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By R. W. Thompkins

"PREFACEThis paper will be published in three parts. Part 1, in this issue, will cover the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.Part 2, to appear in the October issue, will deal with radiation theory applied to uranium ores, other radon migration factors , fact ors affecting the radon gas release rate, measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade, and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and give some example calculations.1.0. Occurrence of Uranium1.0.1. Uranium is widely distributed in nature. Sedimentary rocks contain less than igneous or metamorphic rock s and as the outer 10 miles of the earth's crust is composed of 95 per cent igneous and 5 per cent sedimentary rock, it has been estimated that about 1.3 x 1014 tons of uranium exist in the earth's crust.1.0.2. It is not surprising, therefore, that radiation has existed naturally in the ear h ever since the beginning of time. It is found in such places as:(1) non-uranium mines;(2) houses not close to or connected to uranium mines;(3) ground-water tables supplying drinking water to large populations.1.0.3. All mines do not necessarily have abnormal radiation in them, but it is possible for many mines to have abnormal levels of radiation. Therefore, all underground mining operations should be tested for radiation."

Jan 1, 1982

By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.The October issue carried Part 2, which dealt with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.Part 3, in this issue, concludes the series by discussing the techniques for controlling radiation and providing some example calculations.17.0. Techniques for Controlling Radiation17.1. Altering the Factors In the Diffusion EquationIt has been noted that radon gas emanates from the surfaces of exposed ore to the mine atmosphere. The diffusion laws establish the rate of this flow. The fundamental relationship is that the rate of flow (J) is a function of the pore concentration and the distance from the surface. It is expressed as: []If any of these terms is varied, either naturally or artificially, the rate of gas emanation will be altered.Altering the Diffusion CoefficientThe literature describes many ways to lower the radon gas emanation rates which are dependent on changing the diffusion coefficient:1. A layer of ice on top of a tailings dam or on a soil.2. Humid clayey materials and swamped soils over a radon source."

Jan 1, 1982

By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.This Part 2, which follows, deals with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and provide some example calculations.10.0. Radiation Theory Applied to Uranium Ores10.0.1. The processes of diffusion transport of radon gas, through rock from the fundamental physics is a function o f the radon gas concentration in the interstitial pore spaces and the distance from the surface. Expressed by Fick's first law of diffusion, it is expressed: [ ]10.0.2. The maximum concentration is a function of the emanating power (ß), thus the above equation may be expressed: [ ]10.1. The Effect of Porosity10.1.1. If a constant emanating power is assumed (ß), a family of curves can be obtained for concentrations at varying distances and rock porosities. The curves as originally plotted assumed a constant emanating power of 5 x 10-4 pico curies/litre/sec and show the maximum expected concentrations in the pores in pico curies per litre. Because these concentrations are proportioned to the emanating power, this set of curves can be structured to show the fraction of maximum concentrations possible at various porosities of the rock.10.1.2. Notice that at 10, 20 and 30% porosities a 5-cm sample (hand-sized and drill-sized pieces) has no practical increase in pore concentration. Thus, by measuring the emanating power of hand-sized pieces of ore, the actual radon gas production into any pile of broken ore could be estimated readily."

Jan 1, 1982

By Trent Hamilton

Cameco ? McArthur River Operation is a high-grade uranium mine in northern Saskatchewan. Average grades mined are nearly 20%, more than 20 times higher than other operating uranium mines in the world. The significant risks involved with mining this grade has been effectively mitigated using innovative and unique controls, implemented from development and production mining through to ore processing. The types and sources of radiation are presented and protection measures are discussed. McArthur River?s strong radiation culture is evidenced by continually low radiation exposures while transitioning to new mining zones.

Aug 1, 2010

By S. Sillitoe

In mining, as in other business and engineering enterprises, efficient operation depends upon how well and how quickly the lines of communication can function. Mines have used the telephone on and between levels for many years, but in the hoisting shaft maintenance of physical wire connections for communication with the moving cage or skip has been found, for all practical purposes, impossible. A most natural solution was, therefore, the code-bell or buzzer signal system between fixed levels, and this has been standard practice throughout the mining world for many years. However, this system has serious limitations which make it impossible to signal a cage between levels in the shaft, and it requires crude, hazardous or costly methods for signalling during daily shaft inspection. Radio signalling overcomes these difficulties, because the communication medium is never broken and the cage-tender or shaft inspector can safely signal to, and receive signals from, the hoistman at any time from any position in the shaft, whether stationary or in motion. In addition to both audible and visual code signalling, two-way telephone communication and slack cable alarm are facilities made possible in recent commercially developed equipment.

Jan 1, 1949

By R. W. Boyle, W. Dyck

"Scientists throughout the world have observed radioactive disequilibrium in the uranium decay series. Radiometric and fluorometric determinations of U in plants from the Goldfields district and in sediments and rocks from the Beaverlodge district exhibit marked radioactive disequilibrium. The eU/U ratio in plants rooted in mineralized ground shifts from greater than unity to less than unity for those rooted in background soils. A similar shift is observed in the transition from rocks to stream sediments and to lake sediments in the Beaverlodge district.Results of a Rn-Ra-U survey of lake bottoms in the Key Lake district show that anomalous hydromorphic U from U mineralization is parallelled by anomalous Rn, even though there is much less Ra in the lake-bottom sediments than one would expect from the amount of U present. IntroductionDisequilibrium in the U decay series has been studied for many years and is observed in almost all surficial environments. Rosholt (1959) measured U, 234Pa, 23O'fh, 226Ra, 222Rn, and 210Pb in a large number of U ores and outlined six types of situations to explain disequilibrium. Davy (1974) outlines the geological significance of radioactive disequilibrium situations with respect to exploration. Levinson and Coetzee (1978) discuss possible mechanisms by which separations of parent and daughter elements are affected and suggest analytical pitfalls that may be encountered in the use of radiometric techniques when disequilibrium has occurred. Generally, it is the oxyphile and easily complexed parent 238U (with its associated isotopes 235 U and 234U) that is leached from rocks and soils at a faster rate than are the daughters, 230Th, 226Ra, 2loPb, and 206Pb. This mobilized U is adsorbed on sediments in streams and lakes, or enters groundwaters, where it is eventually precipitated under reducing conditions, occasionally in oregrade concentrations. This surface leaching and"

Jan 1, 1980

By L. M. Lowe, D. G. Feasby, J. R. Goode

"Rare earth resources usually contain minor amounts of radioactive elements. The most widely recognised sources of radioactivity are associated with thorium and uranium. However, also present in the resources are isotopes of rare earth elements (REE) that are themselves radioactive, including lanthanum (La-138), lutetium (Lu-176) and samarium (Sm-147). These radioisotopes, as well as remnants of the natural thorium (Th-232) and uranium (U-238, U-235) decay series, can contribute to significant levels of radioactivity in mixed REE concentrates and in separated products. Levels such as these can present challenges for transport, transboundary movement, product storage, workers’ health and safety, as well as waste management issues at the facilities that separate out the individual REE’s. These are discussed in this paper. A particularly challenging radioactive isotope is Ac-227 (a decay product in the U-235 decay series). Actinium behaves chemically similar to lanthanides and hence normally concentrates with REE multi-element composites. Reliable analysis of Ac-227 is not widely available and the methodology required to deal with this challenge is briefly described. A principle reason for minimization of radioactive content throughout REE processing is restrictive specifications by concentrate purchasers in order to reduce waste management challenges. Approaches to the minimization of radioisotope content in REE concentrates and separated products are outlined in this paper."

Jan 1, 2014

By Alfred C. Lane

WE recently received from Professor A. C. Lane, Emeritus Professor of Geology and Mineralogy, Tufts College, Mass., and a Corresponding Member of this Institute, a very interesting account of some recent developments in radioactive methods of determining the age of minerals and, therefore, of the rocks in which they occur. It deals in particular with studies of the minerals of certain pegmatite dykes on the Huron claims and Bear claims in southeastern Manitoba, which, the results indicate, are among the oldest rocks of the earth's crust. The following article presents a non-mathematical summary of Professor Lane's paper . . It will be noted that he is anxious to obtain suitable samples of certain minerals and rocks for further age studies. We hope some o our members may be able to supply him with the material he needs. It may be well to explain briefly how the age determinations are made. Uranium is continually breaking down, or disintegrating in successive steps through radium, etc., to a final product which is lead (uranium-lead), and the rate at which this change takes place is known. Minerals containing uranium will therefore contain lead also, and the lead-uranium ratio mul-tiplied by a certain factor (approximately 7 ,600) will give the age of the mineral in millions of years. Thorium also disintegrates at a known rate to give lead (thorium-lead) as a final product, and the age of a mineral containing thorium can thus be calculated from the lead-thorium ratio. Thorium breaks down more slowly than uranium. In unit time, one gram of thorium produces about as much lead as 0.36 grams of uranium.-ED.

Jan 1, 1938

By A. M. Gaudin

Introduction The discovery of artificial radioactivity, that is, of radioactivity of acorns other than those which are naturally radioactive, has increased vastly the possibility of using radioactivity as an analytical cool. The incomparable value of radioactive atoms, which are commonly termed tracers, arises from the extreme sensitivity of this analytical method. To get an idea of this extreme sensitivity it may be useful co recall that gravimetric analytical methods will not permit the weighing of anything much lighter than one-hundredth of a milligram of material. Under the most favourable circumstances, this represents an uncertainty in the answer of 1016 acorns, or 10,000,000,000,000,000 acorns. Accurate spectrographic methods possibly have a sensitivity 10,000 times greater than this, but the uncertainty is still of the order of 1012 atoms. The tracer permits ascertainment of decay of a single atom so that its sensitivity, without half trying, can be several orders of magnitude greater than that of any other method available co chemists. In addition co the sensitivity of tracers to which reference has just been made, tracers have another property which makes them unique. A radioactive atom is almost exactly like the corresponding non-radioactive acorn m regard to its electronic structure, and therefore in regard to its chemical properties. The nucleus is different, but the nucleus does not participate in chemical reactions. Therefore, a tracer acorn behaves like an ordinary atom until such time as its nucleus undergoes a catastrophic decay. This unique property permits one to use tracer acorns as atomic spies and therefore to follow the behaviour of acorns of a certain kind among their own kind. In other words, the tracer method permits us to study and measure what we call self-diffusion. All of the uses of tracers that have been made depend on the two properties co which reference has been made.

Jan 1, 1949

By Bruce W. Smith

Non-contacting, radioisotope density and level gauges are discussed. The characteristics of the more commonly used isotopes, the techniques of detection and the methods of presenting information are reviewed. The gauge parameters of accuracy, response time and long-term stability are tabulated with reference to calibration techniques and operating requirements. Automatic control systems, both pneumatic and electrical, are used in conjunction with density gauges on filter feeds, and in thickener underflow and heavy media processes. These systems are described. Procedures for installation, start-up and operator training are outlined, along with considerations of preventative maintenance and service requirements. Typical gauge system costs, including capital expenditure, installation, start-up and service, are presented, wherever possible, in order to provide a basis of comparison with more conventional systems.

Jan 1, 1964

By L. R. Wilkinson, W. J. Howarth, G. J. Wenk

Over a period of three years, a cooperative program in Australia has resulted in the development of radioisotope immersion probes for the on-stream analysis of mineral slurries. Two basic probe types are now available on a commercial basis - fluorescence and absorption probes - and within each type there are a number of variations so that optimum sensitivities can be obtained for elements with atomic number greater than titanium (22), thus covering most metals of interest to modern metallurgy.

Jan 1, 1973

By P. F. Berry

X-ray fluorescence analytical techniques are fairly well established in the mining and metallurgical industries. In recent years, instruments utilizing radioactive isotopes have been developed which, owing to their more compact size, greater reliability and independence of substantial power supplies, are often preferred to X-ray tube installations. Analyses can now readily be carried out in the field, on the factory floor and in otherwise difficult locations. This paper describes many examples of radioisotope X-ray fluorescence for the analysis of metallic minerals, finished metals and alloys and also for the continuous measurement of metallic coatings, such as tin and zinc, on steel. Radiation scatter techniques are also described for certain analyses and for thickness and density measurements.

Jan 1, 1967

By L. M. Lowe, D. B. Chambers, D. G. Feasby

"Potentially economic deposits of rare earth elements (REE) often contain elevated levels of naturally occurring radioactive materials (NORM), primarily thorium and uranium and their associated radioactive decay products. The concentrations of NORM usually exceed typical background levels of natural radioactivity, sometimes by factors of ten or more, and can be of concern relative to occupational radiation protection and the management and disposal of REE mineral processing and metallurgical wastes. This paper provides a summary of the radiological issues normally encountered in the REE concentrate production industry. In addition to an introduction to background radiation and radioactivity, including the thorium and uranium radioactive decay series, radiation levels expected to be encountered in REE concentrate production are outlined. The occupational, environmental and regulatory aspects of REE production related to NORM, including radiation dose limits, radioactive waste disposal guidelines, and threshold VALUES (for the application of transport regulations, are presented.INTRODUCTIONConcurrent with the increasing demand for new sources of rare earth elements (REE) to meet modern industrial needs, there is also an increasing awareness of the radioactivity associated with the REE ores and resources. This is an especially important consideration in addressing questions from the public and local communities who are often concerned about “radiation” and “radioactivity”. Public concern is heightened by reference to legacy issues that arose during times of less regulatory oversight; as well, the benefits of modern technologies, practices and regulation are overlooked. Such concerns are also often inflamed by unfounded claims by non-governmental organizations (NGO’s). Thus, it is important that all concerned have a full understanding of just what the potential risks from radiation associated with REE are, or are not. This paper provides an overview of the sources of radioactivity, the potential implications of radiation and radioactivity in the REE industry, and a brief discussion of established and reliable methods of managing exposure to radiation and radioactivity."

Jan 1, 2012

By G. A. Peebles

"This paper describes the various types of radiometric instruments and the techniques of their operation for grade control, sampling, assaying and probing drill holes at Eldorado Nuclear's uranium mine in northern Saskatchewan. Modifications that have been made to these instruments are discussed, and suggestions are made for the development of more refined and specialized radiometric equipment."

Jan 1, 1969

By M. Al-Hilal, G. Rajja, A. Al-Ali, Y. Jubeli

Abstract -A radiometric survey was carried out over clastic sediments in the immediate vicinity of some phosphatic sediments of Cretaceous age in the Wadi Qasser Al-Hallabat basin of central Syria. The objective was to explore for uranium and to define its dispersion pattern. This was based on ground radiometric surveys and geological studies. All ground surveys (using radon emanometry, track etching, gamma-ray survey and geochemistry) gave similar results, outlining the locations of the radioactive phosphatic formations in the basin, and indicating the dispersion pattern of uranium in the clastic sediments in the surrounding area. The dispersal of uranium from upper Cretaceous phosphatic formation occurs by mechanical weathering and chemical leaching by oxidizing surface waters. A rough estimate is that about one-third of the original uranium content of the Cretaceous sediments has been dispersed. Mechanical erosion is responsible for the main part of this released uranium, which now occurs in Recent sediments. However, the occurrences of spotty secondary U mineralization indicates that another small part of the available uranium must have been chemically leached out by the prevailing oxidizing waters, forming minor surficial minerals.

Jan 1, 1998

By C. Stapel, I. C. Tânczos, R. J. De Meijer

"Abstract -In recent years the Environmental Research Group of the KVI has been developing a number of radiometric techniques that may be employed in mineral sand exploration. These techniques involve: radiometric fingerprinting for assessing sand provenances and mineralogical composition; thermoluminescence for dating and provenance determination of sediments; a towed seabed detector to map seafloors for radiogenic heavy minerals and assessing heavy mineral volumes; and simplified transport mechanism models to explain and predict heavy mineral concentrations.All techniques exploit the property that heavy minerals as a group contain concentrations of naturally occurring uranium and thorium that are a hundred to a thousand times higher than in light minerals. In this paper the physics of a number of methods will be described together with a number of results. Based on these results potential applications to mineral exploration and mining are discussed."

Jan 1, 1994

By C. Stapel, AA Groningen, R. J. De Meijer

"In recent years the Environmental Research Group of the KVI has been developing a number of radiometric techniques that may be employed in mineral sand exploration. These techniques involve: radiometric fingerprinting for assessing sand provenances and mineralogical composition; thermoluminescence for dating and provenance determination of sediments; a towed seabed detector to map seafloors for radiogenic heavy minerals and assessing heavy mineral volumes; and simplified transport mechanism models to explain and predict heavy mineral concentrations.All techniques exploit the property that heavy minerals as a group contain concentrations of naturally occurring uranium and thorium that are a hundred to a thousand times higher than in light minerals. In this paper the physics of a number of methods will be described together with a number of results. Based on these results potential applications to mineral exploration and mining are discussed."

Jan 1, 1994

By G. W. Adams

Foreword While the literature on radium is voluminous, there is no single publication available from Canadian sources which attempts to cover at all fully the world radium industry. The comparatively recent developments in the Wilberforce area, and the consequent arousal of public interest in radium, seemed to call for the publication of such a paper which would be intelligible to the layman. To satisfy this apparent need, the writers submit this paper which contains material derived from various sources, and for which the writers make no claim of originality. Direct references are made throughout the paper to sources of information.

Jan 1, 1931

By J. Schick, V. Granger

Nowadays, all French former uranium mining sites are remediated and redeveloped. If needed, mining waters containing radium have to be treated before discharged into the environment. Classical radium treatment consists in a (Ba,Ra)SO4 salt precipitation and radium monitoring was carried out using a time-consuming analysis called emanometry. Three zeolite samples have been tested to remove 226Ra from mining water. In batch experiment, radium was totally (R=100%) and quickly removed after 2 minutes contact time. Continuous sorption experiments were carried out through a vertical column at lab scale. Chabazite is the most efficient zeolite with an 226Ra activity below 0.2 Bq/L until 60000 Bed Volume. Chabazite is always efficient although radium content in material reaches 150 Bq/g. 226Ra uptake was also tested at semi-industrial scale on a pilot plant. More than 3000 m3 were successfully treated with a radium content below 0.1 Bq/L. The environmental impact assessment of Ra-chabazite was characterized by using batch leaching tests made according to the NF EN 12457-2 standard as applied on all wastes. Ra-chabazite stability is excellent during this test: radium leaching is very low, less than 0.005%. A new 226Ra measurement method was developed by ICP-MS for a better analysis reactivity. This new method was carried out in a couple of minutes with a lower sample volume than emanometry. The validation was performed according to the French NF T90-210 standard for the calibration function definition, the limit of quantification, the accuracy and the interferences.

Jan 1, 2020

By L. A. Mells

"A laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the applicability of a radium selective ion exchange complexer for removing radium from Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. under contract to the Department of Supply and Services using the Saskatchewan Research Council facilities located in Saskatoon, Saskatchewan.The results of this work showed the ion exchange complexer, Dowex XFS 43230.00, to be efficient in removing radium from contaminated water of uranium mining operations with the ultimate loading capacity of the resin on one type of water treated being determined as approximately 1,600 Bq/cm3 of new resin. Although this resin has potential application for treatment of effluent streams in uranium operations it has been identified that the resin efficiency and capacity is directly related to the chemistry of the water being treated and site-specific testwork is required in order to establish reliable design data for full-scale operations.IntroductionThe possible applicability of a radium-selective ion exchange complexer for removing radium from Canadian uranium mining effluents had been identified and discussed as a possible alternative to present radium removal methods during a review of disposal technology options for the National Uranium Tailings Program of the Department of Energy, Mines and Resources(1). Work by other workers(2.3) had shown the complexer to be very efficient in removing radium from contaminated water. Also, plant trials on contaminated minewater at the Mt. Taylor uranium mine in New Mexico is reported to have shown the resin complexer to be efficient under plant operating conditions.As a result, a laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the suitability of this resin for Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. (MCEL) under contract to the Department of Supply and Services using the Saskatchewan Research Council (SRC) facilities located in Saskatoon, Saskatchewan."

Jan 1, 1985