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By R. H. Lien, B. T. Waterman

Passive bioremediation can be a cost effective treatment for a variety of mine waters, including final draindown of closed cyanide heap leaches and seepage from tails dams. These solutions can contain noncompliance concentrations of arsenic, antimony, cyanide, mercury, nitrate, selenium, silver, etc. Passive bioremediation involves treating the contaminated solutions under anaerobic conditions. Contaminants such as mercury and nitrate are effectively removed in passive bioreactors whereas the effect of this treatment on TDS, cyanide, and sulfate is minimal. Several waters from gold heap leach operations were treated in the column tests. These tests determined the effectiveness of contaminant removal from each water and also provided important scaleup design information.

Jan 1, 1997

By Robert J. Storms, David J. Malone, Thomas E. Crandall

Corrosion and abrasion have been present in hydrometallurgical processes for many years. Ceramic lining materials have been used in several applications to protect process vessels from the corrosive and abrasive effects of a wide range of ore slurry processes. This paper reviews the history of ceramic lining systems utilized in hydrometallurgical vessels, the commercial benefits associated with their use, and additional areas of opportunity for the Mining Industry.

Jan 1, 1995

By Tony Weeks, J. Loah, Ian Mcgaffin

PT Newmont Minahasa Raya (PT NMR) operates a 700,000 tonne per annum open cut gold mine in the Minahasa region of North Sulawesi. The operation commenced production in the second quaiter of 1996 and is expected to produce an average of 150 000 to 180 000 ounces of gold per year for the mine life. The deposit is predominately refractory in nature and requires a complex treatment route incorporating dry milling and whole ore roasting followed by conventional cyanidation and adsorp­tion of the gold onto activated carbon. Gold is eluted from the carbon to produce <lore bars assaying approximately 94 percent gold. A scrubbing system for the removal of mercury from the roaster off gases was commissioned in late 1997. Due to the location of the operation, close to the coast and in seismic region with high rainfall submarine tailings placement (STP) was the preferred method of tailings disposal. Prior to dis­posal into the ocean the tailings from the CIP plant are detoxified in a three stage detoxification circuit to treat cyanide, arsenic and mercury. This paper reviews some of the design and operational fea­tures of the whole ore treatment process employed at the Minahasa Gold Mine.

Jan 1, 1998

By Sean E. Armstrong, Deepak Malhotra

Gold extraction from refractory ores as a percentage of total gold production is increasing. The processing technology options for treating difficult-to-process refractory ores are also increasing. The best processing option is dependent on many factors including feed grade and the cause for ore refractoriness. The causes for ore refractoriness are many foldCpreg-rob­bing, encapsulation in pyrite, arsenopyrite or silica, presence of cyanocides, presence of cyanide-insoluble gold compounds, etc.1. The first step in the process development of a refractory gold deposit is to determine the cause for ore refractoriness. The traditional approach of undertaking detailed mineralogical examination of ore types, major and minor mineral constituents and their association does not necessarily provide the metallur­gist all the information needed for characterization of gold-bear­ing ores. For process development programs it is desirable to complement traditional mineralogical methods with diagnostic leach testing, which attempts to quantify the deportation of gold in various mineral matrices. This paper briefly reviews the diagnostic leaching proce­dures and its applications for a wide range of gold-bearing refractory ores, both primary and by-product.

Jan 1, 1996

By Jim Johnson

The purpose of this paper is to summarize and discuss a variety of site specific conditions which are typically evaluated as part of the engineering design process for heap leach pads, solution control ponds, and associated facilities. The following sections will focus primarily on the topographic, climatologic, hydrologic, and geotechnical evaluations critical to selection of heap leach sites, and selection of a preferred heap leach configuration or method. Other important considerations in the design of a heap leach project, including evaluation of ore properties and leachability, pregnant solution processing requirements, spent ore neutralization/disposal requirements, and other anticipated reclamation requirements are beyond the scope of this paper are not addressed in any detail.

Jan 1, 1998

By Tong Deng, Yun Ma

Gold-copper ores have become important gold resources (von Michaelis, 1989), but the gold extraction from such materials posed a challenge due to the detrimental effect of copper species on gold cyanidation. Ammoniacal cyanidation process was rec­ommended (Muir et al., 1989) and practiced (Castello et al., 1992) for gold extraction from the gold ores which contain cop­per at moderate level mostly in form of oxide. This paper pro­vides an example to apply the ammoniacal cyanidation process to processing such a copper bearing gold ore.

Jan 1, 1996

By Marcos C. Filgueiras, Thomas A. Post, Michael A. Giralico, Daniel M. Adams

The leaching of copper, gold, and nickel in tanks requires mixing. Minerals require oxygen, acid and/or base [NH3] to assist in the leaching process. Two basic types of tanks are used for this operation. They are either vertical tanks or closed horizontal tanks called autoclaves. This paper discusses mineral leaching, it's mixing requirements, and autoclaves.

Jan 1, 1999

By Andrew Griffiths

The emphasis in the title of this paper should be placed on the world "Total", since the detoxification of cyanide in its free and weakly-complexed form with H202 has already found application in many areas, including the treatment of mining effluents. One of the most common forms of cyanide found in gold-mill effluents is hexacyanoferrate (usually ferrocyanide), which is included in measurements of total cyanide but is too stable to be oxidized by H202 or any other conventional oxidizing agent. This has led to the view that H202 cannot be used to detoxify effluents containing hexacyanoferrates, when a limit has been set on total cyanide. A process is described in this paper which does meet this requirement, and which has already been demonstated in two Canadian gold mills. Before describing the new process, the terms "free", "total" and "weakly-complexed" cyanide will be defined as they are used in this paper.

Jan 1, 1998

By J. R. Montgomery, T. A. Phillips, F. Blackham, D. J. Adams

Underground water, whether it is a mine seep, in situ leach solu­tion, or a pollution plume, is difficult to track and monitor. Monitoring wells are costly to drill and may be placed in the wrong spot. This report describes a test of an electromagnetic technique to track acid water draining from the Midnite Mine near Spokane WA. The tests successfully mapped the path of acid mine drainage being collected at the mine from two seeps. Several small side branches flowing to smaller seeps and a mix­ing zone where relatively clean water mixed with the acidic water, were also mapped. The study has changed previous opin­ions on the flow of water through the site and will be used as a basis for future site remediation planning.

Jan 1, 1996

By Jeffery S. Thompson

In this report, the effect of catalytic amounts of activators on gold dissolution in clear solutions with gold disks and with slur­ries of gold ores is presented. Activators are nitrogen and sulfur aromatic heterocyclic compounds, which catalyze the gold dis­solution reaction in cyanide and other lixiviant solutions. Gold dissolu!ion studies in clear solutions indicate that the catalyst must bmd to the gold surface to catalyze the dissolution reac­tion. A concentration dependence for activation is observed· the optimum catalyst concentration depends on choice of activtor lixiviant concentration, and solution agitation. Nitrogen and sul fur aromatic heterocycles catalyze gold dissolution in slurries of gold ores with cyanide and other lixiviants. The typical proce­dures of agitated leach and rolling bottles were used to evaluate gold leaching rates. Activation has been demonstrated with a variety of ore types.

Jan 1, 1996

By Rene Steensma

The possibilities of the use of ultrasonics in the extraction of gold and silver is the subject of a study initiated in our laboratory since the beginning of 1986. The study consisted of various aspects of extraction, the results of which are in· different stages of advancement. Reduction in leach time combined with higher recovery are the most striking effects so far. The ultrasonics machine, originally part of a small pilot plant, forms now part of a much larger unit. This has the remarkable effect of even higher recoveries and shorter leach times. These data suggested a study on the possibilities of reduction of thiourea consumption. Although promising, the results of these studies require check testing and will be published as soon as our findings have been confirmed. During the study, which consisted of the application in thiourea and cyanide leaching, some interesting side effects were observed. In the first place, a reduction in penetration time which might make coarse grinding feasible. Secondly, an increase in compaction of the filter cake which reduces pregnant liquor losses, especially with clayey ores and industrial waste products. These will be studied under contract in the near future.

Jan 1, 1998

By Ing. H. Kellerwessel, Ing. M. Esna-Ashari

This paper refers to the new crushing and grinding process, invented by Professor Schonert (Ref. 1), Clausthal, Germany. The process is known as high pressure particle bed comminution or interparticle crushing. Several papers already describe fundamentals of the process, the equipment used, results of lab size and large scale tests and the first results of commercial operations (Ref. 2 to 7). Of course, we will treat the topic from the perspective of a downstream gold ore upgrading or leaching process. Some recently executed testwork indicates that the process provides special advantages in this field. To describe the process generally, in view of the already existing publications.

Jan 1, 1998

By O. Guyot, T. Mulpeter

Sadiola Hill mine is located in the sub-Saharan part of Mali. In its first two years of operations, Sadiola Hill mine had already exceeded expectations with respect to profitability, plant capacity, metallurgical recovery, cash costs and social integration into the area. The advanced control system installed by the authors has been a major contributor in the substantial throughput of the mill over the design tonnage with no loss of recovery. The run-of-mine ore at Sadiola consists of soft clays with a varying percentage of grit, producing a high viscosity slurry. The percentage of grit fed to the plant varies on an hourly basis. This combination was expected to have a large impact on the milling circuit and determined that the early installation of an expert mill control system would be advantageous. Svedala Cisa OCS©, was selected as the most suitable support software. The operational rules and control philosophy are housed in the OCS© graphic-oriented fuzzy expert system while a model­based Soft Sensor has the remarkable ability to detect the variations in grit in the feed. Designed during the second half of 1996, commissioning of the system began in March 1997, the OCS was fully on-line by September. With the implementation of the optimising control strategy a throughput of 5.0 million tons relative to the target of 4.4 million tons was achieved for the 1998-operating year. The Sadiola project confirms that advanced process control techniques are among the most cost-and time-effective methods of improving metallurgical plant performance. The recipe that worked at Sadiola is a mix of metallurgical expertise, proper software selection, adequate design of control philosophy, and excellent plant support and follow­up. The early decision, design and installation of the mill control system has resulted in an enhanced Return on Investment.

Jan 1, 2000

By Chuck Hornaday, Brad Miller

Geosynthetic clay liners (GCLs) are manufactured barrier layers containing a high-quality sodium bentonite clay attached or adhered to geotextiles or a geomembrane. The GCL's low permeability and high strength make it an ideal replacement for low permeability soil or clay liners for mineral extraction and processing containment applications. This paper will discuss the advantages of utilizing a GCL versus compacted clay in containment applications. Some of the advantages include: the GCL's lower permeability (5 x 10-9 centimeters per second (cm/sec)) and corresponding better composite liner leakage protection, the GCL' s greater resistance to desiccation, differential subsidence and freeze­thaw, and lastly, the ease and speed of installing the GCL. This paper will also detail a number of important case studies related to the mineral extraction and processing industry. These case studies include using GCL in two large reclamation capping projects, as a secondary liner in two gold heap leach pads, as a composite liner in a dam for stormwater runoff control, and lastly, as a primary liner for a tailings runoff diversion channel.

Jan 1, 1997

By Leonard Harris

Since the end of the cold war following the collapse of communism, enormous amount of funds are pouring into the developing countries including investments by mining companies for the development of gold and silver mines. A great deal of these funds are destined for expenditure in areas riddled with bandits, terrorists and active and latent criminals bent on stealing the mine operators hard earned production on its way from the mines to markets. Brambles Security Services employs experts in the field of safely transporting gold and silver products under various alternatives and aimed at relieving the mine owners of this responsibility. This paper examines the various service options available.

Jan 1, 1997

By R. C. Dunne, C. T. O'Connor

Flotation practice on eighteen South African flotation plants is described. The plants are categorized as those treating reclaimed tailings, those treating material which has already been subjected to cyanidation or uranium leaching, and those treating milled ore. The similarities and differences are highlighted.

Jan 1, 1998

By Stephen Young

The continuous monitoring of free cyanide levels is an important part of gold recovery operations. Accurate and up to the moment knowledge of the free cyanide concentration can result in substantial cost savings by allowing reduced concentra­tions with lower fluctuations, while maintaining or increasing gold recovery. Reduced free cyanide levels also result in lower detoxification costs at the mill discharge which translates into further savings while meeting environmental requirements. As can be seen from the upper curve in Figure 1 (which is based on in-service measurements), without accurate monitoring and control, cyanide concentration fluctuates during the produc­tion cycle, and is maintained at a high level to err on the side of caution. The lower curve illustrates the improved control permitted by the installation of a CY ANCOR, giving a more consistent concentration over the process cycle, and safely allowing use of a lower concentration.

Jan 1, 1995

By Gordon V. lewis

The Penjom gold mine treats highly preg-robbing carbonaceous ore by using relatively inexpensive gravity and hydrometallurgical methods. The mine is a joint venture between Avocet Gold Limited, a subsidiary of Avocet Mining PLC, a U.K listed mining company with interests in gold and tungsten, and the Pahang State Development Corporation (PKNP) who receive a 2% royalty. The operating team at Penjom embarked on a programme of innovation during 1998 following a realisation that almost all of the primary ore in the gold deposit was highly carbonaceous in nature. Earlier attempts at desliming and leaching the deslimed product through a normal CIL circuit had failed, and through shear necessity, the team turned to new technologies which were considered most suited to the ore characteristics indicated from pre­feasibility testwork. Between April and September, 1998, the mine introduced three key processes, which combined represent the elements of "The Penjom Process". The gravity circuit was boosted to maximise the capture of leachable sulphide and free gold from the relatively carbon free cyclone underflow stream, kerosene and diesel blanking was introduced to treat the cyclone overflow and RIL (resin-in­leach) technology utilised to replace the existing CIL (carbon-in-leach) circuit. Further experimentation with selective resin in partnership with Mintek of South Africa yielded a significant improvement to the process during 1999. Minix­Dowex resin was introduced mid year to replace a non-gold selective resin, which had been used in a flotation/batch leaching circuit for about nine months. Lower carbon levels in the feed at that stage led to the abandonment of flotation and the introduction of continuous RIL, which has been adopted as the major chemical process at the Penjom gold mine since September, 1999. Given the proven performance of the circuit to date, this process may be considered as a low cost option for the treatment of highly carbonaceous ores, particularly those which are not refractory and contain a reasonable percentage of free gold.

Jan 1, 2000

By Scott W. Beckman, Leslie C. Thompson, Joseph A. Kizis

Heap leaching of ore with cyanide is a common and economical means of extracting precious metals (gold and silver) from mined ore. The use of cyanide, and the heap leach process, can seriously impact the environment. In the worst case, catastrophic failure of containment structures can release toxic levels of cyanide into receiving bodies of water, resulting in toxicity to ecological communities and contamination of public water supplies. Furthermore, cyanide degradation products such as nitrates can also impact local streams, lakes, and aquifers. Even if cyanide can be removed, the crushed residual ore may generate acid solutions that can release toxic heavy metals into the environment. Pintail Systems, Inc. (Pintail) of Aurora, CO, in conjunction with technology partners Science Applications International Corporation (SAIC) and Fairmile Gold Corporation (Fairmile), have developed a microbially-based precious metal lixiviant that can be used as an alternative to cyanide. The microbial process, called BioLix, is Pintail's second-generation biotechnology product for the recovery of precious metals from ore. The BioLix process is based on the enzymatic induction of organic lixiviant compounds using proprietary inducing agents and microorganisms. The process operates at near neutral pH and ambient temperatures using non-pathogenic microorganisms and food-grade chemicals. Precious metal extraction is also enhanced through the employment of microorganisms that facilitate mineral-solution reactions such as surfactant generation (improved wettability), and oxidation of gangue minerals that expose mineral surfaces to leaching. In order to demonstrate the effectiveness of the BioLix process, results from laboratory bench-scale experiments and a column study are presented. In addition, new applications for this enabling technology are discussed and include re-leaching of spent ore heaps, in situ leaching, and cyanide replacement for heap leaching.

Jan 1, 2000

By S. R. LaBrooy, J. Avraamides

Thermal reactivation of eluted carbon is an essential part of most carbon-in-pulp gold recovery plants. The effectiveness of the reactivation procedure depends on the nature and level of contaminants adsorbed on the carbon, the efficiency of the elution and the temperature, residence time and atmosphere within the kiln. The most commonly used kilns are evaluated in terms of their operating parameters and performance. Data obtained both in the laboratory and in the field emphasize the importance of carbon feed moisture content, kiln atmosphere and carbon conditioning on the activity of the kiln product.

Jan 1, 1998