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By P. W. A. Walker

"The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.216% W03 and 0.020070 Mo. The deposit is uneconomic at current tungsten prices. IntroductionDuring the 19705, Union Carbide Corporation was a major producer, processor and supplier of tungsten and derivative products to end-user manufacturing industries. The corporation owned and operated two tungsten mines in the United States, and one in Brazil, and operated a plant in the United States which produced ammonium paratungstate (APT) which is an intermediate product in the production of tungsten wire and tungsten carbide for cutting tool insets and hard facings. In 1975 the three mines were ageing with short-life reserves and high production costs. The world market for tungsten was buoyant and prices, in constant dollar terms, had risen steadily over the past 15 years (Fig. 1).It was against this background that a decision was made to explore for tungsten in North America, South Mrica, Australia and Brazil."

Jan 1, 1994

By Walker. P. W. A.

Abstract -The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.2160Jo W03 and 0.020% Mo. The deposit is uneconomic at current tungsten prices.

Jan 1, 1994

By Franc R. Joubin, Donald H. James

"The Property of Rix Athabasca Uranium Mines Limited is in the Beaverlodge area of northwestern Saskatchewan. The mine is 7 miles by road north from the Lake Athabasca port of Bushell which is 250 miles north by aircraft or boat from railhead at Waterways, Alberta.The Rix property is a portion of the former DD 1 concession, obtained in 1949 from the government of Saskatchewan when private prospecting for uranium became permissible. The concession was prospected in detail during the 1950 and 1951 field seasons and a great many radioactive show-ings were discovered. Development and drilling were concentrated in two and later three of these areas, and by late 1952 enough ore had been indicated in the Leonard series and ""Smitty"" zone to justify underground development by adit-drift and shaft respectively.Four hundred feet of drift development on the Leonard No. 1 vein and the sinking of a two-level vertical shaft with related lateral development on the Smitty zone were completed in 1953. In April 1954 the Smitty section was placed in production at a rate averaging 100 tons per day, thereupon becoming the first privately owned post-war uranium producer in Canada. The ore is shipped for processing 12 miles by truck to the mill of Eldorado Mining and Refining Limited.Until recently all of the Company's production was drawn from the Smitty orebody. In April, 1955, ore production commenced from the faulted west extension of the Smitty structure, known as the Rix 62 zone, and from the Leonard No. 1 vein.The Smitty orebody (see Figure 2) is an intensely brecciated lenticular zone bordering both sides of the Smitty fault. The breccia areas are irregularly mineralized with pitchblende, very sparse galena, and pyrite in a gangue of feldspar, chlorite, calcite, and silica, all thoroughly soaked with fine-grained hematite to produce the locally-called ""red alteration"".Tenor of the ore currently being mined is classified information. The average grade estimated, prior to production, was 0.20 per cent (4.0 lbs.) U308 per ton."

Jan 1, 1949

By D. R. Rice

"The Smoky Valley Common Operation is managed and 50 percent owned by Echo Bay Mine' s Round Mountain Gold Corporation. The other partners with 25 percent each are Homestake Mining Company and Case Pomeroy. The operation in central Nevada includes an open pit, 3-stage open-circuit crushing train and heap leaching on asphalt pads. Presently, about 18,000 tons per day of 0.039 troy ounce gold per ton are transferred to the leach pads, and a similar tonnage of leach residue is transferred to a waste dump. One million tons of ore are being leached at any one time.Gold and silver cyanide are adsorbed from pregnant leach solution on activated coconut shell carbon granules. Pressure stripping desorbs values from loaded carbon to electrowinning solution.Three electrowinning cells are operated in parallel. Each contains six cathodes. Each cathode includes about 40 troy ounces (2.7 pounds) of Number 2 medium coarse steel wool. The wetted area of each cathode is about 24 by 30 inches. Solution flow is 2 to 3 gallons per minute per electrowinning cell. Average current flow is 25 amperes per cathode. The voltage is controlled in the range of 3 to 4 volts to maintain desired amperage.Twice a week two cathodes are pulled from each cell and drained. Each cathode is split into four portions. These are put in a steel pan coated with WD-40 and dried overnight.Each dried cathode portion is put into a paper sack. Each group of four sacks corresponding to a cathode is weighed together. The typical weight ratio of loaded cathode wool to new cathodes is 9 or 10 to 1. To each sack is added 35 troy ounces of silica, 45 troy ounces of anhydrous borax, 35 troy ounces of nitre, and 5 troy ounces of fluorspar. The sacks are taped shut."

Jan 1, 1986

By Arthur Laing

"IT is indeed a pleasure to have the opportunity of addressing this group today. Not only does it give me the opportunity of meeting with representatives of what is considered by many to be the most dynamic segment of industry in Canada today, but it also allows me to talk about a subject of para-mount interest to myself, the development of the North, and to explain, if even only briefly, some of our beliefs and hopes in this regard.It is inconceivable that all lands north of the 60th parallel, representing 35 per cent of Canada's total land area, which we believe contain a great natural resource potential, will remain as an undeveloped portion of Canada. The re-sources are there, although the people and private industry are as yet not there in sufficient numbers.It has been estimated that in the west and north of Canada there are 1.6 million cubic miles of sedimentary rocks. Of this figure, 342,-000 are thought to lie in Alberta, 115,000 in British Columbia and about 1 million cubic miles are thought to lie in Canada's northern regions, the bulk in the Arctic Islands. On the basis of apparent volumes of sedimentary rock, we estimate that as much as 13 billion barrels of petroleum may lie beneath the permafrost of the North-west Territories, another 3 billion barrels in the Yukon Territory and 33 billion barrels in the Arctic Islands. This is, indeed, a rich and elusive prize, and one which must be sought with a view to fulfilling demands on the production of petroleum."

Jan 1, 1966

By A. O. Dufresne

WITHOUT transportation, mining would be quite impossible. Any person familiar with the operation of a mine knows full well that from the minute ore is blasted, it is kept moving until it reaches the treatment plant. In the mill, by means of conveyors and elevators, the ore is brought from receiving bins to one machine after another until finally its valuable mineral is separated from the gangue. The finished product must then be shipped -either by boat, rail, or motor trucks to industrial centres, where it undergoes further treatment and transformation into finished commercial goods. Everybody appreciates that the winning of an or-e includes, amongst various operations, the moving of large quantities of material of generally low value. Transportation, therefore, must be considered One of the most important factors in the economics of mining. My assignment, this afternoon, is not to treat of that phase of transportation as it directly affects mining operations, but rather to consider some of the aspects of overland transportation and its influence in bringing about the development of mining camps in Canada. I shall take the liberty of rapidly surveying conditions facing prospectors, mine developers and operators from the time a region is still in a pre-pioneering stage until such time as a mine starts shipping its concentrates.

Jan 1, 1956

By V. C. Wittchen, T. R. Yu, J. E. Croxall

"The consolidated rockfill at Kidd Creek Mines is a weakly cemented, minus 15 cm aggregate which posed problems for conventional drill/blast drifting methods. Consequently, lateral access to mineable ore adjacent to backfilled areas was gained by drifting around the fill in shattered rock.In mid-1987, Kidd Creek Mines began to investigate means of mechanically excavating drifts in backfill . The results of this investigation led to a trial program using a Dosco MK-2A Roadheader to excavate the required drifts in backfill.The roadheader was tested at Kidd Creek Mines from July to November 1988, in 28-735 X /C to be used as the top access for drilling and blasting 32-74/ ST. During this period, the roadheader excavated 54 m of a 4.3 m by 3. 7 m arched drift in backfill. Cutting rates over the period averaged 0.8 m/cutting hour as projected with a daily high of 2.0 m/cutting hour.Wood-lagged 2-piece steel arches on 1.2 m centres were chosen as ground support for the trial. Shotcrete will be tested in a roadheader drive for its potential to improve productivity by replacing the steel arches.The trial program included evaluations of point-attack picks, two sizes of cutter motor, 20 MPa (3000 psi) water-assisted cutting, cuttings-removal systems, and environmental control devices."

Jan 1, 1990

By A. D. Akerman, D. D. Young, G. R. Baiden

The development and maintenance of underground roadways are increasingly important aspects of the modern mining process. With the trend toward automation and track-less mining, roadbeds capable of with standing increased wheel loading have proven necessary to maintain high vehicle speed and reduced maintenance costs. Concrete has been used successfully on some roadways in order to obtain the required characteristics. However, this solution usually involves unacceptable expense. The objective of the Road Router project was to create a drift floor profiling machine capable of cutting a smooth surface out of the existing rock floor of development drifts and ramps. This surface would provide a durable, high strength, low rolling resistance roadbed that would allow for reduced operating cycle times and lower maintenance costs of scoops and haulage trucks. The Road Router has the potential to offer an alternative to concrete with substantial cost savings.

Jan 1, 1997

By Ji Wang

Reflective in-seam wave detection has the advantages of a far detection range and wide applicability. It has been successfully used in detection of many abnormal geological structures in work-faces, such as faults and collapse columns. However, a reflective in-seam wave is a dispersion wave. It has weak energy and is always covered by the direct in-seam wave. In the past, underground seismic explorations were not able to image the opposite roadway using reflective in-seam waves. To solve this problem, we propose a new method of reflective in-seam wave imaging based on adaptive dispersion filtering. This method processes the reflective in-seam wave using a filter with the parameter of transmission distance. The degree of similarity of the filtered and the explosion signal is used to estimate the transmission distance and image the reflective objects. We test and verify this method using real underground seismic data. This research is helpful for the detection of coal mine goafs and abandoned roadways in work-faces or in front of tunneling ends.

Aug 1, 2013

By J. E. Williamson

Introduction 1. Factors on Which the Design of the Roaster Plant was Based The roasting operation at Lake Shore, it was realized from the outset, would be profitable only if costs and losses could be reduced to a low figure. It was absolutely imperative that the operation should be self roasting over the whole range of tonnages and sulphur grades which might obtain during the life of the mine. The roasting operation could not bear the cost in fuel and labour of even a partially fired roast. To meet this requirement, it was necessary to resort to additional insulation in the construction of the roaster and to provide a more flexible means of rabble cooling than the conventional water jacket (see p. 31). A second basic consideration was that of handling a wet, putty-like concentrate. The operating costs of a drier ruled out the possibility of drying the charge before feeding it to the roaster. Moreover, the dusting which would result from charging a dry product virtually all -40 micron (325 mesh) in size would seriously handicap the use of a dryer. Dust lubrication (p. 3S) due to the back-mixing action of the Edwards rabbles, and the use of a Sullivan slapper ( p. 27) on the concentrate filter, completely solved the problem of handling the roast feed. The third consideration was the reduction of dusting to a sufficiently low point that a Cottrell or other dust collecting system was unnecessary. The Edwards roaster when properly supervised, it is believed, can be operated to give the minimum possible dusting. At Lake Shore, the evidence has been that less than 1 per cent dusting occurs at any time and that the greater part of the dust produced is recovered either in the spray tower or in the dust chambers.

Jan 1, 1947

By J B. McConnell

The Thompson smelter has three unique features which form the basis ~f its design: fluid bed roasters which treat nickel concentrate filter cake from the mill, as well as the flux, in order to achieve partial desulphurization; the use of electric furnaces for the smelting of the partially desulphurized, preheated roaster product; and the disposal of slag by water granulation and slag slurry pumping. The installation consists of three fluid bed roasters, each feeding an electric furnace. Nickel concentrate is received at the smelter via pipe line. It is thickened and filtered, and the filter cake, together with siliceous flux, is fed through rotary bin feeders and reciprocating double-gate seals into the fluid bed roasters. Air injected into the roasters through club-head tuyeres oxidizes part of the sulphur and associated iron in the concentrate. The heat of reaction dries and heats the charge. Roaster product is recovered from the gas stream in cyclones and from the roaster bed through automatic valves.

Jan 1, 1963

By F. R. Archibald

Introduction It is the purpose of this paper to review the subject of roasting as preparation of refractory gold ores and concentrates for cyanidation, with particular reference to operations at the mill of Beattie Gold Mines (Que.), Ltd., Duparquet, Quebec. Two earlier papers relating to the Beattie roasting operations are cited as background to the ? present discussion, and more general reference is made to other publications relating? to geology and metallurgy at Beattie. The Beattie roasting plant was built in 1937 as an addition to the existing flotation and cyanidation plant to permit complete processing of the ore at the mine property. Previously, the flotation concentrate had been cyanided, yielding 70 per cent of the gold values, followed by re-flotation of a concentrate from the cyanide residue. This re-floated residue was shipped to a smelter for recovery of gold values unavailable from direct cyanidation. The roasting plant itself is of interest through application in its design of multiple-hearth roasters and a Cottrell plant for separate recovery of dust and arsenic. In the laboratory and plant studies that accompanied development of the plant into a dependable and efficient working unit have been found principles and ideas applicable to other roasting 'problems. Before enlarging on these aspects relating particularly to the Beattie problems and plant, brief consideration is given to roasting in general.

Jan 1, 1949

By F. R. Archibald

MR. A. F. B. Norwood: Having been associated in the past few years with nine different plants roasting aurif erous concentrates in Australia, two of which were new installations for which design and construction were undertaken by the writer, I read Mr. Archibald's paper with very great interest, and I deem it a great privilege, as a member of a sister Institution, to be invited to contribute to the discussion on the paper. I wish to congratulate the author on a very informative and interesting paper, and, although situated many thousands of miles away, I feel I have gathered from it a very close idea of the operating conditions and of the work that has been carried on at the Beattie gold mine. Working along somewhat different lines, it is interesting to note that the conclusions drawn by the author run closely parallel to those accepted in Western Australia, viz., that the object of roasting is to obtain a porous calcine, and that this can best be achieved by roasting first at a temperature below 900 deg. F. to 1,000 deg. F., and then raising the temperature at the finish of the roast. Turning first to the laboratory work, the materials I have studied in Western Australia cover a range from those with little or no arsenic to concentrates carrying as high ?as 20 per cent, i.e., even higher than in the analysis quoted for the eoncentrates from Nepheline Products, Limited. In the ease of arsenic-free pyrite concentrates, the roast is ideally carried out at a temperature ranging from 900 deg. F. to 1,000 ferric oxide is one cause of the refractory gold remaining In deg. F. No improvement in extraction is obtained when the calcines are cyanided by raising the final temperature above this point; nevertheless, in technical practice it is desirable to finish the roast at 1,200 deg. F. in order to decompose basic ferric sulphate and thereby reduce the consumption of chemicals in the subsequent cyanidation step. However, if at any stage of the roast the temperature is raised above 1,200 deg. F., the extraction by cyanidation falls, and continues to do so the higher the maximum temperature that is reached. Line A in the accompanying graph typifies this effect.

Jan 1, 1949

Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

By F. R. Archibald

SINCE the opening of the Beattie mine, in 1933, the concentrate produced by flotation has been considered refractory. As the gold extraction by cyanidation was poor, the concentrate, during the first four and a half years of operation, was shipped to a smelter for further treatment. After the installation of the cyanide plant, in 1934, seventy per cent of the gold in the concentrate was recovered before shipment to the smelter. In 1937, a roasting plant was built so that treatment might be complete at the mine. Much experimental work had been done by a number of investigators prior to the installation of the roasters, but none of them had seriously attempted to identify the causes of, or the elements responsible for, the refractory behaviour of the concentrate. Intensive investigation in this direction commenced in the Beattie lab-oratory in July, 1938, has led not only to the identification of several causes contributory to the refractory behaviour, but also to revisions in procedure and principles with respect to roasting Beattie concentrate in particular and arsenical concentrates in general. The accuracy of the identification of these causes and the soundness of the principles is borne out by interpretation of roasting plant records, by improvements and simplification since applied. to plant operation, and also by laboratory and test-plant results on arsenical concentrate produced by another mine. It is the purpose here to present an account and interpretation of the laboratory investigation, together with a correlation of laboratory and plant results. Incomplete extraction of the gold by cyanidation after roasting is due primarily to the nature of the material roasted, and secondarily to the manner in which it has been roasted. There is a possibility that better extraction may be obtained by improvements in both particulars.

Jan 1, 1939

By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By Roorda H. J, R. R. Saddington, Curlook W

THE copper-nickel sulfide ore deposits of the International Nickel Company of Canada, Limited contain the minerals pyrrhotite, pentlandite, and chalcopyrite. In the extraction of the nickel, copper, and iron, much of the processing involves oxidation of the metals as well as sulfur. Roasting plays a predominant role at several stages in the operations which prepare the constituent metals for refining. Copper, nickel and iron concentrates of various grades, ranging from low-grade nickeliferous pyrrhotite to high-grade nickel sulfide, must be partially or completely oxidized. Figure 1 shows the main points at which roasting is conducted at INCO. Roasting experience at INCO dates back to the time when lump ore was partially roasted in heaps. It has progressed through single hearth roasters, sinter machines, multiple-hearth roasters, flash roasters, and more recently has centered on the development and utilization of fluid bed roasters. The primitive, slow, and inefficient method of heap

Jan 1, 1961

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By A. R. Barnes, N. Stubina

Increasingly, gold producers are forced to treat ever more refractory ores. While ores containing pyrite, arsenopyrite and carbonaceous material have been subjected to complete pressure oxidation (PDX) as the standard process for such ores, recent improvements in fluid bed roasting technologies have led to a resurgence of interest in roasting as a viable alternative. The lower capital and operating costs of roaster installations add further impetus to this trend. The Extractive Metallurgy Group at Xstrata Process Support operates four fluid bed reactors of various sizes which have been utilised on a large number of projects to treat highly refractory ores. Preliminary mineralogical modelling of both the physical and chemical aspects of the roasting process and subsequent testing under carefully controlled conditions has allowed clients to obtain gold recoveries approaching or matching those achievable by PDX. The flexibility of the units to operate in various modes- " bubbling bed", circulating bed, two stage, sub-stoichiometric and combinations of these, and the range of sample sizes accommodated, from a few kilograms to a few tons, has enabled XPS to accommodate clients with a wide variety of gold bearing refractory ores from all over the world. This paper outlines the key challenges of fluid bed roasting of refractory gold ores, describes the methodology used to design the testwork program and provides some results from select test campaigns.

Jan 1, 2011