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By G. E. Maryniak

To date, human space exploration has been almost completely dependent on the use of resources carried with astronauts and cosmonauts from the surface of the Earth. The only exception to this has been the harvesting of solar energy to power space stations like Skylab, Salyut and Mir for long-duration missions. This dependence on materials which must be transported into orbit at costs in excess of $5000 per pound is the fundamental limiting factor in space exploration and operations. It is likely that launch costs can eventually be greatly reduced by means of such innovations as true single stage to orbit vehicles, aerospace planes, or serial electromagnetic or laser launch systems. However, the Earth will always remain an expensive source of materials for space construction and for basic commodities such as propellant and life support liquids and gasses. Fortunately, abundant sources of materials exist which are already in space, outside of the Earth's deep gravity well.

Jan 1, 1992

By D. E. Ranta, Neil D. O’Donnell, Thad B. Ostrowski

Ore reserve estimation at the Syncrude Canada Ltd. open-pit oil sands mine in Northern Alberta has evolved since the project's inception. Early techniques followed a conventional petroleum reservoir analysis format, with relatively widely spaced drill holes and semiquantitative grade data. Experience has developed a more standard mining approach, including classification of geological materials by both lithology and sedimentary origin, timely and multi-purpose drill holes, precise analytical data, empirical recovery factors, a computerized geological data base, and an orebody block model. Future efforts will involve enhancement of existing techniques, use of geostatistical algorithms, quantification of confidence limits, and improved control of the ore model by geological parameters.

Jan 1, 1992

By I. de Jong, G. Van Weert

Silver cyanide adsorbs extremely well on activated carbons. This suggests that the addition of soluble silver salts to trace cyanide containing waste streams should allow efficient cyanide removal with active carbon. Silver losses, however, would make this method expensive and also objectionable, since silver has biocidal effects. When silver impregnated carbon is used, these problems are overcome. Test work has shown that such silver remains on or in the active carbon, that cyanide concentrations can be reduced to the level of detection (< 5 ppb) and that the silver impregnated carbon can be reactivated with equipment similar to that now in use at gold milling operations. Initial results on the type of carbon, the impregnation procedure and the level of silver, and the effect of repeated regeneration are discussed.

Jan 1, 1992

By J. L. Hendrix, M. Ahmadiantehrani, G. Ramadorai

The concept of hypochlorite treatment prior to cyanidation in the heap leaching of low grade carbonaceous gold ores is discussed. Laboratory column leach tests using a low grade carbonaceous ore were performed to investigate the effects of pH, hypochlorite consumption and concentration, and bed height on total gold extraction. At high pH, hypochlorite stability increases and thus, hypochlorite consumption decreases. At room temperature, total gold extraction is proportional to hypochlorite consumption. However, at some point additional hypochlorite consumption does not increase gold extraction. Gold recoveries of 10% and 80% are achieved at 12 and 167 lb/ton hypochlorite consumption, respectively. Increasing hypochlorite concentration increases the rate of extraction. For a given hypochlorite consumption, gold extraction increased with decreasing ore bed height. Finally, using calcium hypochlorite results in higher gold extraction than using sodium hypochlorite at a fixed hypochlorite consumption.

Jan 1, 1992

By James G. Sampson

The discarded phosphatic clays from mining operations have historically been stored behind earthen dams for long periods of time before any reclamation was accomplished. In efforts to expedite the dewatering and reclamation of the clay ponds, the phosphate industry explored alternatives to conventional clay disposal practices. One alternative, employed by CF Industries, Inc., combines the clay and the discarded sand prior to disposal behind earthen dams. The sand encourages the clays to &apos;give up&apos; trapped water more readily resulting in enhanced consolidation behavior. This paper provides an overview of the sand-clay mix process including the reclamation of sand-clay disposal areas.

Jan 1, 1992

By E. B. McNew, J. M. Barnes, A. E. Torma

The applicability of biosorbent materials for the removal of uranium and other heavy metals from synthetic and actual uranium mil 1 tailing (UMT) solutions has been investigated. The biosorbent materials used in this study were barium loaded beads of alginate, alginate-dextran sulfate, alginate-carrageenan, and alginate-xanthan gum. These studies were performed in stirred vessels and packed columns. It was observed that 100 percent of the uranium could be removed from a synthetic solution following 2 hours of contact time in a stirred vessel, and 80-100% of U, V, Mo, Mn, Sr, and Zn could be removed from a UMT effluent solution with a packed column. Kinetic evaluations were performed, using a generalized rate equation, on the biosorption of uranium with these barium loaded beads.

Jan 1, 1992

By J. Hupka

Some aspects of kerosene penetration into tar sand have been investigated. The natural tar sand porosity was measured and used to analyze the performance of the hot water process. Subsequently, pretreatment experiments, using 20 kg tar sand samples (Asphalt Ridge and Whiterocks, Utah), and kerosene as a diluent were carried out at the expected summer temperature (26°C) and the expected winter temperature (-14°C). The natural tar sand porosity accessible by diluent has a crucial impact on the reduction of bitumen viscosity, and influences the penetration time required for successful bitumen separation from tar sand by hot water processing. Thus the tar sand porosity is an important variable which determines appropriate operating conditions. Experimental results indicate that diluent penetration into the Asphalt Ridge tar sand (high porosity) is almost complete after 30 min, whereas for the Whiterocks tar sand (low porosity) the penetration process is much slower, and still not complete after 15 hours regardless of the ambient temperature.

Jan 1, 1992

By M. A. Cristovici

The use of surfactants as wetting agents to suppress sulfide ore dust has been investigated. Numerous surfactants were examined to determine their characteristics and to investigate their ability to improve the wetting of the sulfide ore dust. However, the surfactants selected as suitable dust suppressors proved to have a negative effect on the flotation of ore contaminated with such reagents. A method was developed to eliminate the detrimental influence of dust-suppressing surfactants. It consisted of surfactant adsorption on activated carbon and separation of loaded carbon prior to flotation. The technique is simple and requires minimal changes in the plant flowsheet.

Jan 1, 1992

By S. R. Titley

Results of regional analyses of precious metal habits in Arizona ores lead to interpretations of a fundamental ore control related to geographic location that corresponds with crustal contrasts. Measurements of isotopic and trace element characteristics of Laramide ore-related intrusions lead to interpretations of crustal derivation of apparent ore-related magmas. Interpreted regionally, the numerous kinds of Laramide ores, which include porphyry copper deposits of this southern cordilleran region appear to be phenomena of a specific crustal lithology characterized by a basement of Proterozoic turbidites and (an interpreted) lower crust of amphibolite. This association with a specific basement terrane may be extended in principle from the United states into Mexico where faulted offsets of this basement are similarly favorable to formation of Laramide porphyry ores -to the exclusion of adjacent terranes. Whereas plate tectonic mechanisms may have triggered evolution of these ores, it is hypothesized here that crustal setting and crustal composition are more profound influences of metallogenesis.

Jan 1, 1992

By J. G. Groppo, J. G. Justice, B. K. Parekh

Removal of particulates and/or metal ions from mineral/coal processing waste water is a necessity from the environmental point of view. This paper describes application of a novel AC- electrocoagulation technique to remove the particulates as well as metal ions using AC power. A series of laboratory tests conducted on a stable black water sample obtained from a sub-bitminous coal operation provided a clear supernatant (-10 NTU) from the suspension. The process also shows promise in removal of up to 90 percent of phosphate ions and other metal ions (copper and nickel) from solution. A preliminary economic evaluation of the process will also be included.

Jan 1, 1992

By Miguel N. Herrera, Abbas H. Mirza, Fiona M. Doyle

The standard test methods used to determine the pyrite content of coal and mineral wastes, and their propensity to release acidic drainage, are critically reviewed. In addition to analysis of total sulfur by combustion, test methods using selective oxidation of pyrite by HNO3 and H2O2 are available. The oxidation kinetics of pyrite vary appreciably from sample to sample, and it is difficult to ascertain whether complete dissolution has occurred in heterogeneous materials. The reliability, reproducibility and suitability of different standard test methods were studied, using well characterized ore and coal pyrite samples. The kinetics of pyrite dissolution were also investigated. The results are discussed in terms of the fundamental chemical and physical characteristics of each sample, and the implications for waste characterization are considered.

Jan 1, 1992

By A. Knoll, J. W. Beck, W. C. Brice, E. K. Lehmann

A cooperative study was undertaken in a neutral atmosphere by representatives of the environmental community, the mining industry and state government to identify and resolve environmental issues associated with base and precious metal mining before a commercial mining development is announced. The study included testing Minnesota&apos;s as-yet-untried nonferrous mining regulatory program using three hypothetical mining developments sited in environmentally sensitive areas where future mining could occur. Results include identification of critical paths for regulatory decision making, identification of particularly sensitive environmental issues that mill need continued deliberation before resolution and characterization of data necessary for environmental review and permitting decisions.

Jan 1, 1992

By B. M. Davis, J. Wilkins

The method of conditional simulation is easily implemented on the personal computer when the LU decomposition algorithm of Davis (1987) is employed. This algorithm is fairly compact, yet can generate moderate-sized simulations in a few minutes on a 80286 or 80386-based personal computer. The application of conditional simulation presented here is to generate possible ore inventories from a limited amount of exploration sampling. The simulations can then he examined to decide if the potential inventories are sufficiently attractive to proceed with further exploration. An example showing one application of this approach is presented.

Jan 1, 1992

By K. Cothern, S. Novack, D. A. Johnson, R. Borden, S. Pavlou

A procedure is presented for ranking hazardous waste sites for remedial decisions, and an example with application to mining waste sites is discussed. Typical contaminant concentrations are calculated from field data. Exposure indices that compare these measured concentrations with allowable limits are then computed. The limits are selected to protect both the health of humans (for both carcinogen and noncarcinogen effects) and the health of key organisms in the ecological food web. The additive exposure index for a site, defined as the sum of all contaminant-specific exposure indices, is then used in ranking the sites and assigning each a priority for remedial action. One key source of uncertainty in the process is the estimation of a typical site concentration from data that include values reported as "below certified reporting limit" (BCRL). This uncertainty is compounded in the additive exposure index and therefore may have a substantial effect on the assignment of remediation priority. A general approach is presented for incorporating consideration of BCRL data into uncertainty evaluation when assigning remediation priority designators to hazardous waste sites.

Jan 1, 1992

By Donald P. Spitzer, Peter V. Avotins

The flow properties of thickener underflow slurries can be characterized by their rheological parameters. Most of these slurries exhibit Bingham plastic behavior, characterized by a yield stress, to, and a Bingham viscosity, nB. Red mud is generated as a leach residue in the Bayer process. The use of new Bayer process flocculants which contain hydroxamate functional groups leads to muds which are qua1itatively considerably more fluid than muds generated with conventional polyacrylates or acrylatefamide copolymers. A variety of rheological tests confirm lower yield stresses and less extended floc structures with the new flocculants, at the same solids levels. Conversely, under given viscosity restraints, the new polymers make it possible to operate at higher solids levels, which offers major benefits in processing red muds.

Jan 1, 1992

By David J. Dunn

Materials related problems at mines can be big ones - like a newly completed 1 -m (3.5ft) water pipeline burst during initial filling, grinding ball consumption at double the typical norms on startup of a new semiautogenous grinding (SAG) mill circuit or 30 open-pit haul trucks in the shop for new bed liners after less than a year’s service. Materials engineering provides solutions to these kinds of equipment problems by selecting good materials and designs, by trouble-shooting service failures and by maintaining high quality in vendor-furnished materials and components. Materials with good properties, correctly made and fabricated, correctly installed in mining and processing equipment, produce ore and final products reliably and efficiently. Materials engineering, applied during design phases, specification writing, and receipt and installation of materials, ensures that equipment will have the best possible shot at performing up to expectations. Good calls on materials properties - specifying state-of-art materials produced by competent manufacturers - help mine managers to reduce downtime and mining and processing costs. Materials that are improperly made or specified can make a mining operation less efficient or, possibly, uneconomical.

Jan 1, 1992

By E. Marques Coelho

Cationic flotation of quartz is currently utilized in the concentration of iron ores and the cleaning of phosphate concentrates. The present work deals with depression of quartz in the presence of aluminum aqueous species during cationic flotation. It was established that aluminum species depress the flotation of quartz with an amine, especially under neutral and slightly alkaline conditions. With an amine as the collector, studies of the adsorption (abstraction) of Al species on quartz surfaces, as a function of pH, correlated well with the depression of this mineral. The presence of Al species also enhanced the depressant action of corn starch on quartz. In addition, the sodium salt of ethylenediaminotetraacetic (EDTA) was found to be an effective complexing agent to suppress the depression caused by aluminum ions.

Jan 1, 1992

By T. R. Raponi, D. Barnes

The Williams Mine mines and mills 6000 t/d (6600 stp’d) of gold ore using SAG/ball milling, leaching and CIP, electrowinning and refining. Electrowinning, high-pressure cathode washing, filtering, retorting and refining are based around the use of knitted stainless steel mesh cathodes. Their primary advantage over conventional steel wool cathodes is that electrowon gold can be washed off and the cathode can then be reused. Typically, the knitted cathodes have a useful life of up to 15 months. Gold production of up to15 t/month (50,000 oz/month) is easily processed with this system. Presented is a description of this operation, including a review of the equipment and performance data.

Jan 1, 1992

By G. A. Rowell, T. M. Barczak, J. C. Zelanko

The US Bureau of Mines conducted a multifaceted geomechanics research project at a bump-prone longwall coal mine in eastern Kentucky. This mine presented a unique opportunity to study coal mine bumps because the problem appeared to be confined to areas beneath a sandstone channel of limited areal extent. The Bureau&apos;s research plan sought to exploit the uniqueness of the site by monitoring strata behavior and longwall support reactions as the longwall face approached and passed beneath a sandstone channel. The study incorporated static pillar stress and strata deformation measurements, shield support leg pressure measurements and microseismic monitoring, as well as geologic mapping and the collection of observational data. Data collection was underway when a major coal bump occurred on the longwall face at the mine. Pillar behavior (load and deformation), shield loading and microseismic activity were monitored prior to, during and after the bump. Observations in the tailgate indicated that these pillars were failing prior to and following the face bump. Shield load data, evaluated in an effort to identify trends that could be used to forecast coal bumps, appear to provide a measure of the effectiveness of destressing operations conducted on the face (e.g. shot firing). Analyses of microseismic data revealed anomalous values associated with microseismic "energy" prior to the face bump. In addition, microseismic source-location data and underground observations provided some insight as to the sequence of pillar and face bumps.

Jan 1, 1992

By D. Park, V. Gall

The three-dimensional finite element technique combined with a progressive failure approach were used to simulate stress distributions in a complete mine section that occur in response to a longwall mining operation. Due to the availability of a Cray supercomputer, a large-scale, three-dimensional, finite-element model was developed for the analysis. The Hoek-Brown failure criterion, which describes a realistic behavior of rock masses, was used for the simulation of progressive failure. A comparison of calculated and monitored stresses in the mine has shown that the model gives a good representation of stresses in the mine structure.

Jan 1, 1992