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By C. A. Garcia

The solvent extraction of gold cyanide from alkaline cyanide solutions with monosubstituted guanidines, bis disubstituted guanidines and a tetrasubstituted guanidine was investigated. The guanidine functional group is protonated in alkaline solution and the guanidinium cation is stabilized so that the aurocyanide anion can be extracted even at -pH 12 if an appropriate carrier is used. Typical aprotic carriers including both aliphatic and aromatic solvents limit gold extraction by guanidines to pH 10; whereas the presence of an alcohol extends gold extraction to pH 12. UV spectroscopy suggests that the alcohol facilitates protonation of the guanidines, stabilizes the guanidinium cation, and facilitates gold extraction at high pH.

Jan 1, 1993

By James A. Clum

The shift to lower grade iron ores, e.g., magnetic taconites, resulted in a shift towards agglomeration practices which could effectively deal with the fine particle sizes generated in the liberation and concentration processes. If the iron bearing particles are not extremely fine, e.g., -1/2 in + 100 mesh, sintering is an adequate means of agglomeration.(1) For the more dispersed ores which result in fine concentrates (more than 80%,-325 mesh), the fine particles must be agglomerated by mechanical means before final hardening, e.g., pelletizing.(1) In the pelletizing process, the essentially mechanical step of balling is extremely critical since the strength of the pre-fired pellet determines the firing conditions. The ability of the proper amount of moisture to hold together a ball of the very fine ore concentrate particles has long been recognized. It is a charac¬teristic of the reaction at the interface between the ionic solid of the ore concentrate and the polar water phase which overlays the solids. The strength in such moisture laden balls, the green strength, is a strong function of the water content (Figure 1) and thus deteriorates rapidly for either a small excess or a small deficiency of moisture. For purposes of commercial practice, the control of green ball handling properties by accurate control of ball moisture is too demanding. Moreover, as the ball is heated towards its hardening tempera¬ture, e.g., 1300'C, there is a substantial drying reaction which would lead to such a low dry strength of the ball that it would not support its own weight much less the weight of other balls in a firing furnace.

Jan 1, 1976

By R. A. Hevia

Florida Power and Light is the fifth largest investor-owned electric utility in the country. It has a service territory that covers 35 counties, or 28,000 square miles, 2.5 million customers, and serves 5.6 million people. The total installed capacity is 13,470 MW, generated by four nuclear units, 36 oil and/or gas fired units, and 48 gas turbine units. Traditionally, FPL has been an oil-based utility. In 1979, this dependency on oil became obvious when 42 million barrels of oil were burned during the year. At that time, it was also projected that, based on the current estimates of customer growth and available generation capacity through 1990, FPL's residual fuel oil consumption would increase from the 1979 level of 42 million barrels (6.7 million m3) per year to approximately 55 million barrels (8.7 million m3) per year by the mid-1990's. Concern over this was further aggravated by the fact that it was difficult to estimate both the price and quantity of fuel oil that would be available over the next decade since changes in the world market, decisions by oil producers and refiners, and international political developments would all affect the availability of oil. Also, at that time, the price of residual fuel oil had increased drastically, and there was no reason to think that these prices would soon stabilize. Thus, oil back-out became a primary objective of FPL and since then, FPL has been actively investigating ways to decrease fuel oil consumption.

Jan 1, 1985

By P. Munjal

"Usage of Supercritical CO2 in place of high pressure freshwater has proven to be a potential breakthrough in the technique of fracturing. Tapping of carbon footprints from feasible sources like industries can be used to manufacture Supercritical CO2 required for fracking. Supercritical CO2, being less viscous than water, creates complex and coherent micro-fractures which can connect many more natural fractures greatly, increasing maximally the fractures’ conductivity leading to an increment in production. The better clean-up property of Supercritical CO2 provides auxiliary benefits of immediate evaluation of fracture zones, usage of an optimized quantity of mesh proppant and elimination of the need of swabbing. Also, Coal has a stronger affinity for CO2 than for CH4. When CO2 is present, CH4 on coal is replaced by CO2. This also ensures rigorous recovery of gas from the coal beds. Use of Supercritical CO2 will obliterate many problems as the CO2 used for fracturing is either sequestered beneath the crust or is recovered at the surface and reused. Therefore, injecting CO2 into coalbeds achieves not only enhanced CBM recovery, but also greenhouse sequestration underground. INTRODUCTION Coalbed Methane At various times in the geologic past, earth had dense forests in low-lying wetland areas. Due to natural processes such as flooding, these forests were buried underneath the soil. As more and more soil deposited over them, these dead plant remains were compressed. As the process continued the plant matter was protected from biodegradation and oxidation, usually by mud or acidic water. Under high pressure and high temperature, dead vegetation was slowly converted to coal. The omnibus process of formation of coal, thus, comprises of conversion of dead plant matter into peat, followed by its conversion to lignite, then sub-bituminous coal, after that bituminous coal, and lastly anthracite. This process of enrichment of coal as it is progressively forced deeper into an ambience with higher temperature and pressure involves biological and geological processes that take place over a long period and is called coalification. During coalification, large amounts of methane-rich gas are generated and stored within the coal on internal surfaces; hence comes coalbed methane. Coalbed methane (CBM), a gas formed as part of the geological processes that are responsible for the generation of coal, is adsorbed into the solid matrix of the coal during its formation process. Coalbed methane is distinct from a typical sandstone or other conventional gas reservoirs, as the methane is adsorbed and not absorbed. The methane is in a near-liquid state, lining the inside of pores within the coal. The open fractures in the coal that result from the liberation of volatile materials (and subsequent contraction due to the liberation) from the coal due to the high temperature and pressure conditions encountered, called cleats, may also contain free gas or can be saturated with water."

Jan 1, 2015

By Robert Stefanko

The concept of disposing of liquid industrial wastes by deep-well injection is not a new one. Brines associated with crude oil long have been disposed of in this manner, with the additional benefit of aiding secondary oil recovery. More recently, with the expansion of nuclear energy, the lethal, highly radioactive wastes which are by-products of the fission process have created severe disposal problems. During the past ten years, a variety of industries have resorted to subsurface disposal, some of the details of which are given elsewhere (1,2). The list reveals wide variations in injection rate, pumping pressure, cost, and waste disposition. Included are successful installations in Western Pennsylvania.

Jan 1, 1969

By A. B. Fly

This paper presents the equipment and techniques developed to mine subsurface mineral deposits through 16 inch bore holes entirely by hydraulic methods. Use of this equipment for excavating large cavities in oil and water well producing zones is discussed. Results of surface experiments using high pressure jet streams of water to determine the cutting rates of materials are outlined. Various basic shapes of subsurface excavations that can be mined with the equipment are illustrated and discussed. An example of the cost of mining by this method is presented. Problems encountered in the field operations led to the development of a new explosion type slurry pumping system and related slurry handling equipment.

Jan 1, 1969

By Giovanni Osellame, Jean Habimana

"The Montreal Metro Blue Line Extension Project is part of a metropolitan Program that was launched in 2009 by the Transportation Ministry of Quebec to add additional extensions to existing metro lines in the cities of Montreal, Longueil and Laval with the intention to meet current demand and future growth within the Montreal agglomeration. Specifically the Blue Line Extension Project will add five underground stations to the East of the Montreal. The paper addresses the preparation and the implementation of a three-step geotechnical and geo-environmental investigation program and preliminary design considerations such as the selection of a preferred horizontal and vertical alignment, the selection of construction methods based on previous local experience and current industry trends, as well as preliminary sizing of underground infrastructures. PROJECT BACKGROUND An agreement between the three mayors of the Montreal Metropolitan City agglomeration, namely, Montreal, Longueil and Laval prompted the Government of the Province of Quebec to create a project office to oversee the studies of extending the existing metro network. The last extension of the existing metro network was completed in 2008 with the Laval extension, which consisted of adding three stations from the existing Orange line. The current extension Program consists of three different extensions, namely extending the Orange Line to Laval and finishing the loop, extending the Blue Line to the East of Montreal by adding five stations, and adding five stations on the Southshore of the St-Lawrence River for the Yellow Line extension. The extension program also requires the construction of an underground storage and maintenance garage located to the north-west of the existing Cote-Vertu station on the Orange line. Figure 1 shows the overall extension program with the existing network."

Jan 1, 2016

By Eugene A. Hickok

Seismic surveys utilizing the MD-1 have been performed by Geophysical Specialties Company since 1957 in many parts of the, U. S. and Canada and in several foreign countries. These surveys have proven the refraction seismic technique to be applicable to a wide variety of engineering problems. The best known applications of the instrument have been in the, construction industry, where it is used for the delineation of material and mineral deposits and for bedrock depth determinations. Fast on-the-site depth determinations give reliable subsurface' information even in boulder-strewn soils. A widely publicized use of the MD-1 is to make rippability studies in which the instrument is used to determine the seismic velocity of the materials to be excavated. By use of special tables which correlate rippability with seismic velocities, such as those prepared by the Caterpillar Tractor Company using the MD-1, the rippability of-a specific material may be determined.

Jan 1, 1962

By David E. Thompson, Wesley E. Stimpson

The Massachusetts Bay Transportation Authority (MBTA) Red Line Extension Northwest is currently in the early stages of construction. The 3.1 mile extension of the Red Line from the existing Harvard Square Station in Cambridge, Massachusetts to Alewife Brook Parkway in Cambridge, Massachusetts will include a large, near surface hard rock, rapid transit station chamber at Porter Square in Cambridge (Figure 1). [ ]

Jan 1, 1979

By Gary S. Brierley, Ronald E. Romley, Alan L. Howard

The Price Road Drain Tunnel in Tempe, Arizona is part of the drainage system constructed in conjunction with the Outer Loop Highway in metropolitan Phoenix. The Outer Loop Project is a part of a much larger expressway system that includes other large drainage tunnels such as the Papago Freeway Drain Tunnels. Large diameter downhole inspection borings were utilized to obtain subsurface data for the design of these tunnels. Subsurface data obtained from the large diameter borings resulted in the development of empirical parameters that were successfully incorporated into the Geotechnical Design Summary Report and which satisfactorily predicted ground behavior, formed the basis for improved geotechnical design criteria, and facilitated the cost effective assessment of third party risk. The purpose of this paper is to describe the subsurface exploration program performed for this project and to explain the methods used to evaluate underground construction procedures.

Jan 1, 1991

By David J. Hatem

Public-private partnerships (PPP) are gaining in popularity at the federal, state and local levels as the public sector seeks private capital to finance infrastructure and other projects that traditionally have been funded with public funds. In general, a PPP involves a development agreement between a public owner and a private sector concessionaire. Under the development agreement, the concessionaire is responsible for financing, designing, constructing and typically operating and maintaining the completed project for a concession period (often multi-decades in duration). The concessionaire typically enters into an agreement ? the design-build agreement ? with a design-builder to design and construct the project. The concessionaire may secure financing from banks, investors or from a combination of these and other sources (collectively the financier). While the PPP experience in the United States has been modest to date, an increasing number of projects involving tunneling or other significant subsurface work are already being delivered in the PPP mode. Public owners have significant options to address risk allocation for subsurface conditions on PPP projects. The same sound and fundamental principles of fairness in risk allocation that apply in other major subsurface projects should be applied and adopted in the PPP context

Mar 1, 2014

By James C. Fowler

The use of ground-probing radar as a reflection mapping tool has expanded greatly in the last few years. This tool can now be used to produce near surface information which is very useful to geotechnical engineers. Using the lightweight field equipment now available, it is possible to use the radar within mines and tunnels to obtain information which may impact the safety and production of these operations.

Jan 1, 1979

By Edward Thomas

Yucca Mountain Overview The U.S. Department of Energy?s Yucca Mountain Project is a geologic repository project designed to receive, handle, package, transport, and emplace spent nuclear fuel and high level radioactive waste. The planned repository would be located in Yucca Mountain on the western edge of the Nevada Test Site, about 90 miles northwest of Las Vegas, Nevada, and would include both surface and subsurface areas. Yucca Mountain rock formations consist of successive layers of volcanic rocks (called tuffs) approximately 14 to 11.5 million years old, formed by eruptions of volcanic calderas to the north. With the volcanic rock the potential for methane emission is not an issue and the subsurface repository is a non-gassy (methane) classification. This paper will provide a summary of the development ventilation system design that provides fresh air for subsurface construction activities, and the emplacement ventilation system design that removes heat generated by the waste packages. The subsurface layout, illustrated in Figure 1, contains 108 emplacement drifts, one Performance Confirmation(PC) observation drift, nine intake/exhaust shafts, and three access ramps. The existing Yucca Mountain facilities, shown in bold lines in Figure 1, include a 7.8 km long, 7.62 m (25 ft) diameter U shaped tunnel that is formed by the North and South Ramps at both ends of the Exploratory Studies Facility (ESF) drift and a 1.5 km long, 5.0 m (16.4 ft) diameter Enhanced Characterization of the Repository Block drift (ECRB) that were constructed from 1994 through 1998. These drifts were used for site characterization activities and have been incorporated into the subsurface repository configuration. The unexcavated perimeter access main and exhaust main drifts are typically 7.62 m (25 ft) diameter TBM excavations and the emplacement drifts are 5.5 m (18 ft) diameter TBM excavations. The turnouts leading into the emplacement drifts are to be excavated by either mechanical, or drill and blast methods and serve as the launch chambers for the emplacement drift TBM excavations.

By Malte J. M Gurgel

Subsurface spatial planning is becoming increasingly important in view of competing underground applications. This development is influenced by global agreements to reduce greenhouse gas emissions. Therefore, precise knowledge of the underground space is a basic prerequisite for future applications. The three-dimensional registration and reliable georeferencing of underground infrastructures can establish a holistic geodata basis for such tasks. Those tasks are discussed both for the development of energy projects such as deep geothermal energy as well as for storage applications. Research on geothermal energy has been carried out at RWTH Aachen University as part of the SuperC project in a license field in the Aachen area since 2001. Recently, this research has been extended to include monitoring aspects in the overlapping GEObservatorium Aachen field. The documentation and visualization of underground activities using photogrammetric methods like Structure from Motion is discussed based on recent research in sites for the final disposal of radioactive waste. Finally, both applications provide an outlook on supporting underground projects by using high-resolution geodata.

Feb 1, 2025

By J. N. Albright

Both microgravimetry and crosshole seismic tomography are means by which subsurface collapse and rock failure may be observed. We show results of calculations that predict changes in gravity and gravity gradient that result from void migration, bulking, and hydrology disruption due to room and pillar mining. Crosshole seismic tomography also holds promise for detecting and mapping changes in structure during subsidence. Commercially avail- able logging tools, advances in theory, and recent field results strongly suggest tomographic surveys are now possible. Subsidence phenomena which may be located are faulting, joint separation, bed parting, water table changes, and formation outgassing.

Jan 1, 1982

By S. Peng, Yi Luo

Subsurface strata movements and deformations associated with underground longwall mining activities could cause certain influences to subsurface structures and water bodies. Methods have been developed for the prediction of final and dynamic subsurface movements and deformations induced by underground longwall mining operations in the eastern coal fields. Two new types of strata deformation, vertical and total strains, which could be useful in the field of subsidence research in assessing subsidence influences to the subsurface structures and water bodies, have been introduced. Using the subsurface subsidence prediction model, three types of subsidence influences to surface and subsurface hydrological systems have been identified. Attempts have been made to quantify the two types of subsidence influences that could cause water loss and could lower water levels in aquifers.

Jan 1, 2010

By J. Kretschmann

?We have constructed a world in which the potential for high-tech catastrophe is embedded in the fabric of day-to-day life.? (Malcolm Gladwell) The mining industry is a crucial provider for virtually every person?s needs and thus indispensable. Yet, mining is a complex and risky business: plenty of high risk factors can occur and severely affect nature and the miner?s life and health. Especially for small and medium enterprises (SME) risks may also threaten the economic existence of the company. The responsible and sustainable management of a company should thus be based upon the systematic finding and handling of risks or briefly upon an efficient risk management system. Why do we need risk management? Because nobody is perfect and we make mistakes in the normal course of operation.

Jan 1, 2011

By J. C. Haptonstall

Stoping methods at the Homestake Gold Mine through 1978 had been traditional overhand cut-and-fill, shrinkage or square set. High costs, low-productivity and safety concerns prompted the mine to search for and adopt a "bulk mining" technique as a primary stoping method. Blasthole stoping had been successful but it is very development intensive, and was not suitable for the mine's accelerated mining program. Vertical Crater Retreat stoping was selected, and today accounts for over 50% of ore production. Case histories representing both the successes and failures of VCR stoping in the mine are discussed.

Jan 1, 1986

By Clay Haynes, Tim Pearia, Robert Robinson, Judy Cochran

A 1.89 km-long, 4.5 m-I.D. tunnel was successfully constructed through saturated hard clay, and highly abrasive dense sand and gravel, with groundwater heads ranging from 10 to 20 m. In order to address these conditions, a Lovat earth pressure balance TBM was used, with soil conditioning by foam, water and various polymers. Support was provided by a single-pass segmented concrete lining. Groundwater inflows of 400to 1,600 lpm at times created challenges for changing cutting tools. Surface settlements were generally less than measurement thresholds, except under very low cover at startup. This project provides a pivotal case study of the successful application of EPBM technology in saturated, abrasive glacial soils and the successful application of soil conditioners.

Jan 1, 2003

By D. Bour, C. Nyikos, R. Curtice

Fire in a coal mine can be disastrous on many levels. In most cases, when a fire is detected, mining operations cease and all personnel are evacuated. Underground coal-mine fires are difficult to extinguish, can burn for a long time, and often result in an extended period of lost production. In a worst-case scenario, the mine is permanently sealed and abandoned, resulting in lost jobs, lost natural resources, and possible devastation of the local economy. In some cases, seals placed within the mine to isolate the fire could eliminate the need for sealing the entire mine and the subsequent extended delay in returning the mine to full operation. Previous attempts to place remote seals to extinguish mine fires in active mines have been largely unsuccessful. The West Elk mine experienced an underground fire in early 2000. The fire could not be accessed and extinguished from the active mine workings. A method of constructing seals remotely by drilling boreholes into the affected area was needed to help isolate and extinguish the fire. This paper describes the process by which remote seals were constructed that successfully isolated the fire and provided a means of extinguishing the fire by flooding the area with water. The period of lost production in the West Elk mine was considerably shorter than is typical in similar situations.

Jan 1, 2002