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By Doug Williams, Kent J. McGrew, Dr. Jack Murphy

For some time, selenate has eluded water treatment by conven­tional means such as precipitation and clarification. This has been due to the nearly universal solubility of all oxidized sele­nium species, the low levels required for surface discharge, and almost identical chemical behavior to all forms of oxidized sul­fur. The last characteristic makes selenate particularly difficult to deal with in acid mine waters where sulfate can easily be on the order of one gram per liter. Approaches such as ion exchange or reverse osmosis often tum into total demineraliza­tion schemes for the sake of removing a "trace" selenium species that may be present on the order of 108 sulfate/selenate. Reduction of selenate to selenite or elemental selenium by chemical means has been relatively unresearched. Some limit­ed success has been reported (Murphy, 1988) using ferrous hydroxide as a reducing agent; however, the reaction time as reported is too slow to be useful in a practical plant design. One significant difference between selenate and sulfate is that selenate has been discovered to be reducible in acid solution by elemental iron when catalyzed by soluble copper. Since the +4 or zero valence states of selenium are rather easy to deal with by coprecipitation with iron salts or alum, the elemental iron dis­solved in the process contributes to the overall process by pro­viding sludge upon raising the pH that can be separated by con­ventional clarification. Commercial production of selenium using copper catalyzed reduction of selenite to selenium metal via sulfur dioxide is well established, however, at the < 5 ppb requirements for surface discharge this reduction process equili­brates at levels far too high to be useful to low level selenate removal criteria. The reaction reported herein uses elemental iron for reduction of selenate with copper acting either as a cata­lyst or as a coprecipitation agent. This method, employed with conventional sludging, clarification and filtration can provide an economic method to achieve non detectable selenium (< 0.005 mg/I). Iron consumptions for the conditions tested have been on the order of 3 lbs/1,000 gallons treated. This represents as little as $0.06 or $2.00 per 1,000 gallons based on using a scrap source of iron or the purchase of electrolytic iron for the process.

Jan 1, 1996

By K. R. Weller

In recent years, a variety of new or substantially modified grinding machines have been offered to the mining industry with claims of improved performance relative to standard grinding machines especially rod and ball mills. The incentive for developing such new machines is high, because costs associated with grinding are a very substantial part of the total costs of processing run-of-mine ore, and gold ores are no exception in this regard. The incentive is also high because of the very low conversion of input energy to comminution energy in most tumbling mills. If the most energy-efficient means of mechanical size reduction is slow compression of single particles, then this energy amounts to only about 3% of that used in tumbling mills. It would seem, therefore, that there is a huge potential to do better. This paper examines three types of grinding machine for which claims of higher energy utilisation ( amongst other beneficial claims) have been made, namely the high pressure grinding rolls, the vibrating drum mill and various styles of stirred mill. It presents evidence concerning the claims, examines the range of particle size and particle size reduction over which benefits might reasonably be expected to accrue, discusses the major issues in contention and briefly describes the research the CSIRO Division of Minerals has in progress, both independently and collaboratively, the latter mainly with the Julius Kruttschnitt Mineral Research Centre (JKMRC) via the Cooperative Research Centre for Mining Technology and Equipment (CMTE) and the Australian Mineral Industries Research Association (AMIRA). There are many criteria which may be chosen to assess relative performance of grinding machines. Those used below are:

Jan 1, 1995

By Malcolm J. Lake, P. Brad Marchant, Linda M. Broughton

Thiourea is recognized as a technically competitive alternative to cyanide for gold and silver extraction for a variety of ores and concentrates. This paper describes the results of a recent mini-pilot locked cycle test comparing cyanidation with acidothioureation treatment of gold bearing sulphide concentrate. The gold extractability of both methods was similar. The comparative metallurgical operating conditions and test results are summarized. Detailed byproduct solution analyses and environmental toxicity test results are presented and suggest that thioureation might result in acutely toxic byproducts even after treatment. Comparative process economics are summarized based on preliminary commercial operating flowsheets derived for the locked cycle case study. Capital and operating cost estimates are shown. The results indicate that cyanidation is more economically favorable within the constraints of the case study. Considerations for process selection between thioureation and cyanidation, for conceptual case studies, are discussed.

Jan 1, 1998

By Norbert Patzelt, Hans Knecht, Wolfgang Baum

Future ore reserves of major gold producers in North America and elsewhere will consist of refractory gold ores. About 60 % of the current U.S. gold production is mined in Nevada. Several of the large gold operations in this state indicate that 40 to 90 % of their future ore feeds will contain refractory gold. To compound problems, average head grades for refractory U.S. gold ores have fallen from 8 - 9 g/mt to about 4 g/mt by 1991. In Latin America, 52 % of the gold operations will require milling for optimal recovery. Deeper reserves are, like in North America, refractory. Particularly in hard, (semi)refractory sulfide ores, many operations may experience substantial decreases of gold recov­ery. For example, Martins et al. (1991) report that at an Austra­lian mine, sulfide ore treatment led to 4 - 10 % lower gold reco­veries as the work index increased from 8 kWh/t to 14 kWh/t and the grind coarsened. Many refractory ores should actually be classified as semirefractory since a fine sulfide fracturing and liberation would make 80 - 90 % of the gold cyanide leachable. However, conventional comminution is often prohibitively expensive for these ore types.

Jan 1, 1995

By R M. Whyte, D McArthur, A Macintosh

In designing a gold extraction circuit utilising carbon­in-pulp (CIP) technology a number of process options can be considered. These include various combinations of leach or pre-leach, CIP or carbon-in-leach (CIL) and conventional counter-current or carousel CIP (or CIL) circuits. Factors affecting the process selection include the project's sensitivity to capital and working costs, the project life, and the mineralogy and head grade. Each process option has it's own advantages and disadvantages. This paper compares both the financial and technical aspects of the flow sheet options. The flow sheet, design aspects and operating performance of Anglogold's West Wits No. 2 and 3 Plants which are leach, pump-cell circuits are described.

Jan 1, 2000

By P Simpson, P Bundo

The Eureka Mine is situated in the Guruve district of Zimbabwe, some 150 km north of Harare. The mine was first worked in 1895 and until recently was operated as a typical Zimbabwean "smallworking" with a single owner­operator and small labour force mining at up to 50m depth and processing 50 tonnes per day of ore via grind, gravity recovery and CIP. The gravity circuit comprised a Knelson 12" Centre discharge Concentrator from which a significant but variable portion of production was recovered. In 1996 exploration was commenced by Delta Gold Zimbabwe (Pvt) Ltd (DGZ), a wholly owned subsidiary of Delta Gold NL of Australia, with the aim of testing mineralisation and establishing a large-scale open pit operation. A feasibility study was completed in April 1998. Construction began in August 1998 and first gold was poured in June 1999. The mine is designed to produce 65 000 oz/annum of gold from 1.5 million tonnes of opencast ore grading 2 git Au.

Jan 1, 2000

By Robert W. Bartlett

Heap biooxidation of sulfidic refractory gold ore requires large amounts of oxygen, as shown in Figure 1. Bacteria, Thiobaci/lus ferrooxidans, are donnant at oxygen concentrations below about 3% in air (1 ppm in aqueous solution) because ofmonod kinet­ics. Hence, the maximum possible utilization is only about 75%, and it may be much less than that due to poor air sweep effi­ciency. At the maximum oxygen utilization, an ore containing two percent pyrite requires nearly 100 cubic meters of air per tonne (4,000 cubic feet per ton). The stoichiometric air require­ment to oxidize arsenopyrite is similar to that of pyrite. While the leaching solution percolating through the heap introduces some dissolved oxygen, the amount is insignificant because of the low solubility of oxygen in water, 7 to 8 ppm at atmospheric saturation. There are only three ways to provide oxygen to the heap: either air flow by natural convection, diffusion of oxygen from the surface (through stagnant air in the air-filled void space in the heap), or forced air ventilation of the heap. Each of these processes will be reviewed.

Jan 1, 1996

By Paul D. Chamberlin

In the author's selenium report of 1994 (1), the literature was culled for selenium removal technologies that had a chance of producing effluents with <10 ppb of total selenium. Very few processes could achieve such low concentrations. The EPA dictates such low concentrations. Discharges to fishery waters must be <5 ppb total selenium. The federal max­imum contaminant level ( MCL) for drinking water is 50 ppb. The EPA regulations are for total selenium, not for the species, perhaps because an approved EPA assay method is atomic absorption and it cannot distinguish between species.

Jan 1, 1996

By Reinhold Schulze

Thiourea is being applied as an industrial leaching agent for gold and silver only in a few cases. A CIP technique was developed which eliminates most of the obstacles against its use. Mild conditions for precious metals stripping from the loaded carbon simplifies process conditions in comparison to cyanide CIP technique. Examples are given.

Jan 1, 1998

By Donald R. East

There has been an increasing trend in recent months by regulatory agencies to require that estimates be made of the hydraulic head acting, under operational conditions, on the surface of primary leach pad liners. This move towards inferred performance standards, rather than specifying a prescriptive standard for all sites regardless of economics, is to be generally welcomed. The theory of flow on a sloped beach pad, which was developed by East et al, 1987 (Reference 1 and 3) has been refined and extended. Unitized curves have been developed by graphically displaying the seepage losses and resulting dissolved gold lost as seepage through the primary liner as an aid to pad liner selection and design. Very little information is available of actual hydraulic head profiles acting on the liners beneath heap leached ores. Attempts have been made to measure these by drilling from the top of the heap and installing piezometers at the base. With this procedure it is difficult to obtain accurate data due to the fact that the drilling operation itself creates a highly permeable vertical flow path which may not exist to the same degree elsewhere in the heap. Combined with the fact that it is almost impossible to ensure that the piezometer tip is sitting directly above the liner without the risk of causing some damage to the liner itself. The best time to install hydraulic head monitoring devices on the pad liner is during construction and when piezometers can be carefully placed directly above the liner and suitably protected hydraulic lines laid to ensure full hydrostatic head measurement with simple manometer devices.

Jan 1, 1998

By Steve Hansen

Heap leach mining has long been an economical method for mining oxide copper ore, and with the U.S. Bureau of Mines' discovery of a way to economically strip gold and silver from carbon, it has become the standard in the gold and silver indus­try as well. Sulfide leach in copper recovery has always been a byproduct of oxide leach mining, although the methods and recovery rates have increased with technology. SX-EW has kindled a new interest in large deposits and dormant dumps of low grade sul­fide ore. Gold ore bio-oxidation was developed in the 1980's, but not tried on a large scale until US Gold built the Tonkin Springs Mine. This mine was dedicated to the large scale production of low grade sulfide ore that could be recovered through the newly discovered bio-oxidation method. On a small scale the method worked, but as time went on, problems with the process were costly and recovery was poor. US Gold did not have the finan­cial backing to perfect the process, and the mine was closed in 1990. Since that time, Newmont Gold Company has taken the lead and has dedicated a lot of resources to the perfection and implementation of this method. Some small mines have discov­ered that if they can use this technology they may be able to dou­ble and triple current ore reserves, because they will be able to mine deposits previously considered not to be economical.

Jan 1, 1998

By John J. Mancini

Elastomeric liner products have been used for over two decades in a wide variety of uses including pond liners, hazardous waste barriers, dam face rehabilitation and mining applications. Asphalt blended with polymers is enjoying renewed interest in the engineering community because of its durability, high yield attributes, fewer CQA steps due to seamless installation, and ease of installation and repair. As in other lining technologies, advancements in polymer chemistry and improvements in installation techniques have had dramatic impact on the quality of fluid-applied asphalt (FAA) membranes. Membrane 6, man­ufactured by Deery Oil, Inc. for over 16 years is a hot-applied polymer modified asphalt membrane that can be applied to a variety of substrates in a reinforced configuration or installed directly on an asphalt surface. By blending thermoplastic polymers with asphalt, very favorable stress/strain characteristics can be achieved (Chambers, 1980). Typically the membrane will yield under rel­atively low stress and also exhibit high elongation capability. In service applications where puncture resistance is a concern, fluid applied asphalt materials have the flexibility and com­pressive strength under heavy loading that leach pad designers may find attractive. Additional security is achieved if long term service life is important as in the case of radioactive waste con­tainment. The Department of Energy selected Membrane 6 over seamed liners for a surface barrier that must isolate and contain radioactive waste for 1000 years. Asphalt has a long history of use as a water-stop material and it is believed that this natural construction material combined with SBS polymers will per-form for a millennium. (Freeman, 1994) The process of installing Membrane 6 varies according to job size and the type of surface to be protected. Lining applica­tions on compacted substrates require the membrane to be applied to a scrim cloth (fig 1). Some early pioneers in FAA technology neglected this step and therefore never achieved per­formance levels that satisfied regulatory guidelines. The scrim provides a cohesive surface that promotes membrane flow while achieving high impermeability (2Xl0 '11).

Jan 1, 1996

By Thomas J. DeMull

Amax Gold's Sleeper Mine was brought to production as an open pit mining, cyanidation milling operation in March 1986. The Sleeper deposit is unique in that it contains zones of very high grade gold ore. Despite blending of ore, mill head grades have varied over a broad range. These grade variations were anticipated during mill design and affected, in particular, the sizing and selection of equipment for the CIP circuit. When grades proved to be even higher than anticipated, design operating parameters were adjusted shortly after start-up to accommodate the higher grades. Operating results have been excellent: during the first 18 months of operations the Sleeper mill has processed 375,600 tons of ore and produced 229,000 ounces of gold.

Jan 1, 1998

By Douglas K. Maxwell

Critical components of any Carbon-In-Pulp or Carbon-In-Leach system are the carbon retention screens. One popular design of carbon retention screen is the "NKM" or "Nor-Kai" unit that was developed in South Africa based on units from there and Australia. OSNA Equipment has been manufacturing "NKM" style screens in North America since 1989. OSNA has sold approximately 200 individual NKM screens to date, equipping more than 20 gold leaching plants in the Americas and the Southwest Pacific.

Jan 1, 1996

By Michael R. Straka

ALPKEM A Brief History, Cyanide Questionnaire Conclusions

Jan 1, 1998

By Steve Rule, Jose Roberto Vago, Walter de Moura

Cerro Vangaurdia Gold Mine is a joint venture between AngloGold (the operator), Perez Companc and Formicruz and is situated in the southern province of Santa Cruz, in Argentina, approximately 2,150 km south of the capital, Buenos Aires. The mine is located in a severe, semi-arid environment with very cold winters and little annual rainfall (200mm). It is an open-pit operation, mining several narrow, shallow epithermal quartz veins with . gold and silver mineralisation. Commissioning of the plant commenced in September 1998 and the first dore bar was poured towards the end of the same month. The nominal capacity of the plant is 55,000 tonnes per month, with a design capacity of 60,000 tonnes per month. Prior to finalising the design, an extensive testwork programme was undertaken at Nova Lima, in Brazil, in which all parts of the process were evaluated together on a pilot-plant scale. The process flowsheet selected at Ce1rn Vanguardia is quite novel, in that it includes milling in cyanide, as well as a cyanide recovery and recycling plant on the tailings section of the treatment plant is included. The cyanide recovery process selected was a version of the acidification - volatilization - reabsorption (AVR) process, known as Cyanisorb™. The selection of the Cyanisorb™ process in the plant design was as a direct consequence of two factors:

Jan 1, 2000

By Hans von Michaelis

Welcome to RANDOL GOLD FORUM 88. It is clear from the list of delegates and speakers that this conference will lead to excellent discussions of the latest developments in this fast-moving industry. Less than a year ago Randol International Ltd. published an eleven-volume report titled "Innovations in Gold and Silver Recovery - Phase 111". In the short space of time since then, many new developments have been noted, many of which will be described in this Forum. I believe that some of the more significant innovations currently under development are those that address the following:

Jan 1, 1998

By L. J. Warren

Recent research at the Parker Centre in Pe1ih, Western Australia, has provided opportunities to reduce gold production costs by: reducing lime costs in the carbon-in-pulp process, understanding the mechanism of selective extraction of gold over copper using ammoniacal cyanide, and increasing throughput and improving overflow clarify in thickeners. This paper reviews the work of these three Parker Centre project teams, and highlights those instances where the results have been applied to plant practice.

Jan 1, 1998

By D. D. Carda, S. Dunn, W. E. Dunn, T. Storbeck

Gold chlorination which will be presented in this paper is limited entirely to the use of gaseous chlorine in a fluidized bed reactor at elevated temperatures in the absence of aqueous water. The only water used in this process is that which is used in scrubbing the effluents. Low temperatures are defined as those below 500°C. All experimentation for this paper was carried out on a laboratory scale, with all calculations extrapolated frpm this. Some of the data is drawn from work with other projects which have been operated at pilot and larger scale.

Jan 1, 1998

By Stuart Ratcliffe, Denis Kidby

The development of Vitrokele™ Technology over the last 10 years is reviewed with reference to mine site piloting and com­mercial applications. The first mine site piloting was conducted in Australia in 1989 followed by a further six continuous site trials in Australia, Canada and the USA. These major pilot plant studies are complemented by over 50 laboratory scale batch and pilot testwork programmes. The first commercial plant using Vitrokele™ Technology was the Connemara project commissioned in Zimbabwe in 1995. Subsequent to this, three commercial scale projects have been designed using Vitrokele™ to recover precious metals, base met­als and cyanide. The various projects are discussed with relation to the differ­ing flowsheets applied to each particular case.

Jan 1, 1998