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By Ramana G. Reddy

Thermodynamic modeling and experimental study on impurity capacities and their distribution between mattes or metal and slags in smelting, converting and refining of non-ferrous metals was discussed. A brief review on the recent developments in copper smelting and converting is presented. The analysis showed that, copper smelting capacity increased by a factor of 10 since 60's, smelting rate increased by a factor of more than 5 and process fuel equivalent decreased by a factor of 2. A thermodynamic model for prediction of impurities capacities in slags and their distribution in mattes and slags was developed. The impurities capacities (i.e. sulfur and arsenic) of slags were calculated a priori with no adjustable parameters using the Reddy-Blander model. The capacities predictions were made in a wide range of matte and slag compositions, PSo, and temperatures in conditions pertaining to copper and lead industrial slags. The calculated results for sulfide and arsenate capacities are in good agreement with the available experimental and industrial copper and lead industrial slags data. The sulfide and arsenate capacities in copper slags (fayalite, ferrite and olivine) and lead slags are reviewed. The application of RB model predicted ratios of O2 and S2 partial pressures in industrial copper smelting processes are discussed. Application of this model for the prediction of Sb, Bi and other impurity capacities and their distribution ratios in mattes or metal and slags, in industrial smelting and refining processes is discussed.

Jan 1, 2003

By S. Matsuyama, S. Tomita, H. Kawahara, G. Deguchi

A proper management system of coal mine methane gas associated with underground mining activities is essential for the mine safety due to its nature of explosion. Optimum design of the mine ventilation and gas drainage need accurate prediction of gas flow rate emitted by mining activities. Permeability to gas, which is affected by stress conditions of surrounding rock mass, governs the emission rate of the gases. JCOAL has developed a three dimensional FEM simulation program named Mine Gas Flow 3D (MGF-3D). MGF-3D is designed to predict the volume of methane gas emitted from surrounding coal and rock seams based on stress distribution and permeability change which are determined by 3D stress analysis. In MGF-3D, stress change and/or expansion of fractured zone affected by mining is calculated at the first and then gas emission into roadways and longwall panels under the determined stress conditions is calculated using Darcy’s law. MGF-3D also can set up a number of pre-drainage holes and estimate drainage gas volume from each hole. This function makes MGF-3D remarkable program. These simulations for gas emission can contribute to mine gas utilization plan. Comparison between actual measurement of gas emission in the underground mine and simulation results has been performed and availability for the mine safety and problems with MGF-3D are discussed in this report.

Jan 1, 2003

By Steven Brown, Richard Stephenson, Richard Partch, Hongyu Wang

Filler technology has enjoyed a revolution in attention and achievement in the past half century. The genesis of the advancements is greater find a mental understanding of the synthetic chemistries for and physical properties of colloidal matter and instrumentation capable of characterizing particle size, shape and surface features. Several advanced chemical methods for processing powders are now employed in ceramic, electronic, imaging, medicinal and plastic technology. This presentation will highlight solution phase synthetic methods for in situ coating of fillers such as SiC, Al2O3, AlN and SiO2 and some properties of the product solids.

Jan 1, 2003

Mining is a high risk, high capital and potentially high reward undertaking. A large proportion of the risk comes from a lack of definition of the orebody (which also provides some of the potential) and the unpredictable nature of the market. This makes the planning process difficult but encourages the development of a robust yet flexible mining system. The system should be capable of absorbing some deviation from the anticipated concept without a significant impact on profitability. The mine planning process tends to consist of a series of related but discrete stages. For instance, the pit shells are designed, a schedule for the pit shells is created, a plant fleet is chosen to achieve the schedule and a financial analysis is carried out on that scenario. It is likely a few iterations are carried out using various mill throughputs to produce a favoured financial result. The problem is that handing results from stage æBÆ for use in æCÆ doesnÆt encourage a flexible system. æCÆ is likely to be built for exactly æBÆ. Unfortunately, in mining, æAÆ (the orebody) has the highest potential for variability and impacts everything else downstream. æDÆ the market also has high potential for unplanned variability. These variations can spread and æreverberateÆ through the whole mine process. For example an unexpected increase in ore oversize impacts all downstream mine processes to the primary crusher which may in turn create problems back æupstreamÆ by restricting throughput rate. Also an unexpected drop in demand or price could require modifications to the planned production rates. This paper looks at how mining process simulation can be used to support the development of strategies to counteract unforseen circumstances or alter production to match fluctuations in demand and price.

Jan 1, 2003

By P. Pal Roy, Ajit Raj Ostwal, M. M. Singh

Field investigations have revealed that sawdust can be used as an efficient additive to ANFO for carrying out production blasts in limestone mines. Sawdust can be used at a reasonably reduced cost without sacrificing fragmentation, muck profile and wall control. Such additives lower the detonation pressure of ANFO by acting as low-grade fuel that reacts or burns more slowly in the presence of ammonium nitrate than does fuel oil. On detonation, it eventually forms near-ideal oxygen balance that helps in liberating maximum energy to break the surrounding rock. It also forms a low-density stable mixture that helps in reducing loading density (kg/m) of explosive in the blasthole. Experiments performed at the Hirmi Limestone mine, M/s L&T, and at the Lambasta Limestone mine, M/s Jaypee Rewa Cements, showed the novel acceptance of the technique in a highly competitive market where cost reduction has been a major area of thrust.

Jan 1, 2003

By Z. Hou

ABSTRACT: Short-term strength, damage and healing boundaries for rock salt are experimentally determined and integrated into the Hou/Lux-MDS damage-healing model. This model can be used to describe the mechanical behaviour of rock salt during a damaging process (under high stress to strength ratios) as well as during a healing process (under very low stress to strength ratios with high confining pressure). The development of the damage and the stress to strength ratio in the excavation damaged zone (EDZ) of a storage cavern under a minimum internal pressure as well as the development of the healing of damage and the stress to strength ratio under a subsequent maximum internal pressure are investigated project-related. The results of the investigation make it possible to shift the permissible minimum pressure boundary down, allowing the optimisation of decisive economic characteristics of storage caverns. RÉSUMÉ: Le comportement court terme, l’endommagement et les conditions de colmatage pour le sel gemme ont été étudiés expérimentalement et intégrés dans le model endommagement-colmatage Hou/Lux-MDS. Ce modèle permet de décrire le comportement mécanique de sel gemme pendant le processus d’endommagement (sous fort rapport contrainte-résistance) et le comportement du processus de colmatage sous très faible rapport contrainte-résistance avec forte pression de confinement. Le développement d’endommagement et le rapport de contrainte-résistance dans une zone d’endommagée (EDZ) d’une cavité de stockage avec un maximum de pression de soutènement ont été étudiés. Les résultats de cette étude permettent de conclure qu’il est possible de baisser la pression de soutènement, et par conséquent d’optimiser les caractéristiques économiques décisives des cavité de stockage. ZUSAMENFASSUNG: Für Steinsalz werden Festigkeits-, Schädigungs- und Verheilungsgrenze experimentell ermittelt und in das Schädigungs-Verheilungs-Modell Hou/Lux-MDS integriert. Damit kann das mechanische Verhalten von Steinsalz sowohl bei einem Schädigungsprozess (mit hohen Ausnutzungsgraden) wie auch bei einem Verheilungsprozess (mit niedrigen Ausnutzungsgraden) beschrieben werden. Projektbezogen werden die Schädigungs- und Ausnutzungsgradentwicklung in der Auflockerungszone einer Speicherkaverne unter einem minimalen Innendruck sowie die Verheilungs- und Ausnutzungsgradentwicklung unter einem anschließenden maximalen Innendruck untersucht. Die Untersuchungsergebnisse erlauben, die zulässige Minimaldruckgrenze nach unten zu verschieben, so dass entscheidende wirtschaftliche Kenngrößen von Speicherkavernen optimiert werden können.

Jan 1, 2003

By Steven Wright, Sharif Jahanshahi, Shouyi Sun

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were fixed.The chemical composition of the phases was determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The results of the equilibrium study are presented in terms of how the oxygen and the sulphur pressure affect the distribution of Pt, between the matte and the alloy foil (Lmatte/alloy). Other variables investigated were matte chemistry, i.e., the Fe content and the temperature. The activities of platinum in the mattes were calculated using a regular solution model describing the activity-composition relationship in the alloy."

Jan 1, 2003

By Kobus (J. J. ) Rossouw, P. Chris Pistorius, Johannes Sono

"Different coal properties are important in SL/RN (coal-based rotary kiln) direct reduction of iron ore, and in electrical smelting of prereduced iron ore. Laboratory simulation was used to evaluate two candidate coals, which were similar in volatile content and rank, but differed in reactive maceral content. The tests served to evaluate both the reduction rate (during direct reduction) and the dissolution rate of carbon from the coal into an iron bath.Reduction rates of mixtures of magnetite and devolatilised coal were assessed isothermally, using samples of 55 grams. The off-gas analysis was used to follow the extent of reduction. Results are shown in Figure 1 a). Coal B was expected to be more reactive, based on its higher content of reactive macerals (77%, compared with 61% for Coal A). In line with this, Figure 1 a) does show a higher reduction rate with this coal. However, increasing the reduction temperature increases the reduction rate substantially,especially for the less-reactive Coal A.For the dissolution experiments, samples (mass: 250 g) were melted in an alumina crucible (under a nitrogen atmosphere), to give a starting composition around 1%C. When the desired temperature was reached, 25 g of char was added on top of the melt, through a feeding port. Results are shown in Figure 1 b). The more-reactive Coal B was less crystalline (the graphite crystallite size estimated from X-ray diffraction was 4.6Å, compared with 11.4Å for Coal A). This is associated with a lower dissolution rate in iron."

Jan 1, 2003

By A. V. Tarasov

Investigations of thermodynamic properties of Cu-Ni and Cu-Ni-S systems and mattes have been conducted with the aid of a MC-130 I mass-spectrometer designed for studies of processes of vapor formation of hardly volatile substances. The instrument comprised a combination of an evaporator of Knudsen chamber type with a mass-spectrometer for analysis of the vapor phase. In the process of studies of molten Cu-Ni-S systems and commercial-grade mattes within a temperature interval of 1400-1800 K the partial pressure of sulfur was measured by means of complete isothermal evaporation and the partial pressure of copper and nickel by comparison of ionic currents. The partial pressure values of the components above the molten Cu-Ni-S were used for calculation of activities of the respective components in the melt. The copper and nickel activity data obtained was used for assessing the amount of dissolved losses of these metals in autogenous smelting slags.

Jan 1, 2003

By Paul M. Godlewski, Roberto J. Guardia

Hundreds of highway and rail transportation tunnels in North America have been rehabilitated in the last two decades. Tunnel rehabilitation is usually dictated by an owner’s need to extend the working life of the structure, but typically has the added benefit of increasing capacity (greater speed or increased clearance) and enhancing safety. Not only has rehabilitation proven to be an economical alternative to new tunneling, but it can be safely accomplished by working during short work “windows” without taking the tunnel out of service. This paper presents methodology for planning and designing of tunnel rehabilitation projects, and case histories illustrate successful excavation and support technologies.

Jan 1, 2003

By André Desbiens, Jocelyn Bouchard, René del Villar

"The metallurgical performance of the column flotation process is determined by the concentrate grade and recovery. Although the former can be continuously measured using an on-stream analyzer, the latter must be estimated by a material balance calculation based on seldom verified steady-state assumptions. Consequently, the automatic control and optimization of flotation columns should be performed using secondary variables having a strong influence on the metallurgical performance, such as froth depth, gas hold-up or bubble surface area flux and bias. The aim of this paper is to present a model-based automatic control strategy using froth depth and bias measurements obtained from virtual sensors developed at Laval University. Preliminary pilot plant results on two-phase (water– air) and three-phase system (water – minerals – air) will be presented and eventual industrial implementation of such a strategy as well as the possibility of achieving effective real-time optimization from bias and froth depth measurements will also be discussed.INTRODUCTIONFlotation columns have been widely studied and used in mineral processing for about twenty years. Although a great deal of work has been accomplished to understand the influence of different variables such as froth depth (H), bubble surface area flux (Sb) and bias (Jb) on the metallurgical performance, the measurement of some of these variables is still difficult to be performed – except at the laboratory level – because in most cases, no commercial device yet exists.As a result of this, it is almost impossible to achieve neither efficient control nor optimization of the process at the industrial level, even in open-loop operation. This paper aims at presenting a simple control strategy of froth depth and bias. Description of the sensors used to achieved measurements, preliminary pilot plant results for froth depth control, eventual industrial applications and possibilities for process optimization are also treated."

Jan 1, 2003

By I. Matsunaga, K. Aoki, W. -j. Jung

Blasting is widely used in mining and basic construction because of its speed and economy to destroy the rocks. Blasting has the advantages of reduced excavation costs and shorted construction time when compared to the use of heavy machinery for excavation and cutting such as that with a tunnel boring machine. There are numerous problems with blasting, including the noise, vibration and fly rock. So it is necessary to accurately evaluate fracture mechanics of rocks on the dynamic loading condition to control the fracture process of the blasting. The tests using Hopkinson's effect for the dynamic condition using the precise detonators were performed for various strain rates on three different kinds of rocks. In the tests using Hopkinson's effect for the dynamic condition, the high-speed camera was used to observe the fracture process of the test sample rocks. As the results of experiments there was an increase in the tensile strength of rock with an increase in the strain rate for three kinds of rock on the dynamic loading. The tensile strength of rocks with high porosity on the water saturation condition was decreased on the both static and dynamic condition. It is clear that the strain rate and water saturation were influenced to the tensile strength of the rocks.

Jan 1, 2003

The article presents methods of testing and recording of water amount pumped out in surface mining. The authors describe necessary recommendations how to carry out measurements so that one can separate the surface run-off and groundwater inflow from the total inflow. They demonstrate methods of evaluation of these kinds of inflow in open pits when water amount testing is carried out every eight and 24 hours as well as simple methods when only monthly records of water are available. The authors also describe procedures for evaluating the water inflow when an open pit is dewatered gravitationally and measurements in discharge channels are irregularly carried out.

Jan 1, 2003

By S. Z. Galiyev

In this paper the basic approach to the present planning and quality management of open-pit ore streams is presented. This is accomplished within the framework of a unified system of information management for the administration of a geotechnological complex on open-pit development of mineral deposits.

Jan 1, 2003

By Kang N. Zhong, Hui H. Luo, Yunan Phosphate Chemical Co., Yi H. Wei, Yao J. Li, Yu L. Wang

"The three kinds of phosphate ores (igneous, metasedimentary and sedimentary) found in China have great differences in flotation flowsheets and reagents suite because of their crystal structure and mineral composition. The igneous and metasedimentary apatites have good floatability with fatty acid as collector and waterglass, sodium hydroxide or sodium carbonate as conditioners. The sedimentary phosphate is very difficult to beneficiate by direct flotation because of their poor floatabilities and relatively high content of MgO and SiO2, even though the dolomite depressants are used sometimes.The differences in floatability of apatites in China are closely related to their differences in specific surface area. The amount of collector to float apatite increases with the specific surface area. Apatite with lower specific surface area showed good floatability at lower collector concentration. Apatite with a higher specific surface area needed a higher concentration of collector. The content of CO3 2- will affect the specific surface area of apatite by distortion of its crystal structure and consequently affect its floatability.Dolomite can be easily rejected from apatite in a weak acidic medium (pH=5), especially in phosphoric acid medium by reverse flotation. Quartz and siliceous gangue in sedimentary apatite can be removed by direct flotation using fatty acid or by reverse flotation using amine. Amine is not practically applied because sedimentary apatite in China is usually very fine and needs fine grinding, which always results in excessive, very fine, stable and non-flowable foam.Based on the floatability of phosphate ore in China, a two-stage flotation process, direct and reverse flotation (D+R), was developed to beneficiate sedimentary ore. For the Haikou phosphate ore containing 25.11% P2O5, 3.46% MgO and 16.5% SiO2, a concentrate containing 31.84% P2O5, 0.48% MgO and 14.8% SiO2 can be obtained through a continuous D+R test at a recovery of 89%."

Jan 1, 2003

By Z. Szczepanik, D. Milne, K. Kostakis

Abstract This paper presents the results of a series of creep tests performed on a total of nine samples of Lac du Bonnet granite from the Underground Research Laboratory near Pinawa, Canada. Each of the nine samples were subjected to stresses in excess of 80% of the average uniaxial compressive strength of the granite and were maintained at that level of constant loading for periods of time ranging between a few minutes and several months. Acoustic emission was recorded in order to monitor the development and accumulation of brittle microfracture damage in the samples throughout the long-term loading. According to previously published theoretical predictions and field results, as well as similar experimental results of creep tests in granite, samples should fail when loaded to 70% of their UCS for an extended period of time. Six of the samples did not fail when subjected to stresses in excess of 80% of their UCS over periods of several months and were subsequently subjected to uniaxial compression to failure. The average strength of the samples that had previously been subjected to long-term loading were comparable to the average published strength of this rock. Three of the nine samples had increased end confinement and these three samples failed under long term loading. Résumé Cet article présente les résultats d'une série d'essais de fluage de roche exécutés sur neuf échantillons de granite de Lac du Bonnet, du laboratoire souterrain de recherches près de Pinawa, Canada. Chacun des neuf échantillons a été alors soumis aux charges au-dessus de 80% de la résistance à la UCS moyenne du granit et a été maintenu à ce niveau du chargement constant pendant des périodes s'étendant entre quelques minutes et plusieurs mois. L'émission acoustique a été enregistrée pendant les essais afin d'obtenir des indications des dommages pendant le chargement à long terme. Selon des résultats théoriques précédemment édités et les résultats expérimentaux semblables des essais à long terme en granite, échantillons devrait échouer si chargé à 70% de leur UCS pendant une période prolongée. Six des échantillons n'ont pas cassé quant ils ont été soumis aux charges au-dessus de 80% de leur UCS et ont été plus tard soumis à la compression uniaxiale à la rupture. La force moyenne des échantillons qui avaient été précédemment soumis au chargement à long terme étaient comparable à la force éditée moyenne de cette roche. Trois des neuf échantillons avaient augmenté le confinement de fin et ces trois échantillons ont cassé sous le chargement à long terme. Zusammenfassung Dieser Artikel beschreibt die Resultate von Kriechversuchen, die an neun Proben aus dem Lac du Bonnet Granit des "Underground Research Laboratory" bei Pinawa in Kanada durchgeführt wurden. Jede der neun Proben wurde Drücken unterworfen, die mehr als 80% der einaxialen Druckfestigkeit des Granites entsprechen. Diese Drücke wurden für verschiedene Zeitspannen von wenigen Minuten bis zu einigen Monaten auf einem konstanten Niveau gehalten. Während der gesamten Langzeitbelastung wurden akustische Emissionen aufgezeichnet, um die Entwicklung und gesamthafte Beschädigung der Proben durch Sprödbruch aufzuzeichnen. Entsprechend bisher veröffentlichter theoretischer Vorhersagen, Feldversuchen und auch experimentellen Resultaten von Kriechversuchen an Granitproben wäre ein Versagen der Proben zu erwarten gewesen, wenn sie über längere Zeit einer Last von 70% ihrer einaxialen Druckfestigkeit unterworfen werden. Wider Erwarten trat bei sechs der Proben kein Versagen ein, als sie mit über 80% ihrer einaxialen Druckfestigkeit über mehrere Monate belastet wurden; daher wurden sie im Anschluss bei einaxialer Kompression zum Versagen gebracht. Die mittleren Festigkeiten der im Langzeittest verwendeten Proben sind vergleichbar mit den normalerweise für diesen Gesteinstyp angegebenen Festigkeiten. Drei der neun Proben versagten unter der Langzeitbelastung; diese drei Proben hatten eine erhöhte Endflächenreibung.

Jan 1, 2003

By Khaled Morsy

In this paper a new method to evaluate the stability of yield pillars was introduced. The evaluation of yield pillar stability was conducted in three steps: (1) Estimation of pillar loading - numerical modeling is a good tool to estimate the pillar loading for most of the geological, geometrical and mining conditions. In this study. finite element technique was used to estimate the state of stress, strain, elastic strain energy and plastic energy, etc. at every point within the pillar. (2) Defining the yield pillar loading zones¬. The proposed method considered the non-uniform stress distribution of yield pillars by dividing the area of the yield pillar into three loading zones, namely core, transition and rib zones. (3) Estimation of stability indicators - an appropriate stability measure was proposed for each loading zone. such as; Core Stability Factor. CSF, Pillar Bump Index, PBI and Rib Instability Index. RIF. A case study of successful and unsuccessful yield pillar application was used to assess the applicability of the proposed method.

Jan 1, 2003

ThePike River coal field is located between 700 and 1000 m above sea level on the West Coast of the South Island. The area contains a resource of some 60 million tonnes of coal in a single coal seam and is part of the Paparoa mountain range that receives between 6.0 and 6.5 m of rainfall per annum. The area has been isolated and has received no on the coal plateau but has been extensively logged in the lower 3.5 km of Pike Stream. The PRCC development proposal recognises this and calls for an environmentally benign development that includes underground development of this resource. The coalfield abuts and is partly overlain by the Paparoa National Park. The underground development will enable a number of environmental goals to be readily achieved: it will be out of sight of the public,it will not impact the national park,noise will be mostly absent,there will be absolute minimal disturbance to the land surface,coal will be transported from the mine to a dewatering complex on PRCC land in a slurry pipeline thus obviating the need for trucks and noise in Pike Stream valley,all water draining from the mine will be collected, treated if required to consent standards and discharged from a single point,the road into the area will allow for an effective predator control programme to be undertaken enhancing native bird life,an environment suitable for the reintroduction of Whio (Blue Duck) will be created, andthe net effect of the mine development on the environment will be positive.

Jan 1, 2003

By Yasuo Ojima

The mainstream of copper smelting processes in the world today is a combination of Outokumpu type Flash smelting and PS (Pierse Smith) converting process. Presently it can be estimated that about 50% of the worldwide copper production is produced by the Flash smelting process and 80% by the PS converting process. PS converting process due to its operational flexibility and despite its batch character of operation has been widely used in many smelters for more than 100 years. However, an environmental issue has been pointed out related to this process because of the difficulty of handling the fugitive gases. Recently several copper smelters in the world have been newly construeted and others have executed major modification and modernization. The continuous converting process has been applied in many of them instead of PS converting process. This paper compares PS to the emerging continuous converting process and makes a prospect of the future of the copper converting process.

Jan 1, 2003

By D. W. Alexander

Mine fires, explosions, spontaneous heating and inundations are among the leading causes of catastrophes (unplanned, temporary sealing and recovery of major mines). Many reports are available that detail company efforts to re-establish mining operations and agency efforts to regulate away the causes, but the associated costs are rarely included. The increasing scale of coal operations concentrates earning potential and the financial risk of business interruption in fewer locations. Underground coal mine catastrophes are low probability, high loss events that happen nearly every year. This paper will present an evaluation of coal mine catastrophes from case studies.

Jan 1, 2003