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By E. G. Valdez

Three cryogenic systems that utilized liquid nitrogen, dry ice, and methanol with dry ice were investigated in conjunction with crushing and classifying techniques. The systems were used to aid in separating and reclaiming the metallic components contained in insulated wires, shredded automobile nonferrous metal concentrates, small motors, generators, and rubber tires. Wire strands, 2 to 6 inches long and insulated with polyvinyl chloride and neoprene, were chilled at -60° and -195° C, then roll-crushed and processed by water elutriation; this procedure resulted in two products--a sink fraction that was 99 percent metallic and a float fraction that was 99 percent nonmetallic. Excellent separation of zinc die-casting alloys from copper and aluminum contained in shredded automobile nonferrous metal concentrates was attained by chilling at -72° C for 1 minute, crushing in a grateless hammer mill, and screening. From the screened products, 97.2 and 100 percent of the copper and aluminum, respectively, were recovered in the plus Pinch fraction, and 100 percent of the zinc was recovered in the minus 1-inch fraction of over 97 percent zinc die-cast purity. Laboratory experimental results comparing direct and indirect chilling indicated that a sufficiently low temperature could be attained by indirect chilling to permit use of a liquid C02-dry ice system on insulated wires and mixed nonferrous metallic concentrates.

Jan 1, 1973

Research workers from the Bureau of Mines and industry met with other government and industry representatives at the Mont Chateau Lodge, Morgantown, W. Va., on May 30-31, 1973, to discuss the current status of methane control in eastern U.S. coal mines. The opening remarks, the eight technical presentations, and the discussions of the members of a government-industry panel are published here for the benefit of those concerned with the control of methane in coal mines. In addition, an introduction has been added to present the background of work in this field.

Jan 1, 1973

A general analytical solution of the effect of an inclined contact separating two media of differing electrical properties on a normally incident plane electromagnetic field has been given (Geyer, 1972). These solutions for the electromagnetic response at any observation point P(r, [u]) are given in the form of inverse Lebedev-Kontorovich transforms. Two modes of excitation are considered: (1) case where current density flows across strike of the contact separating the media of differing electrical properties (only Er , E [u] , and Hx differ from zero) and (2) case where current density flows along-strike (only Hr , H [u] , and Ex differ from zero). The electromagnetic fields in the frequency range of interest and for the rock conductivities under consideration are quasi-static in nature so that to a first-order approximation the horizontal magnetic field at the surface of the earth is constant and continuous across the discrete discontinuity in resistivity for case (1) above, and so that the tangential derivative of the horizontal electric field at the surface of the earth is constant and continuous across the discrete discontinuity for case (2) above. Of course, it is well known that where large horizontal gradients in conductivity exist, there also exists large anomalous components of the vertical magnetic field (Weaver, 1963). The recognition of such anomalous components and their magnitudes due to the presence of lateral resistivity changes in the overburden becomes very important in any wavetilt type measurement which may be used to locate a miner. When the lateral change in resistivity becomes quite large, the integral solutions (expressed as Lebedev-Kontorovich transforms) simplify considerably and allow ready numerical evaluation. Examples of the amplitude and phase responses of the radial electric, horizontal electric, and vertical magnetic field in the vicinity of the contrast in resistivity are shown in Figures 2, 3, and 4. Of particular significance is the fact that the anomalous vertical magnetic field is three orders of magnitude larger near the contact than far from the contact. This fact implies that where large resistivity contrasts do occur in the rocks overlying mine workings, that significant errors may be present in wavetilt measurements as used above for location criteria! Another observation insofar as the anomalous vertical magnetic field is concerned is the linear variation of phase as one proceeds away from strike in induction number (increased distance or frequency). For a pulse-excited communications system this phenomena would have a bearing on where the zero crossings would occur (i.e., 'pulse breadth') in the transient coupling between any given source-receiver configuration and at any given receiver site.

Jan 1, 1973

By Rees D. Groves

The Bureau of Mines conducted research on reactions of copper sulfide minerals with chlorine in an aqueous system. Selected samples of covellite, chalcopyrite, chalcocite, bornite, and pyrite were leached with aqueous chlorine solutions. The mineral samples were sized on to minus 100- plus 325-mesh, individually mixed with precleaned sand and leached in an enclosed percolation column. Each mineral was leached in stages to achieve about 90 percent mineral dissolution. The chlorine leaching solutions were produced by reacting sodium hypochlorite with hydrochloric acid within the closed system. The study showed that when the mineral dissolution was complete, the reaction products (copper, iron, and sulfur) were in their highest oxidation states and a stoichiometric amount of chlorine was consumed. Although elemental sulfur formed as an intermediate product, it was oxidized to sulfate during the leach.

Jan 1, 1973

By David E. Siskind

The Bureau of Mines recorded particle accelerations in the mine roof produced by three types of explosives in the Pilot Knob Pellet Co. mine, Pilot Knob, Mo. Examined were the effectiveness of cube root, square root, and two-thirds power scaling in grouping the underground blast vibration data, and the effects of mine geometry, rock type, explosive type, and charge size on blast vibration levels. A propagation law for this mine was determined. The scaling factor of the square root of the charge weight was developed from previous Bureau studies of vibrations from quarry blasts, and in under-ground blasting both square root and cube root scaling were found applicable for scaling particle vibration data. The vibrations from the Pilot Knob blasts were best grouped by a square-root scaling factor. The empirical propagation equation AW1/2 = 76,250 (R/W1/2)-2.61 where A is the peak acceleration in g's, W is the charge weight in pounds, and R is the distance from the blast in feet, may be used to describe vibration amplitudes from charges fired with zero delay caps or with a single cap at Pilot Knob. Statistically significant differences were found in the vibration levels generated by the different explosives. The Power Primer (75-percent weight-strength ammonia gelatin dynamite) produced levels of vibration of 1.7 to 2.4 times those of AN-FO and slurry explosives; the latter two are approximately equal.

Jan 1, 1973

By D. C. Fleck

Electrorefining yttrium from selected low-melting yttrium--base alloys is investigated, and various halide systems are studied as potential electrolytes for use in preparing low-oxygen yttrium by electrorefining unalloyed yttrium. Yttrium cathode products having significantly less metallic impurities than the anode materials were prepared from alloys containing nickel, iron, and manganese by electrorefining in LiCl-YC13 electrolytes at 900° to 1,000° C. Yttrium-copper and yttrium-magnesium alloys are not suitable as anode feed materials, An evaluation of chloride, fluoride, bromide, and mixed chloride-fluoride electrolytes showed that cathode products containing much less oxygen than the anode material can be obtained in the fluoride and mixed chloride-fluoride systems. Initial cathode current density has no apparent effect on the purity of the products obtained in both phases of the investigation.

Jan 1, 1973

By C. Lurie

This final report describes the work performed by Gulton Battery Corporation under USBM Contract No. HO-112033, entitled "Research and Development on Lithium-Nickel Fluoride Batteries For Mint Life Support Equipment". The lithium-nickel fluoride couple was chosen For this investigation because of its high theoretical energy density (626 Wh/lb), its ability to operate at ambient temperatures and the fact that it showed promise as a secondary system. The theoretical energy density of the lithium-nickel fluoride couple is ten times greater than that of the widely used lead-acid battery and three times greater than the silver-zinc battery which has the highest theoretical energy density of the commercially available secondary systems. The experimental program first evaluated the cell components individually. The results of these studies then formed the basis for investigations of cell performance using experimental three-plate cells. These cells consisted of one nickel-fluoride and two lithium electrodes. All work was performed in a glove box under an argon atmosphere which was sufficiently pure to maintain the shiny appearance on freshly prepared lithium surfaces. The major portion of the work effort was concerned with the nickel fluoride electrode. Binder, conductive diluent, fabrication technique, as well as the nickel fluoride active material itself, were considered. Criteria for binder materials were established and six classes of materials encompassing thirteen binders were evaluated. The candidate materials were initially screened for appropriate chemical and physical properties and finally evaluated in three.-plate cells, Two epoxy powders emerged as the most promising binders. Two types of conductive diluent were evaluated. The first is a carbon black of low bulk density and high surface area. This material is a good conductive diluent; however, electrodes fabricated with it lacked good mechanical strength. It was hypothesized that a uni¬form, small particle size, low specific surface area would improve the mechanical properties of the electrodes. Therefore, two samples of graphicic materials, milled to uniform powders in the one-to-ten micron range were evaluated. Electrodes prepared with the graphitic materials had superior mechanical properties, However, their electrical performance was significantly poorer and voltage losses of 0.2 to 0.3 volts were observed. Several electrolyte solutions were evaluated. N-Methyl-2-Pyrrolidone was tested but found to be incompatible in the presence of lithium. Lithium perchlorate, lithium hexafluoroarsenate, and lithium bromide were tested as two-component electrolytes in propylene carbonate solvent and their performance compared with that of the single electrolyte solutions, Lithium perchlorate gave the best performance. Lithium hexafluoroarsenate was also evaluated in methyl formate and appears to give equivalent performance. The lithium perchlorate-propylene carbonate system is preferred as it is easier to handle and less expensive.

Jan 1, 1973

By J. R. McVey

A 10-channel automatic data acquisition system has been designed and environmentally packaged for use with underground strain-gage applications and associated instruments. The system uses commercially available components and is assembled in two plastic enclosures. Environmental control is provided through a specially designed (compressed-air) air-conditioning system and water-resistant cabling. Accuracies of 0.01 pct and resolution of 1 µV have been obtained in underground tests.

Jan 1, 1973

By C. Froger

Since its creation in 1950, the Centre d'Etudes et Recherches des Charbonnages de France at Verneuil-en-Halatte (Oise) has been conducting many investigations concerned with airborne dust measurements, particularly in underground mines. The work has resulted in the development, a few years ago, of a new process of dust sampling, whereby the airborne dust particles are collected by a rotary filter of polyurethane foam rotating at high speed within 8 housing.

Jan 1, 1973

By P. H. Mutschler

The Bureau of Mines studied the costs of transporting fossil fuels, coal, and residual fuel oil from areas of production to consumer regions. Transportation data were stratified by type of carrier, size of shipment, and distance to determine what general effects these variables have upon transportation costs. Economics of haul for coal exist for longer versus shorter distances, and for larger versus smaller trainload sizes. Tanker and barge transportation of residual fuel oil does not show economies of haul for longer distances. It is shown that tanker size and seasonal variation are primary factors influencing the cost of shipping. Railroad transportation data show that coal from western coalfields could be competitive with foreign residual fuel oil in selected midwestern fossil fuel markets. However, the western coal would not be competitive in the New England and the eastern seaboard energy markets.

Jan 1, 1973

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

5. Development of Initial Probing System 5. 1 Introduction The preliminary evaluation of a variety of potential methods for initial probing showed that the optical system using closed circuit television (CCTV) and the sonar, or acoustic ranging, system were the most promising. The former is capable of pro¬viding a visual display of the mine passages in a clear, non-smoky environment, and the latter is capable of providing a map of the spatial location of the coal surfaces making up the entries, as well as objects, such as cribs, mining machines, etc., in the passages in both smoky and non-smoky environments. The sonar system used in conjunction with the CCTV in a clear environment can greatly assist in resolving the spatial distribution of objects seen on the TV screen. Further, in a smoky environment the interpretation of the sonar information could be facilitated if some visual information were also available. CCTV systems exist but require some modifications to suit this particular application. The Industrial Hazards and Communications Division of the Bureau has an ongoing program for the development of such a CCTV system. Rather than duplicate this effort in developing a CCTV system, it was decided to evaluate the possibility of utilizing their system for initial probing, while continuing with the develop¬ment of a system which would work in any environment, including the presence of dense smoke. The concept of using sonar for the initial probing of mine passages represents the application of new technology requiring development. The results of such a development effort undertaken during the course of this program are described in the following sections.

Jan 1, 1973

By Kenneth J. Miner

Pittsburgh bed and Lower Freeport bed coals were tested in the U.S. Bureau of Mines two-stage froth flotation pilot plant, which utilizes a new flotation process to remove pyritic sulfur. The process consists of a first-stage coal flotation step to remove coarse, free pyrite and other refuse in the tailings. The clean coal froth concentrate is then repulped and treated with a coal depressant, a pyrite collector, and a frother to selectively float the remaining pyrite in a second stage. Results in the pilot plant were excellent, comparing well with those obtained in laboratory batch tests. That is, about 70 percent of the pyrite present in the Pittsburgh bed coal and about 90 percent of the pyrite present in the Lower Freeport bed coal were removed with excellent final clean coal recoveries.

Jan 1, 1973

By John F. Elliott

Because of the importance of the steel industry in the economy, a program of study was undertaken to develop a computer model by which it would be possible to predict the need of the industry for raw materials and energy in the next several decades. This report gives the results obtained it a preliminary 6-month program.

Jan 1, 1973

By R. P. Maloney

The economic viability of four depleted mines near Kennicott, Alaska, was determined by the Bureau of Mines to assess their profitability if they were developed today and thus estimate cost data for a medium-sized mine, mill, and town complex. This information should help the State and Federal Governments appraise the potential development of similar-sized mining operations in Alaska. Modern conventional mining and milling techniques were assumed, and I capital and operating costs were derived using flowsheets and standard costing methods. A total capital investment of $37.6 million was necessary to install a 1,000-ton-per-day shrinkage stope mine, flotation-type mill, and support facilities; capital requirements were divided about evenly among the three components. Operating costs, including labor, supplies, power, water, and ' indirect and fixed costs, totaled $42.79 per ton of ore; the mining accounted for nearly one-half the cost. To obtain a 12-percent discounted cash flow rate of return on investment, the analysis showed that the ore could be mined and milled, and the concentrate could be trucked via public roads to a dock facility in Valdez, Alaska, barged to Tacoma, Wash., and smelted and refined for 34.7 cents per pound for copper and 104.0 cents per ounce for silver. The average May 1972 price was 52.6 cents for copper and 158.3 cents for silver. The same set of data was used to examine the economic viability of the mine with the cost of constructing a private road from McCarthy, Alaska, To Valdez, Alaska. The 148-mile road added $53.3 million to the original capital costs and raised the required price of copper to 57.4 cents per pound and the required price of silver to 172.0 cents per ounce. The additional coat of building, maintaining, and paying taxes on a private road from McCarthy, Alaska, to Valdez, Alaska, would make this venture uneconomical.

Jan 1, 1973

By J. W. Walkiewicz

Studies were conducted by the Bureau of Mines to develop a method for fabricating Sm-Co permanent magnets. This method consisted of arc-melting, crushing and grinding the alloy, alining and pressing the powder, and sintering the green compacts. Results indicated that the optimum composition was 36.7±0.3 weight-percent Sm and 63.3±0.3 weight-percent Co. This composition was obtained by blending together Sm2C07 and SmCo5. The maximum values exper¬imentally obtained were MHC = 27.4 kOe, BHc = 7,510 Oe, Br = 7,810 G, and (BH)max = 15.1 MGOe. The optimum sintering temperatures and grinding times for maximum MHc and (BH)max were determined. Lowering the grinding temperature from 0° C to -60° C resulted in a significant increase of magnetic properties.

Jan 1, 1973

By David L. Moffatt

Considerable current interest is evident[l,2] in the use of transient electromagnetic methods for subsurface remote sensing. A transient method is discussed which uses a periodic video-type pulse containing a wide frequency range. A video pulse is used as an interrogating signal both for "target" identification and detection for relatively short depth (c 20 meters) applications in soil and soft rock media. If the medium is favorable, e.g., hard rock, greater depth applications appear to be feasible. The same procedures would be applicable for deep geological exploration but would require a substantial reduction in frequency and increase in target size. It should be noted that video pulse generators with 35 kv peak voltage and nanoseconds base widths are now within the state-of-the-art, thus significant power over broad spectral ranges is possible. In the design of a video pulse sounding system, 5 main problem areas can be identified; 1 ) selection of the pulse shape or spectral content of the video pulse, 2) design of a radiating structure which effectively couples such a pulse into the medium, 3) isolation of the radiating and receiving mechanisms, 4) realistically accounting for the dispersion and attentuation of the medium and the air-medium interface, and 5) interpretation or processing of the received signal waveform. Each of these problem areas will be discussed and illustrated with experimental and/or theoretical results. The Video Pulse Selection of the proper video pulse signal is dictated by 3 considerations, the maximum desired depth of penetration, the attenuation of the medium and the required resolution and size of the target. For a lossy medium, penetration and resolution are clearly at cross purposes and a compromise is necessary. The exact nature of the compromise is dictated by the application, but the spectrum of the video pulse should not contain any frequencies higher than the predicted cut-off, i.e., that frequency which is attenuated to the threshold level of the receiver. As a practical matter, it may be necessary to select 1 or 2 video pulses reasonably suited

Jan 1, 1973

By Roger G. Long

In May 1973, the Bureau of Mines asked Arthur D. Little, Inc. (A DL) to investigate existing industrial communication standards that may be applicable to the problem of developing standards for mine communication, considering that the standards that may ultimately be developed will require simple field procedures for the industry and the inspectorate to determine that communication systems are properly functioning. The emphasis on this study is on telephone communications as related to coal mine applications. B. TASKS The tasks agreed upon for this program were as follows: 1. "Investigate the current practices and existing standards of other industries under government regulation. 2. Determine applicable methods for industry personnel and inspectors to ascertain conformance on-site with minimal test hardware. 3. Review the Bureau's approval, testing and inspection procedure as it may impact the development of such standards. 4. From the above studies investigate the development of installation and performance standards for mine communications, including voice and telemetry. 5. Prepare a written report specifying what standards and field inspection techniques are applicable with recommendations for development of subsequent data and ultimately standards and field inspection techniques. 6. Prepare a written summary of the findings of various investigations with an appendix covering the detailed findings of each investigation. 7. Prepare a list of suggestions of additional assistance the Bureau might require in subsequent phases of developing communication standards and means of ascertaining performance."

Jan 1, 1973

By F. W. Penn

An aircraft auxiliary power unit (APU) was used as an exhaust source for evaluation and refinement of sampling and analytical procedures for gas turbine engines. The unit was also used to determine the emission characteristics of APU's in service and to study the effect of fuel composition and combustor design on exhaust emissions. Carbon monoxide, carbon dioxide, oxides of nitrogen, hydrocarbons, aldehydes, particulate loading, and odor were measured at engine operating modes representing the duty cycle encountered in airline operation. Analyses showed good repeatability, and adequate sensitivity was attained in these experiments. Smoke opacity measurements were not taken owing to the lack of a high-sensitivity smokemeter. Results showed that the minimum emission levels occurred with the standard combustor and Jet A fuel. Emission rates were highly dependent on test mode, but emission patterns as a function of test mode were similar for all fuels and combustors tested. A comparison of three identical design production combustors showed a variation in average emission rates of less than 5 pct.

Jan 1, 1973

By A. J. Farstad

Electromagnetic location tests were conducted by Westinghouse Georesearch Laboratory under the sponsorship of the U. S. Bureau of Mines at the Galena Mine in Northwest Idaho. The objectives of these tests were to evaluate the performance in deep hardrock mines of an electromagnetic location system previously developed for the U. S. Bureau of Mines for use in coal mines. Tests were performed using long wire transmitting antennas as well as horizontal and vertical transmitting loops at depths from 3000 feet to 4300 feet (995 metres to 1311 metres). Surface measurements were made of magnetic field strengths, field strength patterns, and background noise, These measurements were compared with theoretical predictions for a homogeneous ground conductivity consistent with this particular geologic region. The results of the Galena Mine tests show conclusively that light-weight portable electromagnetic transmitters can be effectively utilized to provide uplink communications and location information in deep hardrock mines. Typical metal mines such as Galena utilize deep vertical shafts for mine access and haulage and these shafts produce signal enhancement at the surface from underground electromagnetic transmitters by as much as 30 dB. The results also show that horizontal wire configuration can serve as an effective alternative to the magnetic dipole antenna as a rescue transmitting antennaa and can be used when the required area is not available for deployment of a loop antenna. In spite of the electromagnetic coupling effects observed in the vicinity of the shafts, the location accuracy obtained still provided useful information on the general location of the transmitting sources involved. The horizontal wire location accuracy was within 46 metres, while the vertical magnetic dipole and the horizontal magnetic dipole accuracies were within 152 metres and 110 metres respectively at a 915 metre depth.

Jan 1, 1973

Water pollution has been an integral part of most mining operations in the past. Most mine planners had designed their mining operations with little or no regard for prevention of water pollution. The main planning element was always the economics of mineral recovery. Quite often the cheapest means of mineral recovery resulted in the largest water pollution problems. Recent water pollution laws have introduced a new economic element - water pollution control costs - to be considered in mine planning. Water pollution control costs can be extremely high. Foresighted planning can minimize these costs and provide better water pollution control. Effective pollution control preplanning can eliminate pollution from active mines and minimize pollution that may occur after completion of mining. Presently available technology can practically eliminate water pollution by treatment of the mine water. Use of water treatment during mining has no effect on the levels of water pollution after treatment ceases and the mine is abandoned. Therefore, this section of the report deals with preplanning to reduce water pollution, both present and future, by using at-source control techniques. Proper planning of mining and pollution control techniques should follow the concept of a complete, comprehensive reclamation plan. This plan should have control measures designed for all phases of mining from initiation through completion. Preplanning involves acquiring complete information concerning the future mine site, defining the reasons why mining could cause pollution from the site, and determination of available techniques to prevent or minimize formation or transportation of pollutants. Location of haulage and access roads and other mine related facilities should be included in preplanning for water pollution control. Mine site planning is the primary step in establishing any new mining area and is the key to a successful, non-polluting and economical

Jan 1, 1973