non-linear fracture behavior, which is' hardly found in monolithic ceramic materials. It is inevitable for the CFCCs to exhibit a large fracture toughness so 'that debonding of the fiber/matrix interface; pull-out and bridging of the fibers then' occurs during the fracture process. This series of fracture behavior is known as the so-called ""the mechanism of toughening of the CFCCs"". Thus, different from the MMCs in which strong interfacial bonding is necessary, the interfacial strength of the CFCCs has to be controlled. As techniques for controlling the interfacial strength, it is also known that both a CVD-graphite coating and an h-BN coating are effective to induce the mechanism of toughening[1,2]. In the case, of the Si-C-O or Si-Ti-C-O fibers/glass or crystalline oxide matrix composites, it is reported that the formation of the in-situ graphite layer, which is also effective to increase the fracture toughness of the CFCCs, is often found during the fabrication process such as hot-pressing. The lower the crystallinity of the Si-C-O fibers, the higher is the tendency to form the in-situ graphite layer as found by the chemical reaction between the fibers and the glass matrices[3-12]. On the-other hand crystallized stoichiometric 'SiC fibers are attractive for high temperature service because of the higher phase stability compared to the Si¬C-O or Si-Ti-C-O fibers. However, in the previous, studies, the mechanical properties and the interfacial chemical reaction of the crystallized SiC fibers / glass matrix Composites have still been unknown. In this study, a polycrystalline 'sintered SiC fiber-reinforced MAS glass composite was fabricated. The mechanical properties and microstructure were then investigated. The slurry infiltration technique followed by hot-pressing was used to prepare the composites. The formation of the in-situ graphite layer and the relationship between microstructure and mechanical properties at room temperature were examined by the TEM observation of the fiber/matrix interface."

Jan 1, 2000

By J. W. Neale

Mintek and BacTech have joined forces to provide the metallurgical industry with bacterial-oxidation processes for the treatment of sulphide ores. The processes are aimed at both refractory gold-bearing and base-metal concentrates. Previously, BacTech had commercially implemented the refractory gold process at the Youanmi Gold Mine in Western Australia. More recently, the process has been incorporated in the Sulphide Treatment Plant at the Beaconsfield Gold Mine in Tasmania, Australia. In addition, Mintek and BacTech have recently signed an agreement with the Laizhou Gold Metallurgy Plant in China?s Shandong Province, which will see the third commercial realization of the technology for refractory gold. Development of the base-metal technology is the subject of several papers in the proceedings of this colloquium. The implementation of the refractory gold technology at Beaconsfield is discussed in detail. Some important aspects that are covered include: ?Test work, and the choice of bacterial culture ?Process design choices, and the advantages of the Mintek-BacTech process ?Inoculum build-up ?Plant commissioning ?Plant performance. Besides the Laizhou project, Mintek and BacTech are currently investigating several other commercial prospects for the technology. These include the use of the technology for a gold-copper deposit, where the production of both gold and copper is envisaged.

Jan 1, 2000

By S. Gallagher, A. Mayton, R. Merkel

The prolonged exposure of equipment operators to shock and whole-body vibration (WBV) is linked to cumulative back, neck and abdominal disorders. In low coal mines, space restrictions make it difficult for seat suspensions to isolate operators from shock and WBV. Researchers at NIOSH's Pittsburgh Research Laboratory are responding to these issues by investigating viscoelastic foams. For the full-load case, an ergonomic seat made with viscoelastic foams can isolate the shuttle-car operator from shock at 15 Hz. Researchers used results from additional foam testing using an analytical model to identify viscoelastic foams that provide shock isolation at a frequency below 5 Hz.

Jan 1, 2000

By Ray D. Peterson, Garry G. Blagg

"Molten aluminum is routinely transported hundreds of miles to customers in large ""over-the-road"" crucibles. This is especially common for aluminum recycling organizations handling scrap and by-products. Receiving the aluminum in a molten form can save the customer time and money since in-house melting costs and capital equipment can be avoided. Additionally, the alloy can be on specification and nearly ready to use for the casting operation.A number of transport crucible designs are currently in use. The specifics of each design are based on the needs of the customer, the equipment used at both the producer and the consumer, and over-the-road transportation constraints. Crucibles are designed to maximize carrying capacity, and refractory life while minimizing heat flow and dead weight. These conflicting demands place difficult design criteria on the design engineer.This paper will review the basic advantages and disadvantages associated with molten metal transport, give examples of the design restrictions and examine several types design of crucibles currently in use."

Jan 1, 2000

By S. K. Mishra, S. B. Kanungo

Because conventional (physical) methods of ore dressing are not suitable for reducing the phosphorus contents of high-phosphorous manganese ores from Andhra Pradesh (AP) and the adjoining area in southern Orissa, India, the adoption of chemical methods becomes imperative. An attempt was therefore made to reduce the phosphorus content of partially beneficiated manganese ores from AP by roasting with sodium carbonate and then leaching with hot water. However, due to the higher phosphorus contents of the manganese ores from Nishikhal mines in southern Orissa, and because of their apparent resistance to dephosphorization by roasting with Na2CO3 alone, a mixture of Na2CO3 and NaCl was found to be necessary to reduce the phosphorus content to below 0.15%. Free-energy calculations at 700°C and above indicated that Na2CO3 (or Na2O as the active component) is a more active reagent than NaCl. Various process parameters, such as the temperature and time of roasting, the amount of sodium carbonate and the temperature and time of leaching, were studied to arrive at the optimum conditions for dephosphorization.

Jan 1, 2000

By Mingju Liu

In this research, we measured fractal characteristics of over ten typical outburst areas on different scales and related them to their outburst proneness, in attempts to provide new methods for outburst prediction. It was shown that both faults and folds follow the power law on coal basin scale, mine scale or mining district scale, whichever it is. Fractal dimensions are appropriate indices to describe geological structures quantitatively. Preliminary relationships have been established between outburst proneness and fractal dimension. Comparisons have been made among fractal characteristics and degrees of outburst proneness on all three scales. The results indicate that multi-scale assessment of outburst proneness can be made based on fractal measurements independently or supplemented by other assessment methods.

Jan 1, 2000

By L. M. English

A basic model was developed to help assess methane control needs for the longwall mining of coal in gassy areas. Rather than depending on reservoir and rock mechanical theories, it uses an empirically determined gas emission rate as an input, and it operates on the assumption that, within a specific region and zone, gas emissions will be relatively equivalent for uniform incremental volumes of gob created by mining. The computer program divides longwall panels into segments, keeps track of the face advance and generates emission rates and volumes for both the entire panel and for individual zones within the panel by summing values for all undermined segments. This model can aid in the determina¬tion of the number, size and location of vertical wells or other methane-control applications that are needed for gob gas control.

Jan 1, 2000

Mineralisation was identified at Gladstone Hill as far back as the late 1870s-early 1880s, shortly after the initial discovery of mineralisation at what is now the Martha Mine. Indeed, early recovery problems associated with the Martha mineralisation led to the preferred development of ore bodies within what is now the Union Hill Joint Venture tenement; ore bodies such as Silverton, Amaranth, and Union to name a few. Gladstone Hill forms the basis of the Union Hill Joint Venture, a 50:50 joint venture managed by Au-Ag Resources Ltd (a fully owned subsidiary of Otter Gold Mines Ltd), and Welcome Gold Mines Ltd (a fully owned subsidiary of the Normandy Group). The joint venture participants also operate the adjacent Martha Mine. Mineralisation of Gladstone Hill, as with mineralisation at the adjacent Martha Mine, has been interpreted as a low sulphidation epithermal Ag-Au system hosted within hydrothermally altered andesites of the lower Coromandel Group. Drilling in recent years has successfully identified extensive mineralisation associated with a number of vein sets throughout the tenement including the Gladstone Vein set, the Moonlight Lode and more recently along a north-easterly trend towards the historic Favona workings. A wide range of vein styles is apparent, ranging in character from thin stock works to broader lode-style banded chalcedonic to cherty quartz and have been interpreted as representing multiple phases of emplacement. At shallower levels mineralisation is often hosted by vein clasts within vent breccias. Visible gold is rare, with mineralisation generally associated with very fine-grained pyrite, arsenopyrite and minor electrum. Percentage levels of combined sphalerite-galena-(+/- chalcopyrite) have been intersected at depth however these have been gold poor to date. The potential for the Gladstone Hill area remains to be clearly defined as drilling to date has yet to close off mineralisation both along strike and down dip. If further drilling is successful, the joint venture partners believe Gladstone Hill could contribute significantly to the economic future of current operations.

Jan 1, 2000

By Keiji Okumura, Jiayi Shan, Jian Yang, Masamichi Sano

"A new method of deoxidation and desulfurization of molten iron with magnesium vapor has been developed. An immersion tube, which was filled with pellets of the mixture of magnesia and carbon powders, was put into the molten iron. Magnesium vapor produced by carbothermic reduction of magnesia inside the tube was injected directly into the molten iron with argon carrier gas. The effects of temperature and carrier gas flow rate on deoxidation and desulfurization were investigated. A mathematical model of the reactions was developed. The rates of deoxidation and desulfurization were controlled by mass transfers of magnesium vapor in the gas-phase and oxygen and sulfur in the liquid-phase. This method may offer high efficiency for magnesium deoxidation and desulfurization of molten iron.IntroductionMagnesium is a strong refining agent in steel-making processes1 • At steelmaking temperatures, magnesium has a very low solubility in liquid iron, and a very high vapour pressure2 • Deoxidation and desulfurization with magnesium take place essentially through the interaction of magnesium vapor with oxygen and sulfur dissolved in molten iron, and magnesium can change chemical composition of nonmetallic inclusions3 • However, addition of magnesium to the steel bath is dangerous and does not give high efficiency in the refining process4 • Furthermore, as a refining agent, the price of magnesium is higher than aluminium and CaO fluxes. In the present study, a new method of the deoxidation and desulfurization of molten iron was developed using magnesium vapour in-situ produced by carbothermic reduction of magnesium oxide. Pellets made of mixture of magnesia and carbon powders were charged into an immersion tube, which was made of alumina or graphite. The magnesium vapor was injected directly into the melt. The effects of pellet mass, experimental temperature and carrier gas flow rate were studied on the refining rate. A mathematical model of the refining reaction was proposed on the basis of the experimental results."

Jan 1, 2000

By A. Dogan Paktunc

Abstract - The Mechanic Settlement pluton is a small body of mafic and ultramafic rocks of tholeiitic affinity, occurring in the Late Neoproterozoic volcanosedimentary rocks of the Avalon terrane of the Appalachian Orogen. The lenticular-shaped intrusion is layered and consists of ultramafic and mafic lithologies in at least six cyclic units that are relatively thin or short-lived. The lowermost exposed portion of the intrusion is characterized by the cumulate sequences of olivine and olivineclinopyroxene and display relatively flat rare earth element profiles. In the overlying lithologies, plagioclase is the dominant cumulus phase following olivine in the crystallization sequence. Olivine ranges in composition from Fo73 to Fo85 and plagioclase from An62 to An89. Variations in the compositions of orthopyroxene and clinopyroxene are within Wo0-4En52-87Fs11-45 and Wo39-50En23-50Fs3-19. These mineral compositional variations in part reflect cryptic patterns and correspond to normal fractionation trends in cyclic units. Elevated Pt and Pd concentrations of up to 2.6 ppm occur in ten zones within the central cyclic series in association with both the peridotitic and gabbronoritic rock types. The mineralized zones are about several meters thick and appear to have lateral continuities over several hundred meters, suggesting that they are stratiform. Platinum-group elements (PGE) occur as discrete platinum-group minerals (PGM) including vysotskite, merenskyite, michenerite, sperrylite, stillwaterite, and hollingworthite that are associated with magmatic sulfides composed of pentlandite, pyrrhotite, and chalcopyrite. PGM grains range in size from a few micrometers to well above 20 µm. Sulfur isotope ratios and the Se/S ratios of the mineralized rocks are typically higher than the mantle values. Sulfide saturation probably occurred as a result of assimilation of crustal rocks and magma mixing during emplacement of subsequent pulses of magma. Repetition of the PGE mineralization in rather thin cyclic units suggests that the replenishing magma probably had high PGE levels and was saturated with respect to sulfide during emplacement. Ingression of the replenishing magma into the chamber in a turbulent plume and its mixing with the resident magma was probably responsible for the formation of the PGE mineralizations in the Mechanic Settlement pluton.

Jan 1, 2000

By Barend Botha, Trevor Davids

The presence of an extensive soft siltstone layer in the middle of the inter-burden sequence of rocks at Syferfontein Colliery in the Republic of South Africa prompted tests to determine the effect of different mid-column decks of inert material in the siltstone layer. The objective was to achieve significant cost savings in explosives use whilst not degrading dragline productivity. An important factor that had to be considered was that the initiation systems available in South Africa are not accurate enough to ensure simultaneous initiation of explosives decks in a blasthole. A number of inert materials were tested including ash, drill cuttings, river sand and crushed stone. It was found that the ash, drill cuttings and river sand did not effectively attenuate the shock wave and that the risks of sympathetic detonation or partial disruption of one or the other explosives deck in a blasthole was high. This became much worse when the inert material was saturated with water. Crushed rock was the most effective in attenuating the shock wave, but this material was very expensive to use because it had to be imported onto the mine.

Jan 1, 2000

The history and milestones in the evolution of support systems utilised in the mass-mined chrysotile mines of Shabanie and King are discussed in detail. The use of block caving, false footwall or sublevel caving mining methods brings with it some major support problems, which are exacerbated, in our low rock strength mining environments. The paper discusses the various support elements and systems that have been used successfully or otherwise in these operations. Some predictions for the future of rock reinforcing in our ground conditions are highlighted, in relation to geomechanics, levels of mechanisation and production risk analysis.

Jan 1, 2000

By Nora M. Hutt, Kevin A. Morin

There is currently some pessimism over mixing of net-acid-neutralizing (NAN) and net-acid-generating (NAG) rock to obtain indefinite near-neutral seepage from mined-rock piles. This is due in large part to the lack of well- documented, successful cases of blending and layering, and to the knowledge of unsuccessful attempts. Past work often defined a potentially successful mix in terms of the ratio of net-acid-neutralizing rock to net-acid-generating rock. For example, one case study indicated the bulk pile-wide ratio was approximately 3: 1. Since this exceeded a common ratio used in acid-base accounting, no acidic drainage was predicted. However, acidic drainage appeared within two years. A large part of the ambiguity in mixing arises from attempts to predict success based on a ratio. This paper looks in detail at simple discrete-zone mixing, where at least one truckload of NAG rock is placed in a particular location with no further rehandling or dozing. The lack of acidic drainage in this scenario is dependent on the intervening distance between the discrete NAG zones, along flowpaths occupied by NAN rock. Calculations show that the bulk mixing ratio of a mined-rock pile is not an accurate indication of whether near-neutral drainage can be maintained. For example, a pile with a bulk ratio around 300: 1 could still release some acidic drainage. Calculations also show that the minimum separation distance of the NAG zones (L) can be so great, even with typical NAG and NAN rock, that the mixed pile could safely contain only a few percent of NAG rock, which would not be sufficient for many minesites with NAG rock. The comparison to a more elaborate, computer-based statistical model shows that the simple discrete-zone approach will provide a reliable yes-no indication of whether any acidic drainage will leave a pile. However, predictions of whether combined downstream drainages will be acidic depend on numerous site-specific physical and geochemical factors within and below a pile that cannot be modelled in a general way, like the number of flowpaths and the nature of their intersections.

Jan 1, 2000

By F. Shahbazian

attempt to systematize the knowledge on slag viscosities, the present work was carried out. The Among the physical properties of slags, viscosity is very important in understanding the mass out in the temperature range 1438-1762 Q The rotating cylinder method was used in the viscosity measurements. Crucibles and spindles made out of pure iron were employed. The transfer phenomena in metallurgical processes. The viscosities of fayalitic slags are of great interest in the non-ferrous metal industry, with special reference to copper production. In an slags were prefused before the measurements. In order to take into account the vaporization reactions involving CaF2, pre- and post measurement samples of the slags were chemically analysed and the compositions were ascertained. The results show that in the case of the CaO-SiO2 system, CaF2 additions tend to decrease the viscosity, in accordance with the expectations. In the case of the "FeO"-SiO2 system, at higher "FeO" / SiO2 ratios in the slags, a reverse trend was observed. The results are discussed on the basis of a viscosity model for silicate melts developed in the present laboratory as well as the structural considerations of silicates.

Jan 1, 2000

By Thierry Bernard, J. M. Laboz

2000 HIGH-TECH SEMINAR Blasting Technology, Instrumentation and Explosives Applications

Jan 1, 2000

By Jeffrey Anderson, Cindi Byrns, Andy Davis

A closure plan was developed for the Intera Pond Facility, a former acid leaching collection pond at the BHP Robinson Mining Operations. To properly close the Intera Pond Facility, an engineering plan that was both technical and cost effective was developed. A primary objective of this closure project was to demonstrate to State regulators that following the proposed plan would minimize further degradation of water resources. Field data demonstrated natural attenuation of metal enriched solutes via carbonate reactions. Prospective fate and transport modeling indicated that it would not continue to degrade waters of the State.

Jan 1, 2000

By D. Dimitriadis, T. Polglase, W. Phillips, R. Jenny, M. Botz

Cyanidation processes for the extraction of gold or silver frequently involve the processing of sulfur-containing solids which react with cyanide to form thiocyanate. The formation of thiocyanate is an undesired side-reaction, and in many cases thiocyanate formation results in a prohibitively high cyanide consumption. With the increasing number of gold and silver mining projects which involve the processing of sulfide ores or concentrates or which utilize a biological sulfur oxidation process, more attention has been focused on minimizing thiocyanate formation and in treating solutions to eliminate toxicity associated with thiocyanate. Though not yet commercially applied, there are several technologies available to recover cyanide from thiocyanate to both reduce tailings toxicity and allow the reuse of cyanide otherwise lost to thiocyanate formation. This paper presents an overview of technologies available for recovering cyanide from thiocyanate along with estimated operating costs for the technologies. Pilot testing data suggests that in some cases, cyanide can be recovered from thiocyanate for approximately the same cost as newly purchased cyanide.

Jan 1, 2000