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By K. Adham, C. Lee

Over the last forty years, a number of specific fluidized bed applications in nickel extraction have been developed for commercial use. Five important processes have gained particular acceptance, namely, sulphide ore roasting, nickel sulphide (matte) roasting, nickel oxide reduction, laterite ore pre-reduction, and nickel chloride pyrohydrolysis. These applications involve different feed materials and process conditions, however, all benefit from fast reaction kinetics and high heat and mass transfer rates in the fluidized bed reactors. They have been studied, tested, and implemented by various nickel producers, who have published their results in many papers and patents. This paper examines the design issues surrounding the application of fluidized bed technology to the above nickel processes. Based on the available data in the open literature, computerized process modelling is used to provide generic flowsheets that illustrate the key features of each process.

Jan 1, 2004

By N. N. Rulyov

"Starting from fundamental principles of colloid-hydrodynamic theory of disperse systems we have shown that application of strongly non-uniform hydrodynamic fields allows to achieve not only faster rates of flocculation of suspension, but also supports significant improvements in the quality of clarified water and separation characteristics of solid phase. Specifically, it has been experimentally proven that the new treatment method based on these principles (then termed as ""ultra-flocculation"") allows:•,Increase the output of thickeners and pressure filters by 1,5-1,7 times;•,Decrease solids fall through into the filtrate in the process of vacuum filtration by 2¬3,5 times;•,Improve the rate of purification of water phase in the upright thickener by 1,5-1,9 times;•,Decrease flocculant consumption by 1,5-3 times;•,Increase the effective operational life time of cloth filters by 3-4 times;•,Ensure sustainable operation of separation equipment, i.e. decrease the sensitivity of process to variation in suspension concentration, as well as to variations of suspension composition and dispersion characteristics;•,Apply flocculant solutions of concentration 2-3 times higher, thus increasing the capacity of equipment used for solutions preparation."

Jan 1, 2004

By J. P. Bennett, K. S. Kwong

Slagging gasifiers are used to produce chemicals and/or electricity from feedstocks such as coal and/or petroleum coke. A gasifier environment includes pressures from 400 to 1000 psi, temperatures from 1250-1550°C, are cyclic, reducing gases of CO and 112, and molten ash that interacts with the refractory liner materials. The high Cr2O3 refractory liners of gasifiers fail within 3 to 24 months. Gasifier users seek materials with increased reliability and service life. This paper discusses causes of refractory failure and efforts to increase refractory service life.

Jan 1, 2004

By V. P. Mehrotra, D. W. Fuerstenau, A. -Z. M. Abouzeid

The use of pulverized coal for electric power generation results in the production of vast amounts of fly ash. One potential use for waste fly ash is the production of pellets for lightweight aggregates. This paper is concerned with the role of the physical and chemical characteristics of two different fly ashes in governing their agglomeration or pelletization behavior and their strength characteristics. In batch balling experiments, fly ash pellet growth was found to be extremely sensitive to the amount of moisture added. One ash (Mohave) exhibits marked pozzolanic activity whereas the other (Jim Bridger) does not. The pozzolanic activity has a very pronounced effect on pellet growth kinetics, moisture requirements, and the effect of various additives on growth kinetics. Slow drying under ambient conditions produces strong pellets from Mohave ash whereas Jim Bridger ash pellets lacking in pozzolanic activity are weak. Rapid drying at high temperatures results in weak pellets because water necessary for hardening is driven out of the pellet. Steam curing enhances pellet strength. Locked-cycle pelletizing experiments exhibit expected oscillation in pellet production rates and attendant fluctuations in pellet green strength.

Jan 1, 2004

By M. Askari, M. H. Parsa, S. Kashani-Nejad

Sarcheshmeh refractory consumption rate is about 7.5 - 8 kg/ton of the produced copper, which is almost three times higher than the other smelters practice. High destruction rate of tuyere zone refractory controls vessel productivity and operational lifetime. In this research with the aid of cold model and computational fluid dynamic (CFD), melt recirculation pattern and gas - liquid plume properties in the wide range of gas blowing conditions were studied. Results revealed that in addition to the well-known mechanical refractory destruction mechanism, fast tuyere zone refractory destruction could also be related to the cold bubble cluster formation near tuyere tips and introducing severe thermal shock to the refractory surface. Removing accretion and its strong bonds to the refractories around tuyere tip, causes refractory mechanical destruction and increases tuyere diameter. Increased tuyere diameter, in turn assists gas discharge in the bubbling regime. Air blowing in the bubbling regime result in the formation of big bubble clusters, bubble breakup and back attack occurrence which all found to have major impact on the refractory lifetime. Outcomes of this research, contributed to the plant converting management, blowing hardware and instrumentation improvement.

Jan 1, 2004

By S. Afshar, E. Dajoux, C. Allaire

For various reasons, molten salts, mainly chlorides and fluorides, are used in the aluminum industry. In the holding and melting furnaces, these salts may have different roles such as protecting the metal from oxidation, reducing the metal content of the skim or removing inclusions or impurities from the metal bath. However, the use of these salts may also have some undesirable effects such as easy attack of the furnace lining refractory materials by molten aluminum. The aim of the present investigation was to clarify and to compare the effects of chloride versus fluoride salts, on the corrosion process of the aluminosilicate based refractory materials. A laboratory test and procedure, simulating the conditions at the metal line in the aluminum treatment furnaces, was used. Different aluminum alloys (A1-5wt.%Mg, A1-5.5wt.%Zn and 7075 alloy) and chloride or fluoride salts (MgC12, KC1, CaCl2, NaC1, MgF2, CaF2, NaF and cryolite) were used as well as several aluminosilicate materials. Thermogravimetric measurements were also carried out in order to analyze the effect of the salts on the oxidation of molten aluminum alloys. The experimental results showed that fluoride salts are more aggressive than chlorides against the tested refractory products. It is postulated that the fluorides prevent the formation of a protective oxide layer on the metal surface, favoring at the same time the corrosion of refractories. Moreover, it was found that the presence of Na in fluoride salts increases significantly the aggressiveness of the aluminum alloy towards the refractory samples.

Jan 1, 2004

By F. W. Brackebusch, R. O. Sack

"A method for determining the fineness of Au in electrum from the composition of fahlore coexisting with pyrite and chalcopyrite is presented. This method is based on previously published experimental brackets and activitycomposition models for electrum and fahlore, and it is potentially useful for defining temperatures of hydrothermal mineralization and retrograde evolution of precious metals deposits. The authors demonstrate that it successfully predicts compositions of electrum reported for this assemblage in the literature and illustrate its application for three gold-quartz vein deposits from the Coeur d’Alene mining district, Idaho, that are prospects of the New Jersey Mining Company, the Coleman vein, High-Grade prospect, and Silver Strand mine. Temperatures calculated from average electrum compositions estimated from gravity concentrates (molar Au/(Au+Ag) = 0.76-0.39) and from microprobe analyses of the fahlores (molar Ag/(Ag+Cu) = 0.039 ± 0.004, Zn/(Zn+Fe) = 0.57 ± 0.03, As/(As+Sb) = 0.23 ± 0.02) from the Coleman vein indicate that the electrums underwent retrograde re-equilibration to temperatures between about 80°C and 240°C, roughly 80°C below the temperature of hydrothermal mineralization and 10°C to 40°C above the temperature inferred for retrograde equilibration of Fe and Zn between sphalerite and fahlore. Fahlores from the High-Grade prospect [molar Ag/(Ag+Cu) = 0.009 ± 0.004, Zn/(Zn+Fe) = 0.55 ± 0.11, and As/(As+Sb) = 0.04 ± 0.03] and Silver Strand mineralized zone [molar Ag/(Ag+Cu) = 0.10 ± 0.04, Zn/(Zn+Fe) = 0.63 ± 0.02, and As/(As+Sb) = 0.06 ± 0.02] exhibit strong core to rim depletions in Ag due to retrograde operation of the reaction1/10Cu10Fe2Sb4S13 + Ag + FeS2 =Cu-fahlore electrum pyriteCuFeS2 + 1/10Ag10Fe2Sb4S13chalcopyrite Ag-fahlorewhich proceeds to the left with decreasing temperature. Electrum inclusions in arsenopyrite from the High-Grade prospect [molar Au/(Au+Ag) = 0.90 ± 0.02] define a minimum bound on the temperature of hydrothermal mineralization of 273°C, and the temperatureelectrum composition curve constructed for the most Ag-rich fahlore in the Silver Strand mine indicates that the fineness of its electrum is significantly less than in the other deposits."

Jan 1, 2004

By B. McLaughlin

"The Penna shaft is the deepest single-lift shaft in North America. Agnico-Eagle started sinking the Penna shaft in 1995 with a hoisting plant capable of hoisting 1800 t/d from a 2240-m deep shaft. Exploration success at depth led to the replacement of the existing double drum hoist by another double drum hoist capable of hoisting 7000 t/d. The use of another double drum hoist, instead of a Blair multi-rope winder, to hoist 24.5 t skips was only made possible by lowering the safety factor.This paper describes recent experiences at Penna and in South Africa, and examines the possibility of extending the double drum hoisting system to a depth of 3 km. IntroductionThe original Penna production hoist was a 4.88 m (16 ft) diameter double drum and single clutch machine. Béliveau (1996) and Scott (1996) have described this hoisting plant. In 1998, a decision was made to increase mining capacity from 1800 t to 4500 t of ore per day from the shaft bottom. Final capacity had to include an allowance of 1800 t of waste per day for future capital projects. While daily capacity was to be 6300 t, it would, by taking into account the different rock densities, be equivalent to hoisting 7000 t of ore.The steps taken to lower the safety factor were presented by McLaughlin and Scott"

Jan 1, 2004

By J. Farrell

The Canadian government ratified the Kyoto Protocol in December 2002 and, prior to ratification, committed to equitable distribution of the burden of implementation. The Federal government's Large Final Emitters group is working with industry to develop covenants that will consider the unique nature of the company's operations and not unreasonably burden any one sector or company. Ensuring equitable distribution must consider local, national and international issues. From a Canadian iron ore producers perspective, the fact that most of the iron ore production in the world is in countries that have no Kyoto commitment is a critical issue. Another issue unique to this sector is the increased addition of fluxing agents in iron ore pellet production which has shifted some process related greenhouse gas emissions from steel producers to iron ore producers. While the objectives of the Kyoto Protocol are primarily environmental, the economic implications for Canadian industry are not trivial. For decades Canadian companies have been actively improving energy efficiency and reducing greenhouse gas emissions to maintain a global competitive position. Production of iron ore pellets is an energy intensive process and the Iron Ore Company of Canada (IOCC) is the largest Canadian producer. In 2002 IOCC identified energy and Kyoto Protocol implementation as critical risk factors for their organization and appointed a full time Energy Manager. In January 2003, IOCC initiated a comprehensive process for identifying energy cost reduction opportunities and established an Energy Master plan. This process included:

Jan 1, 2004

By John C. Wilmot, Robert E. Brewer, Royce J. Smith

In March 2003, Phelps Dodge started up an innovative pressure leach facility for processing copper concentrates at the Bagdad mine in Arizona. This paper describes the development of the concentrate leaching plant at Bagdad and the operational results from start up to present. Optimization efforts and an approach to mineralogical modeling of the concentrate to calculate oxygen utilization are also presented.

Jan 1, 2004

By T. Cutard, E. Yeugo Fogaing, C. Gault, H. Marzagui, N. Prompt, M. Huger, C. Deteuf

This paper deals with studies made in the field of the French research network PROMETHEREF. Several refractory castables are considered in this program. In the present paper, one of these materials is considered, it is a low cement castable based on andalusite aggregates. A particular attention is paid to microstructural changes during the first heating and on their effects on the high temperature mechanical behavior. Microstructural evolutions have been characterized by the way of dilatometry, scanning electron microcopy and X-ray diffraction. In-situ observations by environmental scanning electron microscopy gave complementary results on these high temperature microstructural changes. They deal with microcrack formation, phase changes, crystallization, liquid phase formation and sintering. By propagation of ultrasonic waves, high temperature continuous measurements of the Young's modulus have been made. Results confirm the existence of microstructural changes and allow to quantify the Young's modulus variations all along specific thermal cycles. High temperature four point bending tests and room temperature tensile tests were made in the same temperature range. Behavior evolutions could be found and interpreted with the help of previously mentioned results.

Jan 1, 2004

By F. Rojas, M. Sanchez, J. Palacios, O. Pavez

Copper sulfide is the main mining resources in Chile, and most of this metal is obtained via pyrometallurgical extraction in seven copper smelter plants, which extends from the northern Atacama desert to the central part of the country. In 2002, 1,522,000 metric tons of fine copper were produced, with a notorious environmental impact due to the large amount of slag generated, including transportation and disposing problems. Therefore, there is a great interest in finding alternative uses in order to give additional value to the slag. This is a total project development concept, which consider residues as new resources where new components could be obtained, improving sustainability in mining activities and also ensuring clean production processes. Thus, the present work shows a review of copper slag characterization as well as several ways of utilization, including compact material for road and railway installation, part of admixtures in concrete.

Jan 1, 2004

By J. Budac, R. Krentz, P. Cordingley, G. Freeman, M. E. Chalkley, H. Scheie

Pressure hydrometallurgical unit operations have been in commercial use at the Fort Saskatchewan refinery of Sherritt International Corporation for fifty years. This paper traces the history of Sherritt from its origins in northern Manitoba, and the development of the first hydrometallurgical nickel-cobalt refinery in 1954, utilizing pressure hydrometallurgy, to the modern day refinery. Sherritt's involvement with pressure hydrometallurgy during the past 50 years has included the operation of the refinery, the development and licensing of technology, incorporating pressure hydrometallurgical unit operations, to more than 30 companies worldwide, the joint venture at Moa, Cuba involving both leaching and precipitation at elevated temperature and pressure, and the production of specialty metal powders. Developments in each of these areas are reviewed.

Jan 1, 2004

By Carlos F. Perucca, Maria Virginia Ramírez A.

"Chile based SQM S.A., exploits potassium chloride rich salts at the Salar de Atacama, in northern Chile. The process includes the solar evaporation of natural brines existing in the Salar salt bed, followed by conventional flotation to recover Muriate of Potash (MOP) for fertilizer use.This paper describes a structured method developed to aid in understanding the metallurgical response of the solar evaporated salts to conventional flotation. The method uses classical metallurgical data analysis combined with laboratory and plant-scale testing, and rudimentary mineralogical studies.As a result of the study, several changes were made to the flotation circuit which produced an operation that is much more consistent and easier to control, and has an increased recovery. An optimized circuit, currently being financially evaluated, has also been conceptually designed based on the findings of this work.INTRODUCTIONSQM S.A. is the world’s largest producer and distributor of specialty fertilizers, iodine, lithium, as well as a wide array of industrial and specialty chemicals. SQM is a public corporation whose shares are traded in the Santiago and the New York Stock Exchanges.SQM S.A. exploits the mineral rights at the Salar de Atacama in northern Chile. Its production processes involve the solar evaporation of natural brines existing in the Salar salt bed, aimed at the recovery of Potassium, Lithium and Boron compounds."

Jan 1, 2004

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By Stephen L. Chryssoulis, Stamen Dimov

"Preg-robbing has been known for many years, where increased losses are suffered because dissolved gold is removed from solution by adsorption onto carbonaceous matter. In direct cyanidation circuits it is reasonable to conclude that the preg-robbed gold is either in a gold cyanide [Au(CN) - 2, AuCN] or metallic [Au°] form. However, in circuits with a pre-oxidation step possibilities increase and multiply even further because of water recycle streams containing apparent and not-so-apparent gold ligands. It is in these circuits where speciation of sorbed gold, i.e. the identification of the gold compound, is useful. The importance arises from the fact that proper identification of the sorbed gold species can be used to determine how, when, where and why gold was removed from solution, thereby identifying the exact cause of the problem and providing clues as to how it may be rectified.INTRODUCTIONTo the best of our knowledge, this is the first attempt ever to speciate gold preg-robbed by carbonaceous matter using a surface sensitive microbeam technique. This approach enables the direct determination of gold species sorbed on carbonaceous particulates, opening an entirely new field in the understanding of the chemistry of gold sorption on carbon. The reasoning behind this effort was to add to the current knowledge of the detrimental effect chloride ions have on gold recovery by the pressure oxidation and in particular why in the ensuing CIL step, gold is not being desorbed from the surface of the carbonaceous particles (Table 1)."

Jan 1, 2004

By D. Emadi

The ASTM B108 Mould and a Modified Mould were used to cast test bars under a variety of conditions: mould and pouring temperatures, mould coating and tilt. Mechanical properties were determined in the as-cast and heat-treated conditions. The ASTM Mould is less sensitive to casting variables. Enlarging the gating system and adding additional gates to the ASTM mould can improve properties in the tilt position. The reproducibility of properties in as-cast and T6 heat treated bars was investigated.

Jan 1, 2004

By Jeffrey D. Smith, William G. Fahrenholtz, Jose M. Soto

Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy.

Jan 1, 2004

By Stephen R. Grano, Jon Glatthaar, Philippe Steinier, Christopher J. Greet

"The importance of the oxygen content of sulphide mineral pulps in determining which reactions occur, and their subsequent influence on flotation behaviour is grossly underestimated in most operating concentrators. While pH is routinely monitored, Eh and dissolved oxygen measurements are obtained infrequently. However, dissolved oxygen measurements in conjunction with other pulp chemical parameters (i.e. pH, Eh, and EDTA extractable metal ion analysis), can provide valuable insight into where and what type of reactions are occurring within a circuit. Unfortunately, these readings yield “instantaneous” measurements of the pulp chemical parameters.What is needed is a means of establishing how reactive a pulp is, and how this reactivity changes as components of the system are manipulated. Oxygen demand provides an opportunity to do this. Several attempts at measuring the oxygen demand of a pulp have been made in the past with varying degrees of success. Most notable among these are Noranda and BOC Gases.Learning from these experiences, Magotteaux have developed the MagO2 ® demand vessel to measure the oxygen demand of mineral pulps. This paper described the apparatus, and through a case study on Broken Hill lead/zinc ore demonstrates how the MagO2 ® demand vessel is used.INTRODUCTIONThe role of oxygen in flotation is complex. While a considerable body of work exists demonstrating the strong involvement of oxygen in the interactions between sulphide minerals and collector (Gaudin and Finkelstein, 1965; Gaudin, 1974; Woods, 1984; Laajalehto, Nowak and Suoninen, 1993), the presence of oxygen can also affect the oxidation state of sulphide and non-sulphide minerals, which can impact on their flotation behaviour. Further, sulphide mineral oxidation is related to their oxygen demand (Spira and Rosenblum, 1994)."

Jan 1, 2004

By M. W. Lewis

A mine's inherent capacity is dictated by factors such as equipment, design, people, processes, and environment. Actual production may approach, but never surpass, the inherent capacity limit. The inherent capacity ceiling can only be increased through re-engineering. Autonomous haulage systems have the potential to significantly increase a mine ’s inherent and realized capacity. Realized capacity may be maximized through the optimization of soft factors such as the processes, behaviours, and organizational systems, controlling asset utilization, availability, and performance. Truck shovel dispatching systems revolutionized the utilization of mobile assets. High-precision global positioning systems (HP-GPS) are increasingly being adopted to optimize equipment performance. Real-time maintenance management systems have the potential to revolutionize equipment availability and significantly reduce cash costs. This paper explores some of the solutions available to mines to increase their inherent capacity and maximize their realized capacity.

Jan 1, 2004