Search Documents

By V. A. Bryukvin

A characteristic feature of the macrokinetics of the interaction process is the presence of two specifically defined areas of oxidation which had a linear time dependence. The effect of variables, such as residual sulphur content of the melt, temperature and the oxidation potential of the gas phase, on the macrokinetics of oxidation are investigated. Phase composition and structure of products of solidification of partially oxidised melts and thermodynamic properties pentaining to Cu-S-O melts are used to analyze the macrokinetic behaviour and mechanisms of the interaction. The process of interaction of sulfide copper melts with oxygen may be considered as a disproportional absorption process and its mechanism is based on localized interaction on the surface and inside the melt volume. Superficial processes include also the process of primary chemisorption of oxygen by melts at place of metal-metal donor bonds proceeding with formation of oxysulfide liquid solutions and volumetric decomposition of the latter accompanied by evolution of sulfur dioxide and metallization of sulfide melts. It is the degree of dynamic balance of such interaction processes that determines specific individual features of the macro-kinetics and mechanism of oxidation of sulfide copper solutions with oxygen in the gas phase.

Jan 1, 2006

By Li Qihou

Mono-disperse ZnS and CdS nano-particles were prepared by the homogenous precipitation method and the effects of SO42-,NO3- and Cl-ions on crystalline of particles were investigated experimentally. The results showed that these anions had no influence on the crystalline of ZnS, but different crystalline CdS ultrafine particles were produced in different anion systems, where the blend-type CdS was obtained from natrate or sulphate solution, and wurtzite-type CdS from chloride solution. It was ascribed to the coordination of Cl- and Cd2+ that altered the supersaturation of precipitate ions in the solution, the existing growth units and their connecting patterns, thereby producing wurtzite-type CdS with a more stable structure.

Jan 1, 2006

By María Cristina Ruiz

In the processing of copper concentrates by the conventional smelting-converting technology, complying with the increasingly severity of environmental legislation in some countries has become difficult, mainly due to severe fugitive emissions of gases produced during the batch PS (Peirce-Smith) converting step. In this work, the results of an investigation on the pressure leaching with sulfuric acid and oxygen of white metal (produced in a Teniente Converter reactor) are discussed. The study was carried out at laboratory scale and the main variables studied were temperature, concentration of sulfuric acid and partial pressure of oxygen. The experimental results indicated that most of the sulfur in the white metal was oxidized to sulfate in the whole range of temperature studied (105ºC to 150 ºC). The concentration of sulfuric acid over 0.05 M, and oxygen partial pressure over 6 atm had little effect on the dissolution of copper from the white metal. On the other hand, temperature had the most significant effect on copper dissolution; below 130 ºC copper dissolution was incomplete after 5 hours of leaching while at 150 ºC the dissolution was complete in 90 minutes and 10 atm of partial pressure of oxygen

Jan 1, 2006

The paper describes the procedure of data inquiry on the structure of mineral production in Austria and selected results. Goal of the endeavor was to gain more tangible insights into the mining industry as a basis for regulation balancing economical, ecological and social aspects.

Jan 1, 2006

By P. Trueman

A project is underway to convert a validated methodology to a system that will permit the near real time interpretation of loading data from longwall powered supports, allowing rapid adaptation of mining strategies, maintenance scheduling and set pressures for optimal roof control. Such a system has the potential to significantly reduce roof control problems and is a pre-requisite to successfully fully automating a longwall face. The development depended upon a robust methodology for interpreting the pressure sensor data coming from the face in the context of support strata interaction using a novel characteristic load cycle analysis concept. New software was developed capable of handling the large quantity of data emanating from a modern longwall with the current level of signal corruption and loss, accurately delineating load cycles and extracting the critical load cycle features essential for interpreting how the support and strata are interacting. Existing software being used to access the pressure data were found either to be incapable of delineating load cycles at all or, where they could, the accuracy was low, making it impractical to use them in combination with the new advances in load cycle analysis. The software is currently being extended from ?off line? to ?on line? in order to provide a real time response to changing strata conditions.

Jan 1, 2006

By Thomas A. Bailey

Since the advent of longwall mining, various methods and materials have been used during relocation to control the intrusion of the gob in the shield/panline area. (figure 1) Controlling this gob is critical to ensuring a safe, speedy, and productive longwall move. An uncontrolled gob can cause a number of problems, from increased worker exposure to entrapment of equipment to lost production. With an eye toward worker safety and increased productivity, several different methods have been developed to minimize gob intrusion. This presentation will take a look at the history and development of longwall ?screens? and ?mesh?, from chain-link fencing to high-modulus polyester geogrids. The benefits and advantages of these developments will be defined. Since 1994, longwall coal mines have used polymer geogrids during longwall recovery to control intrusion of gob material into the shield/pan line area. As described by Brandon and Collins (1996) in their paper presented at the 15th Ground Control Conference in Golden, CO., mines had used various forms of support, such as welded wire mesh, chain-link fencing, wooden cribbing, props, and steel cable to accomplish this. These methods worked, but were labor-intensive, slow, and provided varying degrees of gob stoppage. Although a few mines still use chain-ink fencing to control the gob, longwall coal mines have generally settled on polyester geogrids to control gob and roof and these mines have been instrumental in providing input in order to develop and improve these geogrids products. he trend during the past twelve years has been to incorporate stronger grids and to eliminate auxiliary reinforcements, such as steel cables and nylon or polyester webbing. A job that once required heavy steel cables, props, and fencing is now accomplished with strong, lightweight, high-modulus polyester grids. When we discuss high-modulus grids, we refer to the ratio between load and strain, as illustrated in figure 2. These grids are woven or knitted from yarns that have been pre-stressed. When these grids come under load, they pick up the load more quickly. This allows less deformation in, in this case, the mine roof. The same principle applies when these grids are used to control the ribs. With less elongation, the grids will hold rib material tighter, thereby keeping travel ways more open.

Jan 1, 2006

By J. D. Steenkamp, G. E. Williams

Keywords: Ilmenite, titania slag, pig iron, rutile, zircon Located on the eastern shores of South Africa, 180 km north of Durban, Richards Bay Minerals (RBM) produces approximately 2.0 million metric tonnes of product annually making RBM a leading producer of titania slag, high purity pig iron, rutile and zircon. Heavy minerals are extracted from the nearby dunes by dredging and concentration on a floating gravity separation plant, followed by separation of the ilmenite, rutile and zircon at the mineral separation plant located at the smelter site. The ilmenite is processed through an oxidizing roast followed by magnetic separation and is then partially reduced to an 85 per cent TiO2 slag in one of four six-in-line a.c. electric arc furnaces. The slag is milled and then classified into two product sizes suitable as a raw material for both the sulphate and chloride pigment processes. The high quality iron produced during the reduction process is further processed to produce various grades of low-manganese iron. Around 95 per cent of the products are exported, yielding a world market share of about 25 per cent of titania slag, rutile, high quality pig iron, and zircon.

Jan 1, 2006

By R. E. Wilmot

The problem of corrosion of reinforcement in concrete structures is internationally recognised and represents the single biggest expenditure in the preservation of steel reinforced concrete structures. While the corrosion protection of the reinforcing steel is no substitute for design and the placement of good quality concrete, it does provide for a viable and economical extension of structural integrity and service life in the day-to-day and practical environment in which concrete structures are constructed. The mechanism of corrosion attack and consequent deterioration of reinforced concrete structures is well understood and documented. New structures can be designed and built to withstand corrosion. However, due to short-term economical restraints, many new reinforced concrete structures continue to suffer as a result of corrosion damage, which results from the corrosion of the steel reinforcing. This paper explores the economic and practical benefits offered by the application of hot dip galvanizing as a viable means of protecting reinforcing steel concrete structures. The paper also discusses technical misconceptions that exist with respect to the application and performance provided by the use of hot dip galvanized reinforcing steel.

Jan 1, 2006

By Emad Farouz

The resistance of very dense glacial outwash formations consisting of sand, gravel and cobble formations can be quite high, and techniques for measuring the strength and deformation properties often cause engineers to underestimate the strength of these layers in drilled shaft design. More realistic measurements of this dense formation can be achieved with slotted steel casing pressuremeter tests. To minimize disturbance and achieve accurate measurements, drilling a pilot hole prior to probe insertion is necessary. Characterizing geologic formations that contain significant amounts of gravel and cobbles is challenging because of scale factor. Inserting a standard pressuremeter probe into this formation without damaging the membrane is difficult. This paper presents a case study for the IR-75 project in Dayton, Ohio, USA, where these dense materials were characterized using a slotted casing pressuremeter, optimizing design by providing more realistic properties of these materials.

Jan 1, 2006

By A. Akerman, C. P. O’Connor, N. Vayenas

"Stereolithography is a well-known rapid prototyping technique in the manufacturing sector. Essentially, it is a three-dimensional printing process that produces plastic prototype parts from standard CAD files. At present, Canadian mining companies are not fully aware of the potential of rapid prototyping techniques (RPTs) for their production and mine design systems. Mining engineers and geologists attempt to visualize and understand the characteristics and layouts of orebodies on computer models, and in cases where it is decided to develop physical models, the process is time-consuming, based on simplified constructions. RPTs, such as stereolithography, can facilitate engineers and geologists to quickly, and with satisfactory accuracy, visualize sections of orebodies and evaluate alternative ore extraction techniques using 3D solid models.The research discussed in this paper is carried out by the Laurentian University Mining Automation Laboratory (LUMAL) in collaboration with Inco Limited and the Integrated Manufacturing Technologies Institute (IMTI) of the National Research Council of Canada. The main objective with this research is to evaluate the applicability of state-of-the-art RPTs to underground hard rock mining systems. RPTs can play a significant role in accelerating the design and development process of mining systems."

Jan 1, 2006

By B. Yalamanchili

Gerdau Ameristeel Beaumont presents its systematic approach for upgrade decisions that has developed over 30 years of ongoing capital projects for quality and cost improvements. This system serves to identify product needs, select process improvement strategies, justify them, and assist multi-department communications and decision-making. This is illustrated with Beaumont mills? last Stelmor upgrade and leads to a discussion of the need to consider Life Cycles of both products and technologies as we move to answer the challenges of the future.

Jan 1, 2006

By H. A. ?ye

The ISO TC 226 (Materials for the production of primary aluminium) has presently issued more than one hundred standards on the materials: alumina, pitch, petroleum coke, carbon anodes, carbon cathodes, ramming paste, fluorides and refractory). The object of the standardization work is to find methods that both material producers and smelters will accept. Methods that are specific for the operational conditions have been developed in addition to more traditional room temperature methods. Examples of important properties under operational conditions are: Air and C02 reactivity of anodes, Equivalent temperature for baked anodes, Sodium expansion of cathode blocks, Shrinkage and Rammability of paste, Penetration of electrolyte into refractories.

Jan 1, 2006

By J J. McEwan

Silver tarnishes readily in common atmospheres and is accelerated in humid atmospheres. Tarnish is the formation of silver sulphide on the surface of silver when it is exposed to a wide range of sulphur-containing atmospheres. Tarnish is unattractive and highly undesirable, and can be removed either with a silver polish or a chemical dip. Dips are generally only recommended when heavy black tarnish cannot be removed with a polish, and care must be taken during cleaning because these can contain aggressive chemicals and give off hazardous and unpleasant smelling fumes. Polishes work best for large areas of plain undecorated silver, and form part of a regular cleaning programme. Some polishes contain chemicals that inhibit tarnishing, but these generally only have a short life. Several methods have been developed to reduce tarnish formation on Silver; these include alloying, surface treatment, and coatings. The authors evaluated a range of self-assembled monolayer (SAM) surface treatments and coatings in earlier research. Four treatments/coatings increased the time to noticeable tarnish by more than ten fold, and the results were reported at the International Corrosion Congress (ICC) in 2005, and at the Mint Directors Conference (MDC) in 2006. SAM treatment using 95% 1-hexadecanethiol (C16H34S) was found to give good anti-tarnish performance and showed potential for the commercial treatment of Sterling silver. Therefore research was performed to optimise the methods of application of this type of coating to provide an easier, faster, and more-user friendly technique to provide an anti-tarnish treatment. Keywords: silver, tarnish resistant coatings.

Jan 1, 2006

By R. S. McDonald

Auburn began operations 40 years ago with an office in Sudbury, Ontario, Canada, to provide services to Inco Limited. Over the next 40 years, operations expanded considerably, with projects being undertaken around the world, servicing the smelting and refining industry. Operating bases have been established in Canada, United States, Mexico, Chile, and Spain, with further growth expected to continue with an operating presence in South Africa. The Auburn Group of companies has serviced the smelting and refining industry for over 35 years. Auburn services a variety of metallurgical plants, and our worldwide experience has gathered considerable knowledge on industry processes and maintenance solutions. Today, the ?Business of Smelting? tackles demanding challenges, and operators search for opportunities and solutions to improve smelter maintenance, reduce operating costs, and decrease downtime. The Auburn Group has developed project teams, technologies, and equipment that provide specialised and innovative solutions to the non-ferrous metal industry to help address these challenges. Our Furnace Services team offers a variety of repair and maintenance services for metallurgical furnaces. Our specialised team has proven methods for completing projects quickly and safely. Our worldwide experience includes turnkey project management, construction, and various scopes of work for demolition and refractory repairs on all types of smelting and refining furnaces. Auburn developed the Results FirstTM programme to provide optimized solutions and results for smelter projects. The programme utilises a proven three-step model for improved results for schedule, budget, safety, and ramp-up to production. Our experienced Project Management teams can handle the planning and construction management of capital projects and plant shutdowns. Our projects have involved smelter/refinery modifications, oxygen plant installations, and sulphuric acid plant audits and maintenance. Our Equipment & Products division supplies specialised equipment and products, which are used in the metals industry for plant maintenance tasks. Our capability to design unique equipment, combined with our ability to source products worldwide, makes us a useful resource to find the best-suited equipment to meet the work-site demands. We specialise in custom remote-control units to handle specific maintenance solutions for smelters and refineries, and custom equipment designs for catalyst handling for Acid Plant maintenance. Our extensive knowledge of and experience with industrial technologies allows us to provide a wide range of Industrial Services. These services include vacuuming, high-pressure water blasting, chemical cleaning, pelletizing, dredging, ore bin clearing, roaster repairs, baghouse/ESP services, and manpower supply for both industrial plants and mines. Auburn?s combined strength of personnel experience, knowledge of industry processes, innovative project methods, and equipment technology make Auburn a unique resource for problem solving on every facet of smelter operations.

Jan 1, 2006

By O. A. Ojo, R. G. Ding, M. C. Chaturvedi

In this study, the fusion zone microstructure of tungsten inert gas weld of a directionally solidified NhAl-base alloy was examined by the standard metallographic techniques involving the use of optical, analytical scanning and transmission electron microscopes equipped with energy dispersive spectrometer. Fusion zone cracking was observed to be closely associated with interdendritic secondary solidification microconstituents identified as consisting of y, y' and NiMo (Y) phases. Depression of solidification temperature to the terminal ternary eutectic reaction temperature of the system during cooling is suggested as an important factor contributing to the fusion zone cracking.

Jan 1, 2006

By T. R. Curr, R. T. Jones

Keywords: Pyrometallurgy, Mintek, DC arc furnace, plasma, smelting, chromite, ilmenite, cobalt, slag, zinc fuming, dust, magnesium, laterite, ferronickel, arc modelling, Pyrosim, thermodynamics The Pyrometallurgy discipline at Mintek was initiated in the early 1970s, to support a growing ferroalloy industry in South Africa. In addition to a range of pyrometallurgical options, Mintek specialises in DC arc furnace technology and has pilot plant facilities up to 5.6 MVA, as well as a strong base in process and arc modelling. Industrial processes have been developed for ferrochromium production, ilmenite smelting, and cobalt recovery from slag. Recent work has been done on such processes as the production of ferronickel from laterite ores, the fuming and condensation of magnesium, and the recovery of platinum group metals from 'difficult' feedstocks.

Jan 1, 2006

By R A. Lynch, D A. Malovichko

The implementation of routine real-time micro-seismic monitoring of open pit mine slopes has been discussed. Some examples of seismic arrays have been given, and a recommendation of suitable seismic sensors made. Unfortunately near-surface sensors are required for good location accuracy, and the effects of reflection, mode conversion and surface waves must be accepted and compensated for during processing of the seismograms. It makes sense that mining at the base of a slope and levels of seismic activity within the slope should be related, and this is confirmed using both 2002-2003 and 2005 seismic data recorded at Navachab mine. An example of how seismic data can be used to gain information about seismically active geological structures has been described. The removal of broken rock, and not blasting nor the breaking of supporting rock, has been found to cause slope micro-seismicity. While the standard Brune source model is suitable for some 20% of the seismic events, unreasonable results are obtained for the rest. A moment tensor inversion has been performed after S-wave splitting and surface effects have been filtered out. This approach confirms a predominantly shear mechanism for a typical high frequency source.

Jan 1, 2006

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na') properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By C. Wieckert

Concentrated solar energy can be used as heat source for the production of metals. One of the most promising respective processes, the solar carbothermic production of Zn from ZnO, is investigated within the European research project SOLZINC, a cooperation of institutes and industries from France, Germany, Israel, Sweden and Switzerland. The solar produced Zn can be used as commodity or as an energy carrier for further processing on demand to electricity in Zn-air fuel cells/batteries or to generate hydrogen by reaction with steam. In both cases the Zn is oxidized to form ZnO, which can be recycled back to the solar plant. In these cyclic processes Zn acts as a means to store and eventually transport solar energy. Second product of the solar process step is a CO-rich offgas, which may e.g. drive a gas engine or may be shifted to hydrogen in a conventional reaction with steam. A pilot plant using 300kW concentrated solar power input has been constructed and operated successfully. 86mass-% of ZnO mixed with 14mass-% of charcoal are reacted to produce Zn and CO at a temperature of about 1200°C, yielding about 50 kg gaseous Zn per hour. Zn-dust with 95% purity is recovered from the offgas system that was designed to produce Zn for Zn-air fuel cells. Based on the results and findings from the pilot plant, a two tons Zn/h solar demonstration plant has been designed conceptually. Cost studies have been performed and scenarios for producing electricity or H2 via these ZnO/Zn-cyclic processes are evaluated.

Jan 1, 2006

By Pastsakom Kitiyodom

In order to estimate the deformation and load distribution of a single pile subjected to dynamic horizontal load as well as vertical load, a simplified method of three-dimensional numerical analysis, KWaveHybrid program, is developed using a hybrid model. In the hybrid model, the pile is modelled as elastic beams, and the soil at each pile node is treated as springs and dashpots in both vertical and horizontal directions. KWaveHybrid is also able to analyse the static response of the pile. Validity of the newly developed program is examined through comparisons with theoretical values and horizontal dynamic and static pile load test results

Jan 1, 2006