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By Chris Castle

The Chatham Rise is a submarine topographic feature lying off the east coast of New Zealand between the South Island and the Chatham Islands and within New Zealand?s jurisdiction. The Chatham Rise hosts economically significant deposits of rock phosphate and other potentially valuable minerals. The deposits comprise nodules lying on, or just below the surface of the seabed in shallow waters. Rock phosphate is an essential ingredient of fertilizer and can be applied directly to pasture. There is a realistic opportunity the phosphate deposits could supply New Zealand?s agricultural requirements for an estimated 30-year period at current rates of consumption.

Jan 1, 2011

By Steven D. Scott

The source of ore metals for base and precious metal volcanogenic massive sulfide (vms) deposits has been debated for decades. Metals can be obtained from high-temperature sea water-rock reactions in subseafloor circulatory hydrothermal systems, or provided by the magmatic fluids that are degassed from magma. The magmatic signatures are largely erased in the hydrothermal system by the overwhelming, long-term circulation of seawater. Melt inclusions in phenocrysts (plagioclase, olivine, pyroxene) of volcanic rocks provide an effective means of understanding the potential for a magmatic contribution to the ore-forming fluids. We present results of a melt inclusion study on the volcanic rocks that host active seafloor hydrothermal fields in the eastern Manus immature back-arc pull-apart basin of Papua New Guinea and an Ordovician-age back arc in New Brunswick, Canada that hosts the ?giant? (330 mmt) Brunswick #12 vms ore deposit. A fluid phase is typically observed in cavities within melt inclusions, indicating that the magma was saturated with volatiles prior to its eruption. The fluid is CO2-dominated with lesser H2O and CH4 in melt inclusions of mafic volcanics and is H2O-rich in felsic volcanics. Tiny crystals and amorphous precipitates (recrystallized at Brunswick #12) of Fe, Ni, Zn, Cu and Mn chlorides, sulfides and oxides coat the walls of the vapor cavities. The crystals include magnetite, magnesite, calcite, anhydrite, gypsum, barite, pyrite, chalcopyrite, halite, silicates and apatite. At Manus, the compositions of the precipitates on the bubble walls of melt inclusions are similar to those found in the vesicles in the matrix glass of the same sample. The ore metals in the volatile phases changed from Ni+Zn+Cu+Fe ? Cu+Zn+Fe ?Fe+Zn (+Pb?) as the magma evolved from basalt, basaltic andesite ? andesite, dacite ? rhyodacite, rhyolite. Glass of the melt inclusions compared to that of the matrix of the rocks from Manus have significantly higher concentrations of H2O (av. 1.64 vs 0.7wt%), Cl (av. 2500 vs1300 ppm) and S (av. 900 vs 100 ppm) suggesting that these volatiles were extensively exsolved from the magma. A minimum of 1.0 to 1.7wt% of magmatic volatiles is estimated to have been degassed before and during the eruptions. The focused discharge of a magmatic fluid as a result of pre-eruptive degassing could be responsible for the metals in the sulfide deposits on the seafloor. If 1 km3 of magma were emplaced in a shallow chamber, then the associated magmatic fluid would be 35.1 million tonnes. If this fluid contained 2.3 wt% Zn and 7.2 wt% Cu (Yang and Scott, 1996, Nature), a total of 0.8 million tonnes of Zn and 2.5 million tonnes of Cu would be to the hydrothermal system.

Jan 1, 2005

By Allan Spencer

In March 2007, Nautilus Minerals Inc. announced that they had commenced their 2007 exploration and development program with the mobilization of the Research Vessel Wave Mercury and the Survey Vessel Aquila onsite Papua New Guinea.

By Tobias Hens, Andrew Frierdich, Barbara Etschmann, Joël Brugger, Barrie Bolton

"Advancing our knowledge about trace metal distribution and abundance provides insight into formation, alteration, and trace element enrichment processes of ferromanganese nodules and crusts. A fundamental understanding of these mechanisms, in turn, has implications for the selective recovery of critical metals and the development of sustainable hydrometallurgical techniques. Synchrotron-based X-ray Fluorescence (SXRF) is a powerful, state-of-the-art analytical tool that can examine geochemical features of Fe-Mn nodules and crusts, such as abundance and distribution of trace elements, in an integrated and efficient manner. By correlating trace element composition and Mn oxidation states in these highly complex samples, it can be determined whether these parameters are related to the Mn oxide mineralogy (vacancy content of crystal lattice) and chemistry.In this study, eleven Fe-Mn nodule and crust samples from three circum-Australian locations – the South Tasman Rise, Lord Howe Rise, and Coral Sea – were analyzed at the Australian Synchrotron, Victoria, Australia. Micrometer-scale spatial resolution of geochemical features, such as concentric growth structures and element distribution, was achieved with high sensitivity (Fig. 1). For instance, Ni could be detected at 10's of ppm to 1 wt% levels. Information on other redox-sensitive trace elements, which are present at 10-1000 ppm levels (e.g., Cu, Co, Ti), were gained by means of fully quantitative elemental composition maps."

Jan 1, 2017

By David A. Larson

The future exploitation of crust deposits will require a dependable characterization system. The U.S. Department of the Interior, Bureau of Mines (Bureau) initiated research to develop a new sampling dredge by conducting a series of cutting and physical property tests on previously collected cobalt-rich manganese crust and substrate samples. Using the engineering parameters derived from these tests, a large, heavy dredge was designed and tested. This heavy dredge was capable of fragmenting and collecting in situ crust, but it created handling problems for the research vessel, thus an aggressive cutting, light-weight dredge was conceived and fabricated. The light-weight dredge is capable of fragmenting and collecting crust and some talus. This dredge can be used on flat or rough seabed terrains. It can be easily retrieved from hang ups and reset to sample again.

Jan 1, 1991

By Carl H. Hobbs

The needs of the on-going basic maintenance operations and proposed enhancement and hurricane protection projects in the City of Virginia Beach exceed the capability land-slide sources of sand. Through the past several years our studies have concentrated on locating and defining suitable quantities of sand appropriate for use on the area's beaches and assessing some of the consequences of dredging in shallow offshore areas. By providing information concerning the geological setting of sand resources, the local wave climate, and benthic infauna, the overall research project has strengthened the knowledge and understanding of several facets of Virginia's inner continental shelf. We have identified three distinct settings for deposits of beach-quality sand, two of which (filled channels and surficial shoals) are distinguishable in relatively unprocessed sub-bottom profiles and cores. The third, a sand facies within a larger stratum, is discernable only with a suite of cores. Sandbridge Shoal, about 5 km offshore of the resort and residential community of Sandbridge appears to contain a substantial quantity of sand that could be exploited with comparatively few problems. It already is designated as the source of material for use in a shoreline protection protect for a federal facility. Fluvial(?) fill of a late Pleistocene channel lust offshore of the main, commercial, resort area may offer a proximal alternative to existing and proposed resources. Ongoing work to describe the local wave climate and the possible impacts of anthropogenic alterations of the bottom topography on wave transformation and studies of the biological community as it might be affected by dredging will help fill-out our series of studies. Prior to utilization of the resource additional work is needed to provide better definition of the limits and magnitude of the sand bodies. Finally decisions concerning the use of specific resources will have to include physical, biological, economic, technical, and social considerations.

Jan 1, 1996

By Michael J. Cruickshank

The State of Hawaii has expressed concern over deterioration of the tourist beaches at Waikiki, which are becoming seriously depleted of sand. In this report the options for acquisition, transportation and placement .of sand on the beach are examined with respect to feasibility and cost. Ten sources of sand were compared, including commercial, from Australia, Maui, and Barbers Point (3), deposits offshore of the Reef Runway (3), offshore of Waikiki (3), and offshore of Molokai from the Penguin Bank (1).

Jan 1, 1991

By Charles W. Finkl

Coastal and marine aggregate (sand and gravel) mining on US continental shelves is a major activity that supplies industrial and commercial demands for these raw materials. Because Pacific, Atlantic, and Gulf coasts contain significant shoreline segments that are in a critical state of erosion, sand-gravel and mixed sediment (sands with a high percentage of silt-plus-clay) deposits are mined in efforts to mitigate land loss. Sandy shores, and to a limited extent gravel coasts, erode by shoreline retreat due to relative sea-level rise and sediment starvation in littoral drift patterns. Mostly gravel shores occur in high latitudes and shorelines often advance seaward due to isostatic rebound following the LGM (Last Glacial Maximum 18,000 YBP). Sandy and fine-grained shores occurring in middle and low latitudes of the conterminous United States are problem coasts that require beach renourishment and reconstruction of barrier islands. Muddy coasts of the Mississippi Delta region are especially problematic because some islands are literally disappearing in response to subsidence. Replacement of sediments lost to the littoral drift system or returned to sedimentary sinks by drowning is thus a critical endeavor that involves annually dredging hundreds of millions of cubic meters of sediments from the continental shelf area. The types of shelf sediments that are amenable to marine mining techniques, their occurrence, and means of detection are highlighted in this paper. Minable Sediments on the Continental Shelf Wide varieties of sedimentary bodies that occur on the continental shelf are amenable to mining for beach renourishment and barrier island (beach-dune-marsh system) reconstruction. Relict terrestrial deposits make up a small but important proportion of shelf sediments that were deposited on coastal plains, now drowned by the post-glacial sea-level rise to form continental shelves. Examples of these deposits include drowned moraines, outwash plains, eskers, and kettles along the northern Atlantic coast in addition to siliciclastics along middle latitude Pacific, Atlantic, and Gulf coasts. Special cases include carbonate sequences along tropical costs of Florida and the muddy coasts of deltas, mostly in Louisiana. Specific types of minable deposits thus include shoreface attached sand sheets, dunes, and ridges in addition to offshore inter-reefal sands (between coral reefs in the Florida Reef Tract), bank deposits, and sand waves (ridges) that extend into US territorial waters. Nearshore siliciclastics include ebb-tidal deltas and bars. Drowned river valleys occur along all three US coasts and can be exploited for their fluvial sands if the covering mud sheets are thin.

Jan 1, 2005

By Derek V. Ellis

A stepwise implementation of seven criteria for screening the physical, chemical and environmental suitability of submarine tailing disposal (STD) at coastal mines is presented. It is expected that similar criteria would be relevant to future deepwater mining. A reconnaissance level study of four preliminary criteria: mine location; coastal bathymetry; feasible outfall locations; and potential for chemical contamination can support or eliminate the prospects for STD. If supportive, detailed, and far more time-consuming hence costly surveys of: environmental background information including oceanography and waste discharge characteristics; projected impacts on other resource uses plus regulatory and community concerns will be essential for environmental protection and to secure the necessary approvals. This review of STD systems on which the proposed screening criteria were based was undertaken by a Cooperative Agreement of the U.S. Bureau of Mines, Alaska Field Operations Center with the University of British Columbia.

Jan 1, 1994

By Dan Johnson

The discovery of rich alluvial diamond deposits on Namibia?s Skeleton Coast in 1908 began a period of intense exploration and mining off the coastal sand; and shallow surf zones. In the mid-60s a Texas entrepreneur, Sam Rollins took the search to the seafloor. The inhospitable conditions encountered made the early going difficult. After a slow start, the past 10 years have seen much progress in geologist?s understanding of the deposition mechanics and the use of sophisticated geo-physical and sampling techniques to aid in the discovery of economic deposits. Diamondfields, in a joint venture with BHP and Benguela Concessions, began an exploration program in 1994 for sea-bed diamonds off the Port of Luderitz in Namibia. This program has progressed to a mine development program with the potential of creating a 500,000 carat per year operation. The mining technologies being considered include state-of-the-art, remotely operated sea-bed crawlers and high volume dredges feeding to semi-mobile processing platforms. The company's objective is to use the best proven technology to create an environmentally responsible operation with the lowest fixed operating costs and the longest and safest weather operating window of any offshore operator working Africa's diamond coast.

Jan 1, 1998

By Tao Chunhui

The seabed deposits type and distribution are very complex at the hydrothermal field. In this paper, we provided an approach to study the seabed deposits classification at the Precious Stone Mountain hydrothermal field (PSMHF) using MultiBeam sonar data . The PSMHF was found in the Galapogas microplate at the Leg 3 of the Chinese COMRA 21st Cruise. Using this approach, the seabed deposits at the PSMHF are mainly classified into three types, which are rock, breccia and sediment, respectively. We can find the distribution of the three types of seabed deposits according to the sonar backscatter data. The rocks are mostly distributed around the hydrothermal vent. The breccia are located at the foot of the vent. Most sediments are distributed at the southwest to the vent due to bottom current. Combining with seabed video, TV-Grab sample and the backscatter data, we draw the map of the seabed deposits distribution at the PSMHF.

Sep 14, 2011

By Henrik Schiellerup, Irene Zananiri, Johan Nyberg, Thomas Kuhn, Luis Somoza, Teresa Medialdea, Maria Judge, Pedro Ferreira, Gerry Stanley, Javier González

The GeoERA Co-Fund action is a joint contribution of 48 national and regional Geological Survey Organisations from 33 European countries “Establishing the European Geological Surveys Research Area to deliver a Geological Service for Europe (GeoERA)”. This is an ERA-NET action under Horizon 2020. The aim of GeoERA is to fund transnational projects contributing to the best use and management of the subsurface, addressing the following four themes: Geo Energy, Ground Water, Raw Materials and Information Platform. The European Commission recognises the significance of raw materials through its Raw Materials Initiative (RMI), the European Innovation Platform on Raw Materials (EIP-RM) and Horizon 2020 funding, specifically through Societal Challenge 5 – Climate Action, Environment, Resource Efficiency and Raw Materials. The GeoERA Raw Materials Theme will contribute to research and innovative developments for minerals inventory, minerals yearbook, exploration, mapping, modelling, metallogeny and critical raw materials in the pan-European framework including the sea. A major element in Europe’s long term economic strategy is to ensure security of supply for strategic and critical metals as part of the Blue Growth Strategy developing sectors that have a high potential for sustainable jobs and growth as seabed mining. The project MINDeSEA results of the collaboration between eight GeoERA Partners and four Non-funded Organizations at various points of common interest for exploration and investigation on seafloor mineral deposits. The Geological Surveys of Spain, Germany, Greece, Ireland, Norway, Portugal, Sweden and Ukraine are organisations with responsibility for coastal, marine geological investigation and mineral resources studies and mapping in their respective countries. The Non-funded participants: the Instituto Português do Mar e da Atmosfera; the United States Geological Survey; the All-Russia Scientific Research Institute for Geology and Mineral Resources of the Ocean; and the Geosciences Institute, host important databases, they have an international reputation for excellence in both science and technology, and are internationally-known experts on seafloor mineralisation and hydrothermal systems. This project addresses an integrative metallogenetic study of principal types of seabed mineral resources (hydrothermal sulfides, ferromanganese crusts, phosphorites, marine placers and polymetallic nodules) in the European Seas. The work program includes all the regional seas around Europe comprising the Atlantic Ocean, the Mediterranean Sea, the Baltic Sea and the Black Sea (Fig. 1). The MINDeSEA working group has both knowledge of and expertise in such types of mineralisation, providing exploration results, sample repositories and databases to produce innovative contributions. The importance of submarine mineralisation systems is related to the abundance and exploitation-potential of

Jan 1, 2018

By Delphine Pierre, Jean-Marie Augustin, Anne-Sophie Alix, Charline Guérin, Cecile Cathalot, Yves Fouquet, Arnaud Gaillot, Ewan Pelleter, Carla Scalabrin, Florian Besson

With the world’s growing demand for metals, seafloor massive sulfides (SMS) deposits are now seen as a possible mineral resource that could contributes to secure metal supply for human needs. SMS deposits are characterized by high concentrations of base metals and at some place high contents of precious and rare metals. Since 1977 and the discovery of the first high temperature (HT) hydrothermal vent and its sulfide mineralization and high biodiversity, more than 300 sites are known today. If the exploration strategy for detection of active hydrothermal sites is now robust, their associated mineralization will not (and must not) constitute a potential target for deep-sea mining due to environmental concerns and technical limitations. Recent studies on SMS deposits are rather focused on extinct and buried mineralized sites characterized by a lower biomass. Several geophysical techniques to explore and detect extinct SMS (eSMS) and buried SMS (bSMS) have been developed (e.g. Kawada and Kasaya, 2017; Szitkar et al., 2017, 2014) using different approaches (e.g. regional or local scale; ship-based or using underwater vehicles) with several degrees of success or limitation. Here we present results from acoustic surveys performed on the TAG hydrothermal district during the BICOSE (2014) and LEVE-SMF (2016) cruises and direct observation provided by HOV (Nautile) dives carried out during HERMINE cruise (2017). Acoustic data were acquired using two different multibeam echosounders (MBES): the hull-mounted Kongsberg EM122 (12 kHz, R/V L’Atalante) and the ROV-mounted RESON SeaBat 7125 (400 kHz, ROV Victor) (Figure 1). After processing, acoustic seafloor backscatter data from both MBES provides complementary qualitative results in relation to the seafloor composition. The analysis of the seafloor backscatter data obtained by near-seafloor surveys with the high-resolution 400 kHz MBES shows a clear relationship between low backscatter strength values and areas covered with pelagic and hydrothermal sediments whereas high backscatter strength values are associated to pillow lavas and basaltic scree. Intermediate backscatter strength values are rather related to old and younger eSMS as well as to mineralization on TAG active mound.

Jan 1, 2018

By M. E. Williamson

In September 2005 Williamson & Associates, Inc. delivered the BMS2 remotely operated seafloor coring system to the Japan Oil, Gas & Minerals National Corporation (JOGMEC). During acceptance trials aboard the JOGMEC research vessel R/V Hakurei Maru No. 2 the BMS2 successfully recovered 7.44 m of rock core in 3377 m water at a site near the crest of a seamount about 500 nm SE of Japan. Hydrogenous ferromanganese oxide crust, basaltic lava, sandstone and volcanic sediments were sampled with near 100% core recovery. The BMS uses rotary rod coring tools to collect samples to a maximum depth of 30 m in water depths up to 6000 m. Depending on bottom type to be sampled, the BMS tool magazine can be loaded with various drilling tools including core barrels with different bit types, drill rod and bore hole casing. The drill has 9 video cameras, a suite of sensors and 60 hydraulic functions powering thrusters, telescoping legs, seawater pumps and all of the standard drilling controls. The BMS provides deep water investigations with the functionality of conventional diamond bit rod drilling currently the mainstay of exploration programs in land mining.

Jan 1, 2005

By V. Zaykov

The Urals massive sulfide deposits are concentrated in Silurian -Devonian fold belt extending for 1500 km with length from 50 to 150 km. By paleodynamic reconstmction it is established that they were formed in submarine parts of island arcs, in inter arc and back arc basins, marginal seas. When "black smokers" were found in rift zones of present oceans, problem searching their analogues in the Urals Paleozoic complexes was arisen. For solving this problem and demonstration of seafloor origin of massive sulfide many quarries and drill cores were carefully sketched and studied. Particular attention was given to correlation between ores and synchronous sedimentary rocks and fossils. Various laboratory methods were used for comparing sulfides from ore hills with ore-clastic sulfides.

Jan 1, 1993

By Peter A. Rona

The Mid-Atlantic Ridge in the central North Atlantic and the Gorda Ridge within the U.S. Exclusive Economic Zone off northern California and southern Oregon are yielding new discoveries of seafloor hydrothermal mineralization. The TAG hydrothermal field in the rift valley of the Mid-Atlantic Ridge near 26 degree N, 45 degree W has been a site of international collaborative research since the discovery there of extensive manganese deposits associated with low temperature hydrothermal activity in 1973 as part of the TAG (Trans-Atlantic Geotraverse Project). The first high-temperature hydrothermal activity, massive sulfide deposits and vent biota discovered in the Atlantic were found at the TAG hydrothermal field in 1985. Collaborative dive series with DSV ALVIN in 1990 and in 1991 with the two Russian MIR submersibles in the TAG field have found and sampled large inactive sulfide mounds in addition to the previously known active sulfide mound. The active sulfide mound on the floor of the rift valley is about 250 m in diameter and 40 m high with a concentric zonation of mineral types and flow regimes decreasing in temperature from 365 degree C black smokers at the center to white smokers and diffuse flow toward the margins. The recent dive series in coordination deep-towed instrument surveys have delineated a zone extending about 5 km along the lower east wall of the rift valley of inactive sulfide mounds up to a kilometer in diameter. MIR Mound in this zone consists of a central sulfide zone about 400 m in diameter and 50 m high surrounded by a halo of low-temperature deposits to 200 m wide. Inactive sulfide chimneys contain the first primary, free gold grains found at a hydrothermal site on a mid-ocean ridge (P.A. Rona, Y.A. Bogdanov, E.G. Gurvich, N.A. Rimski-Korsakov, A.M. Sagalevitch and M. D. Hannington, 199 1 EOS, Transactions, American Geophysical Union, 72:470-471 and Journal of Geophysical Research, submitted).

Jan 1, 1992

By P. A. Rona

The first hydrothermal mineral deposits found at a seafloor spreading center were discovered in the Red Sea by multi-national research vessels between 1963 and 1965. At that time, the deposits were considered a special case related to continental rifting and an early stage of opening of an ocean basin. Since that time, examples of almost all major varieties of volcanic- and sediment-hosted hydrothermal deposits associated with basaltic rocks in the geologic record have been found at present spreading centers. Review of over 100 hydrothermal mineral occurrences presently known at oceanic ridges and rifts indicates that a range of deposit sizes from small to large (> 1 x 106 tonnes) occurs at all seafloor spreading rates. However, larger deposits but fewer per unit length of spreading axis appear to form at slow- than at intermediate- to fast-spreading centers based on available data. Larger deposits are more common in sediment-hosted than in volcanic-hosted settings regardless of spreading rate. A spectrum of hydrothermal deposit varieties (stratiform, stockwork and disseminated sulfides; various forms of sulfate, carbonate, silicate, oxide and hydroxide deposits) occurs in almost all of the tectonic settings. High-intensity, ore-forming, subseafloor, hydrothermal convection systems that conserve heat and mass and concentrate hydrothermal precipitates are extremely localized by anomalous physical and chemical conditions relative to nearly ubiquitous low-intensity hydrothermal activity at and flanking seafloor spreading axes at all spreading rates. Two distinct shapes of volcanic-hosted

Jan 1, 1989

By G. Cherkashov

The geodiversity of seafloor massive sulfides (SMS) deposits at the slow- and ultra-slow spreading ridges is of great variety (Fouquet et al., 2010). Tectonics and magmatism are the two principal factors which control SMS formation and localization. The geological setting of SMS deposits is determined by their position relative to the rift valley and by the types of rocks hosted (Table 1). Depending on the first parameter, SMS deposits could be localized at [ ] the axial volcanic ridge or at the flank of the rift valley. Basalts, deep-seated gabbro, and serpentinized peridotites are distinguished among the hosted rocks. The outcrops of deep-seated rocks are exposed at the flanks of the rift valley. The tectonic mechanism of the lower crust and mantle rocks exhumation process is connected with very large offsets along the detachment faults, resulting in a forming oceanic core complex (OCC) (Smith et al., 2006; MacLeod et al., 2009). The SMS related to OCCs are represented by such ore clusters as Ashadze, Logatchev, Semyenov, and some others (Table 1) and are increasing steadily in number. This fact in combination with widespread OCC formation at the slow-spreading ridges (Escartin et al., 2008) and high grades of metals in SMS related to OCCs has provoked considerable scientific and economic interest in these types of deposits. It could be mentioned in this regard that the first two applications to the International Seabed Authority for prospecting and exploration of sulfides have been submitted for the areas in the spreading centres with wide distribution of the core complexes.

Jan 1, 2011

By Steven D. Scott

A geologist can be likened to a medical pathologist trying to figure out from faint clues how something had lived and how it died, often long after the event. Present-day seafloor hydrothermalism has empowered geologists/pathologists to dissect a living system, in this case volcanogenic massive sulfides (vms) deposits of copper, zinc, lead, silver and gold. On the other hand, a considerable amount of our understanding of seafloor hydrothermal processes and its products stem from our knowledge, much of it from industry, of these same processes and products that formed ancient ores in oceans as much as 2700 million years ago and are now mined on land.

Aug 24, 2006

The seafloor occurrences of KODOS ferromanganese nodules can be classified into four facies based on the morphological types of nodules recovered and seafloor photographs. Facies A, B, and C are relatively unimodal whereas Facies D is bimodal in the size distribution of nodules. Both Facies A and B are highly covered by sediments, but Facies B is higher than facies A in nodule density. Facies C has a high density of small nodules and many traces of bioactivity. Facies D is irregular in nodule density, but occurs close to basement near scarps (Fig. 1). The transparent layer (TL) on subbottom profile records (von Stackelberg et al., 1987) is composed of three sedimentary units, which in cores are distinguished by color. The uppermost Unit I is postulated to be deposited during the past 0.21 Ma and the middle Unit II between 0.42 Ma and 0.21 Ma (MOMAF, 1997). There exists a hiatus between Unit II and Unit III. Unit III was deposited from 3.5 Ma to 1.5 Ma as determined by 10Be/9Be and/or 87Sr/86Sr dating (MOMAF, 2004). Internal textures observed on cut sections of nodules suggest four stages of nodule formation (Choi et al., 2000). The nuclei are either unbroken old nodules probably of hydrogenetic growth (1h and 2h) in Facies A and C, or nodule fragments probably of early diagenetic growth (2d) in Facies D, whereas there are both types in Facies B. The layers surrounding the hydrogenetic nodule nuclei are of hydrogenetic growth (3h and/or 4h) in Facies C, and are of early diagenetic growth (3d and/or 4d) in Facies A, B, and D. The layers surrounding the early diagenetic nodule fragments are mostly of early diagenetic growth (3d and 4d) in Facies A, B, and D. But hydrogenetic encrustations are also found as surface layers on the top in Facies B (Fig. 2).

Jan 1, 2005