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By H. Zhu, Y. Sato, O. Takeda, K. Nakano

Recycling of rare earth magnet wastes is essential to insure the stable supply of rare earth resources. For the development of a novel recycling process, the removal of rare earth oxide from an off-spec alloy magnet was investigated by melting the alloy magnet at 1503 K together with fluoride flux, LiF-50 mol% NdF3 and LiF-?25 mol% NdF3-25 mol% DyF3. After melting, the separation of magnet alloy from the fluoride flux was achieved, and neither suspension of alloy in the flux nor suspension of flux in the alloy was observed. Oxygen concentration in the alloy decreased from 5000 mass-ppm to 160 mass-ppm by utilizing 1.5 times of equivalent amount of flux needed to completely dissolve the oxide. The investigated process is suitable for mildly contaminated waste such as a used (end-of-life) magnet because of its simplicity, low energy consumption and small limitation on location for operation.

Jan 1, 2014

By I. P. Barbosa, P. S. M. Soares, I. O. C. Masson

"Permanent magnets have been applied extensively to several electronic products such as printers, TV sets, microphones, microcomputers and headphones, presently manufactured in large scale by industrial economies. Sm-Co alloys represent about 20% of the world market for permanent magnets and their industrial processors generate 20-30% of magnetic scraps which can be recycled. This paper discusses a process route to recycle SmCo5 using acid treatment, solvent extraction of Sm and electrowinning of Co. The results confirm the feasibility of the alternative proposed. Basic operational variables are suggested as guidelines to design a plant for recycling magnetic scraps.The use of hydrometallurgical processes to recycle scraps from the industry of permanent magnets has been suggested in some recent papers related to recycling of metallic alloys [ 1 ]. These research efforts might be understood as a worldwide tendency towards the development of self sustainable metallurgical processes which mean the reduction of environmental impacts.CETEM -Center for Mineral Technology leads in Brazil several research programs concerning recycling and treatment of industrial residues. The work on samarium purification and concentration by solvent extraction, producing also a solution of cobalt sulfate as partially reported here is one of these programs. Previous results related to the sulfuric acid digestion of SmCo5 are presented somewhere else [2]"

Jan 1, 1997

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By A. Rahimi

Refractory castables based on alumina-silicate aggregates are commonly used in casting wheel components and launders. In this research the recycling process of waste magnesia chrome bricks for production of refractory castable lining for launders and casting wheel ladles at Iranian Sarcheshmeh copper complex (I.S.C.C.) is discussed. The smelting plant of ISCC consumes 4,000 tons refractory materials and produces 2,000 tons waste refractories annually. In order to reduce the environmental pollutions and gain the economical advantages, the recycling of waste refractories proved to be a solution [1]. In ISCC, 800 tons alumina or alumina-silicate refractory castables are used for linings of anode furnace ladles and launders annually [2]. In the present work, the spent bricks from reverberatory, converter and anode furnaces were analyzed in term of microstructural changes from hot zone to the cold end to evaluate the changes in texture and chemical composition. Different formulations based on recycled magnesia chrome aggregates and various particle size distribution and cement content were tested. Economic recycled magnesia chrome refractory mixture was prepared after crushing and sizing the non-deteriorated regions of wasted bricks. After evaluation of physical and mechanical properties of samples, one ton of refractory castable was prepared and successfully installed in the casting wheel ladles.

Jan 1, 2007

By P. Henry

Hydrometal provides an adequate technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy, while keeping the environment cleaner. Two case studies of our integrated hydrometallurgical recycling facility (Hydrométal) in Belgium are discussed.(I) Recycling of Cu-Co cement generated at the second purification step of zinc sulfate solution. (II) Recycling of lead complex materials from the lead industry.

Jan 1, 2008

By V. I. Lakshmanan, R. Roy

"Zinc is the fourth most widely used metal in the world after iron, aluminum and copper. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing the steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Process Research ORTECH Inc. has developed an efficient energy-saving sustainable technology for the recovery of zinc from secondary sources such as galvanized steel scrap, dross, dusts etc. The process consists of treating the zinc containing scrap in an alkaline solution to remove the zinc and thereby producing a zinc free steel scrap for recycle. The zinc containing leach liquor is subjected to a solvent extraction process to recover value added zinc oxide as the final product. In this paper, important industrial processes for the recycling of zinc including the PRO process will be discussed. BACKGROUNDZinc is the fourth most widely used metal in the world after iron, aluminum and copper. Global refined zinc output increased by 2.7 per cent to 13.16 million tonnes in 2011 and is expected to increase by an additional 2.4 per cent to 13.48 million tonnes in 2012 [1]. The primary zinc production is through flotation of zinc concentrate, roasting, leaching and electrowinning. Close to 60% of the metal produced is consumed in galvanizing steel by making a thin layer of zinc coating on the steel surface by hot dip galvanizing. Other major usages of zinc are in the production of brass and bronze, die casting and zinc-air batteries. The additional demand for zinc could come from its addition to fertilizers to increase crop yield.While the demand for zinc is increasing, many mines are scheduled to close in near future after being depleted of ore. The mines set to close between now and 2015 are Teck Resources’ Red Dog Mine in Alaska, Minmetals’ Century Mine in Australia and Vedanta Resource’s Skorpion Mine in Namibia [1]. The depletion of resources due to continued use and exploitation is becoming a great concern for the zinc industry. As a result, the sustainability of natural resources for continued societal care has become extremely important. Resource conservation and recovery by recycling with minimal environmental impact is a key element for sustainable development. In this paper, important industrial processes for the recycling of zinc including the PRO process are presented."

Jan 1, 2012

By \/eena Sahajwalla, Jonathan Dicker, Paul O'Kane, Cath Skidmore, James Dankwah, Magdalena Zaharia, Rita Khanna, David Knights, N Saha-Chaudhury, Somyote Kongkarat

Due to the inherent limitations of current methods of disposal of end of life polymeric materials, avenues are researched towards developing alternative, environmentally friendly and economic recycling processes. Different polymeric materials (i.e. rubber, high density polyethylene (HDPE) and polyethylene therephtalate (PET)), quite distinct in terms of chemical structure and composition, were considered in the present study as carbon resources in EAF steelmaking. Investigations were conducted in both laboratory and industrial scale steelmaking to assess the effectiveness of using these materials as carbon sources for slag foaming in EAF steelmaking. Slag foaming is important because it enhances furnace efficiency.

Jan 1, 2011

Red Chris Project Project Status ? Tahltan, Iskut First Nations MOU ? Bankable Feasibility Study ? BC Environmental Assessment Certificate ? CEAA (Federal Environmental) ? EPCM contracts LOI?s ? US$110 million Project Debt Financing(credit approval pending) ? 1st5 years concentrate production sold ? 99,150 m of drilling in 371 holes First Nations Participation Agreement ?Advanced stage negotiations

May 1, 2006

By Brigitte Lacouture, Yeen Shien Hwang, David Lin

"A baseline survey of the partially open lead regrind circuit at Red Dog Mine indicated poor regrind efficiencies for the three parallel 450 HP tower mills. Driven by the high energy cost and the potential metallurgical gain brought by improved mineral liberation, the Red Dog lead regrind circuit was optimized in two stages.In the first optimization stage, different circuit layouts were evaluated in two plant trials. In June 2003, the regrind circuit was changed to a fully closed circuit. This reduced the tower mill requirement from three to two mills. The circuit modification payback was 11 days through power savings alone.The second stage of optimization was the evaluation of reagent addition. To improve pyrite depression, sodium cyanide was added to the feed of the lead regrind tower mills and tested in a series of plant trials over several mill feed stockpiles. Galena selectivity against pyrite was found to improve in these plant trials. Due to environmental sensitivities, no net increase in cyanide addition to the plant occurred and thus no increase in the cyanide concentrations in the tailings pond or the environment will result.The lead regrind optimization work improved the overall lead metallurgical performance and reduced energy and reagent costs. Economic analysis showed that annual profit increased by as much as US$3.0 M."

Jan 1, 2005

By Alvaro Diaz

Introduction, who is Teck Red Dog and Quebrada Blanca Mines Uniqueness of environment Arctic versus High Altitude Conditions Logistical challenges People and Stakeholders Conclusions

May 1, 2013

By L. M. Southwick

"The history of extractive metallurgy is replete with examples of commercializing new processing technologies. The successes are widely reported, but failures seldom are. This is unfortunate, for usually we can learn more specifics on how to succeed in technology development by studying and thoroughly understanding their failures. Frequently one encounters a red herring that caused the whole effort to fail. A thorough and objective due diligence up front would have identified those red herrings and prevented the pursuit of a bad idea and the resulting destruction of capital. Due diligent analyzes performed before construction of three such bad ideas will be discussed. One is an EAF dust process, which pursued the red herrings of a poor understanding of the business, a naïve view of past experience, and false confidence in the technology. Another will examine the effort to commercialize a new pressure copper leach process that followed the red herrings of inadequate testing of the raw material, application of processing conditions that were inherently unsafe, and an improper assessment of the inherent advantages of past developments. The last is an alternative iron-making process, where the red herrings were incomplete and superficial assessment of prior pilot plant and demonstration plant tests, an assumption that the commercialization model of “build it and we will make it run” was viable, and a technology whose technical fatal flaws had already been identified. Unfortunately, capital destruction often also closes the window to more intelligent pursuit of technology development. TECHNOLOGY COMMERCIALIZATIONThe development and commercialization of new technology is a vital part of keeping industry profitable, able to deal with new sorts of feed stocks and current with economic, product, operational and environmental requirements. This is a difficult task in the best of times, and can be compounded when the developers become enamored of a particularly favorable characteristic of the project or of the product. These “red herrings” divert project focus away from the arduous path to success and, in the end, result in project failure."

Jan 1, 2012

By E. L. Bruce

Red lake is a body of water some thirty miles in length lying about forty miles northwest of the outlet of Lac Seul. It forms one of several large lake expansions on a river which enters the English river from the north, twenty miles below Lac Seul. Before the construction of the National Transcontinental railway a long canoe journey was necessary to reach that part of the English river, and Red lake, two days travel beyond, was one of the furthest outposts of the trading companies in that difficultly accessible triangle of country between Lake Winnipeg, James Bay and the English and Albany rivers. The Hudson's Bay Company post at Red lake is said to be one of the earliest established in the district but there are no records at the post, and as the English and Albany rivers never were used to any great extent as travel routes there is no mention of the place in the diaries of any of the early explorers. Dr. Bell passed through Red lake on his excursion to the Berens river country in 1883, and a brief note mentions that Huronian rocks were seen. To Dr. Dowling, however, belongs the credit for the first thorough description of this basin of sediments and basic volcanics. In 1893 he followed the course of Dr. Bell's trip, of ten years previous, through Red lake to the upper part of the Berens river.

Jan 1, 1926

By K. K. Murray, D. G. Gelderland

"The pressure oxidation autoclave at the Goldcorp’s Red Lake Gold Mines (RLGM) was commissioned in 1991. Since commissioning, the circuit has been well maintained and its capacity increased to mechanical and gaseous oxygen limitations. With advances in available technology, opportunities to produce more sulphide concentrate and a changing business environment, an optimization project has been initiated at RLGM. A multi-phase approach has been developed to optimize both the operations and economics of the circuit. This paper describes the history and future of the autoclave circuit at RLGM.AcknowledmentsWe would like to thank the operations and maintenance staff at Red Lake Gold Mines for their support and openness of mind to enact changes to enhance the operation. We would also like to acknowledge the members of the integrated team from Red Lake maintence, metallurgy, operations and corporate technical services that did the hard work to push past the status quo in order to advance productivity.OpportunityThe Red Lake Gold Mines (RLGM) pressure oxidation (POx) circuit has been in operation for over 25 years processing the high sulphide content gold bearing minerals. Increased sulphide concentrate production from improved flotation recovery and increasing gold sulphide association at depth has led to the POx circuit becoming a throughput bottleneck. The opportunity exists to process increased tonnages of sulphide concentrates and increase gold production. In order to realize this value, it will be necessary to increase the throughput capacity of the POx circuit.BackgroundThe POx autoclave at the RLGM, commissioned in 1991, was Canada’s first gold autoclave. It was installed to replace the two-stage fluid bed roaster that was built when the Campbell mine and mill were constructed in the late Forties. The circuit was originally designed to process 12.5 t/d sulphide sulphur in about 50 t/d of Campbell flotation concentrate. Following the merger of the Campbell and Red Lake Mines in 2006, the POx circuit started processing flotation concentrate from both Campbell and Red Lake Mills. In recent years, the circuit has been processing about 18 t/d sulphide sulphur in 75-85 t/d flotation concentrate."

Jan 1, 2017

By J. B. Mawdsley

"The Red Lake Gold Shore mine is 4/5 mile west of the town of Red Lake, Ontario, and a mile northwest of the Howey mine. It came into production in August 1936, and in a little over 2 years produced 21,099.58 oz. gold from 83,949 tons milled.An investigation of this deposit was made by the writer during parts of September and October, 1937t. The geology of the deposit is also discussed by H. C. Horwood(2) , and the characteristics of the ore were investigated by the Bureau of Mines, Ottawa (1).The orebodies are pipe like and close together, in a north-northwesterly trending zone of dykes, veins, and shear zones in a granodiorite stock, just south of a pronounced valley with a trend of N.65°E. believed to lie along a strong shear zone and fault . The dykes, veins, and mineralization are believed to have been successively emplaced along structures having three general trends and that were due to compressive stresses that alternated, at least four times, from west of north to east of north. In common with many other gold deposits, the gold mineralization here occurred late and followed the last east-of-north stresses.WALL-ROCKSThe mine is within the Dome stock, % mile from its southeast margin. Near the mine the rock is a pink hornblende-biotite granodiorite, grading within short distances, but not abruptly, into a dark grey variety. Near the workings at least, scattered small inclusions form about ½ to 5 per cent of this body. Most of them are fine-grained, angular, or partly rounded, greenstone fragments, but some have been partly granitized and feldspar has been developed in them."

Jan 1, 1954

Outline ?Red Lake Gold Mines ?Red Lake Seismic System ?Applications of Seismic System at Red Lake Mine ?Seismic System Analysis and Customization ?Seismic Software ?Array Design ?Calibration and Source Mechanism ?Auto Picking Optimization ?Acquisition Groups ?Conclusions Goldcorp?s Red Lake Gold Mines ?One of the largest gold producers in Canada ?The operations comprise the former Campbell and Red Lake underground mines, now integrated as the Red Lake Gold Mines (RLGM) ?There are a total of 4 shafts with one internal winze and two main declines beginning at the 21st level ?Daily production approximately 2,600 tons

Aug 1, 2013

By A. W. Davis

"The Red Rose mine is in the Rocher Deboule mountains about 8 miles east of Skeena Crossing and a like distance south of the town of Hazelton; the most northerly settlement on the Prince Rupert line of the Canadian National railway and 177 miles northeast by rail from Prince Rupert. The mine workings are on the north side of Balsam or Red Rose creek; a tributary of Juniper creek that drains via Kitseguecla river into the Skeena near Skeena Crossing. A truck road 11 miles long extends from Skeen a Crossing (elevation 650 feet) to the Red Rose mill (elevation 4; 100 feet). The mine workings lie between 5; 600 and 6; 300 feet above sea-level. Mine and mill are connected by a 1-mile aerial tramway and a tractor trail.The Red Rose claims were staked about 1910 by prospectors attracted to the district by the construction and near completion of the railway between Prince Rupert and Jasper. For a number of years interest centred in prospecting a sheared zone exposed in a ravine between elevations of 5,425 and 5,825 feet. Several adits were driven and some high gold assays were obtained in vein quartz in the sheared zone, but this work did not develop sufficient ore and the property finally closed down. In the early twenties of this century tungsten minerals were discovered in the northern extension of the vein, but nothing was done to test this deposit. Finally, in 1940, spurred by the wartime demand for tungsten, the Consolidated Mining and Smelting Company of Canada drilled the tungsten-bearing vein, and although results were none too encouraging, underground work was begun in June 1941. The latter work disclosed substantial amounts of ore. A small mill, subsequently enlarged, began operation early in January 1942 and by the autumn of 1943 some 1,194,000 pounds of tungsten concentrate had been recovered. Mining ceased in November 1943 because of orders from the Metals Controller that no more shipments would be permitted."

Jan 1, 1954

By N. Novikov, M. Jastrzebski, N. Kryzhanovskaya, D. Shevchenko, I. Kapran, N. V. Novikov, T. Koehler, B. Zaporozhets

"The PFK FeNi Smelter was re-commissioned by Solway Resources in 2002, ending a long period of economic decline in the adjacent town. In 2009 Hatch was retained to design, supply and install a custom furnace crucible that would accommodate a capacity increase from 34 MW to 40 MW and increase campaign life through binding and cooling technologies, as part of ongoing improvement efforts. The involvement of PFK personnel was critical to the successful integration of the new furnace technology with the existing process and operational practice. The furnace upgrade project was completed in 18 months during 2010 – 2011. Since start-up, the furnace has exceeded production expectations, operating successfully at 42 MW.INTRODUCTIONAfter ceasing operations in the 1990’s, the Pobuzhsky Ferronickel Combine (PFK), located in central Ukraine, was stripped of useful equipment and deteriorated while dormant. The surrounding town experienced a period of economic decline throughout the 1990’s. Solway Industries purchased the complex in 2002 and began a systematic incremental program to re-commission the smelter using both local expertise and specialists from other parts of the former Soviet Union. This led to the re-birth of PFK as a successful toll-smelting complex, and a renaissance for the surrounding economy.As part of the continuing improvement program, PFK approached Hatch in 2009 to study the possibility of a capacity expansion from 34 MW to 40 MW. It was decided, based on the results of the study, to design and install a custom furnace crucible integrating the unique PFK FeNi process with modern Hatch furnace technology. This novel approach had many benefits, including: maximum re-use of existing furnace components (off-gas, feed equipment and transformers), minimal impact on upstream and downstream equipment and building structure, and the retention of a familiar operating regime. The latter was a key factor in the success of the project, as it allowed the extensive operating expertise of the PFK staff to remain highly relevant to the upgraded furnace. This led to minimized capital investment, a rapid start-up and no significant operational challenges switching over to the new equipment incorporating Hatch furnace technology."

Jan 1, 2012

By L. Li

To accommodate the large payloads and harsh operating conditions associated with heavy vehicles in the mining industry, off-the-road (OTR) tires are typically used with heavy mining vehicles. These tires have increased abrasion and wear resistance due to their thicker tread, sidewall and bead thicknesses. Given these features, OTR tires are much stiffer than conventional passenger vehicle tires and cannot be mounted to a single-piece rim without damaging the structural integrity of the tire during the mounting process. Therefore, multi-piece wheels are used with OTR tires to facilitate mounting. While these assemblies are necessary, several instances of their failure have been reported to result in injuries or fatalities within the mining workplace. Many of these failures were specifically reported to be caused by the disengagement of the wheel lock ring - a component used to securely engage the assembly during operation. In this study, a threaded-connection locking mechanism has been proposed in place of the traditional lock ring design. The performance of this threaded-connection was numerically evaluated in a pull-out test against a conventional five-piece wheel assembly. The pull-out test was devised as a means of quantifying the engagement ability of each wheel?s locking mechanism. A high degree of modelling accuracy was maintained throughout the analysis by validating the vertical and horizontal static loaddeflection behaviour of the rim model of the five-piece wheel assembly against experimental data. Through validation, the model data were found to be within 10.5 and 4.80 %, for vertical and lateral loaddeflection behaviour, respectively. Results from the pull-out analysis found that the threaded-connection demonstrated a 113 % increase in the force required for disengagement to occur relative to the conventional five-piece design - a force of 9,550 kN in total.

Aug 1, 2013

By N. Hiroyoshi

In the leaching of chalcopyrite with sulfuric acid solutions, the copper extraction rate reaches a maximum at a given redox potential. This article reviews our studies on the determination of the optimum redox potential for chalcopyrite leaching. Shaking flask and column leaching experiments for a chalcopyrite concentrate were performed under various conditions, and the results were analyzed using a normalized redox potential defined from a reaction model assuming the formation of an intermediate CU2S from chalcopyrite. Factors, such as metal ion concentrations, solid/liquid ratio, and presence of iron-oxidizing bacteria, caused significant variations in the copper extraction versus time plots. However the copper extraction rate versus normalized redox potential plots were independent of the above factors and the copper extraction rate reached a maximum at the normalized redox potentials around 0.43. Converting the normalized redox potential to the solution redox potential gives the optimum redox potential for chalcopyrite leaching as a function of cupric and ferrous ion concentrations. This semi-empirical equation can be used to predict the optimum redox potential during leaching operation, and is useful to design the redox-controlled heap leaching for chalcopyrite.

Jan 1, 2007